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At least 199 records · Page 11

Infrared and X-ray evidence of an AGN in the NGC 3256 southern nucleus

We investigate signs of an active galactic nucleus (AGN) in the luminous infrared (IR) galaxy NGC 3256 at both IR and X-ray wavelengths. NGC 3256 has double nuclei: the northern and southern (hereafter, N and S nuclei, respectively). We show that the Spitzer IRAC colors extracted at the S nucleus are AGN-like, and the Spitzer IRS spectrum is bluer at <6 μm than at the N nucleus. We built for the S nucleus an AGN–starburst composite model with a heavily absorbed AGN to successfully reproduce not only the IRAC and IRS specrophotometries at ≃3″, but also the very deep silicate 9.7 μm absorption observed at a 0.″ 36 scale by Díaz-Santos et al. We found a 2.2 μm compact source at the S nucleus in an HST NICMOS image and identified its unresolved core (at 0.″ 26 resolution) with the compact core in previous mid-infrared observations at comparable resolution. The flux of the 2.2 μm core is consistent with our AGN spectral energy distribution model. We also analyzed a deeper than ever Chandra X-ray spectrum of the unresolved (at 0.″ 5 resolution) source at the S nucleus. We found that a dual-component power-law model (for primary and scattered ones) fits an apparently very hard spectrum with a moderately large absorption on the primary component. Together with a limit on equivalent width of a fluorescent Fe–K emission line at 6.4 keV, the X-ray spectrum is consistent with a typical Compton-thin Seyfert 2. We therefore suggest that the S nucleus hosts a heavily absorbed low-luminosity AGN.

79 ASTRONOMY AND ASTROPHYSICS↗

OPTICAL SPECTROSCOPY OF H{alpha} FILAMENTS IN COOL CORE CLUSTERS: KINEMATICS, REDDENING, AND SOURCES OF IONIZATION

We have obtained deep, high spatial and spectral resolution, long-slit spectra of the H{alpha} nebulae in the cool cores of nine galaxy clusters. This sample provides a wealth of information on the ionization state, kinematics, and reddening of the warm gas in the cool cores of galaxy clusters. We find evidence for only small amounts of reddening in the extended, line-emitting filaments, with the majority of filaments having E(B - V) < 0.2. We find, in agreement with previous works, that the optical emission in cool core clusters has elevated low-ionization line ratios. The combination of [O III]/H{beta}, [N II]/H{alpha}, [S II]/H{alpha}, and [O I]/H{alpha} allow us to rule out collisional ionization by cosmic rays, thermal conduction, and photoionization by intracluster medium (ICM) X-rays and active galactic nuclei as strong contributors to the ionization in the bulk of the optical line-emitting gas in both the nuclei and filaments. The data are adequately described by a composite model of slow shocks and star formation. This model is further supported by an observed correlation between the line widths and low-ionization line ratios which becomes stronger in systems with more modest star formation activity based on far-ultraviolet observations. We find that the more extended, narrow filaments tend to have shallower velocity gradients and narrower line widths than the compact filamentary complexes. We confirm that the widths of the emission lines decrease with radius, from FWHM {approx}600 km s{sup -1} in the nuclei to FWHM {approx}100 km s{sup -1} in the most extended filaments. The variation of line width with radius is vastly different than what is measured from stellar absorption lines in a typical giant elliptical galaxy, suggesting that the velocity width of the warm gas may in fact be linked to ICM turbulence and, thus, may provide a glimpse into the amount of turbulence in cool cores. In the central regions (r < 10 kpc) of several systems the warm gas shows kinematic signatures consistent with rotation, consistent with earlier work. We find that the kinematics of the most extended filaments in this sample are broadly consistent with both infall and outflow, and recommend further studies linking the warm gas kinematics to both radio and X-ray maps in order to further understand the observed kinematics.

