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Phosphate Textural Diversity in CI Chondrites and C-Type Asteroids

Introduction: Apatite, Ca 5 (PO 4 ) 3 (CL/F/OH-), is a ubiquitous phosphate found throughout the solar system, including the most primitive solids, CI-chondrites [1,2] and related samples of carbonaceous asteroids Ryugu [3] and Bennu [4], returned by JAXA’s Hayabusa2 and NASA’s OSIRIS-REx missions, respectively. Apatite in these primitive solids is found as individual grains or mineral clusters and has been inferred to form from the hydrothermal sequence during cooling of their respective parent body or bodies. To better understand the formation history and reworking of these early phosphates we have undertaken a highly coordinated study of phosphate microstructures, geochemistry and U/Pb geochronology from a suite of CI meteorites and carbonaceous asteroid samples. These data have identified novel phosphate microstructures and complex relationships across a suite of apatite grains from the early solar system, indicating multiple episodes of growth and modification on the CI parent body(ies). Methods: Samples of CI chondrites, Alais, Ivuna, Orgueil, Oued Chebeika 002, Yamato (Y) 82162, Y980115, Y980134, and two chips of Hayabusa2 Ryugu particles (A0262 and C0263) have been acquired for analysis. The bulk texture of the samples were first scanned by X-ray Computed Tomography (XCT) using the Nikon XT H 320 within the XFACT facility at NASA JSC or the Xradia 620 Versa at the UTCT facility. Based on the identification of petrofabrics or features of interest from the XCT data, samples were chipped, oriented, potted in epoxy and thick sections were prepared. After anhydrously polishing the samples with silicon carbide and dry diamond powder down to 1 µm, the samples were ion polished using a Hitachi ArBlade. Energy dispersive Xray spectrometry (EDS) maps were collected to ID phosphates of interest using a JEOL 7900F SEM. The internal microstructures of identified phosphates were then mapped by electron backscatter diffraction (EBSD) using the JEOL 7900F. Based on the EDS and EBSD data, domains of interest were targeted for quantitative chemical analyses using a JEOL 8530 EPMA. Subsequently, in situ U-Pb and 207 Pb/ 206 Pb ages will be collected using a Cameca ims1290 secondary ion mass spectrometer at UCLA across a range of microstructures. Results: Apatite grains are ubiquitous throughout the CI chondrites and carbonaceous asteroid materials, found as individual grains, disseminated clusters or grain aggregates. Apatite grains are associated with serpentine, magnet-ite, and/or carbonate. Of particular interest, we have identified individual and aggregate polycrystalline grains ex-hibiting an internal ‘honeycomb’ texture (Fig. 1). Some of these grains appear overprinted by subsequent alteration while others remain unaltered. Apatite halogen sites are dominated by the missing component, assumed to be OH, and F, comparable to published values from Bennu, Ryugu and CM-chondrites [3-5]. However, the Yamato CI-like meteorites show a broader range of Cl values, and one grain from Alais is dominated by CL. Summary: Apatite growth features indicate a protracted and complex growth history, consistent with precipitation from an evolving fluid system. The ‘honeycomb’ texture identified in some CI meteorites is, to the best of our knowledge, the first report of such a microstructure in meteoritic phosphate. The microtextures and zoning will guide subsequent age analyses, to better constrain the formation and reworking of phosphate in CI(-like) materials. Acknowledgments: We thank the National Institute of Polar Research, Japan for samples of Y82162, 980115 and 980134 meteorites, ASU’s Buseck Center for Meteorite Studies for samples of Ivuna and Alais meteorites, and JAXA curation for chips of Ryugu material. This work was funded by NASA ROSES LARS grant 24-LARS24-0014. References: [1] Morlok et al., 2016, GCA 70:5371-5394. [2] Alfin g et al., 2019, Geochemistry 79:125532. [3] Nakamura et al. (2022) Science 379:1-15. [4] Seifert et al. (2026) MAPS 61:504-521. [5] Piralla et al. (2021) MAPS 56:809-828.

