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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,801 records · Page 100

Polarization Stability of Amorphous Piezoelectric Polyimides

Amorphous polyimides containing polar functional groups have been synthesized and investigated for potential use as high temperature piezoelectric sensors. The thermal stability of the piezoelectric effect of one polyimide was evaluated as a function of various curing and poling conditions under dynamic and static thermal stimuli. First, the polymer samples were thermally cycled under strain by systematically increasing the maximum temperature from 50 C to 200 C while the piezoelectric strain coefficient was being measured. Second, the samples were isothermally aged at an elevated temperature in air, and the isothermal decay of the remanent polarization was measured at room temperature as a function of time. Both conventional and corona poling methods were evaluated. This material exhibited good thermal stability of the piezoelectric properties up to 100 C.

Park, C.↗

Control Parameter Sensitivity Study for Inverter-Based-Resource Dominated Grids: A Small Signal Stability Approach and Framework

The growing adoption of renewable energy is driving the prevalence of inverter-based resources (IBRs) within power grids. Future power grids will integrate both grid-following IBRs (GFM-IBRs) and grid-forming IBRs (GFL-IBRs) alongside synchronous generators. Therefore, it is crucial to perform stability studies that account for all components and especially control interactions related to IBRs. Extensive research has performed to study the IBR-related stability, however, the sensitivity study of IBRs' control parameters on system stability has not been adequately studied yet, especially from a systematic way. Therefore, this paper conducts a small signal stability analysis for a generic grid with multiple types of resources and develops an analytical framework for assessing the sensitivity of control parameters affecting stability margins. To achieve that, the non-autonomous reduced-order non-linear dynamic model is developed for a generic power system with multiple synchronous generator-based resources (SGBRs), GFM-IBRs, and GFL-IBRs. Based on the analytic model, a systematic framework for parametric sensitivity on systems' asymptotic stability is developed. A parameter sensitivity analysis based on eigenvalue methods is proposed. The impact of the droop controllers of GFM-IBRs, PQ-dispatch and the PLL controller of GFL-IBR on the system asymptotic stability is discussed. This sensitivity study is aiming to provide deep insights on control parameters' impact on system stability, and gives direction for parameter tuning in case of instability.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Calculation of stability derivatives for slowly oscillating bodies of revolution at Mach 1.0

A parabolic method for steady transonic flow is extended to bodies of revolution oscillating in a sonic flow field. A Laplace transform technique is employed to derive the dipole solution, and the Adams-Sears iterative technique is used in the stability derivative calculation. A computer program is developed to perform the stability derivative calculation for the slowly oscillating cone and parabolic ogive. Inputs for the program are body geometry thickness ratio, acceleration constant, and pitch axis location. Sample calculations were performed for the parabolic ogive and circular cone and results are compared with those obtained by using other techniques and the available experimental data for circular cones.

Ruo, S. Y.↗

An MHD variational principle that admits reconnection

The variational approach of Pfirsch and Sudan's averaged magnetohydrodynamics (MHD) to the stability of a line-tied current layer is summarized. The effect of line-tying on current sheets that might arise in line-tied magnetic flux tubes by estimating the growth rates of a resistive instability using a variational method. The results show that this method provides a potentially new technique to gauge the stability of nearly ideal magnetohydrodynamic systems. The primary implication for the stability of solar coronal structures is that tearing modes are probably constant at work removing magnetic shear from the solar corona.

Rilee, M. L.↗

Frequency Stability Enhancement in a Fully Solar Power Grid: A Case Study on the Saudi Model

Recently, renewable energy sources (RES) such as solar photovoltaic (PV) have been recognized for their significant potential. Several studies have explored the issue of frequency stability with high RES penetration. A significant observation related to this issue is the decline in the weighted short circuit ratio (WSCR), which has the potential to adversely affect system stability. This research uniquely focuses on the gradual transition of the Saudi Electricity Company (SEC) system to a fully integrated solar PV grid, offering insight and methodology that can be adapted for other power systems. While a variety of mitigation methods are available, synchronous condensers (SC) were used in this study to stabilize grid frequency, and their implementation has been shown to improve the overall performance of the system. In response to the observed decline in WSCR, a comprehensive short circuit analysis was applied across all regions in the Saudi power grid model to evaluate the reduction in short circuit power and highlight areas requiring enhancement. Finally, scenarios illustrating frequency response with a gradual increase in SCR were analyzed, with the objective of establishing a stable, fully solar PV power system that is resilient to sudden power grid disturbances.

