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Equivalent System Mass Comparison of ECLSS CO2 Removal Technologies

This project employs equivalent system mass (ESM) analyses to evaluate and compare state-of-the-art spacecraft CO2 removal systems. The ESM methodology converts sizing characteristics such as volume, power, and cooling requirements into a unified metric of mass, allowing for simple quantitative comparison of equipment impacts on a system level. Comparison of six high TRL technologies – the Carbon Dioxide Removal System (CDRS), Thermal Amine Scrubber (TAS), Carbon Dioxide Removal Assembly (CDRA), Four-Bed CO2 Scrubber (4BCO2), CO2 and Humidity Control Swing Bed (CHC), and the Carbon Dioxide Removal by Ionic Liquid Sorbent (CDRILS) – was achieved using an existing ESM spreadsheet tool that formerly ranked such technologies for consideration on Gateway. Fidelity of the tool was increased through revision with the most up-to-date sizing and performance data for each technology. ESM values were then estimated using NASA-supplied Lunar, Martian, and low-Earth orbit habitat infrastructure costs. This paper details the ESM approach used, lists major performance variables for each CO2 removal option, and summarizes conclusions of the technology comparison. The results are intended to act as a guide to assist programs in their selection of CO2 technologies best suited for a specific vehicle or mission.

Madeleine C Oliver

Selective ion transport through hydrated micropores in polymer membranes

Abstract Ion-conducting polymer membranes are essential in many separation processes and electrochemical devices, including electrodialysis 1 , redox flow batteries 2 , fuel cells 3 and electrolysers 4,5 . Controlling ion transport and selectivity in these membranes largely hinges on the manipulation of pore size. Although membrane pore structures can be designed in the dry state 6 , they are redefined upon hydration owing to swelling in electrolyte solutions. Strategies to control pore hydration and a deeper understanding of pore structure evolution are vital for accurate pore size tuning. Here we report polymer membranes containing pendant groups of varying hydrophobicity, strategically positioned near charged groups to regulate their hydration capacity and pore swelling. Modulation of the hydrated micropore size (less than two nanometres) enables direct control over water and ion transport across broad length scales, as quantified by spectroscopic and computational methods. Ion selectivity improves in hydration-restrained pores created by more hydrophobic pendant groups. These highly interconnected ion transport channels, with tuned pore gate sizes, show higher ionic conductivity and orders-of-magnitude lower permeation rates of redox-active species compared with conventional membranes, enabling stable cycling of energy-dense aqueous organic redox flow batteries. This pore size tailoring approach provides a promising avenue to membranes with precisely controlled ionic and molecular transport functions.

Science & Technology - Other Topics

Converting Second‐Order Saddle Points to Transition States: New Principles for the Design of 4π Photoswitches

Abstract Molecular photoswitches have demonstrated potential for storing solar energy at the molecular level, with power densities comparable to commercial batteries and hydroelectric energy storage. However, development of efficient photoswitches is hindered by limitations in cyclability and optical properties of existing materials. We here demonstrate that certain limitations in photoswitches based on electrocyclizations stem from the issue of controlling competition between Woodward‐Hoffmann allowed and forbidden pathways. Our approach moves beyond the traditional view of activation barriers and reveals that second‐order saddle points are crucial in dictating the competition between disrotatory and conrotatory pathways. These insights suggest new opportunities to manipulate the competition between these pathways through geometric constraints, fundamentally altering the connectivity of the potential energy surface. Our study also emphasizes the necessity of multi‐reference methods and the need to conduct higher‐dimensional explorations for competing pathways beyond photoswitch design.