CI chondrites↗

Bragg Curve, Biological Bragg Curve and Biological Issues in Space Radiation Protection with Shielding

The space environment consists of a varying field of radiation particles including high-energy ions, with spacecraft shielding material providing the major protection to astronauts from harmful exposure. Unlike low-LET gamma or X-rays, the presence of shielding does not always reduce the radiation risks for energetic charged particle exposure. Since the dose delivered by the charged particle increases sharply as the particle approaches the end of its range, a position known as the Bragg peak, the Bragg curve does not necessarily represent the biological damage along the particle traversal since biological effects are influenced by the track structure of both primary and secondary particles. Therefore, the biological Bragg curve is dependent on the energy and the type of the primary particle, and may vary for different biological endpoints. To achieve a Bragg curve distribution, we exposed cells to energetic heavy ions with the beam geometry parallel to a monolayer of fibroblasts. Qualitative analyses of gamma-H2AX fluorescence, a known marker of DSBs, indicated increased clustering of DNA damage before the Bragg peak, enhanced homogenous distribution at the peak, and provided visual evidence of high linear energy transfer (LET) particle traversal of cells beyond the Bragg peak. A quantitative biological response curve generated for micronuclei (MN) induction across the Bragg curve did not reveal an increased yield of MN at the location of the Bragg peak. However, the ratio of mono-to bi-nucleated cells, which indicates inhibition in cell progression, increased at the Bragg peak location. These results, along with other biological concerns, show that space radiation protection with shielding can be a complicated issue.

Honglu, Wu↗

NASA Technology Investments in Electric Propulsion: New Directions in the New Millennium

The last decade was a period of unprecedented acceptance of NASA developed electric propulsion by the user community. The benefits of high performance electric propulsion systems are now widely recognized, and new technologies have been accepted across the commonly. NASA clearly recognizes the need for new, high performance, electric propulsion technologies for future solar system missions and is sponsoring aggressive efforts in this area. These efforts are mainly conducted under the Office of Aerospace Technology. Plans over the next six years include the development of next generation ion thrusters for end of decade missions. Additional efforts are planned for the development of very high power thrusters, including magnetoplasmadynamic, pulsed inductive, and VASIMR, and clusters of Hall thrusters. In addition to the in-house technology efforts, NASA continues to work closely with both supplier and user communities to maximize the acceptance of new technology in a timely and cost-effective manner. This paper provides an overview of NASA's activities in the area of electric propulsion with an emphasis on future program directions.

Sankovic, John M.↗

An inhomogeneous reference catalogue of identified intervening heavy element systems in spectra of QSOs

Identifications of heavy element line systems, observed in spectra of quasi-stellar objects between 1965 and 1989 inclusive, are collected and tabulated with references. Each system is assigned a quality grade based on the apparent reliability of the data. The highest quality systems are used to characterize the absorbers as a sample. A decrease in C IV line strength with redshift (z), and the corresponding decrease in line density per unit z with z are confirmed. The weakest C IV systems, at high z, are accompanied by relatively stronger Si IV lines, compared to the relative line strengths at low z. The space density of systems with strong lines of first ions is nearly independent of z below z = 3, though it drops at z greater than 3. Preliminary tests for quasar lensing by intervening systems and for clustering of absorbers on large scales are presented.

