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Cometary Coma Chemical Composition (C4) Mission

Cometary exploration remains of great importance to virtually all of space science. Because comets are presumed to be remnants of the early solar nebula, they are expected to provide fundamental knowledge as to the origin and development of the solar system as well as to be key to understanding of the source of volatiles and even life itself in the inner solar system. Clearly the time for a detailed study of the composition of these apparent messages from the past has come. A comet rendezvous mission, the Cometary Coma Chemical Composition (C4) Mission, is now being studied as a candidate for the new Discovery program. This mission is a highly-focussed and usefully-limited subset of the Cometary Rendezvous Asteroid Flyby (CRAF) Mission. The C4 mission will concentrate on measurements that will produce an understanding of the composition and physical makeup of a cometary nucleus. The core science goals of the C4 mission are 1) to determine the chemical, elemental, and isotopic composition of a cometary nucleus and 2) to characterize the chemical and isotopic nature of its atmosphere. A related goal is to obtain temporal information about the development of the cometary coma as a function of time and orbital position. The four short-period comets -- Tempel 1, Tempel 2, Churyumov-Gerasimenko, and Wirtanen -which all appear to have acceptable dust production rates, were identified as candidate targets. Mission opportunities have been identified beginning as early as 1998. Tempel I with a launch in 1999, however, remains the baseline comet for studies of and planning the C4 mission. The C4 mission incorporates two science instruments and two engineering instruments in the payload to obtain the desired measurements. The science instruments include an advanced version of the Cometary Ice and Dust Experiment (CIDEX), a mini-CIDEX with a sample collection system, an X-ray Fluorescence Spectrometer and a Pyrolysis-Gas Chromatograph, and a simplified version of the Neutral Gas and Ion Mass Spectrometer (NIGMS). Both of these instruments have substantial heritage as they are based on those developed for the CRAF Mission. The engineering instruments include a simplified Comet Dust Environmental Monitor (SCODEM) and a navigational Camera, NAVCAM. While neither of the instruments will be permitted to establish science requirements, it is anticipated that significant science return will be accomplished Radio science will also be included.

Carle, Glenn C.↗

The Gas Production Rate and Coma Structure of Comet C/1995 01 (Hale-Bopp)

The University of Wisconsin-Madison and NASA-Goddard conducted a comprehensive multi-wavelength observing campaign of coma emissions from comet Hale-Bopp, including OH 3080 A, [O I] 6300 A, H2O(+) 6158 A, H Balmer-alpha 6563 A, NH2 6330 A, [C I] 9850 A CN 3879 A, C2 5141 A, C3 4062 A, C I 1657 A, and the UV and optical continua. In this work, we concentrate on the results of the H2O daughter studies. Our wide-field OH 3080 A measured flux agrees with other, similar observations and the expected value calculated from published water production rates using standard H2O and OH photochemistry. However, the total [O I] 6300 A flux determined spectroscopically over a similar field-of-view was a factor of 3 - 4 higher than expected. Narrow-band [O I] images show this excess came from beyond the H2O scale length, suggesting either a previously unknown source of [O I] or an error in the standard OH + upsilon to O((sup I)D) + H branching ratio. The Hale-Bopp OH and [O I] distributions, both of which were imaged to cometocentric distances greater than 1 x 10(exp 6) km, were more spatially extended than those of comet Halley (after correcting for brightness differences), suggesting a higher bulk outflow velocity. Evidence of the driving mechanism for this outflow is found in the H(alpha) line profile, which was narrower than in comet Halley (though likely because of opacity effects, not as narrow as predicted by Monte-Carlo models). This is consistent with greater collisional coupling between the suprathermal H photodissociation products and Hale-Bopp's dense coma. Presumably because of mass loading of the solar wind by ions and ions by the neutrals, the measured acceleration of H2O(+) down the ion tail was much smaller than in comet Halley. Tailward extensions in the azimuthal distributions of OH 3080 A, [O I], and [C I], as well as a Doppler asymmetry in the [O I] line profile, suggest ion-neutral coupling. While the tailward extension in the OH can be explained by increased neutral acceleration, the [O I] 6300 A and [C I] 9850 A emissions show 13% and less than 200% excesses in this direction (respectively), suggesting a non-negligible contribution from dissociative recombination of CO(+) and/or electron collisional excitation. Thus, models including the effects of photo-and collisional chemistry are necessary for the full interpretation of these data.