Chemistry

NiH2 Battery Reconditioning for LEO Applications

This paper summarizes reasons for and benefits of reconditioning nickel-hydrogen (NiH2) batteries used for Low Earth Orbit (LEO) applications. NiH2 battery cells do not have the classic discharge voltage problems more commonly associated with nickel-cadmium (NiCd) cells. This is due, in part, to use of hydrogen electrodes in place of cadmium electrodes. The nickel electrode, however, does have a similar discharge voltage signature for both cell designs. This can have an impact on LEO applications where peak loads at higher relative depths of discharge can impact operations. Periodic reconditioning provides information which can be used for analyzing long term performance trends to predict usable capacity to a specified voltage level. The reconditioning process described herein involves discharging NiH2 batteries at C/20 rates or less, to an average cell voltage of 1.0 volts or less. Recharge is performed at nominal C/5 rates to specified voltage/temperature (V/T) charge levels selected to restore required capacity with minimal overcharge. Reconditioning is a process of restoring reserve capacity lost on cycling, which is commonly called the memory effect in NiCd cells. This effect is characterized by decreases in the discharge voltage curve with operational life and cycling. The end effect of reconditioning NiH2 cells may be hidden in the versatility, of that design over the NiCd cell design and its associated negative electrode fading problem. The process of deep discharge at lower rates by way of reconditioning tends to redistribute electrolyte and water in the NiH2 cell electrode stack, while improving utilization and charge efficiency. NiH2 battery reconditioning effects on life are considered beneficial and may, in fact. extend life based on NiCd experience. In any case, usable capacity data obtained from reconditioning is required for performance evaluation and trend analysis. Characterization and life tests have provided the historical data base used to determine the need for reconditioning in most battery applications. The following sections briefly describe the background of NiH2 battery reconditioning and testing at Lockheed Martin Missiles & Space (LMMS) and other aerospace companies.

Armantrout, J. D.

Experimental Demonstration of a Supersonic Spike Ejector

Spike diffusers are presented as a means to improve supersonic ejector efficiency via reduction in shock losses. Design, fabrication, and testing of an articulated prototype is described. Experimental results are compared to empirical performance curves representing the loci of optimal one- and two-stage conventional ejectors driven by dry air and discharging to atmosphere. Operated at a compression ratio of ~10 with all inputs equal, the spike ejector is shown to have achieved up to 2.19X and 1.83X the secondary mass throughput of the one- and two-stage references, respectively. This suggests the potential of spike diffusers to reduce ejector operating costs by ~50%.

wind tunnel

Advancing Protein Display on Bacterial Spores through an Extensive Survey of Coat Components

The profound stability of bacterial spores makes them a promising platform for biotechnological applications like biocatalysis, bioremediation, drug delivery, etc. However, though the Bacillus subtilis spore is composed of >40 types of proteins, only ∼12 have been explored as fusion carriers for protein display. Here, we assessed the suitability of 33 spore proteins (SPs) as enzyme display carriers by direct allele tagging at native genomic loci. Of the 33 SPs investigated, 26 formed functional fusions with β-glucuronidase (GUS)─a ∼272 kDa homotetramer. This almost triples the number of SPs assessed for enzyme display and doubles the number of functional fusions documented in the literature. We quantitatively assessed 1) SP promoter activation dynamics, 2) GUS activity on spores, 3) surface availability, and 4) protection from thermal and proteolytic degradation. Multicopy expression and pairwise coexpression of the most promising SP-GUS fusions highlighted the complexity of spore structure/assembly and the difficulty in predicting compatibility between different SP fusions. We also assessed the suitability of engineered spores to degrade PET (polyethylene terephthalate) films and found that surface-exposed SPs were most effective. Beyond the broad survey, a key outcome of our work was the identification of SscA (small spore coat assembly protein A) as an effective spore display carrier. SscA supported enzyme activity at least 4-fold higher than any other SP, including the well-established anchor, CotY. We attribute this to its promoter, which demonstrated early and sustained activation relative to other SPs and its small size (∼3 kDa), which likely minimally interferes with enzyme folding, oligomerization, and activity. Labeling and genetic studies, its hydrophobic nature, and low surface availability suggest that SscA assembles within the inner spore coat, which makes it stabilizing and suitable for many biocatalytic applications. Overall, this work serves as a knowledge base to advance the biotechnological utility of B. subtilis spores.

