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At least 199 records · Page 11

Southern Ocean Aerosols Field Campaign Report

Atmospheric processes over the Southern Ocean have a profound influence on regional and global climate. This is a part of the world where global climate models perform particularly poorly, with models persistently overpredicting the amount of sunlight reaching the Earth's surface (Regayre et al. 2020). A major challenge when trying to improve the representation of atmospheric processes in this part of the globe is the scarcity of observations capable of constraining our understanding. During 2024/25 a U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility field campaign (CAPE-k) deployed a suite of instrumentation at the kennaook/Cape Grim atmospheric monitoring station in Tasmania, Australia to provide detailed cloud-aerosol observations in this region in order to address the greatest source of uncertainty in climate models – atmospheric aerosols and how they influence cloud formation (Carslaw et al. 2013). In support of the ARM observations, an Australian Research Council (ARC)-funded project “Southern Ocean aerosols: sources, sinks and impact on cloud properties,” led by the Queensland University of Technology, complemented the ARM measurements with a suite of chemical measurements at the kennaook/Cape Grim site in northwestern Tasmania to provide more information on the processes controlling aerosol formation and growth. The deployment of the University of York LIF-SO2 instrument (Temple et al. 2025) in the ARM mobile facility container was part of this chemistry-focused deployment. Increased observational efforts are critical for understanding sources and sinks of Southern Ocean aerosols, in particular the role of marine micro-organisms (phytoplankton, algae) on aerosols formation, their properties and growth, cloud droplet formation, and the conversion of cloud droplets to ice crystals and precipitation. The observational focus of the ARC-funded project is aerosol chemical composition and their gaseous precursors. The remote nature of the Southern Ocean poses a significant analytical challenge when studying gaseous precursors, as low concentrations are often below the limits of detection of commercial instrumentation. Historically this has meant that observations have had to be time-averaged over days to weeks to achieve the limits of detection required. Although useful when considering overall average levels of aerosol precursors, this time-averaging obscures temporal variability that can provide insight into the controlling processes. Over recent years advances in analytical techniques have made high-time-resolution measurements of key gas-phase aerosol precursors achievable with sufficiently low limits of detection.

54 ENVIRONMENTAL SCIENCES↗

HPTLC Analysis and Chemical Composition of Selected Melaleuca Essential Oils

Tea tree oil (TTO) is a volatile essential oil obtained by distillation, mainly from the Australian native plant Melaleuca alternifolia (Maiden & Betche) Cheel (Myrtaceae). In this study, a comparative analysis of the chemical constituents of seven tea tree oils (M. alternifolia) and four other Melaleuca spp. oils (M. cajuputi, (M Ca ), two chemotypes of M. quinquenervia, (M Ne and M Ni ), and M. ericifolia (M Ro )) was carried out using gas chromatography–mass spectrometry (GC-MS) and high-performance thin-layer chromatography (HPTLC). Among the seven TTOs, terpinen-4-ol (37.66–44.28%), γ-terpinene (16.42–20.75%), α-terpinene (3.47–12.62%), α-terpineol (3.11–4.66%), and terpinolene (2.75–4.19%) were the most abundant compounds. On the other hand, the most abundant compounds of the other Melaleuca oils varied, such as 1,8-cineole (64.63%) in M Ca oil, (E)-nerolidol (48.40%) and linalool (33.30%) in M Ne oil, 1,8-cineole (52.20%) in M Ni oil, and linalool (38.19%) and 1,8-cineole (27.57%) in M Ro oil. HPTLC fingerprinting of Melaleuca oils enabled the discrimination of TTO oils from other Melaleuca spp. oils. Variation was observed in the profile of the R f values among EOs. The present study shows that HPTLC is one of the best ways to identify and evaluate the quality control in authenticating TTOs, other Melaleuca EOs, or EOs from other species within the Myrtaceae.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Transits of Known Planets Orbiting a Naked-eye Star

