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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Relative reactivity of ribosyl 2'-OH vs. 3'-OH in concentrated aqueous solutions of phosphoimidazolide activated nucleotides

Phosphoimidazolide activated ribomononucleotides (*pN, see structure) are useful substrates for the non-enzymatic synthesis of oligonucleotides. In the presence of metal ions, aqueous solutions of *pN yield primarily the two internucleotide-linked (pN2' pN and pN3' pN) and the pyrophosphate-linked (N5' ppN) dimers. Small amounts of cyclic dimers and higher oligomers are also produced. In this study the relative reactivity of 2'-OH vs. 3'-OH was determined from the ratio of the yields of pN2' pN vs. pN3' pN. Experiments were performed at 23 degrees C in the range 7.2 < or = pH < or = 8.4 with substrates that differ in nucleobase (guanosine (G), cytidine (C), uridine (U), and adenosine (A)) and leaving group (imidazole (Im), 2-methylimidazole (2-MeIm) and 2,4-dimethylimidazole (2,4-diMeIm)). Two metal ions (Mg2+ or Mn2+) were employed as catalysts. The conditions used here, i.e. a substrate concentration in the range 0.1 M to 1.0 M and metal ion concentration in the range 0.05 M to 0.2 M, favor base-stacking interactions. The ratio pN2' pN: pN3' pN = 2'-5': 3'-5' was found independent of nucleobase and typically varied between 2 to 3 indicating that the 2'-OH is about 2 to 3 times more reactive than the 3'-OH. *pN with Im, compared to 2-MeIm and 2,4-diMeIm leaving group, produce lower yields of internucleotide linked dimers, and a higher pN2' pN: pN3' pN ratio. Trends in the data, observed with all three leaving groups, suggest an increase in pN2' pN: pN3' pN ratio with decreasing substrate concentration (up to 5.47 with 0.051 M ImpG). The observations are in accord with earlier studies reporting a relative reactivity 2'-5': 3'-5' = 6 to 9 obtained with Im as the leaving group, in dilute nucleotide solutions and under conditions that disfavor stacking. It is speculated that the concentration induced change in the relative reactivity is the result of self-association via base-stacking that enhances selectively the proximity of the 3'-OH of one molecule to the reactive P-N bond of an other molecule. The implication of these conclusions for oligomerization/ligation reactions is discussed.

NASA Discipline Exobiology↗
NASA NTRS2020

A New Method to Correct the Electrochemical Concentration Cell (ECC) Ozonesonde Time Response and its Implications for "Background Current" and Pump Efficiency

The electrochemical concentration cell (ECC) ozonesonde has been the main instrument for in situ profiling of ozone worldwide; yet, some details of its operation, which contribute to the ozone uncertainty budget, are not well understood. Here, we investigate the time response of the chemical reactions inside the ECC and how corrections can be used to remove some systematic biases. The analysis is based on the understanding that two reaction pathways involving ozone occur inside the ECC that generate electrical currents on two very different timescales. The main fast-reaction pathway with a time constant of about 20 s is due the conversion of iodide to molecular iodine and the generation of two free electrons per ozone molecule. A secondary slow-reaction pathway involving the buffer generates an excess current of about 2 %–10 % with a time constant of about 25 min. This excess current can be interpreted as what has conventionally been considered the “background current”. This contribution can be calculated and removed from the measured current instead of the background current. Here we provide an algorithm to calculate and remove the contribution of the slow-reaction pathway and to correct for the time lag of the fast-reaction pathway. This processing algorithm has been applied to ozonesonde profiles at Costa Rica and during the Central Equatorial Pacific Experiment (CEPEX) as well as to laboratory experiments evaluating the performance of ECC ozonesondes. At Costa Rica, where a 1 % KI, 1/10th buffer solution is used, there is no change in the derived total ozone column; however, in the upper troposphere and lower stratosphere, average reported ozone concentrations increase by up to 7 % and above 30 km decrease by up to 7 %. During CEPEX, where a 1 % KI, full-buffer solution was used, ozone concentrations are increased mostly in the upper troposphere, with no change near the top of the profile. In the laboratory measurements, the processing algorithms have been applied to measurements using the majority of current sensing solutions and using only the stronger pump efficiency correction reported by Johnson et al. (2002). This improves the accuracy of the ECC sonde ozone profiles, especially for low ozone concentrations or large ozone gradients and removes systematic biases relative to the reference instruments. In the surface layer, operational procedures prior to launch, in particular the use of filters, influence how typical gradients above the surface are detected. The correction algorithm may report gradients that are steeper than originally reported, but their uncertainty is strongly influenced by the prelaunch procedures.

