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At least 1,801 records · Page 100

Performance improvement of Ge-Sb-Te material by GaSb doping for phase change memory

Effects of GaSb doping on phase change characteristics of Ge-Sb-Te material are investigated by in situ resistance and x-ray diffraction measurement, optical spectroscopy, and x-ray photoelectron spectroscopy. The crystallization temperature and data retention of Ge-Sb-Te material increase significantly by the addition of GaSb, which results from the high thermal stability of amorphous GaSb. In addition, GaSb-doped Ge-Sb-Te material exhibits faster crystallization speed due to the change in electronic states as a result of the formation of chemical bonds with Ga element. Incorporation of GaSb is highly effective way to enhance the comprehensive performance of Ge-Sb-Te material for phase change memory.

36 MATERIALS SCIENCE↗

Single-field slice-imaging with a movable repeller: Photodissociation of N{sub 2}O from a hot nozzle

We present a new photo-fragment imaging spectrometer, which employs a movable repeller in a single field imaging geometry. This innovation offers two principal advantages. First, the optimal fields for velocity mapping can easily be achieved even using a large molecular beam diameter (5 mm); the velocity resolution (better than 1%) is sufficient to easily resolve photo-electron recoil in (2 + 1) resonant enhanced multiphoton ionization of N{sub 2} photoproducts from N{sub 2}O or from molecular beam cooled N{sub 2}. Second, rapid changes between spatial imaging, velocity mapping, and slice imaging are straightforward. We demonstrate this technique's utility in a re-investigation of the photodissociation of N{sub 2}O. Using a hot nozzle, we observe slice images that strongly depend on nozzle temperature. Our data indicate that in our hot nozzle expansion, only pure bending vibrations – (0, v{sub 2}, 0) – are populated, as vibrational excitation in pure stretching or bend-stretch combination modes are quenched via collisional near-resonant V-V energy transfer to the nearly degenerate bending states. We derive vibrationally state resolved absolute absorption cross-sections for (0, v{sub 2} ≤ 7, 0). These results agree well with previous work at lower values of v{sub 2}, both experimental and theoretical. The dissociation energy of N{sub 2}O with respect to the O({sup 1}D) + N{sub 2} + Σ{sup +}{sub g} asymptote was determined to be 3.65 ± 0.02 eV.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Flame dynamics in a micro-channeled combustor

The increasing use of Micro-Electro-Mechanical Systems (MEMS) has generated a significant interest in combustion-based power generation technologies, as a replacement of traditional electrochemical batteries which are plagued by low energy densities, short operational lives and low power-to-size and power-to-weight ratios. Moreover, the versatility of integrated combustion-based systems provides added scope for combined heat and power generation. This paper describes a study into the dynamics of premixed flames in a micro-channeled combustor. The details of the design and the geometry of the combustor are presented in the work by Kariuki and Balachandran [1]. This work showed that there were different modes of operation (periodic, a-periodic and stable), and that in the periodic mode the flame accelerated towards the injection manifold after entering the channels. The current study investigates these flames further. We will show that the flame enters the channel and propagates towards the injection manifold as a planar flame for a short distance, after which the flame shape and propagation is found to be chaotic in the middle section of the channel. Finally, the flame quenches when it reaches the injector slots. The glow plug position in the exhaust side ignites another flame, and the process repeats. It is found that an increase in air flow rate results in a considerable increase in the length (and associated time) over which the planar flame travels once it has entered a micro-channel, and a significant decrease in the time between its conversion into a chaotic flame and its extinction. It is well known from the literature that inside small channels the flame propagation is strongly influenced by the flow conditions and thermal management. An increase of the combustor block temperature at high flow rates has little effect on the flame lengths and times, whereas at low flow rates the time over which the planar flame front can be observed decreases and the time of existence of the chaotic flame increases. The frequency of re-ignition of successive flames decreases at higher flow rates and increases at higher temperatures. The data and results from this study will not only help the development of new micro-power generation devices, but they will also serve as a validation case for combustion models capable of predicting flame behavior in the presence of strong thermal and flow boundary layers, a situation common to many industrial applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Auto-combustion synthesis and characterization of Mg doped CuAlO{sub 2} nanoparticles

