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NASA NTRS2016

A Giant Radio Halo in a Low-Mass Sz-selected Galaxy Cluster: ACT-CLJ0256.5+0006

We present the detection of a giant radio halo (GRH) in the Sunyaev-Zel'dovich (SZ)- selected merging galaxy cluster ACT-CL J0256.5+ 0006 (z = 0.363), observed with the Giant Metrewave Radio Telescope at 325 and 610 MHz. We find this cluster to host a faint (S610 = 5.6 +/- 1.4mJy) radio halo with an angular extent of 2.6 arcmin, corresponding to 0.8 Mpc at the cluster redshift, qualifying it as a GRH. J0256 is one of the lowest mass systems, M500, SZ = (5.0 +/- 1.2) × 10(exp14) M, found to host a GRH. We measure the GRH at lower significance at 325 MHz (S325 = 10.3 +/- 5.3mJy), obtaining a spectral index measurement of α610 325 = 1.0+ 0.7 − 0.9. This result is consistent with the mean spectral index of the population of typical radio haloes, alpha = 1.2 +/- 0.2. Adopting the latter value, we determine a 1.4 GHz radio power of P1.4 GHz = (1.0 +/- 0.3) × 10(exp 24)W/Hz, placing this cluster within the scatter of known scaling relations. Various lines of evidence, including the intracluster medium morphology, suggest that ACT-CL J0256.5+ 0006 is composed of two subclusters. We determine a merger mass ratio of 7:4, and a line-of-sight velocity difference of v⊥ = 1880 +/- 210 km/s. We construct a simple merger model to infer relevant time-scales in the merger. From its location on the P1.4GHz-LX scaling relation, we infer that we observe ACT-CL J0256.5+ 0006 just before first core crossing.

Knowles, Kendra↗
DOE OSTI2024

Astronomical Spectroscopy with Skipper CCDs: First Results from a Skipper CCD Focal Plane Prototype at SIFS

We present the first on-sky results from an ultra-low-readout-noise Skipper CCD focal plane prototype for the SOAR Integral Field Spectrograph (SIFS). The Skipper CCD focal plane consists of four 6k $\times$ 1k, 15 $\mu$m pixel, fully-depleted, $p$-channel devices that have been thinned to $\sim$250 $\mu$m, backside processed, and treated with an anti-reflective coating. These Skipper CCDs were configured for astronomical spectroscopy, i.e., a single-sample readout noise $< 4.3$\,e$^-$\,rms/pixel, the ability to achieve multi-sample readout noise $\ll 1\,$e$^-$\,rms/pix, full-well capacities $\sim$40,000--65,000 e$^-$, low dark current and charge transfer inefficiency ($\sim 2$ $\times$ $10^{-4}$ e$^-$/pixel/s and 3.44 $\times$ $10^{-7}$, respectively), and an absolute quantum efficiency of $\gtrsim 80\%$ between 450\,nm and 980\,nm ($\gtrsim 90\%$ between 600\,nm and 900\,nm). We optimize the readout sequence timing to achieve sub-electron noise ($\sim 0.5$\,e$^-$\,rms/pix) and photon-counting ($\sim 0.22$\,e$^-$\,rms/pix) readout noise over an area of 2k $\times$ 4k and 110 $\times$ 4k pixels, respectively in a readout time of $\lesssim 17$min. We observed two Lyman-$\alpha$ emitting quasars (HB89\,1159$+$123 and QSO\,J1621$–$0042) at redshift $z \sim 3.5$, two moderate redshift galaxy clusters (CL\,J1001$+$0220 and SPT-CL\,J2040$-$4451), an emission line galaxy at $z = 0.3239$, a candidate member star of the Bo\"{o}tes~II ultra-faint dwarf galaxy, and five CALSPEC spectrophotometric standard stars (HD074000, HD60753, HD106252, HD101452, HD200654). We present charge-quantized, photon-counting observation of the quasar HB89\,1159$+$123 and show the detector sensitivity increase for faint spectral features. We demonstrate signal-to-noise performance improvement for SIFS for observations in the low-background, readout-noise-dominated regime. We outline preliminary scientific studies that will leverage the SIFS-Skipper CCD data to derive new cosmological measurements in the context of dark matter and galaxy evolution.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1993

