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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
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NASA NTRS1991

Rainfall estimation over oceans from scanning multichannel microwave radiometer and special sensor microwave/imager microwave data

The brightness temperature (T sub b) measured at 37 GHz shows fairly strong emission from rain, and only slight effects caused by scattering by ice above the rain clouds. At frequencies below 37 GHz, were the fov is larger and the volume extinction coefficient is weaker, it is found that the observations do not yield appreciable additional information about rain. At 85 GHz (fov = 15 km), where the volume extinction is considerably larger, direct information about rain below the clouds is usually masked. Based on the above ideas, 37 GHz observations with a 30 km fov from SMMR and SSM/I are selected to develop an empirical method for the estimation of rain rate. In this method, the statistics of the observed T sub b's at 37 GHz in a rain storm are related to the rain rate statistics in that storm. The underestimation of rain rate, arising from the inability of the radiometer to respond sensitively to rain rate above a given threshold, is rectified in this technique with the aid of two parameters that depend on the total water vapor content in the atmosphere. The retrieved rain rates compare favorably with radar observations and monthly mean global maps of rain derived from this technique over the oceans.

Prabhakara, C.↗
NASA NTRS1992

Rainfall estimation over oceans from SMMR and SSM/I microwave data

The brightness temperature (T sub b) measured at 37 GHz shows fairly strong emission from rain, and only slight effects caused by scattering by ice above the rain clouds. At frequencies below 37 GHz, where the FOV is larger and the volume extinction coefficient is weaker, it is found that the observations do not yield appreciable additional information about rain. At 85 GHz (FOV = 15 km), where the volume extinction is considerably larger, direct information about rain below the clouds is usually masked. Based on the above idea, 37 GHz observations with a 30 km FOV from SMMR and SSM/I are selected to develop an empirical method for the estimation of rain rate. In this method, the statistics of the observed T sub b's at 37 GHz in a rain storm are related to the rain rate statistics in that storm. The underestimation of rain rate, arising from the inability of the radiometer to respond sensitively to rain rate above a given threshold is rectified in this technique with the aid of two parameters that depend on the total water vapor content in the atmosphere. The retrieved rain rates compare favorably with radar observations and monthly mean global maps of rain derived from this technique over the oceans.

Prabhakara, C.↗
NASA NTRS2017

Harmonized Landsat/Sentinel-2 Reflectance Products for Land Monitoring (Invited)

Many land applications require more frequent observations than can be obtained from a single 'Landsat class' sensor. Agricultural monitoring, inland water quality assessment, stand-scale phenology, and numerous other applications all require near-daily imagery at better than 1ha resolution. Thus the land science community has begun expressing a desire for a '30-meter MODIS' global monitoring capability. One cost-effective way to achieve this goal is via merging data from multiple, international observatories into a single virtual constellation. The Harmonized Landsat/Sentinel-2 (HLS) project has been working to generate a seamless surface reflectance product by combining observations from USGS/NASA Landsat-8 and ESA Sentinel-2. Harmonization in this context requires a series of radiometric and geometric transforms to create a single surface reflectance time series agnostic to sensor origin. Radiometric corrections include a common atmospheric correction using the Landsat-8 LaSRC/6S approach, a simple BRDF adjustment to constant solar and nadir view angle, and spectral bandpass adjustments to fit the Landsat-8 OLI reference. Data are then resampled to a consistent 30m UTM grid, using the Sentinel-2 global tile system. Cloud and shadow masking are also implemented. Quality assurance (QA) involves comparison of the output 30m HLS products with near-simultaneous MODIS nadir-adjusted observations. Prototoype HLS products have been processed for approximately 7% of the global land area using the NASA Earth Exchange (NEX) compute environment at NASA Ames, and can be downloaded from the HLS web site (https://hls.gsfc.nasa.gov). A wall-to-wall North America data set is being prepared for 2018. This talk will review the objectives and status of the HLS project, and illustrate applications of high-density optical time series data for agriculture and ecology. We also discuss lessons learned from HLS in the general context of implementing virtual constellations.