The synthesis of pure and Mg doped Copper aluminumoxide CuAlO{sub 2}nanoparticles, a promising p-type TCO (transparent conducting oxide) have been done bysol gel auto combustion method using NaOH as a fuel, calcinated at 600°C. The structural properties were examined by XRD and SEM techniques. The optical absorption spectra of CuAlO{sub 2} sample recorded by UV-VIS spectrophotometer in the range of 200 to 800 nm have been presented. The crystallite size was determined by powder X-ray diffraction technique. The electrical behavior of pure and Mg doped CuAlO{sub 2} has been studied over a wide range of frequencies by using complex impedance spectroscopy.The variation of a.c. conductivity has been studied as function of frequency and temperature. The data taken together conclude that doping causes decreases in the ac conductivity of the nanoparticles as compared with the pure nanoparticles. Mg doping affects the optical properties and band gap.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Spectroscopic and theoretical studies of the low-lying states of BaO{sup +}

The BaO{sup +} cation is of interest from the perspectives of electronic structure and the potential for cooling to ultra-cold temperatures. Spectroscopic data for the ion have been obtained using a two-color photoionization technique. The ionization energy for BaO was found to be 6.8123(3) eV. The ground state of BaO{sup +} was identified as X{sup 2}Σ{sup +}, and both vibrational and rotational constants were determined. Vibrationally resolved spectra were recorded for A{sup 2}Π, the first electronically excited state. These data yielded the term energy, vibrational frequency, and the spin-orbit interaction constant. Relativistic electronic structure calculations were carried out using multi-reference configuration interaction (MRCI), coupled cluster and density functional theory methods. Transition moments for the pure vibrational and A{sup 2}Π-X{sup 2}Σ{sup +} transitions were predicted using the MRCI method.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Qualification of a sublimation tool applied to the case of metalorganic chemical vapor deposition of In{sub 2}O{sub 3} from In(tmhd){sub 3} as a solid precursor

A solid delivery system consisting of a source canister, a gas management, and temperature controlled enclosure designed and manufactured by Air Liquide Electronics Systems was tested in the context of gas-phase delivery of the In(tmhd){sub 3} solid precursor. The precursor stream was delivered to a thermal metalorganic chemical vapor deposition reactor to quantify deposition yield under various conditions of carrier gas flow and sublimation temperature. The data collected allowed the determination of characteristic parameters such as the maximum precursor flow rate (18.2 mg min{sup −1} in specified conditions) and the critical mass (defined as the minimum amount of precursor able to attain the maximum flow rate) found to be about 2.4 g, as well as an understanding of the influence of powder distribution inside the canister. Furthermore, this qualification enabled the determination of optimal delivery conditions which allowed for stable and reproducible precursor flow rates over long deposition times (equivalent to more than 47 h of experiment). The resulting In{sub 2}O{sub 3} layers was compared with those elaborated via pulsed liquid injection obtained in the same chemical vapor deposition chamber and under the same deposition conditions.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Green synthesis of ZnO nanoparticles via complex formation by using Curcuma longa extract

Synthesis of ZnO nanoparticles(NPs) were conducted via Zn(II) complex formation by using Curcuma longa extract as template. Curcuma longa extract has the ability to form zinc ions complex with curcumin as ligating agent. Study on synthesis was conducted by monitoring thermal degradation of the material. Successful formation of zinc oxide nanoparticles was confirmed by employing x-ray diffraction, surface area analysis and transmission electron microscopy(TEM) studies. From the XRD analysis it is denoted that ZnO in hexagonal wurtzite phase was formed and particle size was varied as varied temperature. The data are also confirmed by TEM analysis which shows the particle sie at the range 20-80nm. The NPs exhibited excelent photocatalytic activity for methylene blue degradation and also significant antibacterial activity for Eschericia coli. The activity in methylene blue degradation was also confirmed from fast chemical oxygen demand (COD) reduction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A small porous-plug burner for studies of combustion chemistry and soot formation

We have developed and built a small porous-plug burner based on the original McKenna burner design. The new burner generates a laminar premixed flat flame for use in studies of combustion chemistry and soot formation. The size is particularly relevant for space-constrained, synchrotron-based X-ray diagnostics. In this paper, we present details of the design, construction, operation, and supporting infrastructure for this burner, including engineering attributes that enable its small size. We also present data for charactering the flames produced by this burner. These data include temperature profiles for three premixed sooting ethylene/air flames (equivalence ratios of 1.5, 1.8, and 2.1); temperatures were recorded using direct one-dimensional coherent Raman imaging. We include calculated temperature profiles, and, for one of these ethylene/air flames, we show the carbon and hydrogen content of heavy hydrocarbon species measured using an aerosol mass spectrometer coupled with vacuum ultraviolet photoionization (VUV-AMS), and soot-volume-fraction measurements obtained using laserinduced incandescence (LII). In addition, we provide calculated mole-fraction profiles of selected gas-phase species and characteristic profiles for seven mass peaks from AMS measurements. Using these experimental and calculated results, we discuss the differences between standard McKenna burners and the new miniature porous-plug burner introduced here.