Some of the most scientifically valuable transiting planets are those that were already known from radial velocity (RV) surveys. This is primarily because their orbits are well characterized and they preferentially orbit bright stars that are the targets of RV surveys. The Transiting Exoplanet Survey Satellite (TESS) provides an opportunity to survey most of the known exoplanet systems in a systematic fashion to detect possible transits of their planets. HD 136352 (Nu{sup 2} Lupi) is a naked-eye (V = 5.78) G-type main-sequence star that was discovered to host three planets with orbital periods of 11.6, 27.6, and 108.1 days via RV monitoring with the High Accuracy Radial velocity Planet Searcher (HARPS) spectrograph. We present the detection and characterization of transits for the two inner planets of the HD 136352 system, revealing radii of 1.482{sub −0.056}{sup +0.058} R {sub ⊕} and 2.608{sub −0.077}{sup +0.078} R {sub ⊕} for planets b and c, respectively. We combine new HARPS observations with RV data from the Keck/High Resolution Echelle Spectrometer and the Anglo-Australian Telescope, along with TESS photometry from Sector 12, to perform a complete analysis of the system parameters. The combined data analysis results in extracted bulk density values of ρ{sub b}=7.8{sub −1.1}{sup +1.2} g cm{sup −3} and ρ{sub c}=3.50{sub −0.36}{sup +0.41} g cm{sup −3} for planets b and c, respectively, thus placing them on either side of the radius valley. The combination of the multitransiting planet system, the bright host star, and the diversity of planetary interiors and atmospheres means this will likely become a cornerstone system for atmospheric and orbital characterization of small worlds.

79 ASTRONOMY AND ASTROPHYSICS↗

The Most Metal-poor Stars in the Inner Bulge

The bulge is the oldest component of the Milky Way. Since numerous simulations of Milky Way formation have predicted that the oldest stars at a given metallicity are found on tightly bound orbits, the Galaxy’s oldest stars are likely metal-poor stars in the inner bulge with small apocenters (i.e., R {sub apo} ≲ 4 kpc). In the past, stars with these properties have been impossible to find due to extreme reddening and extinction along the line of sight to the inner bulge. We have used the mid-infrared metal-poor star selection of Schlaufman & Casey (2014) on Spitzer/Galactic Legacy Infrared Mid-Plane Survey Extraordinaire data to overcome these problems and target candidate inner bulge metal-poor giants for moderate-resolution spectroscopy with Anglo-Australian Telescope/AAOmega. We used those data to select three confirmed metal-poor giants ([Fe/H] = −3.15, −2.56, −2.03) for follow-up high-resolution Magellan/Magellan Inamori Kyocera Echelle spectroscopy. A comprehensive orbit analysis using Gaia DR2 astrometry and our measured radial velocities confirms that these stars are tightly bound inner bulge stars. We determine the elemental abundances of each star and find high titanium and iron-peak abundances relative to iron in our most metal-poor star. We propose that the distinct abundance signature we detect is a product of nucleosynthesis in the Chandrasekhar-mass thermonuclear supernova of a CO white dwarf accreting from a helium star with a delay time of about 10 Myr. Even though chemical evolution is expected to occur quickly in the bulge, the intense star formation in the core of the nascent Milky Way was apparently able to produce at least one Chandrasekhar-mass thermonuclear supernova progenitor before chemical evolution advanced beyond [Fe/H]∼−3.

79 ASTRONOMY AND ASTROPHYSICS↗

An ASKAP Search for a Radio Counterpart to the First High-significance Neutron Star–Black Hole Merger LIGO/Virgo S190814bv

We present results from a search for a radio transient associated with the LIGO/Virgo source S190814bv, a likely neutron star–black hole (NSBH) merger, with the Australian Square Kilometre Array Pathfinder. We imaged a 30 deg 2 field at ΔT = 2, 9, and 33 days post-merger at a frequency of 944 MHz, comparing them to reference images from the Rapid ASKAP Continuum Survey observed 110 days prior to the event. Each epoch of our observations covers 89% of the LIGO/Virgo localization region. We conducted an untargeted search for radio transients in this field, resulting in 21 candidates. For one of these, AT2019osy, we performed multiwavelength follow-up and ultimately ruled out the association with S190814bv. All other candidates are likely unrelated variables, but we cannot conclusively rule them out. We discuss our results in the context of model predictions for radio emission from NSBH mergers and place constrains on the circum-merger density and inclination angle of the merger. This survey is simultaneously the first large-scale radio follow-up of an NSBH merger, and the most sensitive widefield radio transients search to-date.