Bacillus subtilis

NASA Aerospace Flight Battery Systems Program: An Update

The major objective of the NASA Aerospace Flight Battery Systems Program is to provide NASA with the policy and posture to increase and ensure the safety, performance, and reliability of batteries for space power systems. The program was initiated in 1985 to address battery problems experienced by NASA and other space battery users over the previous ten years. The original program plan was approved in May 1986 and modified in 1990 to reflect changes in the agency's approach to battery related problems that are affecting flight programs. The NASA Battery Workshop is supported by the NASA Aerospace Flight Battery Systems Program. The main objective of the discussions is to aid in defining the direction which the agency should head with respect to aerospace battery issues. Presently, primary attention in the Battery Program is being devoted to issues revolving around the future availability of nickel-cadmium batteries as a result of the proposed OSHA standards with respect to allowable cadmium levels in the workplace. The decision of whether or not to pursue the development of an advanced nickel-cadmium cell design and the qualification of vendors to produce cells for flight programs hinges on the impact of the OSHA ruling. As part of a unified Battery Program, the evaluation of a nickel-hydrogen cell design options and primary cell issues are also being pursued to provide high performance NASA Standards and space qualified state-of-the-art cells. The resolution of issues is being addressed with the full participation of the aerospace battery community.

Manzo, Michelle A.

Modeling the Potential Impact of Storage on the US Power Sector in a Multisector Dynamic Context

The electric power sector is expected to grow in size, importance, and complexity around the world as economies expand and electric supply technologies and demand patterns evolve in significant ways. At the same time the electric power sector may see substantial increases in VRE generating technologies which can add variability and uncertainty to the diurnal and seasonal profile of electric supply. With these forces in play, the emergence of modular, flexible electricity storage technologies may have profound impacts on the operation of electric power systems. Here we reduce a storage modeling gap in MSD models by incorporating grid-based electricity storage into the electric sector dynamics of the Global Change Analysis Model-USA (GCAM-USA) with improved power sector representation. We find a potentially significant role for storage technologies in the future of the U.S. power system, with storage capacity ranging from 7.7 to 14.7 GW in 2050 and 13.9 to 31.6 GW in 2100 across several techno-economic scenarios. We also find that storage can help to smooth variability in residual load arising from evolving electricity demands and the introduction of high shares of VRE to the electric grid. This reduces reliance on high-cost peaking generators, improves system-wide capacity factors, and limits curtailment of VRE.

Patel, Pralit L.

Manufacturing Research in Support of Saturn V

Research achievements applicable to the production of Saturn V components a r e described in this report. Leakage at the mechanical connections in high-pressure lines has been minimized or eliminated through the use of precisely flared tubes. Flaring to close tolerance is done with a n orbital flaring adapter, and the forming operation is precisely controlled with an electronic control console. A technique of “aging” or heat-treatment hardening of aluminum materials has been used to form cylindrical-tank segments and double-contoured gore segments precisely, and to remove weld distortions). The control of weld porosity has been improved as a result of research which demonstrated the close correlation between electrical energy input per inch of weld and weld porosity and metallurgical quality. Based on this information, the gas metallic arc method has been used successfully for two-pass welding, and thinner gage aluminum has been welded (LOX tunnel to fuel bulkhead) with an MSFC designed gas metallic arc unit.

COMPOSITE MATERIAL

Galileo Li/SO sub 2 battery modules program update

In order to meet the power needs of NASA's Galileo Probe, the Li/SO2 high rate D cells used in the battery modules have undergone some design changes, as upgrading of hardware quality requirements, and significant testing. A description of the design changes and the cell test data that are of a general nature is presented here. This data includes capacities, open circuit voltages, and internal resistance comparisons. A significant data base was built up over the years and continues to grow.

Smith, R. A.