47 OTHER INSTRUMENTATION↗

A CO 2 laser heating system for in situ high pressure-temperature experiments at HPCAT

We present a CO 2 laser heating setup for synchrotron x-ray diffraction inside a diamond anvil cell, situated at HPCAT (Sector 16, Advanced Photon Source, Argonne National Lab, Illinois, USA), which is modular and portable between the HPCAT experiment hutches. Specifically, the system allows direct laser heating of wide bandgap insulating materials to thousands of degrees at static high pressures up to the Mbar regime. Alignment of the focused CO 2 laser spot is performed using a mid-infrared microscope, which addressed past difficulties with aligning the invisible radiation. The implementation of the mid-infrared microscope alongside a mirror pinhole spatial filter system allows precise alignment of the heating laser spot and optical pyrometry measurement location to the x-ray probe. A comparatively large heating spot (~50 μ m) relative to the x-ray beam (<10 μ m) reduces the risk of temperature gradients across the probed area. Each component of the heating system and its diagnostics have been designed with portability in mind and compatibility with the various experimental hutches at the HPCAT beamlines. We present measurements on ZrO 2 at 5.5 GPa which demonstrate the improved room-temperature diffraction data quality afforded by annealing with the CO 2 laser. We also present in situ measurements at 5.5 GPa up to 2800 K in which we do not observe the postulated fluorite ZrO 2 structure, in agreement with recent findings.

47 OTHER INSTRUMENTATION↗

Electronic structure of NdO via slow photoelectron velocity-map imaging spectroscopy of NdO –

Electronically excited NdO is a possible product of the chemistry associated with the release of Nd into the ionosphere, and emission from these states may contribute to the observations following such experiments. To better characterize the energetics and spectroscopy of NdO, we report a combined experimental and theoretical study using slow photoelectron velocity-map imaging spectroscopy of cryogenically cooled NdO – anions (cryo-SEVI) supplemented by wave function-based quantum-chemical calculations. Using cryo-SEVI, we measure the electron affinity of NdO to be 1.0091(7) eV and resolve numerous transitions to low-lying electronic and vibrational states of NdO that are assigned with the aid of the electronic structure calculations. Additionally, temperature-dependent data suggest contributions from the (2)4.5 state of NdO – residing 2350 cm –1 above the ground anion state. Finally, photodetachment to higher-lying excited states of NdO is also reported, which may help to clarify observations from prior release experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Design of a Multi-Monochromatic X-ray Imager (MMI) for Kr K-shell line emission

We report the Multi-Monochromatic X-ray Imager (MMI) is a time-gated spectrometer used in implosion experiments at the OMEGA laser facility. From the data, electron temperature and density spatial distributions can be obtained at different implosion times. Previous MMI designs used Ar K-shell emission (3–6 keV) as a spectroscopic tracer and provided a spectral resolution of around 20 eV. However, Ar K-shell line emission becomes less useful at electron temperatures above 2 keV due to over-ionization. Kr K-shell (12–16 keV) has been shown to be an attractive alternative to diagnose hot implosion cores in recent publications. The purpose of this paper is to show a new point design that allows the MMI to detect this higher photon energy range with suitable spectral resolution. The algorithm used to find the optimal design couples a ray-tracing code and an exhaustive parameter space search. This algorithm may be useful as a tool to find optimal MMI designs for other purposes, i.e., other spectral regions for other spectroscopic tracers. So, the main change between the two designs is the replacement of the multi-layer mirror with a flat Bragg Ge (220) crystal. The final Kr K-shell MMI design has a photon energy range from 12 to 16.1 keV.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Amorphous calcium carbonate particles form coral skeletons

Significance Whether coral skeleton crystals grow by attachment of ions from solution or particles from tissue determines ( i ) corals’ growth rate, ( ii ) how they survive acidifying oceans, and ( iii ) the isotopes in the crystals used for reconstructing ancient temperatures. Our data show that two amorphous precursors exist, one hydrated and one dehydrated amorphous calcium carbonate; that these are formed in the tissue as ∼400-nm particles; and that they attach to the surface of coral skeletons, remain amorphous for hours, and finally crystallize into aragonite. Since these particles are formed inside tissue, coral skeleton growth may be less susceptible to ocean acidification than previously assumed. Coral bleaching and postmortem dissolution of the skeleton will occur, but a calcification crisis may not.