Reflectance↗
NASA NTRS1995

SeaWiFS technical report series. Volume 31: Stray light in the SeaWiFS radiometer

Some of the measurements from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) will not be useful as ocean measurements. For the ocean data set, there are procedures in place to mask the SeaWiFS measurements of clouds and ice. Land measurements will also be masked using a geographic technique based on each measurment's latitude and longitude. Each of these masks involves a source of light much brighter than the ocean. Because of stray light in the SeaWiFS radiometer, light from these bright sources can contaminate ocean measurements located a variable number of pixels away from a bright source. In this document, the sources of stray light in the sensor are examined, and a method is developed for masking measurements near bright targets for stray light effects. In addition, a procedure is proposed for reducing the effects of stray light in the flight data from SeaWiFS. This correction can also reduce the number of pixels masked for stray light. Without these corrections, local area scenes must be masked 10 pixels before and after bright targets in the along-scan direction. The addition of these corrections reduces the along-scan masks to four pixels before and after bright sources. In the along-track direction, the flight data are not corrected, and are masked two pixels before and after. Laboratory measurements have shown that stray light within the instrument changes in a direct ratio to the intensity of the bright source. The measurements have also shown that none of the bands show peculiarities in their stray light response. In other words, the instrument's response is uniform from band to band. The along-scan correction is based on each band's response to a 1 pixel wide bright sources. Since these results are based solely on preflight laboratory measurements, their successful implementation requires compliance with two additional criteria. First, since SeaWiFS has a large data volume, the correction and masking procedures must be such that they can be converted into computationally fast algorithms. Second, they must be shown to operate properly on flight data. The laboratory results, and the corrections and masking procedures that derive from them, should be considered as zeroeth order estimates of the effects that will be found on orbit.

Hooker, Stanford B.↗
NASA NTRSDate not supplied

A New ML-Based Adaptive Thinning Methodology to Improve the Impact of AIRS and CrIS Assimilation on Global Tropical Cyclone Forecasts

This work builds on previous research performed by this team to improve the forecast of Tropical Cyclones (TCs) by assimilating AIRS and CrIS radiances into the NASA Global Earth Observing System (GEOS). Past published work demonstrated that the assimilation of radiances with variable density was beneficial to TC forecasting in the GEOS. In the previous setup, a fixed-size moving square named 'TC domain' was activated by the so-called TC-vitals, an international real-time message accessible to all NWP forecasting centers, that documents the existence of a TC, its estimated position, and its size. The information from TC-vitals activated a switch in the GEOS, which allowed to reduce the distance used for thinning AIRS and CrIS data inside a 15 degrees by 15 degrees moving TC domain centered on the storm, so that more data were assimilated in the vicinity of the TC during its lifetime. The methodology produced improved TC analyses and led to better forecasts, particularly related to intensity, without damaging the global forecast skill. In the new version, the adaptive thinning methodology is based on a machine-learning technique. The technique searches for TCs and creates TC masks by using cloud-top temperatures from all geostationary satellites without the need for additional information. It is being trained against the International Best Track Archive for Climate Stewardship (IBTrACS) data base. Once a TC mask is created, a switch identical to the one used in the previous adaptive thinning method is activated, allowing the GEOS to ingest more data in the TC-shaped size-changing domain that follows the storm. As of today, the team has been able to successfully assimilate data inside the ML-detected TC domains. Future work includes an improved capability of reducing false alarm rates (i.e., cloud systems that are erroneously labeled as TCs).

Oreste Reale↗
NASA NTRS1994

Reanalysis of Mariner 9 UV Spectrometer Data for Ozone, Cloud, and Dust Abundances, and Their Interaction Over Climate Timescales

Mariner 9 UV spectrometer data have been reinverted for the ozone abundance. The spectra were fit by models which covered the full range in observed solar zenith angle, cloud, dust and ozone amount, ice albedo and look angles. Errors in ozone retrieval with this data are tabulated over a range in theses conditions and are shown graphically. This work shows that significant underestimation of ozone occurred in earlier analysis of Mariner 9 data, and that much of the observed variability in Mars ozone is due to masking of ozone by clouds and dust. An in-situ measurement by balloon is recommended as it is the only technique capable of accurately inferring the ozone abundance in all conditions. Recommendations for future research are also presented. 7 manuscripts have been published in refereed journals, and three are in review. A review of these publications and presentations is in the report.