79 ASTRONOMY AND ASTROPHYSICS↗

Tropospheric and stratospheric wildfire smoke profiling with lidar: mass, surface area, CCN, and INP retrieval

We present retrievals of tropospheric and stratospheric height profiles of particle mass, volume, surface area, and number concentrations in the case of wildfire smoke layers as well as estimates of smoke-related cloud condensation nuclei (CCN) and ice-nucleating particle (INP) concentrations from backscatter lidar measurements on the ground and in space. Conversion factors used to convert the optical measurements into microphysical properties play a central role in the data analysis, in addition to estimates of the smoke extinction-to-backscatter ratios required to obtain smoke extinction coefficients. The set of needed conversion parameters for wildfire smoke is derived from AERONET observations of major smoke events, e.g., in western Canada in August 2017, California in September 2020, and southeastern Australia in January–February 2020 as well as from AERONET long-term observations of smoke in the Amazon region, southern Africa, and Southeast Asia. The new smoke analysis scheme is applied to CALIPSO observations of tropospheric smoke plumes over the United States in September 2020 and to ground-based lidar observation in Punta Arenas, in southern Chile, in aged Australian smoke layers in the stratosphere in January 2020. These case studies show the potential of spaceborne and ground-based lidars to document large-scale and long-lasting wildfire smoke events in detail and thus to provide valuable information for climate, cloud, and air chemistry modeling efforts performed to investigate the role of wildfire smoke in the atmospheric system.

54 ENVIRONMENTAL SCIENCES↗

Ozone depletion in the Arctic and Antarctic stratosphere induced by wildfire smoke

Abstract. A record-breaking stratospheric ozone loss was observed over the Arctic and Antarctica in 2020. Strong ozone depletion occurred over Antarctica in 2021 as well. The ozone holes developed in smoke-polluted air. In this article, the impact of Siberian and Australian wildfire smoke (dominated by organic aerosol) on the extraordinarily strong ozone reduction is discussed. The study is based on aerosol lidar observations in the North Pole region (October 2019–May 2020) and over Punta Arenas in southern Chile at 53.2∘ S (January 2020–November 2021) as well as on respective NDACC (Network for the Detection of Atmospheric Composition Change) ozone profile observations in the Arctic (Ny-Ålesund) and Antarctica (Neumayer and South Pole stations) in 2020 and 2021. We present a conceptual approach on how the smoke may have influenced the formation of polar stratospheric clouds (PSCs), which are of key importance in the ozone-depleting processes. The main results are as follows: (a) the direct impact of wildfire smoke below the PSC height range (at 10–12 km) on ozone reduction seems to be similar to well-known volcanic sulfate aerosol effects. At heights of 10–12 km, smoke particle surface area (SA) concentrations of 5–7 µm2 cm−3 (Antarctica, spring 2021) and 6–10 µm2 cm−3 (Arctic, spring 2020) were correlated with an ozone reduction in terms of ozone partial pressure of 0.4–1.2 mPa (about 30 % further ozone reduction over Antarctica) and of 2–3.5 mPa (Arctic, 20 %–30 % reduction with respect to the long-term springtime mean). (b) Within the PSC height range, we found indications that smoke was able to slightly increase the PSC particle number and surface area concentration. In particular, a smoke-related additional ozone loss of 1–2 mPa (10 %–20 % contribution to the total ozone loss over Antarctica) was observed in the 14–23 km PSC height range in September–October 2020 and 2021. Smoke particle number concentrations ranged from 10 to 100 cm−3 and were about a factor of 10 (in 2020) and 5 (in 2021) above the stratospheric aerosol background level. Satellite observations indicated an additional mean column ozone loss (deviation from the long-term mean) of 26–30 Dobson units (9 %–10 %, September 2020, 2021) and 52–57 Dobson units (17 %–20 %, October 2020, 2021) in the smoke-polluted latitudinal Antarctic belt from 70–80∘ S.