14 SOLAR ENERGY↗

STABILITY PROBLEMS IN MISSILE STRUCTURES

A number of specific buckling problems relating to missile propellant tanks and transition sections are enumerated. In some cases approximate techniques used by missile designers to determine stability are mentioned. The inadequacies of these approximate methods and the unavailability of appropriate usable information is stressed. Furthermore, the mathematical complexities of nonlinear buckling problems are considered. Some possibly fruitful areas of mathematics to simplify these complexities are discussed with the hope that research in these areas will provide a batter means through which the analyst may supply the designer with more realistic and accurate theoretical data.

MISSILE↗

New adaptive optics control strategy for petawatt-class laser chains

A new generation of ultra-high intensity femtosecond petawatt- and above-class lasers requires new approaches to wavefront corrections. New challenges for adaptive optics consist in overcoming the constraints of potentially bigger diameters, larger amplitude aberrations, faster optics, higher risk of damaging optical components and faster and easier maintenance. Here we present a new technology of a mechanical deformable mirror, which has a large stroke, high temporal stability, low hysteresis, no print-through effect, easy, safe and fast maintenance and an operating frequency up to 10 Hz. We propose the full correction of the final focal spot in the target chamber by a combination of a standard adaptive optics system, a simple focal plane camera and a phase retrieval correction process. We test the reliability of the correction system in terms of intensity variation and wavefront stability. We further verify correction robustness of the method on a large spectral bandwidth and finally perform a focal spot correction on a terawatt laser system in both low and high-power regimes. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of control surface mass unbalance on the stability of a closed-loop active control system

An inertial energy approach similar to the aerodynamic energy method for flutter suppression is used to investigate the effects of mass-unbalanced control surfaces on the stability of a closed-loop system. It is demonstrated that a spanwise section for sensor location can be obtained which ensures minimum sensitivity to the mode shapes of the aircraft. Leading-edge control is characterized by a compatibility between inertial stabilization and aerodynamic stabilization that trailing-edge control lacks.

Nissim, E.↗

New Approach for Temporal Stability Evaluation of Pseudo-Invariant Calibration Sites (PICS)

Pseudo-Invariant Calibration Sites (PICS) are one of the most popular methods for in-flight vicarious radiometric calibration of Earth remote sensing satellites. The fundamental question of PICS temporal stability has not been adequately addressed. However, the main purpose of this work is to evaluate the temporal stability of a few PICS using a new approach. The analysis was performed over six PICS (Libya 1, Libya 4, Niger 1, Niger 2, Egypt 1 and Sudan 1). The concept of a “Virtual Constellation” was developed to provide greater temporal coverage and also to overcome the dependence limitation of any specific characteristic derived from one particular sensor. TOA reflectance data from four sensors consistently demonstrating “stable” calibration to within 5%—the Landsat 7 ETM+ (Enhanced Thematic Mapper Plus), Landsat 8 OLI (Operational Land Imager), Terra MODIS (Moderate Resolution Imaging Spectroradiometer) and Sentinel-2A MSI (Multispectral Instrument)–were merged into a seamless dataset. Instead of using the traditional method of trend analysis (Student’s T test), a nonparametric Seasonal Mann-Kendall test was used for determining the PICS stability. The analysis results indicate that Libya 4 and Egypt 1 do not exhibit any monotonic trend in six reflective solar bands common to all of the studied sensors, indicating temporal stability. A decreasing monotonic trend was statistically detected in all bands, except SWIR 2, for Sudan 1 and the Green and Red bands for Niger 1. An increasing trend was detected in the Blue band for Niger 2 and the NIR band for Libya 1. These results do not suggest abandoning PICS as a viable calibration source. Rather, they indicate that PICS temporal stability cannot be assumed and should be regularly monitored as part of the sensor calibration process.

Tuli, Fatima Tuz Zafrin↗

Thermal Stability Results of a Fischer-Tropsch Fuel With Various Blends of Aromatic Solution

Fischer-Tropsch (F-T) jet fuel composition differs from petroleum-based, conventional commercial jet fuel because of differences in feedstock and production methodology. F-T fuel typically has a lower aromatic and sulfur content and consists primarily of iso and normal paraffins. The ASTM D3241 specification for Jet Fuel Thermal Oxidation Test (JFTOT) break point testing method was used to test the breakpoint of a baseline commercial grade F-T jet fuel, and various blends of this F-T fuel with an aromatic solution. The goal of this research is to determine the effect of aromatic content on the thermal stability of F-T fuel. The testing completed in this report was supported by the NASA Fundamental Aeronautics Subsonic Fixed Wing Project. Two different aromatic content fuels from Rentech, as well as these fuels with added aromatic blend were analyzed for thermal stability using the JFTOT method. Preliminary results indicate a reduction in thermal stability occurs upon increasing the aromatic content to 10% by adding an aromatic blend to the neat fuel. These results do not specify a failure based on pressure drop, but only on tube color. It is unclear whether tube color correlates to more deposition on the tube surface or not. Further research is necessary in order to determine if these failures are true failures based on tube color. Research using ellipsometry to determine tube deposit thickness rather than color will be continued in follow-up of this study.