Morgenthaler, Jeffrey P.↗

HCO+ in the coma of comet Hale-Bopp

Maps of comet C/1995 O1 (Hale-Bopp) in the millimeter-wave emission of the ion HCO+ revealed a local minimum near the nucleus position, with a maximum about 100,000 km in the antisolar direction. These observed features of the HCO+ emission require a low abundance of HCO+ due to enhanced destruction in the inner coma of the comet, within a region of low electron temperature (Te). To set constraints on the formation of HCO+ in the coma, as well as the location and magnitude of the transition to higher Te, the data are compared with the results of ion-molecule chemistry models.

Non-NASA Center↗

Spectroscopic Investigations of Fragment Species in the Coma

The content of the gaseous coma of a comet is dominated by fragment species produced by photolysis of the parent molecules issuing directly from the icy nucleus of the comet. Spectroscopy of these species provides complementary information on the physical state of the coma to that obtained from observations of the parent species. Extraction of physical parameters requires detailed molecular and atomic data together with reliable high-resolution spectra and absolute fluxes of the primary source of excitation, the Sun. The large database of observations, dating back more than a century, provides a means to assess the chemical and evolutionary diversity of comets.

Feldman, Paul D.↗

Comet 81p/Wild 2: The Updated Stardust Coma Dust Fluence Measurement for Smaller (Sub 10-Micrometre) Particles

Micrometre and smaller scale dust within cometary comae can be observed by telescopic remote sensing spectroscopy [1] and the particle size and abundance can be measured by in situ spacecraft impact detectors [2]. Initial interpretation of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft [3] appears to show that very fine dust contributes not only a small fraction of the solid mass, but is also relatively sparse [4], with a low negative power function describing grain size distribution, contrasting with an apparent abundance indicated by the on-board Dust Flux Monitor Instrument (DFMI) [5] operational during the encounter. For particles above 10 m diameter there is good correspondence between results from the DFMI and the particle size inferred from experimental calibration [6] of measured aerogel track and aluminium foil crater dimensions (as seen in Figure 4 of [4]). However, divergence between data-sets becomes apparent at smaller sizes, especially submicrometre, where the returned sample data are based upon location and measurement of tiny craters found by electron microscopy of Al foils. Here effects of detection efficiency tail-off at each search magnification can be seen in the down-scale flattening of each scale component, but are reliably compensated by sensible extrapolation between segments. There is also no evidence of malfunction in the operation of DFMI during passage through the coma (S. Green, personal comm.), so can the two data sets be reconciled?