54 ENVIRONMENTAL SCIENCES↗

Assessing the cloud radiative bias at Macquarie Island in the ACCESS-AM2 model

Abstract. As a long-standing problem in climate models, large positive shortwave radiation biases exist at the surface over the Southern Ocean, impacting the accurate simulation of sea surface temperature, atmospheric circulation, and precipitation. Underestimations of low-level cloud fraction and liquid water content are suggested to predominantly contribute to these radiation biases. Most model evaluations for radiation focus on summer and rely on satellite products, which have their own limitations. In this work, we use surface-based observations at Macquarie Island to provide the first long-term, seasonal evaluation of both downwelling surface shortwave and longwave radiation in the Australian Community Climate and Earth System Simulator Atmosphere-only Model version 2 (ACCESS-AM2) over the Southern Ocean. The capacity of the Clouds and the Earth’s Radiant Energy System (CERES) product to simulate radiation is also investigated. We utilize the novel lidar simulator, the Automatic Lidar and Ceilometer Framework (ALCF), and all-sky cloud camera observations of cloud fraction to investigate how radiation biases are influenced by cloud properties. Overall, we find an overestimation of +9.5±33.5 W m−2 for downwelling surface shortwave radiation fluxes and an underestimation of -2.3±13.5 W m−2 for downwelling surface longwave radiation in ACCESS-AM2 in all-sky conditions, with more pronounced shortwave biases of +25.0±48.0 W m−2 occurring in summer. CERES presents an overestimation of +8.0±18.0 W m−2 for the shortwave and an underestimation of -12.1±12.2 W m−2 for the longwave in all-sky conditions. For the cloud radiative effect (CRE) biases, there is an overestimation of +4.8±28.0 W m−2 in ACCESS-AM2 and an underestimation of -7.9±20.9 W m−2 in CERES. An overestimation of downwelling surface shortwave radiation is associated with an underestimated cloud fraction and low-level cloud occurrence. We suggest that modeled cloud phase is also having an impact on the radiation biases. Our results show that the ACCESS-AM2 model and CERES product require further development to reduce these radiation biases not just in shortwave and in all-sky conditions, but also in longwave and in clear-sky conditions.

54 ENVIRONMENTAL SCIENCES↗

Cloud phase and macrophysical properties over the Southern Ocean during the MARCUS field campaign

To investigate the cloud phase and macrophysical properties over the Southern Ocean (SO), the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF2) was installed on the Australian icebreaker research vessel (R/V) Aurora Australis during the Measurements of Aerosols, Radiation, and Clouds over the Southern Ocean (MARCUS) field campaign (41 to 69° S, 60 to 160° E) from October 2017 to March 2018. To examine cloud properties over the midlatitude and polar regions, the study domain is separated into the northern (NSO) and southern (SSO) parts of the SO, with a demarcation line of 60°S. The total cloud fractions (CFs) were 77.9 %, 67.6 %, and 90.3 % for the entire domain, NSO and SSO, respectively, indicating that higher CFs were observed in the polar region. Low-level clouds and deep convective clouds are the two most common cloud types over the SO.

54 ENVIRONMENTAL SCIENCES↗

MARCUS Ice Nucleating Particle Measurements (revised 7/2020)

These data list ice nucleating particle (INP) number concentrations active in the immersion freezing mode. Aerosol filters were collected during 4 voyages of the Aurora Australis vessel from 02 November 2017 to 22 March 2018, as part of the Measurements of Aerosols, Radiation and Clouds over the Southern Ocean (MARCUS) study. These voyages transected the Southern Ocean from Hobart, Tasmania to four Australian Antarctic Division stations, including three in Antarctica. Collections were made over alternating periods of 24 and 48 hours using open-faced polycarbonate filters that were approximately 18 m MSL, sited near the AOS trailer and other AMF measurements. The volume of air filtered ranged from 19000 to 38000 standard liters per filter sample. Filters were stored and returned frozen to Colorado State University (CSU), where immersion freezing measurements over a range from 0 to -28 degC were made using the CSU Ice Spectrometer (IS). Collected particles from each filter were resuspended in filtered, deionized water, and then dispensed into the IS and cooled to obtain cumulative INP temperature spectra. Aliquots of suspensions from selected samples were also heat treated (95 degC for 20 min) to denature and deactivate biological INPs, and digested in 10% H2O2 at 95 degC under UV-B for 20 min to remove all organic carbon INPs, prior to measurement using the IS.

