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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Tilt Modulation Distortions in Wave Topography Measured by a Scanning Radar Altimeter

Work continues on estimating tilt modulation distortions in the wave topography measured by a scanning radar altimeter. To quantify this effect, a two-dimensional simulation has been performed in the cross-track plane only which assumed that sinusoidal waves of constant wavelength propagate in the cross-track direction (and are infinitely long-crested in the along-track direction). The initial results reported earlier for a Gaussian surface scattering model indicated that when the highest reasonable value of mss is used in the simulation (the Plant limit of 0.08), the nadir values of the ratio of the apparent to actual wave height are the same as for the omnidirectional scattering case. But as the off-nadir angle increased, the apparent wave height increased and became larger than the actual wave height by about 10 degrees off-nadir. And the shorter the wavelength, the larger the apparent wave height increase. This represented a systematic over-estimate of the wave amplitude for waves propagating in the cross-track direction. For lower values of mss the situation worsened. The simulation has been improved by incorporating actual variations of backscattered power with incidence angle measured by the SRA instead of the Gaussian model. The resulting distortion was about half that originally reported. The 3-dimensional simulation to model waves propagating at various azimuthal angles relative to the cross-track plane is still in progress. The results of this model will be verified by comparing them with Scanning Radar Altimeter (SRA) data and optimum correction procedures will be developed. An assessment of the improved 2-dimensional model indicates that the distortion will generally be small in the data taken during the Southern Ocean Waves Experiment (SOWEX) presently be analyzed. But tilt modulation effects are of great concern for SRA data collected during the 1998 hurricane season since the minimum aircraft altitude was 1.5 km and it frequently flew higher. For a given wave length and steepness, the effect increases with increasing aircraft altitude, and is larger for waves propagating in the cross-track direction, which was generally the situation during the hurricane flights.

Walsh, Edward J.↗
NASA NTRS2006

Electrostatic Properties of PE and PTFE Subjected to Atmospheric Pressure Plasma Treatment; Correlation of Experimental Results with Atomistic Modeling

The use of an atmospheric pressure glow discharge (APGD) plasma was used at KSC to increase the hydrophilicity of spaceport materials to enhance their surface charge dissipation and prevent possible ESD in spaceport operations. Significant decreases in charge decay times were observed after tribocharging the materials using the standard KSC tribocharging test. The polarity and amount of charge transferred was dependent upon the effective work function differences between the respective materials. In this study, polyethylene (PE) and polytetrafluoroethylene (PTFE) were exposed to a He+O2 APGD. The pre and post treatment surface chemistry was analyzed by X-ray photoelectron spectroscopy and contact angle measurements. Semi-empirical and ab initio calculations were performed to correlate the experimental results with some plausible molecular and electronic structure features of the oxidation process. For the PE, significant surface oxidation was observed, as indicated by XPS showing C-O, C=O, and O-C=O bonding, and a decrease in the surface contact angle from 98.9 deg to 61.2 deg. For the PTFE, no C-O bonding appeared and the surface contact angle increased indicating the APGD only succeeded in cleaning the PTFE surface without affecting the surface structure. The calculations using the PM3 and DFT methods were performed on single and multiple oligomers to simulate a wide variety of oxidation scenarios. Calculated work function results suggest that regardless of oxidation mechanism, e.g. -OH, =0 or a combination thereof, the experimentally observed levels of surface oxidation are unlikely to lead to a significant change in the electronic structure of PE and that its increased hydrophilic properties are the primary reason for the observed changes in its electrostatic behavior. The calculations for PTFE argue strongly against significant oxidation of that material, as confirmed by the XPS results.

Trigwell, Steve↗
NASA NTRS1981

The effect of data analysis techniques on the interpretation of wide-angle longwave radiation measurements

Three different data analysis techniques - shape factor, parameter estimation, and deconvolution - have been applied to the same set of satellite radiation measurements to determine their effect on the estimated radiation field. The measurements are from a wide-angle, horizon-to-horizon, nadir-pointing sensor. The shape factor technique reduces each measurement to a radiant exitance at the top of the atmosphere by simple division by a constant. The parameter estimation technique processes all measurements together as a batch and defines the radiant exitance as a least-squares fit to the data. The deconvolution technique takes advantage of the fact that spherical harmonics are the eigenfunctions of the measurement operator. All three techniques are derived, and their assumptions, advantages and disadvantages are discussed. Their results are compared globally, zonally, regionally and on a spatial spectrum basis. All three techniques give comparable results for global parameters; however, results on a regional scale were quite different. The standard deviations of the regional differences in radiant exitance varied from 7.4 to 13.5 W/sq m. Of the three techniques, the parameter estimation technique produced the best regional results and is the choice of the author.