Lindner, Bernhard Lee↗
NASA NTRS2008

Reconfigurable Processing for Satellite On-Board Automatic Cloud Cover Assessment (ACCA)

Clouds have a critical role in many studies such as weather- and climate-related investigations. However, they represent a source of errors in many applications, and the presence of cloud contamination can hinder the use of satellite data. In addition, sending cloudy data to ground stations can result in an inefficient utilization of the communication bandwidth. This requires satellite on-board cloud detection capability to mask out cloudy pixels from further processing. Remote sensing satellite missions have always required smaller size, lower cost, more flexibility, and higher computational power. Reconfigurable Computers (RCs) combine the flexibility of traditional microprocessors with the power of Field Programmable Gate Arrays (FPGAs). Therefore, RCs are a promising candidate for on-board preprocessing. This paper presents the design and implementation of an RC-based real-time cloud detection system. We investigate the potential of using RCs for on-board preprocessing by prototyping the Landsat 7 ETM+ ACCA algorithm on one of the state-of-the-art reconfigurable platforms, SRC-6. It will be shown that our work provides higher detection accuracy and over one order of magnitude improvement in performance when compared to previously reported investigations.

El-Araby, Esam↗
NASA NTRS2022

Chapter 10 - Remote Sensing Measurements of Aerosol Properties

Satellite instruments have proven especially capable at monitoring the quantity of airborne particles in columns of atmosphere, globally. This chapter describes the principles of satellite measurements and retrieval algorithms, and surveys current instruments and their capabilities. We outline the issues associated with retrieval algorithms, such as surface characterization and aerosol proximity to clouds, and the challenges with interpretation of the results. The relationship between measured aerosol properties and climate-relevant aerosol properties simulated in models is outlined, as well as how measurements are used to evaluate models. Most space-based aerosol instruments are passive sensors that measure reflected sunlight at multiple wavelengths, some at multiple viewing angles. A few are active sensors that send out their own laser light and measure the returned signal. Except when clouds are present, the excess amount of light scattered back to space, beyond that expected from the surface and atmospheric gas, is attributed to aerosol. Satellite measurements are used in many ways in aerosol research. They often provide the only method for monitoring hazardous phenomena such as major wildfire and volcanic eruption plumes, especially in remote areas. Stable, long-term, near-global-scale satellite data records make it possible to identify regional and global aerosol trends. Aerosol radiative effects on climate can be quantified on a near-global scale and used to estimate the strength of aerosol–radiation and aerosol–cloud interactions as well as to evaluate climate model simulations of these interactions. Aerosol-type mapping from satellite imagery is helpful for source attribution, model validation, and to constrain particle light-absorption properties that are essential for radiative forcing calculations. The range of aerosol properties retrieved from satellite observations has grown considerably since the first global estimates of aerosol optical depth (τ a) over ocean were made in the late 1970s. Methods for retrieving particle size and light-absorption properties were explored in the 1990s using multispectral, multi-angle observations, and polarization in visible and near-infrared wavelengths. Sensitivity to particle light absorption, primarily from black or brown carbon content, improved with the inclusion of UV channels, and sensitivity to very thin aerosol layers in the upper troposphere and lower stratosphere was advanced with the use of limb-sounding instruments and active sensors. There are limitations to every measurement technique, including satellite aerosol remote sensing. For wide-swath, passive instruments, aerosol retrievals near clouds can present substantial challenges as far as 15 km away due to cloud-scattered light contaminating the signal. In nearly all cases, retrievals over bright snow and ice surfaces are precluded because surface reflectance uncertainties can overwhelm the aerosol signal. Similarly, meteorological cloud is identified and masked out where possible. Data from passive sensors also lack vertical resolution except those that view toward the limb or where multi-angle imagery is acquired over plumes from wildfires, erupting volcanoes, and wind-blown dust. Yet, passive sensors provide vastly more coverage than the active instruments that mitigate these issues. Particle microphysical information is qualitative from all remote sensing techniques, relying on proxies to infer particle composition, hygroscopicity, and the amount of light-absorbing material. Further, particles smaller than about 200 nm diameter cannot be distinguished from atmospheric gas molecules with remote sensing, which hinders studies of cloud condensation nuclei and their effects on clouds. Most satellite instruments dedicated to aerosol observations are in low-Earth, near-polar, sun-synchronous orbits, which means they cross the equator at the same local time each day. Most are set on cycles that repeat approximately every 16 days, which makes it difficult to monitor aerosol evolution locally. Geostationary satellites make it possible to observe changes occurring from minutes to hours over regions up to 8000 km in size, but lack coverage of high latitudes, and often provide more limited constraints on aerosol properties. Ground-truth data are vital for satellite aerosol-retrieval validation. The AErosol RObotic NETwork (AERONET) of sun photometers was created in 1993 and has become an established global network of over 350 instruments for validating satellite measurements. The network, as well as global networks of ground-based lidars, solar flux radiometers and other sun photometers, are widely used for evaluating global satellite retrievals and model simulations. NASA's Earth Observing System (EOS) program beginning in 1999 led to improvements in reliability, spatial resolution, and spectral resolution (and hence, to improved particle size discrimination and light absorption properties). Satellite payloads include advanced broad-swath and multi-angle imagers, along with the first space-based active sensor focused largely on long-term aerosol monitoring. Since about 2002, Europe's SENTINEL and operational meteorological satellite fleets are also providing sustained aerosol observations, with planned continuation until at least 2030. Satellite remote sensing instruments offer valuable data for evaluating aerosol representations in global climate models. They have been used to assess aerosol optical and physical properties, trends and distributions, and are applied increasingly as direct model constraints in data assimilation to create global aerosol reanalysis products. Aerosol optical depth is the most common quantity adopted for routine model evaluation, including multiwavelength data to loosely constrain particle-size distributions. These evaluations of multiple models have revealed general biases in their regional aerosol amounts and seasonal patterns of transport and removal. Although satellite measurements have near-global coverage, substantial errors can be introduced into the model observation comparison unless attention is paid to spatial and temporal collocation, cloud screening, subgrid-scale variability, and measurement uncertainties that vary with retrieval conditions.