Searching for Lyman alpha emission from a possible Zel'dovich pancake

The detection of 2 x 10(exp 14) solar mass of neutral hydrogen at a redshift of 3.397 has been reported. Top-down theories of structure formation predict such a mass of hydrogen collapsing to form a protocluster of galaxies. We sought to observe this object in Lyman-alpha, which could be produced through ionization by the metagalactic ionizing radiation field or through internal ionization processes. On 29 Apr. 1992, the region of the reported HI emission for 1800 seconds with the 1.3 meter McGraw-Hill reflector at Michigan-Dartmouth-M.I.T. Observatory was observed. Because the H1 emission reported has a transverse scale of 300 sec, a 1/3.06 reducing camera and a Thomson CCD were used to obtain a field of view of about 600 sec by 840 sec. A filter 88 A wide, centered at 5354 A was used; Lyman-alpha emission at z = 3.4 is redshifted to 5347 A. In order to avoid saturating the CCD with a bright star in the field, nine 200 second exposures were taken. The combination of these images shows no obvious extended Lyman-alpha emission at a level of about 28 magnitudes per square arcsecond. The field observed also shows a distant cluster of galaxies. In order to determine if the cluster could in any way be associated with the cloud of neutral hydrogen at z = 3.4, we sought to estimate its redshift from the size and magnitude of the galaxies and of the cluster as a whole. Omega = 1 and H(sub O) = 50 km s(sup -1) Mpc(sup -1) were adopted; our redshift estimates range from z = 0.2 to z = 0.6. The cluster is clearly not associated with the HI cloud at z = 3.4.

Cox, Caroline↗
NASA NTRS1992

Planetary Camera observations of NGC 1275 - Discovery of a central population of compact massive blue star clusters

The discovery of a population of bright blue pointlike sources within 5 kpc of the nucleus of NGC 1275 using HST Planetary Camera observations is reported. The typical object has MV of about -12 to -14. They are all blue, with V - R of less than about 0.3. The color distribution and lack of excess H-alpha emission are consistent with nearly all being continuum sources. Many sources are unresolved even with the HST and consequently have sizes of less than about 15 pc. It is suggested that these are young star clusters that will evolve to look like globular clusters. They are bluer than any clusters seen in the Milky Way or M87, and brighter than the blue clusters seen in the LMC. Ages of several hundred million years or less and corresponding masses of 10 exp 5 - 10 exp 8 solar masses are derived.

Holtzman, Jon A.↗
NASA NTRS1990

Starburst outflows from nearby galaxies

Starburst outflows from NGC 5461, 1569 and M82 are discussed. The Sc I galaxy, M101, is reknowned for the kpc-size superassociations of star clusters and HII regions that dominate its spiral arms. NGC 5461 is one of the brightest of these superassociations, rivaling the Large Magellanic Cloud in H alpha luminosity. The NGC 5461 superassociation is dominated by a single unresolved HII region of outstanding luminosity (approx. 1000 Orion nebulae). Detailed examination of corresponding continuum images indicates that only the southern plume has any sort of stellar counterpart. The other plumes are clearly diffuse with no underlying hot stars. An image of NGC 1569 is discussed. Besides showing the peculiar arm noted by Zwicky (1971) and the filamentary extensions to the North and South (as noted by Hodge 1974), this image also reveals two arc-like features of diffuse ionized gas to the South. Both arcs are concentric with the bright center of the galaxy - where the super star clusters, A and B are located. The inner arc (Arc 1) appears to follow the same curve as the SW arm thus suggesting that the two features represent limb-brightened fragments of vast superbubble that was blown out by a central starburst sometime in the past. As the classic starburst galaxy, M82 displays all the luminous hallmarks of intense high-mass star formation and outflow activity. The diffuse H alpha and x ray emitting gas along the minor axis provides especially good evidence for a bipolar outflow of hot gas which is shock heating the swept-up interstellar medium (ISM) to temperatures of approx. 10(exp 4) K. An image shows the H alpha emission within the disk and along the minor axis. Another image shows the same field in the light of near-infrared. Both figures are based on charge coupled device images taken with the McGraw-Hill 1.3 m telescope (Waller 1989). The longer wavelength emission clearly shows a more extended morphology along the major axis. The morphological discrepancy is most likely due to the greater obscuration by dust suffered by the H alpha photons. A third image shows the map of visual extinction that researchers derive from a pixel-by-pixel comparison of the (SIII) and H alpha fluxes. The greatest extinctions are evident along an arc that includes two especially obscured regions on opposite sides of the bursting nucleus.