Green, R. N.↗
NASA NTRS1983

First-order wetting transition at a liquid-vapor interface

Evidence from reflectance and contact angle measurements is presented that three-phase mixtures of i-C3H7OH-C7F14 exhibit a first-order wetting phase transition at the liquid-vapor interface at 38 C. Equilibration phenomena support this interpretation. Ellipsometry was used to measure the apparent thickness of the intruding layer in the three-phase mixture. At temperatures slightly above the wetting temperature T(w), the intruding layer's thickness is several hundred angstroms and its variation with temperature is extremely weak. Below T(w), three-phase contact can occur between the vapor and both the upper and lower liquid phases; one of the angles which characterizes this contact has a very simple temperature dependence. The thickness of the intruding layer, monitored as the solutions approached equilibrium, is found to depend quite weakly on the height spanned by the upper liquid phase in the vicinity of a first-order wetting transition.

Schmidt, J. W.↗
NASA NTRS1974

Measurement error analysis in determination of small-body gravity fields

We consider analytically the use of existing instrumentation in determining asteroid gravity fields from orbiting spacecraft. Asteroids (Eros as an example) are modeled as homogeneous triaxial ellipsoids, with gravitational potential given by a sperical-harmonic expansion. Mass concentrations are modeled as point masses. The character of spacecraft orbits about asteroids is discussed, along with detectibility of gravitational coefficients and of mass concentrations. A Kalman-filtering treatment of the observation process, for Eros as example, shows that using DSN tracking and onboard gravity gradiometry, radar altimetry, and celestial angle measurements, a single orbit yields asteroid mass to 0.03% and coefficients C20 to C44 to 1% accuracies.

Friedlander, A. L.↗
NASA NTRS1992

Three-dimensional unstructured grid generation via incremental insertion and local optimization

Algorithms for the generation of 3D unstructured surface and volume grids are discussed. These algorithms are based on incremental insertion and local optimization. The present algorithms are very general and permit local grid optimization based on various measures of grid quality. This is very important; unlike the 2D Delaunay triangulation, the 3D Delaunay triangulation appears not to have a lexicographic characterization of angularity. (The Delaunay triangulation is known to minimize that maximum containment sphere, but unfortunately this is not true lexicographically). Consequently, Delaunay triangulations in three-space can result in poorly shaped tetrahedral elements. Using the present algorithms, 3D meshes can be constructed which optimize a certain angle measure, albeit locally. We also discuss the combinatorial aspects of the algorithm as well as implementational details.

Barth, Timothy J.↗
NASA NTRS1971

Earth orbiting Sisyphus system study

The feasibility of employing an optical meteoroid detecting system, known as Sisyphus, to measure the near-earth particulates from an earth orbiting vehicle, is considered. A Sisyphus system can discriminate between natural and man-made particles since the system measures orbital characteristics of particles. A Sisyphus system constructed for the Pioneer F/G missions to Jupiter is used as the baseline, and is described. The amount of observing time which can be obtained by a Sisyphus instrument launched into various orbits is determined. Observation time is lost when, (1) the Sun is in or near the field of view, (2) the lighted Earth is in or near the field of view, (3) the instrument is eclipsed by the Earth, and (4) the phase angle measured at the particle between the forward scattering direction and the instrument is less than a certain critical value. The selection of the launch system and the instrument platform with a dedicated, attitude controlled payload package is discussed. Examples of such systems are SATS and SOLRAD 10(C) vehicles, and other possibilities are AVCO Corp. S4 system, the OWL system, and the Delta Payload Experiment Package.

Jurkevich, I.↗
NASA NTRS1993

Method and apparatus for deflection measurements using eddy current effects

A method and apparatus for inserting and moving a sensing assembly with a mechanical positioning assembly to a desired remote location of a surface of a specimen under test and measuring angle and/or deflection by sensing the change in the impedance of at least one sensor coil located in a base plate which has a rotatable conductive plate pivotally mounted thereon so as to uncover the sensor coil(s) whose impedance changes as a function of deflection away from the center line of the base plate in response to the movement of the rotator plate when contacting the surface of the specimen under test is presented. The apparatus includes the combination of a system controller, a sensing assembly, an eddy current impedance measuring apparatus, and a mechanical positioning assembly driven by the impedance measuring apparatus to position the sensing assembly at a desired location of the specimen.