York, Donald G.↗

Dissipation of Turbulence in the Solar Wind as Measured by Cluster

Turbulence in fluids and plasmas is a scale-dependent process that generates fluctuations towards ever-smaller scales until dissipation occurs. Recent Cluster observations in the solar wind demonstrate the existence of a cascade of magnetic energy from the scale of the proton Larmor radius, where kinetic properties of ions invalidate fluid approximations, down to the electron Larmor radius, where electrons become demagnetized. The cascade is quasi-two-dimensional and has been interpreted as consisting of highly oblique kinetic Alfvenic fluctuations that dissipate near at the electron gyroradius scale via proton and electron Landau damping. Here we investigate for the first time the spatial properties of the turbulence at these scales. We report the presence of thin current sheets and discontinuities with spatial sizes greater than or approximately equal to the proton Larmor radius. These isolated structures may be manifestations of intermittency, and such would localize sites of turbulent dissipation. Studying the relationship between turbulent dissipation, reconnection and intermittency is crucial for understanding the dynamics of laboratory and astrophysical plasmas.

Goldstein, Melvyn↗

Proposal for Testing and Validation of Vacuum Ultra-Violet Atomic Laser-Induced Fluorescence as a Method to Analyze Carbon Grid Erosion in Ion Thrusters

Previous investigation under award NAG3-25 10 sought to determine the best method of LIF to determine the carbon density in a thruster plume. Initial reports from other groups were ambiguous as to the number of carbon clusters that might be present in the plume of a thruster. Carbon clusters would certainly affect the ability to LIF; if they were the dominant species, then perhaps the LIF method should target clusters. The results of quadrupole mass spectroscopy on sputtered carbon determined that minimal numbers of clusters were sputtered from graphite under impact from keV Krypton. There were some investigations in the keV range by other groups that hinted at clusters, but at the time the proposal was presented to NASA, there was no data from low-energy sputtering available. Thus, the proposal sought to develop a method to characterize the population only of atoms sputtered from a graphite target in a test cell. Most of the ground work had been established by the previous two years of investigation. The proposal covering 2003 sought to develop an anti-Stokes Raman shifting cell to generate VUW light and test this cell on two different laser systems, ArF and YAG- pumped dye. The second goal was to measure the lowest detectable amounts of carbon atoms by 156.1 nm and 165.7 nm LIF. If equipment was functioning properly, it was expected that these goals would be met easily during the timeframe of the proposal, and that is the reason only modest funding was requested. The PI was only funded at half- time by Glenn during the summer months. All other work time was paid for by Whitworth College. The college also funded a student, Charles Shawley, who worked on the project during the spring.

Stevens, Richard↗

HD 47755, a new eclipsing binary

The IUE spectra of the close binary star HD 47755 have been examined in order to determine its geometry, chemical composition, and light curve. UBV fluxes in the spectra, when dereddened for E(B-V) = 0.09 yield an effective temperature of 16,500 K. The ratio of the mean radii of the stars is found to agree well with an old blueband spectrophotometric value. Eclipses in the binary have been observed and a complex green light curve is derived. It is suggested that the wind from at least one of the components of HD 47755 is the source of the complexity in the light curve. The geometry of the HD 47755 is compared to that of V 641 Mon, A definite cluster member of NGC 2264. The interstellar line spectrum is found to be similar to that of V 641 Mon and the column densities for a few interstellar ions are given in a table. Evaluation of the nonastrometric evidence indicates that HD 47755 is also a member of NGC 2264.

Koch, R. H.↗

Surface diffusion activation energy determination using ion beam microtexturing

The activation energy for impurity atom (adatom) surface diffusion can be determined from the temperature dependence of the spacing of sputter cones. These cones are formed on the surface during sputtering while simultaneously adding impurities. The impurities form clusters by means of surface diffusion, and these clusters in turn initiate cone formation. Values are given for the surface diffusion activation energies for various materials on polycrystalline Cu, Al, Pb, Au, and Ni. The values for different impurity species on each of these substrates are approximately independent of impurity species within the experimental uncertainty, suggesting the absence of strong chemical bonding effects on the diffusion.