aerosol properties↗
NASA NTRS2000

Design-Filter Selection for H2 Control of Microgravity Isolation Systems: A Single-Degree-of-Freedom Case Study

Many microgravity space-science experiments require active vibration isolation, to attain suitably low levels of background acceleration for useful experimental results. The design of state-space controllers by optimal control methods requires judicious choices of frequency-weighting design filters. Kinematic coupling among states greatly clouds designer intuition in the choices of these filters, and the masking effects of the state observations cloud the process further. Recent research into the practical application of H2 synthesis methods to such problems, indicates that certain steps can lead to state frequency-weighting design-filter choices with substantially improved promise of usefulness, even in the face of these difficulties. In choosing these filters on the states, one considers their relationships to corresponding design filters on appropriate pseudo-sensitivity- and pseudo-complementary-sensitivity functions. This paper investigates the application of these considerations to a single-degree-of-freedom microgravity vibration-isolation test case. Significant observations that were noted during the design process are presented. along with explanations based on the existent theory for such problems.

Hampton, R. David↗
NASA NTRS2001

Calibration of of Sun Photometers and Sky Radiance Sensors

The main source of error in retrieving aerosol optical thicknesses using sun photometry comes from the determination of the TOA voltages. The degradation of interference filters is the most important source of the long-term changes in the cross-calibrations. Although major improvements have been made in the design of the filters (interference filters fabricated using ion-assisted deposition), the filters remain the principal factor limiting performance of the sun photometers. Degradation of filters necessitates frequent calibration of sun photometers and frequent measurements of the filter transmission or the relative system response. The degradation of the filters mounted on the CIMEL sun photometers have been monitored since 1993 by the Aerosol Robotic Network (AERONET) project. The decay reported by Holben et al. for the first two years of a CIMEL#s operation is between 1 and 5%. Nevertheless, the filters mounted on CIMEL instruments are regularly replaced after two years of use. The cross-calibration technique consists of taking measurements concurrently with the uncalibrated and the reference sun photometers. While analyzing measurements, the quality of the calibration has to be checked, using the following considerations: (1) any cirrus clouds suspected to be masking the sun, during the calibration period, need to be reported and the corresponding data set removed; and (2) the stability of the day needs to be checked. This chapter will describe calibration techniques, facilities, and protocols used for calibrating sun photometers and sky radiometers.

Pietras, Christophe↗
NASA NTRS2008

Large-Scale Structure of the Molecular Gas in Taurus Revealed by High Spatial Dynamic Range Spectral Line Mapping