Chern, Engmin J.↗
NASA NTRS1988

Surface flow visualization of separated flows on the forebody of an F-18 aircraft and wind-tunnel model

A method of in-flight surface flow visualization similar to wind-tunnel-model oil flows is described for cases where photo-chase planes or onboard photography are not practical. This method, used on an F-18 aircraft in flight at high angles of attack, clearly showed surface flow streamlines in the fuselage forebody. Vortex separation and reattachment lines were identified with this method and documented using postflight photography. Surface flow angles measured at the 90 and 270 degrees meridians show excellent agreement with the wind tunnel data for a pointed tangent ogive with an aspect ratio of 3.5. The separation and reattachment line locations were qualitatively similar to the F-18 wind-tunnel-model oil flows but neither the laminar separation bubble nor the boundary-layer transition on the wind tunnel model were evident in the flight surface flows. The separation and reattachment line locations were in fair agreement with the wind tunnel data for the 3.5 ogive. The elliptical forebody shape of the F-18 caused the primary separation lines to move toward the leeward meridian. Little effect of angle of attack on the separation locations was noted for the range reported.

Fisher, David F.↗
NASA NTRS1998

The Space Interferometry Mission

The Space Interferometry Mission (SIM) is the next major space mission in NASA's Origins program after SIRTF. The SIM architecture uses three Michelson interferometers in low-earth orbit to provide 4 microarcsecond precision absolute astrometric measurements on approx. 40,000 stars. SIM will also provide synthesis imaging in the visible waveband to a resolution of 10 milliarcsecond, and interferometric nulling to a depth of 10(exp -4). A near-IR (1-2 micron) capability is being considered. Many key technologies will be demonstrated by SIM that will be carried over directly or can be readily scaled to future Origins missions such as TPF. The SIM spacecraft will carry a triple Michelson interferometer with baselines in the 10 meter range. Two interferometers act as high precision trackers, providing attitude information at all time, while the third one conducts the science observations. Ultra-accurate laser metrology and active systems monitor the systematic errors and to control the instrument vibrations in order to reach the 4 microarcsecond level on wide-angle measurements. SIM will produce a wealth of new astronomical data. With an absolute positional precision of 4 microarcsecond, SIM will improve on the best currently available measures (the Hipparcos catalog) by 2 or 3 orders of magnitude, providing parallaxes accurate to 10% and transverse velocities to 0.2 km/s anywhere in the Galaxy, to stars as faint as 20th magnitude. With the addition of radial velocities, knowledge of the 6-dimension phase space for objects of interest will allow us to attack a wide array of previously inaccessible problems such as: search for planets down to few earth masses; calibration of stellar luminosities and by means of standard candles, calibration of the cosmic distance scale; detecting perturbations due to spiral arms, disk warps and central bar in our galaxy; probe of the gravitational potential of the Galaxy, several kiloparsecs out of the galactic plane; synthesis imaging of circumstellar disks around young stellar objects; imaging the narrow-line regions of AGNs in the optical; direct distance determination of a half dozen nearby spiral galaxies using rotational kinematics, thereby sidestepping reddening and metallicity issues in the calibration of distance estimators like Tully-Fisher; imaging exozodiacal dust disks (when operating in its nulling mode, SIM will be sensitive, at a distance of (beta) Pic (20 pc), to scales ranging from 0.2 to 5 AU).

Unwin, Stephen C.↗
DOE OSTI2024

An integrated approach to derive relative permeability from capillary pressure

Surface tension affects all aspects of fluid flow in porous media. Through measurements of surface tension interaction under multiphase conditions, a relative permeability curve can be determined. Relative permeability is a numerical description of the interaction between two or more fluids and the porous media. It is a critical parameter for various tools that characterize subsurface multiphase flow systems, such as numerical simulation for carbon sequestration, oil and gas development, and groundwater contamination remediation. Therefore, it is critical to get a good statistical distribution of relative permeability in the porous media under study. Empirical formula for determining relative permeability from capillary pressure are already well established but do not provide the needed flexibility that is required to match laboratory-derived relative permeability curves. By expanding the existing methods for calculating relative permeability from capillary pressure data, it is possible to create both two and three-phase relative permeability curves. Mercury intrusion capillary pressure (MICP) data from the Morrow 'B' Sandstone coupled with interfacial tension and contact angle measurements were used to create a suite of relative permeability curves. Furthermore, these curves were then calibrated to a small sample of existing laboratory curves to elucidate common fitting parameters for the formation that were then used to create relative permeability curves from MICP data that does not have an associated laboratory-measured relative permeability curve.