Waller, William H.↗
NASA NTRS2016

A Giant Radio Halo in a Low-Mass SZ-Selected Galaxy Cluster: ACT-CL J0256.5+0006

We present the detection of a giant radio halo (GRH) in the Sunyaev-Zel'dovich (SZ)-selected merging galaxy cluster ACT-CL J0256.5+0006 (zeta = 0.363), observed with the Giant Metrewave Radio Telescope at 325 MHz and 610 MHz. We find this cluster to host a faint (S(sub 610) = 5.6 +/- 1.4 mJy) radio halo with an angular extent of 2.6 arcmin, corresponding to 0.8 Mpc at the cluster redshift, qualifying it as a GRH. J0256 is one of the lowest-mass systems, M(sub 500,SZ) = (5.0 +/- 1.2) x 10(sup14) solar mass foud to host a GRH. We measure the GRH at lower significance at 325 MHz (S(sub 325) = 10.3 +/- 5.3 mJy), obtaining a spectral index measurement of alpha sup 610 sub 325 = 1.0(sup +0.7)(sub 0.9). This result is consistent with the mean spectral index of the population of typical radio halos, alpha = 1.2 +/- 0.2. Adopting the latter value, we determine a 1.4 GHz radio power of P(sub 1.4GHz) = (1.0 +/- 03) x 10(sup 24) W Hz(sup -1), placing this cluster within the scatter of known scaling relations. Various lines of evidence, including the ICM morphology, suggest that ACT-CL J0256.5+0006 is composed of two subclusters. We determine a merger mass ratio of 7:4, and a line-of-sight velocity difference of perpendicular = 1880 +/- 210 km s(sup -1). We construct a simple merger model of infer relevant time-scales in the merger. From its location on the P1.4GHz-L(sub x) scaling relation, we infer that we observe ACT-CL J0256.5+0006 just before first core crossing.

core crossing↗
NASA NTRS1988

Lyman-alpha clouds as a relic of primordial density fluctuations

Primordial density fluctuations are studied using a CDM model and primordial clouds some of which are expanding, driven by pressure gradients created when the medium is photionized, and some of which are massive enough to continue collapsing in spite of the pressure. Normalization of CDM models to the clustering properties on large scales are used to predict the parameters of collapsing clouds of subgalactic mass at early epochs. It is shown that the abundance and dimensions of these clouds are comparable to those of the Lyman-alpha systems. The evolutionary history of the clouds is computed, utilizing a spherically symmetric hydrodynamics code with the dark matter treated as a collisionless fluid, and the H I column density distribution is evaluated as a function of N(H I) and redshift. The observed cloud parameters come out naturally in the CDM model and suggest that Lyman-alpha clouds are the missing link between primordial density fluctuations and the formation of galaxies.

Bond, J. R.↗
NASA NTRS1982

Two-dimensional spectral classifications for O stars in the southern Milky Way

Spectral classifications in the two-dimensional system are given for 53 additional O stars in the southern hemisphere. A number of these stars are members of the interesting clusters NGC 3324, Trumpler 14/16, NGC 3603, and NGC 6334, which are discussed in particular. A 4-m H-alpha photograph of the remarkable nebulosities associated with NGC 6334 is reproduced.

Walborn, N. R.↗
NASA NTRS1987

Measurements of the cosmic background radiation

Maps of the large scale structure (theta is greater than 6 deg) of the cosmic background radiation covering 90 percent of the sky are now available. The data show a very strong 50-100 sigma (statistical error) dipole component, interpreted as being due to our motion, with a direction of alpha = 11.5 + or - 0.15 hours, sigma = -5.6 + or - 2.0 deg. The inferred direction of the velocity of our galaxy relative to the cosmic background radiation is alpha = 10.6 + or - 0.3 hours, sigma = -2.3 + or - 5 deg. This is 44 deg from the center of the Virgo cluster. After removing the dipole component, the data show a galactic signature but no apparent residual structure. An autocorrelation of the residual data, after substraction of the galactic component from a combined Berkeley (3 mm) and Princeton (12 mm) data sets, show no apparent structure from 10 to 180 deg with a rms of 0.01 mK(sup 2). At 90 percent confidence level limit of .00007 is placed on a quadrupole component.