Viewgraph topics include: optical image of Taurus; dust extinction in IR has provided a new tool for probing cloud morphology; observations of the gas can contribute critical information on gas temperature, gas column density and distribution, mass, and kinematics; the Taurus molecular cloud complex; average spectra in each mask region; mas 2 data; dealing with mask 1 data; behavior of mask 1 pixels; distribution of CO column densities; conversion to H2 column density; variable CO/H2 ratio with values much less than 10(exp -4) at low N indicated by UV results; histogram of N(H2) distribution; H2 column density distribution in Taurus; cumulative distribution of mass and area; lower CO fractional abundance in mask 0 and 1 regions greatly increases mass determined in the analysis; masses determined with variable X(CO) and including diffuse regions agrees well with the found from L(CO); distribution of young stars as a function of molecular column density; star formation efficiency; star formation rate and gas depletion; and enlarged images of some of the regions with numerous young stars. Additional slides examine the origin of the Taurus molecular cloud, evolution from HI gas, kinematics as a clue to its origin, and its relationship to star formation.

molecular clouds↗
NASA NTRS1992

Image masking using polygon fills and morphological transformations

Polygon-fill operations and morphological transformations are effective computational tools for the land-masking and coastline-correction preprocessing operations often applied to AVHRR data prior to oceanographic applications. These masking operations, in conjunction with cloud-screening techniques, can be used on such other oceanographically significant remote-sensing data as those of the Coastal Zone Color Scanner, GOES, and Landsat. The sensitivity of the methods to regional variations in atmospheric conditions and land-ocean temperature gradients is assessed for tropical, midlatitude, and high latitude regions.

Simpson, James J.↗
NASA NTRS1975

Study of sea ice in the Sea of Okhotsk and its influence on the Oyashio current

The author has identified the following significant results. Two photographic techniques were applied to Skylab S190A multispectral pictures for extracting oceanic patterns at the sea surface separately from cloud patterns. One is the image-masking technique and another a stereographic analysis. The extracted oceanic patterns were interpreted as areas where the amount, or the concentration of phytoplankton was high by utilizing surface data of water temperature, ocean current by GEK, and microplankton.

Watanabe, K.↗
NASA NTRS2013

Radar Range Sidelobe Reduction Using Adaptive Pulse Compression Technique

Pulse compression has been widely used in radars so that low-power, long RF pulses can be transmitted, rather than a highpower short pulse. Pulse compression radars offer a number of advantages over high-power short pulsed radars, such as no need of high-power RF circuitry, no need of high-voltage electronics, compact size and light weight, better range resolution, and better reliability. However, range sidelobe associated with pulse compression has prevented the use of this technique on spaceborne radars since surface returns detected by range sidelobes may mask the returns from a nearby weak cloud or precipitation particles. Research on adaptive pulse compression was carried out utilizing a field-programmable gate array (FPGA) waveform generation board and a radar transceiver simulator. The results have shown significant improvements in pulse compression sidelobe performance. Microwave and millimeter-wave radars present many technological challenges for Earth and planetary science applications. The traditional tube-based radars use high-voltage power supply/modulators and high-power RF transmitters; therefore, these radars usually have large size, heavy weight, and reliability issues for space and airborne platforms. Pulse compression technology has provided a path toward meeting many of these radar challenges. Recent advances in digital waveform generation, digital receivers, and solid-state power amplifiers have opened a new era for applying pulse compression to the development of compact and high-performance airborne and spaceborne remote sensing radars. The primary objective of this innovative effort is to develop and test a new pulse compression technique to achieve ultrarange sidelobes so that this technique can be applied to spaceborne, airborne, and ground-based remote sensing radars to meet future science requirements. By using digital waveform generation, digital receiver, and solid-state power amplifier technologies, this improved pulse compression technique could bring significant impact on future radar development. The novel feature of this innovation is the non-linear FM (NLFM) waveform design. The traditional linear FM has the limit (-20 log BT -3 dB) for achieving ultra-low-range sidelobe in pulse compression. For this study, a different combination of 20- or 40-microsecond chirp pulse width and 2- or 4-MHz chirp bandwidth was used. These are typical operational parameters for airborne or spaceborne weather radars. The NLFM waveform design was then implemented on a FPGA board to generate a real chirp signal, which was then sent to the radar transceiver simulator. The final results have shown significant improvement on sidelobe performance compared to that obtained using a traditional linear FM chirp.