Rossnagel, S. M.↗

A hydrodynamic approach to cosmology: The mixed dark matter cosmological scenario

We compute the evolution of spatially flat, mixed cold and hot dark matter models containing both baryonic matter and two kinds of dark matter. Hydrodynamics is treated with a highly developed Eulerian hydrodynamic code (see Cen 1992). A standard particle-mesh (PM) code is also used in parallel to calculate the motion of the dark matter components. We adopt the following parameters: h equivalent to (sub 0)/100 km/s Mpc(exp -1) = 0.5, OMEGA(sub C) = 0.3, and OMEGA(sub B) = 0.06, with amplitude of the perturbation spectrum fixed by the Cosmic Background Explorer Satellite (COBE) Dark Matter Radiation (DMR) measurements (Smoot et al. 1992) being sigma (sub 8) = 0.67. Four different boxes are simulated with box sizes of L = (64, 16, 4, 1) h(exp -1) Mpc, respectively, the two small boxes providing good resolution but little valid information due to absence of large-scale power. We use 128(exp 3) approximate 10(exp 6.3) baryonic cells, 128(exp .3) cold dark matter particles, and 2 x 128(exp 3) hot dark matter particles. In addition to the dark matter we follow separately six baryonic species (H, H(+), He, He(+), He(++), e(-)) with allowance for both (nonequilibrium) collisional and radiative ionization in every cell. The background radiation field is also followed in detail with allowance made for both continuum and line processes, to allow nonequilibrium heating and cooling processes to be followed in detail. The mean final Zeldovich-Sunyaev y parameter is estimated to be y Bar = (5.4 + or - 2.7) x 10(exp -7) below currently attainable observations, with a rms fluctuation of approximately delta bar y = (0.6 + or - 3.0) x 10(exp -7) on arcminute scales. The rate of galaxy formation peaks at an even later epoch (z approximate 0.3) than in the standard (OMEGA = 1, sigma sub 8 = 0.67) cold dark matter (CDM) model (z approximate 0.5) and, at a redshift of z = 4, is nearly a factor of 100 lower than for the CDM model with the same value of sigma sub 8. With regard to mass function, the smallest objects are stabilized against collapse by thermal energy: the mass-weighted mass spectrum has a broad peak in the vicinity of M(sub B) = 10(exp 9.5) solar mass with a reasonable fit to the Schechter luminosity function if the ratio of baryon mass to blue light is approximately 4. In addition, one very large PM simulation was made in a box with size (320 h(exp - 1) Mpc) containing 3 x 200(exp 3) = 10(exp 7.4) particles. Utilizing this simulation we find that the model yields a cluster mass function which is about a factor of 4 higher than observed, but a cluster-cluster correlation length marginally lower than observed, but that both are closer to observations than in the (COBE) normalized CDM model. The one-dimensional pairwise velocity dispersion is 605 + or - 8 km/s at 1/h separation, lower than that of the DCM model normalized to COBE, but still significant higher than observations (Davis & Peebles 1983). A plausible velocity bias b(sub v) = 0.8 + or - 0.1 on this scale will reduce but not remove the discrepancy. The velocity auto-correlat ion function has a coherence length of 40/h Mpc, which is somewhat lower than the observed counterpart. In all these respects the model would be improved by decreasing the cold fraction of the dark OMEGA(sub CDM)/ (OMEGA(sub CDM) + OMEGA(sub HDB). But formation of galaxies and clusters of galaxies is much later in this model than in COBE-normalized CDM, perhaps too late. To improve on these constraints a larger ratio of OMEGA(sub CDM)/ (OMEGA(sub CDM) + OMEGA(sub HDM)) is required than the value of 0.67 adopted here. It does not seem possible to find a value for this ratio which would satisfy all tests. Overall, the model is similar both on large and intermediate scales to the standard CDM model normalized to the same value of sigma(sub B), but the problem with regard to late formation of galaxies is more severe in this model than in that CDM model. Adding hot dark matter, significantly improves the ability of the COBE-normalized CDM scenario to fit existing observations, but the model is in fact not as good as the CDM model with the same sigma(sub 8) and is still probably unsatisfactory with regard to several critical tests.