Lubin, P.↗
NASA NTRS1994

Two-fluid simulations of galaxy formation

We investigate the formation of galaxies and larger structure with a simulation modeling two gravitationally coupled fluids representing dark matter and baryons. The baryon gas dynamics are calculated with a smoothed particle hydrodynamics (SPH) method, and the physics modeled includes thermal pressure, shock heating, and radiative cooling. We simulate a 16 Mpc periodic cube with 64(exp 3) particles in each fluid and 10% baryon mass fraction. We confirm, for the first time experimentally, disk formation as a natural consequence of hierarchical clustering in a large-scale cosmological environment. The majority of isolated galaxies exhibit centrifugally supported disks. A power-law relation between cold baryonic mass and maximum rotation velocity is found, M varies as nu(sub rot)(exp alpha) with alpha = 2.5 after correcting for differential numerical resolution. Both the spatial and velocity distributions of the simulated galaxies are biased with respect to the dark matter. A counts-in-cells analysis indicates that an unphysical degree of merging in the central cluster is likely responsible for the antibias signal in the correlation function. A robust, scale-dependent velocity bias is measured. The ratio of galaxy to dark matter pairwise velocity dispersions on a scale of 1 Mpc is 0.7. The amplitude is only mildly dependent on redshift or mass cutoff and scales with separation as r(exp 0.2). The degree to which these results depend on numerical parameters is discussed. Mass resolution plays a key role in controlling the resulting fraction of cold, dense baryons. The mass fraction associated with galaxies decreases by a factor of approximately greater than 3 when the mass per particle is increased by a factor 8. Photoionization and energy input from supernova will have to be included to determine more carefully the fraction of highly dissipated material and the characteristics of the stellar component of galaxies.

Evrard, August E.↗
NASA NTRS2004

An 80 Mpc Filament of Galaxies at Redshift z=2.38

We present the detection of 34 Lyman-alpha emission-line galaxy candidates in a 80 x 80 x 60 co-moving Mpc region surrounding the known z=2.38 galaxy cluster J2143-4423. We have confirmed 15 of these candidates in followup spectroscopy with 2dF at the AAT. The peak space density is a factor of 4 greater than that found by field samples at similar redshifts. The distribution of these galaxy candidates contains several 5-10 Mpc scale voids. We compare our observations with mock catalogs derived from the VIRGO consortium Lambda-CDM N-body simulations. Fewer than 1\% of the mock catalogues contains voids as large as we observe. Our observations thus tentatively suggest that the galaxy distribution at redshift 2.38 contains larger voids than predicted by current models. The distribution of galaxies suggests a filament or cross-section of a great wall at least 80 x 10 Mpc in transverse extent. Three of the candidate galaxies and one previously discovered galaxy have the large luminosities and extended morphologies of "Lyman-alpha blobs". X-ray properties and physical characteristics of those blobs will be discussed in an accompanying poster by Williger et al.

Woodgate, B.↗
DOE OSTI2025

The z ∼ 1.03 Merging Cluster SPT-CL J0356–5337: New Strong Lensing Analysis with HST and MUSE

We present a strong lensing analysis and reconstruct the mass distribution of SPT-CL J0356−5337, a galaxy cluster at redshift z = 1.034. Our model supersedes previous models by making use of new multiband Hubble Space Telescope data and Multi-Unit Spectroscopic Explorer (MUSE) spectroscopy. We identify two additional lensed galaxies to inform a more well-constrained model using 12 sets of multiple images in five separate lensed sources. The three previously known sources were spectroscopically confirmed by G. Mahler et al. at redshifts of z = 2.363, z = 2.364, and z = 3.048. We measured the spectroscopic redshifts of two of the newly discovered arcs using MUSE data, at z = 3.0205 and z = 5.3288. We increase the number of cluster member galaxies by a factor of 3 compared to previous work. We also report the detection of extended Lyα emission from several background galaxies. We measure the total projected mass density of the two major subcluster components, one dominated by the brightest cluster galaxy and the other by a compact group of luminous red galaxies. We find ${M}_{{\rm{B}}{\rm{C}}{\rm{G}}}(\lt 80\,\rm{kpc})=3.9{3}_{-0.14}^{+0.21}\times 1{0}^{13}$ M⊙ and ${M}_{{\rm{LRG}}}(\lt 80\,\rm{kpc})=2.9{2}_{-0.23}^{+0.16}\times 1{0}^{13}$ M⊙, yielding a mass ratio of $1.3{5}_{-0.08}^{+0.16}$ . The strong lensing constraints offer a robust estimate of the projected mass density regardless of modeling assumptions; allowing more substructure in this line of sight does not change the results or conclusions. Our results corroborate the conclusion that SPT-CL J0356−5337 is dominated by two mass components and is likely undergoing a major merger on the plane of the sky.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1975

Lattice model theory of the equation of state covering the gas, liquid, and solid phases