Price, M. C.↗

Comet C2012 S1 (ISON)s Carbon-rich and Micron-size-dominated Coma Dust

Comet C/2012 S1 (ISON) was unique in that it was a dynamically new comet derived from the Nearly Isotropic Oort cloud reservoir of comets with a sun-grazing orbit. We present thermal models for comet ISON (rh approx.1.15 AU, 2013-Oct-25 11:30 UT) that reveal comet ISON's dust was carbon-rich and dominated by a narrow size distribution dominated by approx. micron-sized grains. We constrained the models by our SOFIA FORCAST photometry at 11.1, 19.7 and 31.5 microns and by a silicate feature strength of approx.1.1 and an 8-13microns continuum greybody color temperature of approx. 275-280 K (using Tbb ∝ r−0.5 h and Tbb approx. 260-265 K from Subaru COMICS, 2013-Oct-19 UT)[1,2]. N-band spectra of comet ISON with the BASS instrument on the NASA IRTF (2013-Nov-11-12 UT) show a silicate feature strength of approx. 1.1 and an 11.2microns forsterite peak.[3] Our thermal models yield constraints the dust composition as well as grain size distribution parameters: slope, peak grain size, porosity. Specifically, ISON's dust has a low silicate-to- amorphous carbon ratio (approx. 1:9), and the coma size distribution has a steep slope (N4.5) such that the coma is dominated by micron-sized, moderately porous, carbon-rich dust grains. The N-band continuum color temperature implies submicronto micron-size grains and the steep fall off of the SOFIA far-IR photometry requires the size distribution to have fewer relative numbers of larger and cooler grains compared to smaller and hotter grains. A proxy for the dust production rate is fρ approx.1500 cm, akin to Afρ. ISON has a moderate-to-low dust-to-gas ratio. Comet ISON's dust grain size distribution does not appear similar to the few well-studied long-period Nearly Isotropic Comets (NICs), namely C/1995 O1 (Hale-Bopp) and C/2001 Q4 (NEAT) that had smaller and/or more highly porous grains and larger sizes, or C/2007 N4 (Lulin) and C/2006 P1 (McNaught) that had large and/or compact grains. Radial transport to comet-forming disk distances (≥ 20 AU) is easier for smaller grains (≤1 micron) than for larger grains (approx. 20 microns like Stardust terminal particles). The presence of predominantly micron-sized and smaller grains suggests comet ISON may have formed either earlier in disk evolution whereby larger grains did not have the time to be transported to distances beyond Neptune, or the comet formed so far out in the disk that larger grains did not traverse such large radial distances. The high carbon-content of ISON's refractory dust appears to be complimented by the presence of limitedlifetime organic (CHON-like) grain materials: preliminary analyses of near-IR and high-resolution optical spectra indicate that gas-phase daughter molecules C2, CN, and CH were more abundant than their parent molecules (C2H2, C2H6, measured in the near- IR). Dust composition as well as grain size distribution parameters (slope, peak grain size, and porosity) give clues to comet origins.

NASA/DLR Stratospheric Observatory↗

Mapping the Gas Turbulence in the Coma Cluster: Predictions for Astro-H

Astro-H will be able for the first time to map gas velocities and detect turbulence in galaxy clusters. One of the best targets for turbulence studies is the Coma cluster, due to its proximity, absence of a cool core, and lack of a central active galactic nucleus. To determine what constraints Astro-H will be able to place on the Coma velocity field, we construct simulated maps of the projected gas velocity and compute the second-order structure function, an analog of the velocity power spectrum. We vary the injection scale, dissipation scale, slope, and normalization of the turbulent power spectrum, and apply measurement errors and finite sampling to the velocity field. We find that even with sparse coverage of the cluster, Astro-H will be able to measure the Mach number and the injection scale of the turbulent power spectrum-the quantities determining the energy flux down the turbulent cascade and the diffusion rate for everything that is advected by the gas (metals, cosmic rays, etc.). Astro-H will not be sensitive to the dissipation scale or the slope of the power spectrum in its inertial range, unless they are outside physically motivated intervals. We give the expected confidence intervals for the injection scale and the normalization of the power spectrum for a number of possible pointing configurations, combining the structure function and velocity dispersion data. Importantly, we also determine that measurement errors on the line shift will bias the velocity structure function upward, and show how to correct this bias.