Equivalent System Mass Comparison of ECLSS CO 2 Removal Technologies

This project employs equivalent system mass (ESM) analyses to evaluate and compare state-of-the-art spacecraft CO 2 removal systems. The ESM methodology converts sizing characteristics such as volume, power, and cooling requirements into a unified metric of mass, allowing for simple quantitative comparison of equipment impacts on a system level. Comparison of six high TRL technologies – the Carbon Dioxide Removal System (CDRS), Thermal Amine Scrubber (TAS), Carbon Dioxide Removal Assembly (CDRA), Four-Bed CO 2 Scrubber (4BCO2), CO 2 and Humidity Control Swing Bed (CHC), and the Carbon Dioxide Removal by Ionic Liquid Sorbent (CDRILS) – was achieved using an existing ESM spreadsheet tool that formerly ranked such technologies for consideration on Gateway. Fidelity of the tool was increased through revision with the most up-to-date sizing and performance data for each technology. ESM values were then estimated using NASA-supplied Lunar, Martian, and low-Earth orbit habitat infrastructure costs. This paper details the ESM approach used, lists major performance variables for each CO 2 removal option, and summarizes conclusions of the technology comparison. The results are intended to act as a guide to assist programs in their selection of CO 2 technologies best suited for a specific vehicle or mission.

Madeleine Oliver

Improvement in the Thermal-to-Structural Model Mapping Process for Integrated Modeling for the Roman Space Telescope

Integrated Modeling has been a key component of verifying optical requirements for the Nancy Grace Roman Space Telescope (RST) that are either impossible or impractical to verify exclusively through ground testing. Two major areas for integrated Modeling are Jitter and Thermal Distortion that require the exchanges of model performance predictions across disciplines. In both cases, distortions are impressed on optical models to evaluate the impact on boresight alignment and wave front error. In the case of Jitter, the disturbances are driven by reactions to motions most often from actuators; however, in the case of thermal distortion, the motions are driven by thermal expansion or contraction as a result of changing temperatures. This then requires a link further upstream to the thermal model, which is used to predict the thermal performance and temperature gradients and stability. The process for mapping temperatures from a thermal model to a corresponding structural model has been performed numerous times through the RST project lifecycle, with improvements in the accuracy, verification, and effort sought throughout. This paper describes some of the recent improvements to the process, including: capture of the visualization parameters, automatic generation of the mapped images for both the thermal and structural model groupings, and reduction in the effort to assemble the full set of mapped temperatures. These upgrades have greatly reduced the manual effort associated with thermal mapping and allowed for faster turn-around of Integrated Modeling predictions.

Thermal Mapping

Mars Sample Retrieval Lander Thermal Protection System Design

The Mars Sample Return (MSR) Sample Retrieval Lander (SRL) was slated to launch in 2031 and enter Mars’ atmosphere after a 15-month cruise. After several iterations of vehicle design and trajectories, the latest mission architecture included a 4.72-meter diameter entry capsule entering the Martian atmosphere at 8 km/s, marking a 3.5x increase in kinetic energy when entering the atmosphere in comparison to Mars 2020. Designed to be the heaviest and fastest vehicle to enter Mars’ atmosphere, SRL required slim mass margins, and as such, the thermal protection system (TPS) design methodology needed to be tailored appropriately. The entry capsule aeroshell is composed of a heatshield, backshell, parachute support cone, and parachute lid, as shown in Fig. 1.

Hannah Alpert

Thermalization and criticality on an analogue–digital quantum simulator

Abstract Understanding how interacting particles approach thermal equilibrium is a major challenge of quantum simulators 1,2 . Unlocking the full potential of such systems towards this goal requires flexible initial state preparation, precise time evolution and extensive probes for final state characterization. Here we present a quantum simulator comprising 69 superconducting qubits that supports both universal quantum gates and high-fidelity analogue evolution, with performance beyond the reach of classical simulation in cross-entropy benchmarking experiments. This hybrid platform features more versatile measurement capabilities compared with analogue-only simulators, which we leverage here to reveal a coarsening-induced breakdown of Kibble–Zurek scaling predictions 3 in theXYmodel, as well as signatures of the classical Kosterlitz–Thouless phase transition 4 . Moreover, the digital gates enable precise energy control, allowing us to study the effects of the eigenstate thermalization hypothesis 5–7 in targeted parts of the eigenspectrum. We also demonstrate digital preparation of pairwise-entangled dimer states, and image the transport of energy and vorticity during subsequent thermalization in analogue evolution. These results establish the efficacy of superconducting analogue–digital quantum processors for preparing states across many-body spectra and unveiling their thermalization dynamics.