58 GEOSCIENCES↗
DOE OSTI2025

Simulation insights into wetting properties of hydrogen-brine-clay for hydrogen geo-storage

Hydrogen geo-storage is attracting substantial interdisciplinary interest as a cost-effective and sustainable option for medium- and long-term storage. Hydrogen can be stored underground in diverse formations, including aquifers, salt caverns, and depleted oil and gas reservoirs. The wetting dynamics of the hydrogen-brine-rock system are critical for assessing both structural and residual storage capacities, and ensuring containment safety. Through molecular dynamics simulations, we explore how varying concentrations of cushion gases (CO 2 or CH 4 ) influence the wetting properties of hydrogen-brine-clay systems under geological conditions (15 MPa and 333 K). We employed models of talc and the hydroxylated basal face of kaolinite (kaoOH) as clay substrates. Our findings reveal that the effect of cushion gases on hydrogen-brine-clay wettability is strongly dependent on the clay-brine interactions. Notably, CO 2 and CH 4 reduce the water wettability of talc in hydrogen-brine-talc systems, while exerting no influence on the wettability of hydrogen-brine-kaoOH systems. Detailed analysis of free energy of cavity formation near clay surfaces, clay-brine interfacial tensions, and the Willard-Chandler surface for gas-brine interfaces elucidate the molecular mechanisms underlying wettability changes. Our simulations identify empirical correlations between wetting properties and the average free energy required to perturb a flat interface when clay-brine interactions are less dominant. Here, our thorough thermodynamic analysis of rock-fluid and fluid-fluid interactions, aligning with key experimental observations, underscores the utility of simulated interfacial properties in refining contact angle measurements and predicting experimentally relevant properties. These insights significantly enhance the assessment of gas geo-storage potential. Prospectively, the approaches and findings obtained from this study could form a basis for more advanced multiscale simulations that consider a range of geological and operational variables, potentially guiding the development and improvement of geo-storage systems in general, with a particular focus on hydrogen storage.

25 ENERGY STORAGE↗
NASA NTRS2011

Airborne Radar Interferometric Repeat-Pass Processing

Earth science research often requires crustal deformation measurements at a variety of time scales, from seconds to decades. Although satellites have been used for repeat-track interferometric (RTI) synthetic-aperture-radar (SAR) mapping for close to 20 years, RTI is much more difficult to implement from an airborne platform owing to the irregular trajectory of the aircraft compared with microwave imaging radar wavelengths. Two basic requirements for robust airborne repeat-pass radar interferometry include the ability to fly the platform to a desired trajectory within a narrow tube and the ability to have the radar beam pointed in a desired direction to a fraction of a beam width. Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) is equipped with a precision auto pilot developed by NASA Dryden that allows the platform, a Gulfstream III, to nominally fly within a 5 m diameter tube and with an electronically scanned antenna to position the radar beam to a fraction of a beam width based on INU (inertial navigation unit) attitude angle measurements.

Hensley, Scott↗
DOE OSTI2026

Measurement of the angle between jet axes in Pb-Pb collisions at $\sqrt{s_{NN}}$ =5.02 TeV

This paper presents the first measurement of the angle between different jet axes (denoted as Δ⁢𝑅 axis ) in Pb-Pb collisions. The measurement is carried out in the 0–10 % most-central events at $\sqrt{s_{NN}}$ = 5.02 TeV. Jets are assembled by clustering charged particles at midrapidity using the anti-𝑘 T algorithm with resolution parameters 𝑅 = 0.2 and 0.4 and transverse momenta in the intervals 40 < 𝑝$^{ch jet}_{T}$ < 140 GeV/𝑐 and 80 < 𝑝$^{ch jet}_{T}$ < 140 GeV/𝑐, respectively. Measurements at these low transverse momenta enhance the sensitivity to quark-gluon plasma (QGP) effects. A comparison to models implementing various mechanisms of jet energy loss in the QGP suggests that the observed narrowing of the Pb-Pb distribution relative to 𝑝𝑝 can be explained if quark-initiated jets are more likely to emerge from the medium than gluon-initiated jets. These new measurements disfavor intrajet 𝑝 T broadening as implemented in a simple model calculation with the Baier-Dokshitzer-Mueller-Peigne-Schiff formalism for energy loss in the QGP. The comparison of Pb-Pb and 𝑝𝑝 collisions shows sensitivity to the angular scale at which the QGP can resolve two independent splittings, favoring mechanisms that incorporate incoherent energy loss.