The three stable states of matter and the corresponding phase transitions were obtained with a single model. Patterned after Lennard-Jones and Devonshires's theory, a simple cubic lattice model containing two fcc sublattices (alpha and beta) is adopted. The interatomic potential is taken to be the Lennard-Jones (6-12) potential. Employing the cluster variation method, the Weiss and the pair approximations on the lattice gas failed to give the correct phase diagrams. Hybrid approximations were devised to describe the lattice term in the free energy. A lattice vibration term corresponding to a free volume correction is included semi-phenomenologically. The combinations of the lattice part and the free volume part yield the three states and the proper phase diagrams. To determine the coexistence regions, the equalities of the pressure and Gibbs free energy per molecule of the coexisting phases were utilized. The ordered branch of the free energy gives rise to the solid phase while the disordered branch yields the gas and liquid phases. It is observed that the triple point and the critical point quantities, the phase diagrams and the coexistence regions plotted are in good agreement with the experimental values and graphs for argon.

Bonavito, N. L.↗
NASA NTRS1994

The metallicity of M4: Accurate spectroscopic fundamental parameters for four giants

High-quality spectra, covering the wavelength range 5480 to 7080 A, have been obtained for four giant stars in the intermediate-metallicity CN-bimodal globular cluster M4 (NGC 6121). We have employed a model atmosphere analysis that is entirely independent from cluster parameters, such as distance, age, and reddening, in order to derive accurate values for the stellar parameters effective temperature, surface gravity, and microturbulence, and for the abundance of iron relative to the Sun, (Fe/H), and of calcium, Ca/H, for each of the four stars. Detailed radiative transfer and statistical equilibrium calculations carried out for iron and calcium suggest that departures from local thermodynamic equilibrium are not significant for the purposes of our analysis. The spectroscopically derived effective temperatures for our program stars are hotter by about 200 K than existing photometric calibrations suggest. We conclude that this is due partly to the uncertain reddening of M4 and to the existing photometric temperature calibration for red giants being too cool by about 100 K. Comparison of our spectroscopic and existing photometric temperatures supports the prognosis of a significant east-west gradient in the reddening across M4. Our derived iron abundances are slightly higher than previous high-resolution studies suggested; the differences are most probably due to the different temperature scale and choice of microturbulent velocities adopted by earlier workers. The resulting value for the metallicity of M4 is (Fe/H )(sub M4) = -1.05 + or - 0.15. Based on this result, we suggest that metallicities derived in previous high-dispersion globular cluster abundance analyses could be too low by 0.2 to 0.3 dex. Our calcium abundances suggest an enhancement of calcium, an alpha element, over iron, relative to the Sun, in M4 of (Ca/H) = 0.23.

Drake, J. J.↗
NASA NTRS1994

Near-infrared imaging of FSC 10214+4724 with the W. M. Keck Telescope

Near-infrared observations of the z = 2.286 IRAS source FSC 10214+4724, made with the near-infrared camera on the W. M. Keck Telescope, are reported. Deep broad-band images at 2.15 and 1.27 micrometers, and narrow-band images at 2.165 and 2.125 micrometers with 0.6 sec to 0.9 sec seeing show that FSC 10214+4724 consists of at least three distinct components in a compact group of galaxies. The source of the infrared luminosity appears to be in a strongly interacting galaxy that has a luminosity of approximately 100 times that of a present-day L* galaxy. The interaction suggests and 'age' of this galaxy of approximately equal to 10(exp 9) yr. The H-alpha emission is resolved as a source of diameter approximately equal to 5 kpc, suggesting that a starburst contributes to the observed H-alpha emission. There is an excess of objects in the FSC 10214+4724 field that could represent galaxies in an associated cluster.

