Effects of intentional impurities on the thermal stability of nitronium perchlorate.
Intentional impurities effects on nitronium perchlorate thermal stability explained by change in cation and anion vacancies
Gorzynski, C. S., Jr.↗
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Effect of salts and organic solvents on the activity of Halobacterium cutirubrum catalase.
Salts and organic solvents effect on halophile Halobacterium cutirubrum catalase, noting enzyme activity inhibition by cation and anion
Lanyi, J. K.↗
Studies in fundamental chemistry of fuel cell reactions Quarterly report, 1 Oct. - 31 Dec. 1969
Anion adsorption at solid electrolyte interfaces, organic compounds for high energy batteries, oxygen dissolution reaction, sodium diffusion in crystals and related studies for fuel cells
Bockris, J. OM.↗
Study directed at development of an implantable biotelemetry ion detector
A literature search was conducted to currently update known information in the field of ion-selective electrodes. The review attempts to identify present trends in cation and anions selective electrodes pertinent to the area of bioimplantable units. An electronic circuit was designed to provide the high impedance interface between the ion-selective sensors and signal-processing equipment. The resulting design emphasized the need for low power and miniaturization. Many of the circuits were constructed and used to evaluate the ion-selective electrodes. A cuvette capable of holding the ion-selective and the reference electrodes was designed and constructed. This equipment was used to evaluate commercially available ion-selective electrodes and the electrodes designed and constructed in the study. The results of the electrode tests are included.
Hanley, L. D.↗
Absorbing-sphere model for calculating ion-ion recombination total cross sections.
An 'absorbing-sphere' model based on the Landau-Zener method is set up for calculating the upper limit thermal energy (300 K) reaction rate and the energy dependence of the total cross sections. The crucial parameter needed for the calculation is the electron detachment energy for the outer electron on the anion. It is found that the cross sections increase with decreasing electron detachment energy.
Olson, R. E.↗
Mechanical behavior of polycrystalline ceramics: Brittle fracture of SiC-Si3N4 materials
Research on the fracture behavior of silicon nitride and silicon carbide is reported along with the role of anion impurities in the fabrication and behavior of magnesium oxide. The results of a survey of crack propagation in SiC and Si3N4 are presented. Studies in the following areas are reported: development of a fracture toughness testing technique, constant moment beam, microcrack examination, and etching techniques.
Ceipold, M. H.↗
Solubilities of noble gases in magnetite - Implications for planetary gases in meteorites.
Solubilities of noble gases in magnetite were determined by growing magnetite in a noble-gas atmosphere between 450 and 700 K. Henry's law is obeyed at pressures up to .01 atm for He, Ne, Ar and up to .00001 atm for Kr, Xe, with the following distribution coefficients at 500 K: He 0.042, Ne 0.016, Ar 3.6, Kr 1.3, Xe 0.88, some 100 to 100,000 times higher than previous determinations on silicate and fluoride melts. Apparent heats of solution are in sharp contrast with earlier determinations on melts which were small and positive, but are comparable to the values for clathrates. Presumably the gases are held in anion vacancies.
Lancet, M. S.↗
Mechanical behavior of polycrystalline ceramics: Brittle fracture of Si C - Si3N4 materials
The results are described of the final stage of the research involving the role of anions in the behavior of magnesium oxide, as well as the continued efforts of the fracture behavior of silicon nitride materials. These efforts, particularly the first, are further sub-divided in subsections describing individual types of behavior of materials.
Leipold, M. H.↗
Synthesis of calcium superoxide
Efforts to prepare Ca(O2) sub 2 from reactions of calcium compounds with 100% O3 and with O(D-1) atoms generated by photolysis of O3 at 2537 A are described. Samples of Ca(OH) sub 2, CaO, CaO2, Ca metal, and mixtures containing suspected impurities to promote reaction have been treated with excess O3 under static and flow conditions in the presence and absence of UV irradiation. Studies with KO2 suggest that the superoxide anion is stable to radiation at 2537 A but reacts with oxygen atoms generated by the photolysis of O3 to form KO3. Calcium superoxide is expected to behave in an analogous.
Rewick, R. T.↗
Matrix isolation technique for the study of some factors affecting the partitioning of trace elements
The factors that affect the preferred positions of cations in ionic solid solutions were investigated utilizing vibrational spectroscopy. Solid solutions of the sulfate and chromate ions codoped with La(+3) and Ca(+2) in a KBr host lattice were examined as a function of the polyvalent cation concentration. The cation-anion pairing process was found to be random for Ca(+2), whereas the formation of La(+3)-SO4(-2) ion pairs with a C2 sub v bonding geometry is highly preferential to any type of La(+3)-CrO4(-2) ion pair formation. The relative populations of ion pair site configurations are discussed in terms of an energy-entropy competition model which can be applied to the partition of trace elements during magmatic processes.
Grzybowski, J. M.↗
Elasticity of some mantle crystals structures. III - Spessartite-almandine garnet
Measurements of the pressure dependence of the elastic constants of spessartite-almandine garnet are given. The basis for velocity systematics among the available natural and synthetic garnet data is then examined. As for any dense oxide, the natural anion in garnet is dominant in size. The ionic sizes of the cations in the various sites are used to determine the extent to which it might be expected that garnets of different chemical formulas are analogous in elastic properties. The results are used to predict that the elastic velocities in garnet-transformed MgSiO3 are the same as those in pyrope (Mg3Al2Si3O12).