58 GEOSCIENCES↗

Millimeter observations of CS, HCO{sup +}, and CO toward five planetary nebulae: following molecular abundances with nebular age

Millimeter and sub-millimeter observations of CO, CS, and HCO{sup +} have been conducted toward five planetary nebulae (PNe: K4-47, NGC 6537 (Red Spider), M2-48, NGC 6720 (Ring), and NGC 6853 (Dumbbell)), spanning an age range of 900-10,000 yr, using the Sub-Millimeter Telescope and the 12 m antenna of the Arizona Radio Observatory. The J = 5 → 4, J = 3 → 2, and J = 2 → 1 transitions of CS at 245, 147, and 98 GHz, as well as the J = 3 → 2 and J = 1 → 0 lines of HCO{sup +} at 268 and 89 GHz, were detected toward each source. At least three rotational transitions of CO have also been observed, including the J = 6 → 5 and J = 4 → 3 lines at 691 and 461 GHz. CS had not been definitively identified previously in PNe, and new detections of HCO{sup +} were made in four of the five nebulae. From a radiative transfer analysis of the CO and CS data, kinetic temperatures of T {sub K} ∼ 10-80 K and gas densities of n(H{sub 2}) ∼ 0.1-1 × 10{sup 6} cm{sup –3} were determined for the molecular material in these sources. Column densities for CO, CS, and HCO{sup +} were N {sub tot} ∼ 0.2-5 × 10{sup 16} cm{sup –2}, N {sub tot} ∼ 0.4-9 × 10{sup 12} cm{sup –2}, and N {sub tot} ∼ 0.3-5 × 10{sup 12} cm{sup –2}, respectively, with fractional abundances, relative to H{sub 2}, of f ∼ 0.4-2 × 10{sup –4}, f ∼ 1-4 × 10{sup –8}, and f ∼ 1 × 10{sup –8}, with the exception of M2-48, which had f(HCO{sup +}) ∼ 10{sup –7}. Overall, the molecular abundances do not significantly vary over a duration of 10,000 yr, in contrast to predictions of chemical models. The abundances reflect the remnant asymptotic giant branch shell material, coupled with photochemistry in the early PN phase. These observations also suggest that PNe eject substantial amounts of molecular material into the diffuse interstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗

CMB constraint on non-Gaussianity in isocurvature perturbations

We study the CMB constraints on non-Gaussianity in CDM isocurvature perturbations. Non-Gaussian isocurvature perturbations can be produced in various models at the very early stage of the Universe. Since the isocurvature perturbations little affect the structure formation at late times, CMB is the best probe of isocurvature non-Gaussianity at least in the near future. In this paper, we focus on non-Gaussian curvature and isocurvature perturbations of the local-type, which are uncorrelated and in the form ζ = ζ{sub G}+(3/5)f{sub NL}(ζ{sub G}{sup 2}−(ζ{sub G}{sup 2})) and S = S{sub G}+f{sub NL}{sup (ISO)}(S{sub G}−(S{sub G}{sup 2})), and constrain the non-linearity parameter of isocurvature perturbations, f{sub NL}{sup (ISO)}, as well as the curvature one f{sub NL}. For this purpose, we employ several state-of-art techniques for the analysis of CMB data and simulation. Assuming that isocurvature perturbations are subdominant, we apply our method to the WMAP 7-year data of temperature anisotropy and obtain constraints on a combination α{sup 2}f{sub NL}{sup (ISO)}, where α is the ratio of the power spectrum of isocurvature perturbations to that of the adiabatic ones. When the adiabatic perturbations are assumed to be Gaussian, we obtained a constraint α{sup 2}f{sub NL}{sup (ISO)} = 40±66 assuming the power spectrum of isocurvature perturbations is scale-invariant. When we assume that the adiabatic perturbations can also be non-Gaussian, we obtain f{sub NL} = 38±24 and α{sup 2}f{sub NL}{sup (ISO)} = −8±72. We also discuss implications of our results for the axion CDM isocurvature model.