Lindsey, Jennifer↗

A Vitrimer Acts as a Compatibilizer for Polyethylene and Polypropylene Blends

Abstract Polymer compatibilization plays a critical role in achieving polymer blends with favorable mechanical properties and enabling efficient recycling of mixed plastic wastes. Nonetheless, traditional compatibilization methods often require tailored designs based on the specific chemical compositions of the blends. In this study, we propose a new approach for compatibilizing polymer blends using a dynamically crosslinked polymer network, known as vitrimers. By adding a relatively small amount (1–5 w/w%) of a vitrimer made of siloxane‐crosslinked high‐density polyethylene (HDPE), we successfully compatibilized unmodified HDPE and isotactic polypropylene (iPP). The vitrimer‐compatibilized blend exhibited enhanced elongation at break (120 %) and smaller iPP domain sizes (0.4 μm) compared to the control blend (22 % elongation at break, 0.9 μm iPP droplet size). Moreover, the vitrimer‐compatibilized blend showed significantly improved microphase stability during annealing at 180 °C. This straightforward method shows promise for applications across various polymer blend systems.

Yokoyama, Kosuke↗

A Vitrimer Acts as a Compatibilizer for Polyethylene and Polypropylene Blends

Polymer compatibilization plays a critical role in achieving polymer blends with favorable mechanical properties and enabling efficient recycling of mixed plastic wastes. Nonetheless, traditional compatibilization methods often require tailored designs based on the specific chemical compositions of the blends. In this study, we propose a new approach for compatibilizing polymer blends using a dynamically crosslinked polymer network, known as vitrimers. By adding a relatively small amount (1–5 w/w%) of a vitrimer made of siloxane‐crosslinked high‐density polyethylene (HDPE), we successfully compatibilized unmodified HDPE and isotactic polypropylene (iPP). The vitrimer‐compatibilized blend exhibited enhanced elongation at break (120 %) and smaller iPP domain sizes (0.4 μm) compared to the control blend (22 % elongation at break, 0.9 μm iPP droplet size). Moreover, the vitrimer‐compatibilized blend showed significantly improved microphase stability during annealing at 180 °C. This straightforward method shows promise for applications across various polymer blend systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Study on the heat removal for fuel debris using heat pipes

Simple method to retrieve fuel debris by meta-stabilizing: Heat removal system is needed. Heat removal using heat pipes: Cover fuel debris with geopolymer. What is a heat pipe: Heat transport medium with cycles of evaporation and condensation. It consists of the container, working fluid, and the wick. Advantage: Internal vacuum structure, small amount of working fluid, Massive heat transfer due to high-speed movement of hydraulic fluid. Cycle of hydraulic fluid with capillary structure. Because the cycle works independently of gravity, we can set heat pipes at free angle. We evaluated the availability of heat pipes within PCV. Investigation of hydrogen and oxygen concentration of internal gas collected by water replacement method: Non-condensable gas was confirmed inside the heat pipe irradiated by gamma rays. The heat removal effect by the heat pipe greatly descends to the extent close to the copper pipe by Gamma ray irradiation. The above reason was presumed to be that non-condensable gas was generated by radiolysis and the active length of the condensation part of the heat pipe decreased. Counter measures to decrease the amount of non-condensable gas is necessary for using heat pipes under radiation environment. We are doing the experiments to check changes in non-condensable gas generation by using catalysts or other kinds of liquids under Gamma ray irradiation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Final Project Report for DOE/EERE High-Capacity and Low-Cost Hydrogen-Storage Sorbents for Automotive Applications