Cen, Renyue↗

Modeling of the Convection and Interaction of Ring Current, Plasmaspheric and Plasma Sheet Plasmas in the Inner Magnetosphere

Distinctive sources of ions reside in the plasmasphere, plasmasheet, and ring current regions at discrete energies constitute the major plasma populations in the inner/middle magnetosphere. They contribute to the electrodynamics of the ionosphere-magnetosphere system as important carriers of the global current system, in triggering; geomagnetic storm and substorms, as well as critical components of plasma instabilities such as reconnection and Kelvin-Helmholtz instability at the magnetospheric boundaries. Our preliminary analysis of in-situ measurements shoves the complexity of the plasmas pitch angle distributions at particularly the cold and warm plasmas, vary dramatically at different local times and radial distances from the Earth in response to changes in solar wind condition and Dst index. Using an MHD-ring current coupled code, we model the convection and interaction of cold, warm and energetic ions of plasmaspheric, plasmasheet, and ring current origins in the inner magnetosphere. We compare our simulation results with in-situ and remotely sensed measurements from recent instrumentation on Geotail, Cluster, THEMIS, and TWINS spacecraft.

Fok, Mei-Ching↗

Temperature Structure in the Perseus Cluster Core Observed with Hitomi

The present paper investigates the temperature structure of the X-ray emitting plasma in the core of the Perseus cluster using the 1.8-20.0 keV data obtained with the Soft X-ray Spectrometer (SXS) onboard the Hitomi Observatory. A series of four observations were carried out, with a total effective exposure time of 338 ks and covering a central region _ 7′ in diameter. The SXS was operated with an energy resolution of _5 eV (full width at half maximum) at 5.9 keV. Not only fine structures of K-shell lines in He-like ions but also transitions from higher principal quantum numbers are clearly resolved from Si through Fe. This enables us to perform temperature diagnostics using the line ratios of Si, S, Ar, Ca, and Fe, and to provide the first direct measurement of the excitation temperature and ionization temperature in the Perseus cluster. The observed spectrum is roughly reproduced by a single temperature thermal plasma model in collisional ionization equilibrium, but detailed line ratio diagnostics reveal slight deviations from this approximation. In particular, the data exhibit an apparent trend of increasing ionization temperature with increasing atomic mass, as well as small differences between the ionization and excitation temperatures for Fe, the only element for which both temperatures can be measured. The best-fit two-temperature models suggest a combination of 3 and 5 keV gas, which is consistent with the idea that the observed small deviations from a single temperature approximation are due to the effects of projection of the known radial temperature gradient in the cluster core along the line of sight. Comparison with the Chandra/ACIS and the XMM-Newton/RGS results on the other hand suggests that additional lower-temperature components

Aharonian, Felix↗

Observation and theory of Pc 5 waves with harmonically related transverse and compressional components

The properties of 23 magnetic pulsation events observed by the AMPTE CCE spacecraft are studied. These events are selected on the basis of the field magnitude which oscillated at the second harmonic of a simultaneously present transverse oscillation. The events have a second harmonic period of 80-600 s (roughly the Pc 5 range), are observed in cluster in the dawn (0300-0800 magnetic local time, MLT) and dusk (1600-2100 MLT) sectors, and are localized near the magnetic equator. Although the azimuthal wave number estimated from an ion finite Larmor radius effect, is generally large (about 50), there is a marked difference between the events observed in the dawn and dusk sectors. In the dawn sector the waves have low frequencies (1-5 mHz), indicate left-hand polarization with respect to the ambient magnetic field, and propagate eastward with respect to the spacecraft. In the dusk sector the waves have high frequencies (5-15 mHz), indicate right-hand polarization, and propagate westward. It is suggested that the waves are all westward propagating in the plasma rest frame and that local-time-dependent Doppler shift is the reason for the local time dependence of the wave properties.