79 ASTRONOMY AND ASTROPHYSICS↗

HerMES: Spectral energy distributions of submillimeter galaxies at z > 4

We present a study of the infrared properties for a sample of seven spectroscopically confirmed submillimeter galaxies (SMGs) at z > 4.0. By combining ground-based near-infrared, Spitzer IRAC and MIPS, Herschel SPIRE, and ground-based submillimeter/millimeter photometry, we construct their spectral energy distributions (SEDs) and a composite model to fit the SEDs. The model includes a stellar emission component at λ{sub rest} < 3.5 μm, a hot dust component peaking at λ{sub rest} ∼ 5 μm, and cold dust component which becomes significant for λ{sub rest} > 50 μm. Six objects in the sample are detected at 250 and 350 μm. The dust temperatures for the sources in this sample are in the range of 40-80 K, and their L {sub FIR} ∼ 10{sup 13} L {sub ☉} qualifies them as hyper-luminous infrared galaxies. The mean FIR-radio index for this sample is around (q) = 2.2 indicating no radio excess in their radio emission. Most sources in the sample have 24 μm detections corresponding to a rest-frame 4.5 μm luminosity of Log{sub 10}(L {sub 4.5}/L {sub ☉}) = 11 ∼ 11.5. Their L {sub 4.5}/L {sub FIR} ratios are very similar to those of starburst-dominated SMGs at z ∼ 2. The L {sub CO} – L {sub FIR} relation for this sample is consistent with that determined for local ULIRGs and SMGs at z ∼ 2. We conclude that SMGs at z > 4 are hotter and more luminous in the FIR but otherwise very similar to those at z ∼ 2. None of these sources show any sign of the strong QSO phase being triggered.

79 ASTRONOMY AND ASTROPHYSICS↗

Expansion of the Direct Feed High-Level Waste Glass Composition in the High Al Range

Baseline glass compositions have been developed and demonstrated for successful immobilization of Hanford high-level waste (HLW) prepared through a pretreatment process. Recent enhanced waste glass formulations have shown promise to increase the waste loading of pretreated sludge compositions from a broader range of HLW feeds. This project proposes to increase the loading of minimally pretreated Hanford HLW in glass by expanding the existing database and glass property-composition models. Estimated direct-feed high level waste (DFHLW) compositions were generated by the Hanford Tank Operations Contractor and used by Pacific Northwest National Laboratory to determine target glass compositions. Gaps in existing data were identified including one high-priority gap in the high Al compositional region. This report summarizes the data collected during the characterization of the DFHLW High Al Glass Matrix. These glasses were intentionally designed with high aluminum concentrations (15 to 30 wt%) and a high likelihood of nepheline formation, which is known to negatively affect glass durability. Some glasses were expected to either fail or approach property constraints to fill data gaps in poorly understood regions of the compositional space due to lack of data. Out of the 50 glasses tested, 14 glasses formed nepheline, while the model predicted nepheline formation in 20 glasses. All quenched glasses met the product consistency test durability constraint; however, 8 glasses failed this constraint after undergoing the canister centerline cooling treatment. Additionally, 17 glasses did not meet the viscosity constraints, 4 failed the EC constraints, and 2 exceeded the allowable T2% for spinel crystal formation. All glasses satisfied the SO 3 solubility limit. The resulting dataset provides valuable information to improve model accuracy and reduce prediction uncertainty. These insights will ultimately support the development of more robust glass formulation strategies, enabling higher waste loadings, reducing operational risks, and expanding the processing envelope.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A MODEL ATMOSPHERE ANALYSIS OF ALPHA AURIGAE A

This work presents the first quantitative composite model atmosphere analysis of Capella, the brightest near-equal-mass spectroscopic binary and principal star of the constellation Auriga. Its high-resolution spectrum leads to a slightly metal-rich object at [Fe/H] = +0.05 {+-} 0.08 dex. In line with its young age and its kinematics, this consistently associates Capella with the Hyades moving group. The measured projected rotational velocities, vsin i{sub Aa} = 3.5 {+-} 0.8 km s{sup -1} and vsin i{sub Ab} = 35.4 {+-} 3.2 km s{sup -1}, both agree with rotational and orbital coplanarity and synchronous orbital rotation for the Aa component. At an orbital period P = 104 d the primary's bound rotation together with the almost zero orbital eccentricity are both key characteristics of this binary and clearly imply that the Aa component must have passed the tip of the giant branch. Whether in that phase Capella also became a mass transfer system remains inconclusive at present, though the high rotational velocity of the less evolved Hertzsprung gap secondary and the very diverse lithium abundances of both its components render this a plausible case.