electrochemical concentration cell (ECC) ozonesond↗
NASA NTRS2022

Dilution of Boundary Layer Cloud Condensation Nucleus Concentrations by Free Tropospheric Entrainment During Marine Cold Air Outbreaks

Recent aircraft measurements over the northwest Atlantic enable an investigation of how entrainment from the free troposphere (FT) impacts cloud condensation nucleus (CCN) concentrations in the marine boundary layer (MBL) during cold-air outbreaks (CAOs), motivated by the role of CCN in mediating transitions from closed to open-cell regimes. Observations compiled over eight flights indicate predominantly far lesser CCN concentrations in the FT than in the MBL. For one flight, a fetch-dependent MBL-mean CCN budget is compiled from estimates of sea-surface fluxes, entrainment of FT air, and hydrometeor collision-coalescence, based on in-situ and remote-sensing measurements. Results indicate a dominant role of FT entrainment in reducing MBL CCN concentrations, consistent with satellite-observed trends in droplet number concentration upwind of CAO cloud-regime transitions over the northwest Atlantic. Relatively scant CCN may widely be associated with FT dry intrusions, and should accelerate cloud-regime transitions where underlying MBL air is CCN-rich, thereby reducing regional albedo.

Boundary Layer Cloud Condensation Nucleus Concentr↗
NASA NTRSDate not supplied

Ground Testing of an Oxygen Concentrator in a Simulated International Space Station (ISS) Cabin Environment

The method for supplying medical oxygen to respiratorily-compromised astronauts on the International Space Station (ISS) and in future Orion missions consists of drawing oxygen from high pressure oxygen tanks. An Oxygen Concentrator Module (OCM) is a device that pulls in ambient air and separates out the nitrogen, resulting in a high concentration oxygen source. This technology has the potential to eliminate resupply and oxygen-enrichment issues associated with using high pressure oxygen tanks and become an alternative technology to support medical oxygen operations for future exploration missions. In this study, we test the long-term performance of a Commercial Off-the-Shelf (COTS) OCM in a simulated ISS cabin environment. Humidified air, carbon dioxide, and fifteen representative trace contaminants are continuously injected through a enclosed test chamber where the OCM is challenged. This study included the first successful demonstration of the Trace Gas Injection System (TGIS), which reliably and continuously produced ISS levels of trace contaminants, carbon dioxide, and humidity in an enclosed environment. The TGIS is a new and unique ground capability with significant implications for Test Readiness Level (TRL) advancement of COTS items and Government Furnished Equipment (GFE). This study demonstrated that the tested OCM reliably delivers enriched oxygen mostly at desired performance specifications. This study also demonstrated that the OCM does not inadvertently concentrate trace gases in its oxygen product stream, as detectable concentrations of trace contaminants in the oxygen product stream were at all times below the simulated ISS levels.

medical oxygen↗
NASA NTRSDate not supplied

Ground Testing of an Oxygen Concentrator in a Simulated International Space Station (ISS) Cabin Environment