Takahashi, K.↗

Theoretical study of polarizabilities and hyperpolarizabilities of Ne, HF, F(-), and OH(-)

Theoretical calculations are presented for the polarizability parameters through the fourth power of an applied static electric field for Ne and HF and through the second power in the field for the negative ions F(-) and OH(-). Large Gaussian basis sets are employed and electron correlation is incorporated using the modified coupled pair functional (MCPF) method and for Ne and HF using coupled-cluster single- and double-excitation (CCSD) methods with two approaches of including the effect of triple excitations. The MCPF method is found to perform well in relation to the more rigorous CCSD method.

Chong, Delano P.↗

The violet interstellar medium associated with the Carina Nebula

The interstellar spectrum of HD 93205, an 03V star in the cluster Tr16, located inside the most active part of the Great Carina Nebula was analyzed using data extracted directly from raw IUE images. From the analysis of 67 lines of 25 atoms, ions and molecules, up to six discrete absorption components spanning a maximum velocity range of approximately 375 km 5/1 were identified. The component structure for different species is tabulated and sample absorption lines, indicating at the top the positions of the six components, labelled A to F are shown. Ion column densities appropriate to each component which can be resolved in at least one line were derived by constructing empirical curves of growth and by fitting the observations with corresponding theoretical absorption line profiles. The most important results concerning each component are discussed.

Pettini, M.↗

RAPID: The imaging energetic particle spectrometer on Cluster

The RAPID spectrometer for the Cluster mission, an advanced particle detector for the analysis of suprathermal plasma distributions in the energy range from 20 to 400 keV and from 2 keV/nuc to 1500 keV for electrons and ions, respectively, is presented. Novel detector concepts in combination with pinhole acceptance permit the measurement of angular distributions over a range of 180 deg in polar angle for either species. The detection principle for the ionic component is based on a two dimensional analysis of a particle's velocity and energy. Electrons are identified by the well known energy range relationship. The detection techniques are described and selected areas in geospace are used to highlight the scientific objectives of this investigation.

Wilken, B.↗

An APFIM/AEM Study of Phase Decompositions in Fe-Ni Alloys at Low Temperatures

A combined atom probe field ion microscopy and analytical electron microscopy characterization has been performed on laboratory aged martensitic and austenitic specimens of FeNi and FeNiP alloys. These techniques revealed that the martensitic 24.1 and 28.6 at.% Ni alloys decomposed during aging for 1 year at 300 C to form face centered cubic precipitates of approx. 56 at.% Ni in a body centered cubic matrix containing approx. 20 at.% Ni. Some thin platelets were observed in the field ion micrographs of the austenitic Fe-42.9 at. % Ni alloy and the Fe-43.2 at.% Ni-0.44 at.% P alloy after aging at 400 and 350 C. Atom probe analysis revealed phosphorus clustering in the ternary alloy aged at 300 C.

Zhang, J.↗

Diagnosis of NMOS DRAM functional performance as affected by a picosecond dye laser

A picosec pulsed dye laser beam was at selected wavelengths successfully used to simulate heavy-ion single-event effects (SEEs) in negative channel NMOS DRAMs. A DRAM was used to develop the test technique because bit-mapping capability and previous heavy-ion upset data were available. The present analysis is the first to establish such a correlation between laser and heavy-ion data for devices, such as the NMOS DRAM, where charge collection is dominated by long-range diffusion, which is controlled by carrier density at remote distances from a depletion region. In the latter case, penetration depth is an important parameter and is included in the present analysis. A single-pulse picosecond dye laser beam (1.5 microns diameter) focused onto a single cell component can upset a single memory cell; clusters of memory cell upsets (multiple errors) were observed when the laser energy was increased above the threshold energy. The multiple errors were analyzed as a function of the bias voltage and total energy of a single pulse. A diffusion model to distinguish the multiple upsets from the laser-induced charge agreed well with previously reported heavy ion data.

Kim, Q.↗