79 ASTRONOMY AND ASTROPHYSICS↗

Hydrostratigraphic Region 3 Model - with and without HSU Capillary Pressure

Farnsworth Unit (FWU) CO2EOR Eclipse compositional model: Hydrostratigraphic Region 3 model uses the HS3 relative permeability curves assigned heterogeneously by hydrostratigraphic unit. The model with capillary pressure applies the HS3 curves heterogeneously by hydrostratigraphic unit.

Capillary Pressure↗

Search for physics beyond the standard model in dilepton mass spectra in proton-proton collisions at √s = 8 TeV

Dimuon and dielectron mass spectra, obtained from data resulting from proton-proton collisions at 8 TeV and recorded by the CMS experiment, are used to search for both narrow resonances and broad deviations from standard model predictions. The data correspond to an integrated luminosity of 20.6 (19.7) fb –1 for the dimuon (dielectron) channel. No evidence for non-standard-model physics is observed and 95% confidence level limits are set on parameters from a number of new physics models. The narrow resonance analyses exclude a Sequential Standard Model Z SSM ' resonance lighter than 2.90 TeV, a superstring-inspired Z ψ ' lighter than 2.57 TeV, and Randall-Sundrum Kaluza-Klein gravitons with masses below 2.73, 2.35, and 1.27 TeV for couplings of 0.10, 0.05, and 0.01, respectively. A notable feature is that the limits have been calculated in a model-independent way to enable straightforward reinterpretation in any model predicting a resonance structure. The observed events are also interpreted within the framework of two non-resonant analyses: one based on a large extra dimensions model and one based on a quark and lepton compositeness model with a left-left isoscalar contact interaction. Lower limits are established on MS, the scale characterizing the onset of quantum gravity, which range from 4.9 to 3.3 TeV, where the number of additional spatial dimensions varies from 3 to 7. Thus lower limits on Λ, the energy scale parameter for the contact interaction, are found to be 12.0 (15.2) TeV for destructive (constructive) interference in the dimuon channel and 13.5 (18.3) TeV in the dielectron channel.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Utah FORGE: Composite 3D Seismic Velocity Model

This is a composite 3D seismic velocity that was constructed from compiled information from several local studies regarding seismic velocities and structural information. This seismic velocity model is provided in NonLinLoc format (slow_len), which is readily usable in NonLinLoc software. Other model formats and versions of the model can be produced using the Python script provided with this data set. Details on how the model was created and prior velocity and structural information was used is provided in the accompanying documentation.

15 GEOTHERMAL ENERGY↗

Evidence for Lignin–Carbohydrate Complexes from Studies of Transgenic Switchgrass and a Model Lignin–Pectin Composite

Lignin–carbohydrate complexes (LCCs) form through interactions of lignin with plant cell wall polysaccharides and are thought to be a significant source of biomass recalcitrance. In this work, we investigated LCCs formed between lignin and pectin homogalacturonan (HG). The structural changes in HG deficient transgenic switchgrass (GAUT4-knockdown, GAUT4-KD) after hot water pretreatment were compared to wild-type plants using small-angle neutron scattering (SANS), which showed that there were ~2.2-fold more lignin aggregates in GAUT4-KD biomass compared to the wild type. This demonstrated that decreased pectin resulted in more lignin redistribution and suggested that interactions between lignin and HG restrict lignin mobility in plant cell walls. To better understand the types of interactions between lignin and pectin, a model composite was prepared by polymerizing either protiated or partially deuterated coniferyl alcohol to form a dehydrogenation polymer (DHP) in the presence of HG. Small-angle X-ray scattering (SAXS) showed that the DHP and HG form a highly interconnected network structure that is not observed in a physical mixture of the individual polymers. Contrast matching SANS revealed the structure of DHP and HG in the composite and showed that the HG forms a swollen interconnected polymer network (power-law exponent, P = 1.5) interspersed with DHP particles (radius of gyration, Rg, 264 Å) that are composed of solvent-accessible DHP polymers (P = 2.3). Fourier transform infrared spectroscopy showed a unique ester absorption band in the DHP/HG composites. Solid-state nuclear magnetic resonance (NMR) analysis also supports interactions between DHP and HG. Overall, this study provides new insights into the relationship between primary and secondary cell wall polymers during cell wall synthesis and how LCCs formed between pectin and lignin could represent a previously unrecognized source of biomass recalcitrance. This knowledge may help develop new approaches to modulate cell wall properties to improve biofuel and bioproduct production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