clusters: intracluster medium↗

A MULTI-WAVELENGTH ANALYSIS OF SPITZER SELECTED COMA CLUSTER GALAXIES: STAR FORMATION RATES AND MASSES

We present a thorough study of the specific star formation rates (sSFRs) for MIPS 24 {mu}m selected galaxies in the Coma cluster. We build galaxy spectral energy distributions using optical (u', g', r', i', z'), near-infrared (J, H, K{sub s} ), and mid- to far-infrared (Infrared Array Camera and MIPS) photometry. New and archival spectra confirm 210 cluster members. Subsequently, the total infrared luminosity, galaxy stellar mass, and sSFR for the members are determined by measuring best-fit templates. Using an array of complementary diagnostics, we search for any contaminating active galactic nuclei, but find few. We compare obscured SFRs to unobscured rates derived from extinction-corrected H{alpha} emission line measurements. The agreement between these two values leads us to conclude that there is no evidence for an additionally obscured component. In our spectroscopic sample, complete to 80% for r' < 19.5, we find that all starbursts are blue and are dwarfs, having masses <10{sup 9} M{sub sun}. Examining the location of these starbursts within the cluster, we confirm that there is a lower fraction in the cluster core.

79 ASTRONOMY AND ASTROPHYSICS↗

A QUARTER-CENTURY OF OBSERVATIONS OF COMET 10P/TEMPEL 2 AT LOWELL OBSERVATORY: CONTINUED SPIN-DOWN, COMA MORPHOLOGY, PRODUCTION RATES, AND NUMERICAL MODELING

We report on photometry and imaging of Comet 10P/Tempel 2 obtained at Lowell Observatory from 1983 through 2011. We measured a nucleus rotation period of 8.950 {+-} 0.002 hr from 16 nights of imaging acquired between 2010 September and 2011 January. This rotation period is longer than the period we previously measured in 1999, which was itself longer than the period measured in 1988, and demonstrates that Tempel 2 is continuing to spin down, presumably due to torques caused by asymmetric outgassing. A nearly linear jet was observed which varied little during a rotation cycle in both R and CN images acquired during the 1999 and 2010 apparitions. We measured the projected direction of this jet throughout the two apparitions and, under the assumption that the source region of the jet was near the comet's pole, determined a rotational pole direction of R.A./decl. = 151 Degree-Sign /+59 Degree-Sign from CN measurements and R.A./decl. = 173 Degree-Sign /+57 Degree-Sign from dust measurements (we estimate a circular uncertainty of 3 Degree-Sign for CN and 4 Degree-Sign for dust). Different combinations of effects likely bias both gas and dust solutions and we elected to average these solutions for a final pole direction of R.A./decl. = 162 Degree-Sign {+-} 11 Degree-Sign /+58 Degree-Sign {+-} 1 Degree-Sign . Photoelectric photometry was acquired on 3 nights in 1983, 2 nights in 1988, 19 nights in 1999/2000, and 10 nights in 2010/2011. The activity exhibited a steep 'turn-on' {approx}3 months prior to perihelion (the exact timing of which varies) and a relatively smooth decline after perihelion. The activity during the 1999 and 2010 apparitions was similar; limited data in 1983 and 1988 (along with IUE data from the literature) were systematically higher and the difference cannot be explained entirely by the smaller perihelion distance. We measured a 'typical' composition, in agreement with previous investigators. Monte Carlo numerical modeling with our pole solution best replicated the observed coma morphology for a source region located near a comet latitude of +80 Degree-Sign and having a radius of {approx}10 Degree-Sign . Our model reproduced the seasonal changes in activity, suggesting that the majority of Tempel 2's activity originates from a small active region located near the pole. We also find that a cosine-squared solar angle function gives the best fit as compared to a standard cosine function.

79 ASTRONOMY AND ASTROPHYSICS↗

HUBBLE SPACE TELESCOPE AND HI IMAGING OF STRONG RAM PRESSURE STRIPPING IN THE COMA SPIRAL NGC 4921: DENSE CLOUD DECOUPLING AND EVIDENCE FOR MAGNETIC BINDING IN THE ISM