79 ASTRONOMY AND ASTROPHYSICS↗

Planck satellite constraints on pseudo-Nambu-Goldstone boson quintessence

The pseudo-Nambu-Goldstone Boson (PNGB) potential, defined through the amplitude M {sup 4} and width f of its characteristic potential V (φ) = M {sup 4}[1 + cos(φ/ f )], is one of the best-suited models for the study of thawing quintessence. We analyse its present observational constraints by direct numerical solution of the scalar field equation of motion. Observational bounds are obtained using Supernovae data, cosmic microwave background temperature, polarization and lensing data from Planck , direct Hubble constant constraints, and baryon acoustic oscillations data. We find the parameter ranges for which PNGB quintessence gives a viable theory for dark energy. This exact approach is contrasted with the use of an approximate equation-of-state parametrization for thawing theories. We also discuss other possible parameterization choices, as well as commenting on the accuracy of the constraints imposed by Planck alone. Overall our analysis highlights a significant prior dependence to the outcome coming from the choice of modelling methodology, which current data are not sufficient to override.

79 ASTRONOMY AND ASTROPHYSICS↗

PATCHY ACCRETION DISKS IN ULTRA-LUMINOUS X-RAY SOURCES

The X-ray spectra of the most extreme ultra-luminous X-ray sources—those with L ≥ 10{sup 40} erg s{sup –1}—remain something of a mystery. Spectral roll-over in the 5-10 keV band was originally detected in the deepest XMM-Newton observations of the brightest sources; this is confirmed in subsequent NuSTAR spectra. This emission can be modeled via Comptonization, but with low electron temperatures (kT{sub e} ≅ 2 keV) and high optical depths (τ ≅ 10) that pose numerous difficulties. Moreover, evidence of cooler thermal emission that can be fit with thin disk models persists, even in fits to joint XMM-Newton and NuSTAR observations. Using NGC 1313 X-1 as a test case, we show that a patchy disk with a multiple temperature profile may provide an excellent description of such spectra. In principle, a number of patches within a cool disk might emit over a range of temperatures, but the data only require a two-temperature profile plus standard Comptonization, or three distinct blackbody components. A mechanism such as the photon bubble instability may naturally give rise to a patchy disk profile, and could give rise to super-Eddington luminosities. It is possible, then, that a patchy disk (rather than a disk with a standard single-temperature profile) might be a hallmark of accretion disks close to or above the Eddington limit. We discuss further tests of this picture and potential implications for sources such as narrow-line Seyfert-1 galaxies and other low-mass active galactic nuclei.

79 ASTRONOMY AND ASTROPHYSICS↗

Field, frequency, and temperature dependencies of the surface resistance of nitrogen diffused niobium superconducting radio frequency cavities

We investigate the rf performance of several single-cell superconducting radio-frequency cavities subjected to low temperature heat treatment in nitrogen environment. The cavities were treated at temperature 120 – 165 ° C for an extended period of time (24–48 h) either in high vacuum or in a low partial pressure of ultrapure nitrogen. The improvement in Q 0 with a Q rise was observed when nitrogen gas was injected at ∼ 300 ° C during the cavity cooldown from 800 ° C and held at 165 ° C , without any degradation in accelerating gradient over the baseline performance. The treatment was applied to several elliptical cavities with frequency ranging from 0.75 to 3.0 GHz, showing an improved quality factor as a result of low temperature nitrogen treatments. The Q rise feature is similar to that achieved by nitrogen alloying Nb cavities at higher temperature, followed by material removal by electropolishing. The surface modification was confirmed by the change in electronic mean free path and tuned with the temperature and duration of heat treatment. The decrease of the temperature-dependent surface resistance with increasing rf field, resulting in a Q rise, becomes stronger with increasing frequency and decreasing temperature. The data suggest a crossover frequency of ∼ 0.95 GHz above that the Q rise phenomenon occurs at 2 K. Some of these results can be explained qualitatively with an existing model of intrinsic field-dependence of the surface resistance with both equilibrium and nonequilibrium quasiparticle distribution functions. The change in the Q slope below 0.95 GHz may result from masking contribution of trapped magnetic flux to the residual surface resistance. Published by the American Physical Society 2024

43 PARTICLE ACCELERATORS↗

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