2016 Update of Hanford Glass Property Models and Constraints for Use in Estimating the Glass Mass to be Produced at Hanford by Implementing Current Enhanced Glass Formulation Efforts

Recent glass formulation and melter testing data have suggested that significant increases in waste loading in high-level waste (HLW) and low-activity waste (LAW) glasses are possible over current system planning estimates. In 2013 a set of models and constraints based on these data were developed and published (Vienna et al. 2013). Since that report roughly 200 additional glasses have been tested and lessons were learned in the application of the preliminary set of models and constraints. This report summarizes the advancements in glass formulation and glass property estimation since Vienna et al. 2013 (using the additional data and lessons learned) and updates the recommended set of enhanced glass property-composition models and constraints for use in River Protection Project (RPP) planning. The combined data (although limited in some cases) were evaluated to determine a set of constraints and models that could be used to estimate the maximum loading of specific waste compositions in glass. It is recommended that these models and constraints be used to estimate the likely HLW and LAW glass masses that would result if the current glass formulation studies are successfully completed. It is recognized that some of the models are preliminary in nature and will change in the coming years. In addition, the models do not currently address the prediction uncertainties that would be required before they could be used in plant operations. The models and constraints are only meant to give an indication of rough glass masses and are not intended to be used in quality-affecting activities or decisions. A current research program is in place to develop the data, models, and uncertainty descriptions for that purpose. A fundamental tenet underlying the research reported in this and the previous document is the attempt to be less conservative, but still realistic, than previous studies when developing constraints for the estimation of glass to be produced by implementing current enhanced glass formulation efforts. The less conservative approach documented herein should allow for the estimate of glass masses that may be realized if the current efforts in enhanced glass formulations are completed over the coming years, and are as successful as early indications suggest they may be. Because of this approach, there is an unquantifiable uncertainty in the ultimate glass mass projections due to model prediction uncertainties that must be considered, along with other system uncertainties, such as waste compositions and amounts to be immobilized, split factors between LAW and HLW, etc. A plan to estimate the impact of those uncertainties has been developed and a future update will document the results.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

X-Ray Diffraction and Product Consistency Test Results for the Phase 6 Study of Nepheline Formation in High-Level Waste Glasses

Hanford high-level waste (HLW) contains relatively high concentrations of Al 2 O 3 . A major constraint limiting the waste loading of high-Al 2 O 3 glasses is nepheline (nominally NaAlSiO 4 ) formation upon slow cooling of HLW glasses after melts are poured into steel canisters. The model currently planned to be used at the Hanford Waste Treatment and Immobilization Plant (WTP) for avoiding nepheline formation is too conservative and drastically limits waste loading. To increase operational flexibility and effectively operate the WTP, the effects of glass composition on glass properties must be determined and glass property-composition models must be developed. Determining the impacts of glass composition on nepheline formation and the effects of nepheline on Product Consistency Test (PCT) response is an important part of this effort. As a part of this effort, data related to the Hanford high-Al 2 O 3 HLW composition region was generated to supplement existing data for model development. Twenty glasses were fabricated, heat treated, and analyzed for crystallinity and PCT response. The heat treatment was designed to mimic the canister centerline cooling (CCC) profile of Hanford HLW glass canisters. It was found that only 6 of the 20 prepared glasses (#4, #7, #8, #10, #19, and #20) formed nepheline upon heat treatment. All glasses except for one (#19) precipitated spinel upon quenching and no glasses contained nepheline upon quenching. Of the 20 glasses, the PCT-normalized boron release of the quenched glasses and all but five of the CCC glasses satisfied the environmental assessment glass benchmark value (16.695 g/L). The CCC glass samples that exceeded the limit were #8 (48.21 g/L), #10 (19.77 g/L), #13 (20.17 g/L), #19 (60.85 g/L), and #20 (61.08 g/L). Those glasses coincide with the highest amounts of nepheline found in the CCC glasses, except for #13, which did not form nepheline after CCC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Sorption testing and generalized composite surface complexation models for determining uranium sorption parameters at a proposed in-situ recovery site