The method for supplying medical oxygen to respiratorily-compromised astronauts on the International Space Station (ISS) and in future Orion missions consists of drawing oxygen from high pressure oxygen tanks. An Oxygen Concentrator Module (OCM) is a device that pulls in ambient air and separates out the nitrogen, resulting in a high concentration oxygen source. This technology has the potential to eliminate resupply and oxygen-enrichment issues associated with using high pressure oxygen tanks and become an alternative technology to support medical oxygen operations for future exploration missions. In this study, we test the long-term performance of a Commercial Off-the-Shelf (COTS) OCM in a simulated ISS cabin environment. Humidified air, carbon dioxide, and fifteen representative trace contaminants are continuously injected through an enclosed test chamber where the OCM is challenged. This study included the first successful demonstration of the Trace Gas Injection System (TGIS), which reliably and continuously produced ISS levels of trace contaminants, carbon dioxide, and humidity in an enclosed environment. The TGIS is a new and unique ground capability with significant implications for Test Readiness Level (TRL) advancement of COTS items and Government Furnished Equipment (GFE). This study demonstrated that the tested OCM reliably delivers enriched oxygen mostly at desired performance specifications. This study also demonstrated that the OCM does not inadvertently concentrate trace gases in its oxygen product stream, as detectable concentrations of trace contaminants in the oxygen product stream were at all times below the simulated ISS levels.

medical oxygen↗
NASA NTRS1972

Nonuniform concentration - A mechanism for drag reduction.

A large reduction in drag coefficient has been observed in certain external flows of aqueous solutions with high molecular weight polymer additives. A change in the near wake configuration is phenomenologically responsible for the drag reduction, but the underlying mechanism is presently unknown. An analogy to known phenomena in particulate suspensions is drawn which suggests nonuniform concentration of the polymer additive as an explanation. An analysis of the boundary layer on a sphere with varying viscosity was made to investigate the effect. The results indicate early transition to turbulence for concentration variations whose length scale is small compared with the momentum boundary layer thickness. Stabilization and delayed transition are indicated for thicker concentration layers. Observations are suggested for the thin concentration layers.

Rivard, W. C.↗
NASA NTRS1973

Electron concentrations calculated from the lower hybrid resonance noise band observed by Ogo 3.

A noise band at the lower hybrid resonance (LHR) is often detected by the VLF and ELF receivers on Ogo 3, using the electric antenna. In some cases the noise band is at the geometric mean gyrofrequency as measured by the Goddard Space Flight Center (GSFC) magnetometer, and local LHR in a dense H(+) plasma is indicated; in such cases, electron concentration can be calculated, if it is assumed that heavy ions are negligible. Observations at midlatitudes and altitudes of a few earth radii show local concentrations as low as 1.4 electrons/cu cm. In one case the concentrations obtained from the LHR noise band agree with those measured simultaneously by the GSFC ion mass spectrometer within a factor of 2. In another case the concentration is observed to fall by a factor of 2 in 150 km and then to decrease roughly as R to the minus fourth power, in agreement with whistler measurements outside the plasmapause.

Burtis, W. J.↗
NASA NTRS1975

Altitudinal, diurnal and latitudinal dependences for ionic concentrations formed by corpuscular fluxes in the stratosphere and mesosphere

On the basis of over 15 rocket measurements of ionic concentrations below 80 km, the height, daily and latitudinal dependences between positive ionic concentrations and cosmic ray intensity below 60 km as well as between ionic concentrations and corpuscular streams within the 60-80 km altitude range are compared. It is shown that ionic concentration and cosmic ray intensity below 60 km at night are likely to be interrelated, in conformity with Chapman's theory of the simple layer. In daytime, all phenomena are aggravated by photodetachment and ion exchange reactions with the participation of ozone. Between 60-80 km, besides ordinary cosmic rays, there must exist an additional corpuscular stream.