Remarkable dust extinction features in the deep Hubble Space Telescope (HST) V and I images of the face-on Coma cluster spiral galaxy NGC 4921 show in unprecedented ways how ram pressure strips the ISM from the disk of a spiral galaxy. New VLA HI maps show a truncated and highly asymmetric HI disk with a compressed HI distribution in the NW, providing evidence for ram pressure acting from the NW. Where the HI distribution is truncated in the NW region, HST images show a well-defined, continuous front of dust that extends over 90° and 20 kpc. This dust front separates the dusty from dust-free regions of the galaxy, and we interpret it as galaxy ISM swept up near the leading side of the ICM–ISM interaction. We identify and characterize 100 pc–1 kpc scale substructure within this dust front caused by ram pressure, including head–tail filaments, C-shaped filaments, and long smooth dust fronts. The morphology of these features strongly suggests that dense gas clouds partially decouple from surrounding lower density gas during stripping, but decoupling is inhibited, possibly by magnetic fields that link and bind distant parts of the ISM.

79 ASTRONOMY AND ASTROPHYSICS↗

THE LACK OF DIFFUSE, NON-THERMAL HARD X-RAY EMISSION IN THE COMA CLUSTER: THE SWIFT BURST ALERT TELESCOPE'S EYE VIEW

The Coma Cluster of galaxies hosts the brightest radio halo known and has therefore been the target of numerous searches for associated inverse Compton (IC) emission, particularly at hard X-ray energies where the IC signal must eventually dominate over thermal emission. The most recent search with the Suzaku Hard X-ray Detector failed to confirm previous IC detections with RXTE and BeppoSAX, instead setting an upper limit 2.5 times below their non-thermal flux. However, this discrepancy can be resolved if the IC emission is very extended, beyond the scale of the cluster radio halo. Using reconstructed sky images from the 58-month Swift Burst Alert Telescope (BAT) all-sky survey, the feasibility of such a solution is investigated. Building on Renaud et al., we test and implement a method for extracting the fluxes of extended sources, assuming specified spatial distributions. BAT spectra are jointly fit with an XMM-Newton EPIC-pn spectrum derived from mosaic observations. We find no evidence for large-scale IC emission at the level expected from the previously detected non-thermal fluxes. For all non-thermal spatial distributions considered, which span the gamut of physically reasonable IC models, we determine upper limits for which the largest (most conservative) limit is {approx}<4.2 x 10{sup -12} erg s{sup -1} cm{sup -2} (20-80 keV), which corresponds to a lower limit on the magnetic field B > 0.2 {mu} G. A nominal flux upper limit of <2.7 x 10{sup -12} erg s{sup -1} cm{sup -2}, with corresponding B > 0.25 {mu} G, is derived for the most probable IC distribution given the size of the radio halo and likely magnetic field radial profile.

79 ASTRONOMY AND ASTROPHYSICS↗

THE EVOLUTION OF RADIO GALAXIES AND X-RAY POINT SOURCES IN COMA CLUSTER PROGENITORS SINCE z {approx} 1.2

Using Chandra imaging spectroscopy and Very Large Array (VLA) L-band radio maps, we have identified radio sources at P{sub 1.4GHz} {>=} 5 x 10{sup 23} W Hz{sup -1} and X-ray point sources (XPSs) at L{sub 0.3-8 keV} {>=} 5 x 10{sup 42} erg s{sup -1} in L > L* galaxies in 12 high-redshift (0.4 < z < 1.2) clusters of galaxies. The radio galaxies and XPSs in this cluster sample, chosen to be consistent with Coma Cluster progenitors at these redshifts, are compared to those found at low-z analyzed in Hart et al. Within a projected radius of 1 Mpc of the cluster cores, we find 17 cluster radio galaxies (11 with secure redshifts, including one luminous FR II radio source at z = 0.826, and six more with host galaxy colors similar to cluster ellipticals). The radio luminosity function (RLF) of the cluster radio galaxies as a fraction of the cluster red-sequence (CRS) galaxies reveals significant evolution of this population from high-z to low-z, with higher power radio galaxies situated in lower temperature clusters at earlier epochs. Additionally, there is some evidence that cluster radio galaxies become more centrally concentrated than CRS galaxies with cosmic time. Within this same projected radius, we identify seven spectroscopically confirmed cluster XPSs, all with CRS host galaxy colors. Consistent with the results from Martini et al., we estimate a minimum X-ray active fraction of 1.4% {+-} 0.8% for CRS galaxies in high-z clusters, corresponding to an approximate 10-fold increase from 0.15% {+-} 0.15% at low-z. Although complete redshift information is lacking for several XPSs in z > 0.4 cluster fields, the increased numbers and luminosities of the CRS radio galaxies and XPSs suggest a substantial (9-10-fold) increase in the heat injected into high-redshift clusters by AGNs compared to the present epoch.