Solid-phase iron concentrations and generalized composite surface complexation models were used to evaluate procedures in determining uranium sorption on oxidized aquifer material at a proposed U in situ recovery (ISR) site. At the proposed Dewey Burdock ISR site in South Dakota, USA, oxidized aquifer material occurs downgradient of the U ore zones. Solid-phase Fe concentrations did not explain our batch sorption test results,though total extracted Fe appeared to be positively correlated with overall measured U sorption. Batch sorption test results were used to develop generalized composite surface complexation models that incorporated the full genericsorption potential of each sample, without detailed mineralogiccharacterization. The resultant models provide U sorption parameters (site densities and equilibrium constants) for reactive transport modeling. The generalized composite surface complexation sorption models were calibrated to batch sorption data from three oxidized core samples using inverse modeling, and gave larger sorption parameters than just U sorption on the measured solidphase Fe. These larger sorption parameters can significantly influence reactive transport modeling, potentially increasing U attenuation. Because of the limited number of calibration points, inverse modeling required the reduction of estimated parameters by fixing two parameters. The best-fit models used fixed values for equilibrium constants, with the sorption site densities being estimated by the inversion process. While these inverse routines did provide best-fit sorption parameters, local minima and correlated parameters might require further evaluation. Despite our limited number of proxy samples, the procedures presented provide a valuable methodology to consider for sites where metal sorption parameters are required. Furthermore, these sorption parameters can be used in reactive transport modeling to assess downgradient metal attenuation, especially when no other calibration data are available, such as at proposed U ISR sites.

54 ENVIRONMENTAL SCIENCES↗

Absorber Column CFD model validation against PNNL’s device-scale absorber column on the LCFS unit

Absorber column has been widely used for CO 2 capture in the coal-fired power plants. High-fidelity CFD models play an important role in absorber column design and solvents optimization, which help enhance the CO 2 capture efficiency and reduce the operation cost. This report provides a comprehensive description of the development of CFD absorber models at two different levels, the design and implementation of PNNL’s device-scale absorber column experiment, and the methodology to combine the CFD results, experiment data, and Aspen model for a better understanding of the interface area in packed column. A composite model is firstly proposed in the Discrete Element Method (DEM) packing process, which can model the complex geometry of various packing elements. This generates a realistic packing pattern and accurate packing porosity ε and specific area a p compared to the actual values for absorber column used in LCFS. Two level of CFD absorber models were developed, namely the full-size column model (FCM) to simulate the entire packed column with a focus on the wall/entrance effects, and the representative column model (RCM) to simulate a section of column with a focus on the sensitivity study of interface area. A Design of Experiment (DoE) plan was developed to guide the collection of 100 run CFD data and 12 experiment runs. The 100 CFD runs were carried out in the RCM with Pro-Pak packing and cover a wide operation range and solvent properties. Impact of influential factors on the interface area in packed column were investigated in details. The CFD interface area was then combined with the experimental data and Aspen model to infer some information of the effective contact angle in the column. The accuracy and uncertainties in the interface area and contact angle can be quantified.

01 COAL, LIGNITE, AND PEAT↗

Benchmark Imagery Project: Selection of Real World Images for Creating Composite Images of Facilities