54 ENVIRONMENTAL SCIENCES↗

Cloud Condensation Nuclei Particle Counter from Kennaook Cape Grim

When utilizing these data from Kennaook Cape Grim please acknowledge the Australian Bureau of Meteorology and the Commonwealth Scientific and Industrial Research Organisation (CSIRO) for their long-term and continued support of the Kennaook Cape Grim Baseline Air Pollution Monitoring Station. In addition, please contact the Lead Scientists responsible for the collection of these data sets (melita.keywood@csiro.au, ruhi.humphries@csiro.au and Erin.dunne@csiro.au) to discuss collaboration and authorship opportunities.

54 ENVIRONMENTAL SCIENCES↗

Aerosol Chemical Speciation Monitor (ACSM) Time-of-Flight (ToF) from Kennaook Cape Grim

When utilizing these data from Kennaook Cape Grim please acknowledge the Australian Bureau of Meteorology and the Commonwealth Scientific and Industrial Research Organisation (CSIRO) for their long-term and continued support of the Kennaook Cape Grim Baseline Air Pollution Monitoring Station. In addition, please contact the Lead Scientists responsible for the collection of these data sets (melita.keywood@csiro.au, ruhi.humphries@csiro.au and Erin.dunne@csiro.au) to discuss collaboration and authorship opportunities.

54 ENVIRONMENTAL SCIENCES↗

Baseline status of BOM instruments at Kennaook Cape Grim

When utilizing these data from Kennaook Cape Grim please acknowledge the Australian Bureau of Meteorology and the Commonwealth Scientific and Industrial Research Organisation (CSIRO) for their long-term and continued support of the Kennaook Cape Grim Baseline Air Pollution Monitoring Station. In addition, please contact the Lead Scientists responsible for the collection of these data sets (stuart.baly@bom.gov.au, melita.keywood@csiro.au, ruhi.humphries@csiro.au and Erin.dunne@csiro.au) to discuss collaboration and authorship opportunities.

54 ENVIRONMENTAL SCIENCES↗

Ultrafine Condensation Particle Counter from Kennaook Cape Grim (a1-level)

When utilizing these data from Kennaook Cape Grim please acknowledge the Australian Bureau of Meteorology and the Commonwealth Scientific and Industrial Research Organisation (CSIRO) for their long-term and continued support of the Kennaook Cape Grim Baseline Air Pollution Monitoring Station. In addition, please contact the Lead Scientists responsible for the collection of these data sets (melita.keywood@csiro.au, ruhi.humphries@csiro.au and Erin.dunne@csiro.au) to discuss collaboration and authorship opportunities.

54 ENVIRONMENTAL SCIENCES↗

Report from Mars - Mariner IV, 1964-1965

The successful mission of Mariner IV is a most gratifying conclusion to the first generation of lunar and planetary exploration, which has been based on lightweight automatic unmanned spacecraft in constant communication with Earth, designed for lunar impact or planetary encounter. The flight of this first Mars probe is noteworthy not only for the outstanding quantity and quality of scientific data but also as the verification of large and useful advances in a number of technological areas. The Mariner Mars Project of 1964-1965 was conducted for the National Aeronautics and Space Administration by the Jet Propulsion Laboratory; it was made possible by the valued assistance and support of many government agencies, scientific institutions, and industrial concerns. Among these are NASA's Lewis Research Center (Launch Vehicle Systems Manager) and their prime contractors, Lockheed Missiles and Space Corporation and General Dynamics/Convair; Goddard Space Flight Center (Launch Operations) and other agencies at Cape Kennedy; the agencies of the Australian, South African, and Spanish governments which operate overseas tracking stations; many hundreds of American industrial contractors and vendors; and a number of scientists in various fields of endeavor. The Project was established in late 1962 with the objective of conducting scientific observations near the planet Mars and returning the data to Earth for study and analysis; secondary objectives were to develop and study the equipment and techniques involved and to make certain scientific measurements of the interplanetary environment on the way to Mars. Successful accomplishment of these objectives under the severe constraints which were a part of the mission is a tribute to every single individual who shared in the preparation and execution of the Mariner Mars Project.

MARINER IV SPACE PROBE↗