Bragin, Y. A.↗
NASA NTRS1975

Determination of nitric oxide concentrations from sunrise E-region electron density measurements

Midlatitude sunrise electron density profiles have been analyzed in order to determine nitric oxide concentrations in the range 100-160 km. In general, the determinations are restricted to heights for which the ionization of nitric oxide by direct solar Lyman-alpha radiation is the main contribution to the growth of the E region. The concentrations obtained are larger, by factors of approximately 3 to 4, than those obtained from the midlatitude airglow measurements of other workers. Concentrations have been obtained from one sunset measurement and these are significantly lower than the sunrise values. The results also give a clear indication of increasing nitric oxide concentrations above 120 km with increasing solar activity.

Monro, P. E.↗
NASA NTRS1975

The absolute concentration of O/3P/ in the earth's stratosphere

Results are presented for an experimental application of the laminar flow-through/resonance technique, which allows direct observations of the absolute concentration of atoms and radicals in the earth's upper atmosphere. Atomic resonance fluorescence was used in conjunction with a parachute-borne flow-through module deployed from a balloon at a height of 40 km to determine the concentration of ground-state atomic oxygen at 40 to 25 km in the atmosphere. The equipment is described, and the measurements and experimental uncertainties are plotted. It is shown that the observed absolute concentration of ground-state atomic oxygen is similar to that predicted by model calculations, and it is concluded that this technique provides a simple and direct means of measuring atomic and radical concentrations in the part-per-trillion range in unperturbed stratospheric samples.

Anderson, J. G.↗
NASA NTRS1976

Meteorological adjustment of yearly mean values for air pollutant concentration comparison

Using multiple linear regression analysis, models which estimate mean concentrations of Total Suspended Particulate (TSP), sulfur dioxide, and nitrogen dioxide as a function of several meteorologic variables, two rough economic indicators, and a simple trend in time are studied. Meteorologic data were obtained and do not include inversion heights. The goodness of fit of the estimated models is partially reflected by the squared coefficient of multiple correlation which indicates that, at the various sampling stations, the models accounted for about 23 to 47 percent of the total variance of the observed TSP concentrations. If the resulting model equations are used in place of simple overall means of the observed concentrations, there is about a 20 percent improvement in either: (1) predicting mean concentrations for specified meteorological conditions; or (2) adjusting successive yearly averages to allow for comparisons devoid of meteorological effects. An application to source identification is presented using regression coefficients of wind velocity predictor variables.

Sidik, S. M.↗
NASA NTRS1977

Relation of morphology of electrodeposited zinc to ion concentration profile

The morphology of electrodeposited zinc was studied with special attention to the ion concentration profile. The initial concentrations were 9M hydroxide ion and 1.21M zincate. Current densities were 6.4 to 64 mA/sq cm. Experiments were run with a horizontal cathode which was observed in situ using a microscope. The morphology of the zinc deposit was found to be a function of time as well as current density; roughly, the log of the transition time from mossy to large crystalline type deposit is inversely proportional to current density. Probe electrodes indicated that the electrolyte in the cathode chamber was mixed by self inducted convection. However, relatively large concentration gradients of the involved species existed across the boundary layer of the cathode. Analysis of the data suggests that the morphology converts from mossy to large crystalline when the hydroxide activity on the cathode surface exceeds about 12 M. Other experiments show that the pulse discharge technique had no effect on the morphology in the system where the bulk concentration of the electrolyte was kept homogeneous via self induced convection.

May, C. E.↗
NASA NTRS1977

Impurity concentrations and surface charge densities on the heavily doped face of a silicon solar cell

Increased solar cell efficiencies are attained by reduction of surface recombination and variation of impurity concentration profiles at the n(+) surface of silicon solar cells. Diagnostic techniques are employed to evaluate the effects of specific materials preparation methodologies on surface and near surface concentrations. It is demonstrated that the MOS C-V method, when combined with a bulk measurement technique, yields more complete concentration data than are obtainable by either method alone. Specifically, new solar cell MOS C-V measurements are combined with bulk concentrations obtained by a successive layer removal technique utilizing measurements of sheet resistivity and Hall coefficient.