The "Benchmark Imagery" project is a DOE NA-22-funded effort whose three-year goal is to create a suite of imagery (both real and composite) that can be used to test geospatial algorithms used for extracting semantic content from overhead images of industrial facilities. A composite image is an image that contains both real elements such as photographic imagery and synthetic elements such as 3D models. Composite images have the advantage of being customizable and distributable, and they can contain complete ground truth. It is our goal to generate composite images which appear realistic to both human and algorithm. When generating composite images of facilities we use real overhead imagery to increase realism and decrease effort. To construct all elements with purely synthetic textures would require too much effort and still may not look as realistic as a real image. We use real time 3D rendering software "SceneWorks" for rendering composite images. In SceneWorks, a scene is constructed by placing 3D models of facility components on top of a base terrain. A base terrain is a 3D model constructed from digital elevation mapping (DEM) data and then textured with overhead orthorectified imagery. The base terrain is constructed to be geospatially accurate using a real location’s source data (DEM and Imagery.) This document outlines the selection criteria in selecting appropriate location and source data for constructing the base terrain. Imagery should have resolution equal or better than desired composite image resolution. The imagery should have no seams. Seams can occur when two or more different imagery data sets exist in a single area with neither set covering the entire area. Elevation data (DEM) resolution generally should be 1/9 arc second or better depending on the variability of elevation. The imagery must contain a flat clearing of land large enough for multiple facility types. There should be no high-rise buildings anywhere in the base terrain.

42 ENGINEERING↗

Defense Waste Processing Facility (DWPF) Viscosity Model: Revisions for Processing High TiO 2 Containing Glasses

Radioactive high-level waste (HLW) at the Savannah River Site (SRS) has successfully been vitrified into borosilicate glass in the Defense Waste Processing Facility (DWPF) since 1996. Vitrification requires stringent product/process (P/P) constraints since the glass cannot be reworked once it is poured into ten foot tall by two foot diameter canisters. A unique “feed forward” statistical process control (SPC) was developed for this control rather than statistical quality control (SQC). In SPC, the feed composition to the DWPF melter is controlled prior to vitrification. In SQC, the glass product would be sampled after it is vitrified. Individual glass property-composition models form the basis for the “feed forward” SPC. The models transform constraints on the melt and glass properties into constraints on the feed composition going to the melter in order to guarantee, at the 95% confidence level, that the feed will be processable and that the durability of the resulting waste form will be acceptable to a geologic repository. The DWPF SPC system is known as the Product Composition Control System (PCCS). The DWPF will soon be receiving wastes from the Salt Waste Processing Facility (SWPF) containing increased concentrations of TiO 2 , Na 2 O, and Cs 2 O . The SWPF is being built to pretreat the high-curie fraction of the salt waste to be removed from the HLW tanks in the F- and H-Area Tank Farms at the SRS. In order to process TiO 2 concentrations >2.0 wt% in the DWPF, new viscosity data were developed over the range of 1.90 to 6.09 wt% TiO 2 and evaluated against the 2005 viscosity model. An alternate viscosity model is also derived for potential future use, should the DWPF ever need to process other titanate-containing ion exchange materials. The ultimate limit on the amount of TiO 2 that can be accommodated from SWPF will be determined by the three PCCS models, the waste composition of a given sludge batch, the waste loading of the sludge batch, and the frit used for vitrification.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Quantitative interpretation of time-lapse seismic data at Farnsworth field unit: Rock physics modeling, and calibration of simulated time-lapse velocity responses

Here, this study investigates the contribution of fluid saturation variation to the time-lapse velocity response by performing fluid substitution modeling. The methodology is exemplified by the time-lapse seismic monitoring of carbon dioxide at Farnsworth field unit (FWU). In order to evaluate the fluid distribution in a matured oil reservoir, the Southwest Regional Partnership (SWP) acquired multiple vertical seismic profile (VSP) surveys at different times during the CO 2 –water alternatinggas (WAG) injection period. In this work, we present a thorough methodology for computing the elastic response of the saturated rock for different fluid saturations using a site-specific petro-elastic model (PEM). The output from the PEM was combined with results from a fluid compositional model to compute the seismic velocities at times corresponding to each VSP survey. To produce a calibrated simulated response, the measured time-lapse seismic velocities were integrated into the numerical simulation model. The mismatches between the predicted and measured time-lapse velocities were minimized through an iterative calibration process using a trained artificial neural network proxy (ANN) coupled with a particle swarm optimizer (PSO). Our study indicates that the hybrid optimization workflow can effectively perform the history matching. With an accurate prediction of the hydrodynamic properties, the migration of CO 2 within the subsurface was modeled by predicting the spatial velocity distribution for a radius of 305 m around the injection well. The technology demonstrated and the expertise gained from this study can guide similar CO 2 -WAG projects.

58 GEOSCIENCES↗