Li, Lihua↗
NASA NTRS1992

Overview for the reanalysis of Mariner 9 UV spectrometer data for ozone, cloud, and dust abundances, and their interaction over climate timescales

Mariner 9 UV spectrometer data were reinverted for the ozone abundance, cloud abundance, dust abundance, and polar-cap albedo. The original reduction of the spectra ignored the presence of atmospheric dust and clouds, even though their abundance is substantial and can mask appreciable amounts of ozone if not accounted for (Lindner, 1988). The Mariner 9 ozone data has been used as a benchmark in all theoretical models of atmospheric composition, escape, and photochemistry. A second objective is to examine the data for the interrelationship of the ozone cycle, dust cycle, and cloud cycle, on an annual, inter-annual, and climatic basis, testing predictions by Lindner (1988). This also has implications for many terrestrial ozone studies, such as the ozone hole, acid rain, and ozone-smog. A third objective is to evaluate the efficacy of the reflectance spectroscopy technique at retrieving the ozone abundance on Mars. This would be useful for planning ozone observations on future Mars missions or the terrestrial troposphere.

Lindner, Bernhard Lee↗
NASA NTRS1973

Experimental masking of RBV images to reduce stationary residual inaccuracies in radiometric correction

Return beam vidicon tube calibration data are used to correct spatially non-uniform radiance response in individual vidicons, during post-acquisition signal processing. However, examination of different ERTS-1 RBV-1, -2, and -3 image scenes showed stationary, repetitive residual inaccuracies in shading correction, large enough to affect qualitative and quantitative image analyses. Photographic masks designed to reduce residual shading were prepared from RBV-1, -2, and -3 images of a relatively cloud-free ocean scene of uniform reflectance. When applied to other RBV scenes, the masks enabled more closely corrected RBV images to be printed. Illustrations are given of RBV-1 image before and after correction, compared with an equivalent MSS spectral image of the same scene.

Ross, D. S.↗
NASA NTRS1997

Development of a Simulated Data Set for the SeaWiFS Mission

A realistic simulated data set is essential for mission readiness preparations and can potentially assist in all phases of ground support for a future mission. Such a data set was created for the Sea-viewing Wide Field-of-view Sensor (SeaWiFS), a global ocean color mission due for launch in 1997. This data set incorporates a representation of virtually every known aspect of the flight mission. Thus, it provides a high fidelity data set for testing most phases of the ground system, Including data processing, data transfers, calibration and validation, quality control, and mission operations. The data set is constructed for a seven-day period, March 25-31, 1994. Specific features of the data set: it includes Global Area Coverage (GAC), recorded Local Area Coverage (LAC), and real-time High Resolution Picture Transmission (HRFIT) data for the seven-day period; it includes a realistic orbit which is propagated using a Brouwer-Lyddane model with drag; the data correspond to a command schedule based on the orbit for this seven-day period; it includes total (at-satellite) radiances for ocean, land, clouds, and ice; it utilizes a high-resolution land/sea mask; it includes actual SeaWiFS spectral responses; it includes the actual sensor saturation responses; it is formatted according to current onboard data structures; and it includes corresponding telemetry (instrument and spacecraft) data. The methods are described and some examples of the output are given.

Gregg, Watson W.↗
NASA NTRS2015

Thermodynamic Derivation of the Activation Energy for Ice Nucleation

Cirrus clouds play a key role in the radiative and hydrological balance of the upper troposphere. Their correct representation in atmospheric models requires an understanding of the microscopic processes leading to ice nucleation. A key parameter in the theoretical description of ice nucleation is the activation energy, which controls the flux of water molecules from the bulk of the liquid to the solid during the early stages of ice formation. In most studies it is estimated by direct association with the bulk properties of water, typically viscosity and self-diffusivity. As the environment in the ice-liquid interface may differ from that of the bulk, this approach may introduce bias in calculated nucleation rates. In this work a theoretical model is proposed to describe the transfer of water molecules across the ice-liquid interface. Within this framework the activation energy naturally emerges from the combination of the energy required to break hydrogen bonds in the liquid, i.e., the bulk diffusion process, and the work dissipated from the molecular rearrangement of water molecules within the ice-liquid interface. The new expression is introduced into a generalized form of classical nucleation theory. Even though no nucleation rate measurements are used to fit any of the parameters of the theory the predicted nucleation rate is in good agreement with experimental results, even at temperature as low as 190 K, where it tends to be underestimated by most models. It is shown that the activation energy has a strong dependency on temperature and a weak dependency on water activity. Such dependencies are masked by thermodynamic effects at temperatures typical of homogeneous freezing of cloud droplets; however, they may affect the formation of ice in haze aerosol particles. The new model provides an independent estimation of the activation energy and the homogeneous ice nucleation rate, and it may help to improve the interpretation of experimental results and the development of parameterizations for cloud formation.

Cirrus clouds↗