Wang, H.↗
Radiative transitions involving the /2p2/ 3Pe metastable autodetaching state of H-
A Hylleraas bound-state wave function and 1s-2s-2p close-coupling continuum wave functions are used to calculate the absorption coefficient for the free-bound transition of H(1s) + e + quantum to a H anion in (2p2,3Pe) and the differential emission rate for the inverse process. The absorption and emission spectral maximum is found to be at a photon wavelength of 1219.5 A, an improvement of 2 A on other calculations. This free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.
Jacobs, V. L.↗
Improved ion exchange membrane
Membrane, made from commercially-available hollow fibers, is used in reverse osmosis, or dialysis. Fiber has skin layers which pass only small molecules. Macromolecules cannot penetrate skin. Fibers can also be used to remove other undesirable anions, such as phosphate, sulfate, carbonate, and uranium in form of uranium-sulfate complex.
Rembaum, A.↗
Covalent bonding of polycations to small polymeric particles
Process produces small spherical polymeric particles which have polycations bound to them. In emulsion form, particles present large positively charged surface which is available to absorb polyanions. This properly can be used in removing heparin from blood or bile acids from the digestive tract. Other anions, such as DNA and RNA, can also be removed from aqueous solutions.
Rembaum, A.↗
Development and evaluation of ion exchange hollow fibers
An ion exchange hollow fiber impregnated with a vinylpyridine base was developed. The basic exchange resin used to impart the necessary permselectivity to the hollow fiber is a copolymer of vinylpyridine and dibromoethane prepared according to Rembaum. A slight pressure was used to impregnate the exchange monomer mixture into the void structure of the fiber wall, and with maintenance of subambient temperatures, the rate of cross-linking is slow enough to allow the growing polymer to permeate the wall structure before significant increase in polymer molecular weight. These ion exchange fibers are produced from polyacrylonitrile hollow fibers with an appropriate wall structure that enables the impregnating vinylpyridine monomer mixture to form a truly semipermeable anion barrier after curing.
Smith, J. K.↗
Research for preparation of cation-conducting solids by high-pressure synthesis and other methods
It was shown that two body-centered-cubic skeleton structures, the Im3 KSbO3 phase and the defect-pyrochlore phase A(+)B2X6, do exhibit fast Na(+)-ion transport. The placement of anions at the tunnel intersection sites does not impede Na(+)-ion transport in (NaSb)3)(1/6 NaF), and may not in (Na(1+2x)Ta2 5F)(Ox). The activation energies are higher than those found in beta-alumina. There are two possible explanations for the higher activation energy: breathing of the bottleneck (site face or edge) through which the A(+) ions must pass on jumping from one site to another may be easier in a layer structure and/or A(+)-O bonding may be stronger in the cubic structures because the O(2-) ion bonds with two (instead of three) cations of the skeleton. If the former explanation is dominant, a lower activation energy may be achieved by optimizing the lattice parameter. If the latter is dominant, a new structural principle may have to be explored.
Goodenough, J. B.↗
Photochemical synthesis of simple organic free radicals on simulated planetary surfaces - An ESR study
Electron spin resonance (ESR) spectroscopy provided evidence for formation of hydroxyl radicals during ultraviolet photolysis (254 nm) at -170 C of H2O adsorbed on silica gel or of silica gel alone. The carboxyl radical was observed when CO or CO2 or a mixture of CO and CO2 adsorbed on silica gel at -170 C was irradiated. The ESR signals of these radicals slowly disappeared when the irradiated samples were warmed to room temperature. However, reirradiation of CO or CO2, or the mixture CO and CO2 on silica gel at room temperature then produced a new species, the carbon dioxide anion radical, which slowly decayed and was identical with that produced by direct photolysis of formic acid adsorbed on silica gel. The primary photochemical process may involve formation of hydrogen and hydroxyl radicals. Subsequent reactions of these radicals with adsorbed CO or CO2 or both yield carboxyl radicals, CO2H, the precursors of formic acid. These results confirm the formation of formic acid under simulated Martian conditions and provide a mechanistic basis for gauging the potential importance of gas-solid photochemistry for chemical evolution on other extraterrestrial bodies, on the primitive earth, and on dust grains in the interstellar medium.
Tseng, S.-S.↗
Coacervate-like microspheres from lysine-rich proteinoid
Microspheres form isothermally from lysine-rich proteinoid when the ionic strength of the solution is increased with NaCl or other salts. Studies with different monovalent anions and with polymers of different amino acid composition indicate that charge neutralization and hydrophobic bonding contribute to microsphere formation. The particles also form in sea water, especially if heated or made slightly alkaline. The microspheres differ from those made from acidic proteinoid but resemble coacervate droplets in some ways (isothermal formation, limited stability, stabilization by quinone, uptake of dyes). Because the constituent lysine-rich proteinoid is of simulated prebiotic origin, the study is interpreted to add emphasis to and suggest an evolutionary continuity for coacervation phenomena.
Rohlfing, D. L.↗