Matthews, K.↗
NASA NTRS1996

Fault Diagnosis of Power Systems Using Intelligent Systems

The power system operator's need for a reliable power delivery system calls for a real-time or near-real-time Al-based fault diagnosis tool. Such a tool will allow NASA ground controllers to re-establish a normal or near-normal degraded operating state of the EPS (a DC power system) for Space Station Alpha by isolating the faulted branches and loads of the system. And after isolation, re-energizing those branches and loads that have been found not to have any faults in them. A proposed solution involves using the Fault Diagnosis Intelligent System (FDIS) to perform near-real time fault diagnosis of Alpha's EPS by downloading power transient telemetry at fault-time from onboard data loggers. The FDIS uses an ANN clustering algorithm augmented with a wavelet transform feature extractor. This combination enables this system to perform pattern recognition of the power transient signatures to diagnose the fault type and its location down to the orbital replaceable unit. FDIS has been tested using a simulation of the LeRC Testbed Space Station Freedom configuration including the topology from the DDCU's to the electrical loads attached to the TPDU's. FDIS will work in conjunction with the Power Management Load Scheduler to determine what the state of the system was at the time of the fault condition. This information is used to activate the appropriate diagnostic section, and to refine if necessary the solution obtained. In the latter case, if the FDIS reports back that it is equally likely that the faulty device as 'start tracker #1' and 'time generation unit,' then based on a priori knowledge of the system's state, the refined solution would be 'star tracker #1' located in cabinet ITAS2. It is concluded from the present studies that artificial intelligence diagnostic abilities are improved with the addition of the wavelet transform, and that when such a system such as FDIS is coupled to the Power Management Load Scheduler, a faulty device can be located and isolated from the rest of the system. The benefit of these studies provides NASA with the ability to quickly restore the operating status of a space station from a critical state to a safe degraded mode, thereby saving costs in experimentation rescheduling, fault diagnostics, and prevention of loss-of-life.

Momoh, James A.↗
DOE OSTI2021

Constraining Cosmic Microwave Background Temperature Evolution With Sunyaev–Zel’Dovich Galaxy Clusters from the Atacama Cosmology Telescope

The Sunyaev–Zel'dovich (SZ) effect introduces a specific distortion of the blackbody spectrum of the cosmic microwave background (CMB) radiation when it scatters off hot gas in clusters of galaxies. The frequency dependence of the distortion is only independent of the cluster redshift when the evolution of the CMB radiation is adiabatic. Here, using 370 clusters within the redshift range 0.07 ≲ z ≲ 1.4 from the largest SZ-selected cluster sample to date from the Atacama Cosmology Telescope, we provide new constraints on the deviation of CMB temperature evolution from the standard model $\alpha ={0.017}_{-0.032}^{+0.029}$, where $T(z)={T}_{0}{\left(1+z\right)}^{1-\alpha }$. This result is consistent with no deviation from the standard adiabatic model. Combining it with previous, independent data sets we obtain a joint constraint of α = –0.001 ± 0.012. Attributing deviation from adiabaticity to the decay of dark energy, this result constrains its effective equation of state ${w}_{\mathrm{eff}}=-{0.998}_{-0.010}^{+0.008}$.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Materials Data on NbSeF9 by Materials Project

NbSeF9 is alpha Po structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three NbSeF9 clusters. there are two inequivalent Nb5+ sites. In the first Nb5+ site, Nb5+ is bonded to six F1- atoms to form NbF6 octahedra that share corners with three SeF6 octahedra. The corner-sharing octahedra tilt angles range from 2–3°. There is three shorter (1.89 Å) and three longer (2.00 Å) Nb–F bond length. In the second Nb5+ site, Nb5+ is bonded to six F1- atoms to form NbF6 octahedra that share corners with three equivalent SeF6 octahedra. The corner-sharing octahedral tilt angles are 1°. There is three shorter (1.89 Å) and three longer (2.00 Å) Nb–F bond length. There are two inequivalent Se4+ sites. In the first Se4+ site, Se4+ is bonded to six F1- atoms to form distorted SeF6 octahedra that share corners with three NbF6 octahedra. The corner-sharing octahedra tilt angles range from 1–3°. There are a spread of Se–F bond distances ranging from 1.73–2.37 Å. In the second Se4+ site, Se4+ is bonded to six F1- atoms to form distorted SeF6 octahedra that share corners with three equivalent NbF6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are three shorter (1.74 Å) and three longer (2.36 Å) Se–F bond lengths. There are twelve inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Nb5+ atom. In the second F1- site, F1- is bonded in a distorted linear geometry to one Nb5+ and one Se4+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Nb5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Nb5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Se4+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Se4+ atom. In the seventh F1- site, F1- is bonded in a single-bond geometry to one Nb5+ atom. In the eighth F1- site, F1- is bonded in a distorted linear geometry to one Nb5+ and one Se4+ atom. In the ninth F1- site, F1- is bonded in a single-bond geometry to one Se4+ atom. In the tenth F1- site, F1- is bonded in a single-bond geometry to one Se4+ atom. In the eleventh F1- site, F1- is bonded in a distorted linear geometry to one Nb5+ and one Se4+ atom. In the twelfth F1- site, F1- is bonded in a distorted linear geometry to one Nb5+ and one Se4+ atom.

36 MATERIALS SCIENCE↗