This report provides a review of the objectives, progress, and milestones of the research conducted during this project on the topic of developing innovative metal-organic frameworks (MOFs) and porous organic polymers (POPs) for high-capacity and low-cost hydrogen-storage sorbents in automotive applications.1 The objectives of the proposed research were to develop new materials as next-generation hydrogen storage sorbents that meet or exceed DOE’s 2017 performance targets of gravimetric capacity of 0.055 kg H 2 /kg system and volumetric capacity of 0.040 kg H 2 /L system at a cost of $400/kg H 2 stored . Texas A&M University (TAMU) and Argonne National Laboratory (ANL) collaborated in developing low-cost and high-capacity hydrogen-storage sorbents with appropriate stability, sorption kinetics, and thermal conductivity. The research scope and methods developed to achieve the project’s goals include the following: Advanced ligand design and synthesis to construct MOF sorbents with optimal hydrogen storage capacities, low cost and high stability; Substantially improve the hydrogen uptake capacity and chemical stability of MOF-based sorbents by incorporating high valent metal ions during synthesis or through the post-synthetic metal metathesis oxidation approach; Enhance sorbent storage capacity through material engineering and characterization; Generate a better understanding of the H 2 -sorbent interaction through advanced characterization and simulation. Over the course of the project 5 different MOFs were developed and studied: PCN-250, PCN-12, PCN-12’, PCN-608 and PCN-609.2-3 Two different samples were submitted to the National Renewable Energy Laboratory (NREL) in order to validate their hydrogen adsorption capacity, PCN-250 and PCN-12. Neither of these samples reached the project’s Go/No-Go requirements but the data obtained did further prove the hypothesis that the presence of open metal sites oriented towards MOF pores help to surpass the predicted hydrogen uptakes described by Chahine’s rule.4 These observations are believed to have a major impact on the hydrogen storage community, and may potentially lead to the development of a material that could meet the DOE goals for hydrogen storage systems for automotive applications.

08 HYDROGEN↗

Decoupled direct method for sensitivity analysis in combustion kinetics

An efficient, decoupled direct method for calculating the first order sensitivity coefficients of homogeneous, batch combustion kinetic rate equations is presented. In this method the ordinary differential equations for the sensitivity coefficients are solved separately from , but sequentially with, those describing the combustion chemistry. The ordinary differential equations for the thermochemical variables are solved using an efficient, implicit method (LSODE) that automatically selects the steplength and order for each solution step. The solution procedure for the sensitivity coefficients maintains accuracy and stability by using exactly the same steplengths and numerical approximations. The method computes sensitivity coefficients with respect to any combination of the initial values of the thermochemical variables and the three rate constant parameters for the chemical reactions. The method is illustrated by application to several simple problems and, where possible, comparisons are made with exact solutions and those obtained by other techniques.

Radhakrishnan, Krishnan↗

A Dynamic Pricing Method to Manage the Impact of EV Charging on the Grid Using RL

This work addresses the challenge of managing electrical vehicle (EV) charging loads on distribution feeders with the increase in deployment of fast charging stations. To mitigate the adverse impacts on feeder health, a novel dynamic grid-informed pricing approach is proposed. This approach leverages reinforcement learning (RL) to determine hourly charging prices based on real-time grid conditions. A synthetic environment was developed to train the reinforcement learning agent. A model of an IEEE 34-bus distribution feeder with EV charging stations has been developed in OpenDSS utilizing Caldera for realistic EV charging profiles. Test cases demonstrate that the dynamic pricing strategy achieves higher energy delivery to the EV end user at a lower cost compared to constant pricing methods, while lowering voltage deviations and congestion. This approach offers more granular price adjustments, responding dynamically to feeder conditions and potentially improving grid stability and efficiency. The communication architecture to implement this dynamic pricing method is described. This research contributes to the development of smart grid-informed charging solutions that can reduce the cost of charging to the end user while also helping the grid.

EV charging, dynamic pricing, grid-informed chargi↗

A dynamic pricing method to manage the impact of EV charging on the grid using RL

This work addresses the challenge of managing electrical vehicle (EV) charging loads on distribution feeders with the increase in deployment of fast charging stations. To mitigate the adverse impacts on feeder health, a novel dynamic grid-informed pricing approach is proposed. This approach leverages reinforcement learning (RL) to determine hourly charging prices based on real-time grid conditions. A synthetic environment was developed to train the reinforcement learning agent. A model of an IEEE 34-bus distribution feeder with EV charging stations has been developed in OpenDSS utilizing Caldera for realistic EV charging profiles. Test cases demonstrate that the dynamic pricing strategy achieves higher energy delivery to the EV end user at a lower cost compared to constant pricing methods, while lowering voltage deviations and congestion. This approach offers more granular price adjustments, responding dynamically to feeder conditions and potentially improving grid stability and efficiency. The communication architecture to implement this dynamic pricing method is described. This research contributes to the development of smart grid-informed charging solutions that can reduce the cost of charging to the end user while also helping the grid.

24 - POWER TRANSMISSION AND DISTRIBUTION↗

Stability of fringe counting interferometers

Two configurations of an automatic bidirectional, fringe-counting corner-cube interferometer are compared. They differ only in the method of quadrature phase introduction. The one using polarization coding has good phase stability at optical path differences as large as 955 mm, the one using adjacent beams has such poor phase stability as to render it useless at path differences greater than 700 mm. A useful well-defined alignment procedure is given for the corner-cube interferometer.

Edgerton, J. W.↗

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