Science & Technology - Other Topics

ResStock Measure Documentation: Residential Two-Stage Geothermal Heat Pump (4.0 COP, 20.5 EER) With Light Envelope Improvements

This report is part of series describing a variety of different ResStock(TM) measures. "Measures" refers to energy efficiency retrofits that can be applied to buildings during modeling. This documentation covers the "Residential Two-Stage Geothermal Heat Pump (4.0 COP, 20.5 EER) With Light Envelope Improvements" measure upgrade methodology and briefly discusses key results. All results can be accessed on the ResStock Open Energy Data Initiative "End-Use Load Profiles for the U.S. Building Stock" data lake and on the data viewer at resstock.nlr.gov.

15 GEOTHERMAL ENERGY

Using Open Innovation in Reducing Risk to Crews

In the exploration of destinations outside of Earth's neighborhood, specifically Mars, scientific and engineering inquiries have occurred by two means; observations from satellites and observations by landed spacecraft. Satellite observations (Mariner, MRO, Mars Odyssey, provide global-scale spatial and temporal data while landed spacecraft (Viking, Mars Pathfinder, Spirit, Opportunity, Phoenix Mars Lander) investigate highly localized areas of the surface of the planet. In preparation for human exploration, extensive knowledge of the surface and atmospheric environments should be known before the first human leaves Earth. The primary goal of performing reconnaissance on Mars on a sub-global scale is to know as much as possible about the environment to which crews will be subjected. At the current rate of launching and landing probes to Mars, it will take a very long time to understand the surface and atmospheric conditions associated with the regions where prospective crews may land. Meanwhile electronics and electrical systems are rapidly getting smaller. One can argue that to acquire the knowledge of the region, one must take hundreds, maybe thousands of measurements simultaneously. One means to perform such a task is to deploy a swarm of sensors. Such a swarm would perform an in-situ assessment of the region. Imagine a close flyby mission to Mars for example, where mini- to micro-sensors are deposited into the atmosphere over half an orbit or more. The sensors, captured by the atmospheric drag and Martian gravity slowly descend buffeted about by Martian winds and weather until they settle on the surface a great time later (think of how long dust takes to settle). As they descend they communicate a vast array of data; temperature, chemistry, pressure, radiation dose, electric or magnetic properties from a region of the planet and an individual sensor need not measure the same quantity as its neighbors. Initially, they could move at the whim of the environment but later versions could have locomotion or propulsion mechanisms. Humans wouldn't need to decide where the sensors go, the sensors do that for themselves. This is a key strength of a sensor swarm. The intelligence relies on the group not on a decision maker on earth. Real time sensor inputs direct what the swarm considers most interesting to investigate resulting in emergent behavior. We issued a $20,000 challenge to the global innovators to provide solutions as to how such a swarm could be initialized and by what protocols and methodologies by which they operate. Over 400 innovators from 49 countries took a look at the problem, with three receiving partial awards for solutions.

Mel Ferebee

Behavior of Ullage Bubbles During Blowdown in Low-g Experiment (BUBBLE): Overview of a Cryogenic Tank Depressurization Test

Behavior of Ullage Bubbles during Blowdown in Low-g Experiment (BUBBLE) is a cryogenic tank depressurization drop tower experiment currently being designed at NASA Glenn Research Center. There is a need for liquid level rise data while venting a cryogenic propellant tank below the liquid saturation pressure in a reduced gravity environment. When a cryogenic tank is vented to a vapor pressure below the liquid saturation pressure, bubbles become entrained in the liquid causing the bulk liquid-vapor interface to rise. In reduced gravity, bubble rise velocity is diminished leading to a larger liquid level rise compared to a 1g environment. The purpose of the experiment is to gain further understanding of tank depressurization fluid physics and obtain high-fidelity data for model validation in 1g and reduced gravity environments. On-orbit cryogenic propellant tanks operating at high fill levels must efficiently manage venting operations to avoid the risk of liquid entrainment in the vent line, which could lead to asymmetric control thruster loads, freezing and clogging, and loss of liquid propellant. Validated models could be used to design settling and venting profiles to reduce risk and increase efficiency for cryogenic storage and transfer operations.

tank venting