Acharya, S. [LPC] (ORCID:0000000292135329)↗
DOE OSTI2024

Modulating the Contact Angle between Nonpolar Polymers and SiO 2 Nanoparticles

Polymer–nanoparticle interactions play an important role in determining the morphology and properties of polymer nanocomposites and controlling the polymeric reactions involving heterogeneous catalysts. Here, in this study, we modulate the interactions between nonpolar polymers and nanoparticles by modifying the nanoparticle surface chemistry and quantify the interaction strength through direct contact angle measurements. We investigate the interactions of three nonpolar polymers, polystyrene, polyethylene, and polycyclooctene, with silica nanoparticles whose surface chemistry has been modified by atomic layer deposition of titania and calcium carbonate and by alkyl silanization. Significant differences in polymer–nanoparticle interactions are observed, which can be attributed to differences in the polarizability of the polymers and oxide surface composition. Compared to fully hydrogenated polycyclooctene, polycyclooctene is shown to have stronger interactions with most metal oxides; however, this trend is reversed following alkyl silanization of the silica nanoparticles, which makes the surface of the particles less polar. These differences in interactions can be leveraged to make polymer nanocomposites with unique properties and enable the selective conversion of polymers without the need for separations.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Persistent Classification: Understanding Adversarial Attacks by Studying Decision Boundary Dynamics

ABSTRACT There are a number of hypotheses underlying the existence of adversarial examples for classification problems. These include the high‐dimensionality of the data, the high codimension in the ambient space of the data manifolds of interest, and that the structure of machine learning models may encourage classifiers to develop decision boundaries close to data points. This article proposes a new framework for studying adversarial examples that does not depend directly on the distance to the decision boundary. Similarly to the smoothed classifier literature, we define a (natural or adversarial) data point to be ( γ , σ)‐stable if the probability of the same classification is at least for points sampled in a Gaussian neighborhood of the point with a given standard deviation . We focus on studying the differences between persistence metrics along interpolants of natural and adversarial points. We show that adversarial examples have significantly lower persistence than natural examples for large neural networks in the context of the MNIST and ImageNet datasets. We connect this lack of persistence with decision boundary geometry by measuring angles of interpolants with respect to decision boundaries. Finally, we connect this approach with robustness by developing a manifold alignment gradient metric and demonstrating the increase in robustness that can be achieved when training with the addition of this metric.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Bio-Oil Impact on Water Diffusion and Durability of Bitumen: Influence of Aging and Salinity

Bio-oils derived from inexpensive biomass offer environmentally friendly options for modifying bitumen for improved durability or rejuvenating aged material, although their impact on bitumen moisture resistance can be mixed. A better understanding of water diffusion into bitumen and its interactions with bio-oil compounds would aid the development of effective bio-oils. In this study, the effect of water exposure on bio-oil-modified bitumen blends was examined by de-wetting contact angle measurements and differential FTIR spectroscopy. The bio-oils improved the anti-stripping behavior of the bitumen but also increased water absorption which could weaken cohesive strength. Short-term thermal aging increased water diffusion for all bitumen blends including the control, probably due to the presence of more oxidized compounds. Negative peaks of alkanes and polar groups in the differential FTIR data suggest the co-diffusion of surfactant molecules towards the bitumen-water interface. Basic pH increased de-wetting of some bitumen blends from silica, possibly by attacking the silica surface itself. The presence of salt in solution altered the bitumen surface composition through the formation of salt complexes with bitumen or bio-oil compounds. In particular, the formation of calcium-carboxylate complexes appeared to greatly improve anti-stripping effects of bio-oils. Water diffusion into most of the bitumen blends was insensitive to pH or salt concentration except for a few notable outliers. Identifying the compounds responsible for increasing or decreasing water diffusion in these outlier cases would be valuable developing future bio-oil formations that avoid or promote those compounds.

Hung, Albert M.↗