Weinberg, I.↗
NASA NTRS1978

Design and fabrication of a low-specific-weight parabolic dish solar concentrator

A segmented design and fabrication and assembly techniques were developed for a 1.8 m (6 ft) diameter parabolic concentrator for space application. This design and these techniques were adaptable to a low cost, mass-produced concentrator. Minimal machining was required. Concentrator segments of formed magnesium were used. The concentrator weighed only 1.6 kg sq m (0.32 lbm/sq ft).

Richter, C. W.↗
NASA NTRS1978

The effect of increased carbon dioxide concentrations on stratospheric ozone

Consideration is given to the influence on ozone of an increased carbon dioxide concentration, for which a measurable growth has been observed in the recent past. Increased carbon dioxide can indirectly affect ozone by perturbing atmospheric temperatures, which will alter ozone production, whose rate displays a fairly strong temperature dependence. This paper presents one-dimensional model results for the steady state ozone behavior when the CO2 concentration is twice its ambient level; the results account for coupling between chemistry and temperature. When the CO2 level doubled, the total ozone burden increased in relation to the ambient burden by 1.2-2.5%, depending on the vertical diffusion coefficient used. Above 30 km, ozone concentrations were larger than the ambient values, a maximum increase of 16% being reached at 43 km. In this region the relative variations were insensitive to the choice of diffusion coefficient. Below 30 km, ozone concentrations were smaller than the unperturbed values and were sensitive to the vertical diffusion profile in this region (10-30 km).

Boughner, R. E.↗
NASA NTRS1978

Time-dependence of sea-ice concentration and multiyear ice fraction in the Arctic Basin

Microwave images of sea ice obtained by Nimbus-5 and the NASA CV-990 airborne laboratory are used to determine the time variation of the sea-ice concentration and multiyear ice fraction within the pack ice in the Arctic Basin. The images, constructed from data acquired from the electrically scanned microwave radiometer, are analyzed for four seasons during 1973-1975. Observations indicate significant variations in the sea-ice concentration in the spring, late fall, and early winter. Sea-ice concentrations as low as 50% were detected in large areas in the interior of the Arctic polar sea-ice pack. The applicability of passive-microwave remote sensing for monitoring the time dependence of sea-ice concentration is considered.

Gloersen, P.↗
NASA NTRS1978

Ionized dopant concentrations at the heavily doped surface of a silicon solar cell

Data are combined with concentrations obtained by a bulk measurement method using successive layer removal with measurements of Hall effect and resistivity. From the MOS (metal-oxide-semiconductor) measurements it is found that the ionized dopant concentration N has the value (1.4 + or - 0.1) x 10 to the 20th power/cu cm at distances between 100 and 220 nm from the n(+) surface. The bulk measurement technique yields average values of N over layers whose thickness is 2000 nm. Results show that, at the higher concentrations encountered at the n(+) surface, the MOS C-V technique, when combined with a bulk measurement method, can be used to evaluate the effects of materials preparation methodologies on the surface and near surface concentrations of silicon cells.

Weinberg, I.↗
NASA NTRS1978

Concentrator enhanced solar arrays design study

The analysis and preliminary design of a 25 kW concentrator enhanced lightweight flexible solar array are presented. The study was organized into five major tasks: (1) assessment and specification of design requirements; (2) mechanical design; (3) electric design; (4) concentrator design; and (5) cost projection. The tasks were conducted in an iterative manner so as to best derive a baseline design selection. The objectives of the study are discussed and comparative configurations and mass data on the SEP (Solar Electric Propulsion) array design, concentrator design options and configuration/mass data on the selected concentrator enhanced solar array baseline design are presented. Design requirements supporting design analysis and detailed baseline design data are discussed. The results of the cost projection analysis and new technology are also discussed.

Lott, D. R.↗