79 ASTRONOMY AND ASTROPHYSICS↗

NARROW DUST JETS IN A DIFFUSE GAS COMA: A NATURAL PRODUCT OF SMALL ACTIVE REGIONS ON COMETS

Comets often display narrow dust jets but more diffuse gas comae when their eccentric orbits bring them into the inner solar system and sunlight sublimates the ice on the nucleus. Comets are also understood to have one or more active areas covering only a fraction of the total surface active with sublimating volatile ices. Calculations of the gas and dust distribution from a small active area on a comet's nucleus show that as the gas moves out radially into the vacuum of space it expands tangentially, filling much of the hemisphere centered on the active region. The dust dragged by the gas remains more concentrated over the active area. This explains some puzzling appearances of comets having collimated dust jets but more diffuse gaseous atmospheres. Our test case is 67P/Churyumov-Gerasimenko, the Rosetta mission target comet, whose activity is dominated by a single area covering only 4% of its surface.

79 ASTRONOMY AND ASTROPHYSICS↗

THE ALLEN TELESCOPE ARRAY Pi GHz SKY SURVEY. III. THE ELAIS-N1, COMA, AND LOCKMAN HOLE FIELDS

We present results from a total of 459 repeated 3.1 GHz radio continuum observations (of which 379 were used in a search for transient sources) of the ELAIS-N1, Coma, Lockman Hole, and NOAO Deep Wide Field Survey fields as part of the Pi GHz Sky Survey. The observations were taken approximately once per day between 2009 May and 2011 April. Each image covers 11.8 square degrees and has 100'' FWHM resolution. Deep images for each of the four fields have rms noise between 180 and 310 {mu}Jy, and the corresponding catalogs contain {approx}200 sources in each field. Typically 40-50 of these sources are detected in each single-epoch image. This represents one of the shortest cadence, largest area, multi-epoch surveys undertaken at these frequencies. We compare the catalogs generated from the combined images to those from individual epochs, and from monthly averages, as well as to legacy surveys. We undertake a search for transients, with particular emphasis on excluding false positive sources. We find no confirmed transients, defined here as sources that can be shown to have varied by at least a factor of 10. However, we find one source that brightened in a single-epoch image to at least six times the upper limit from the corresponding deep image. We also find a source associated with a z = 0.6 quasar which appears to have brightened by a factor {approx}3 in one of our deep images, when compared to catalogs from legacy surveys. We place new upper limits on the number of transients brighter than 10 mJy: fewer than 0.08 transients deg{sup -2} with characteristic timescales of months to years; fewer than 0.02 deg{sup -2} with timescales of months; and fewer than 0.009 deg{sup -2} with timescales of days. We also plot upper limits as a function of flux density for transients on the same timescales.

79 ASTRONOMY AND ASTROPHYSICS↗

Subaru weak-lensing survey of dark matter subhalos in the Coma cluster: Subhalo mass function and statistical properties

We present a 4 deg{sup 2} weak gravitational lensing survey of subhalos in the very nearby Coma cluster using the Subaru/Suprime-Cam. The large apparent size of cluster subhalos allows us to measure the mass of 32 subhalos detected in a model-independent manner, down to the order of 10{sup –3} of the virial mass of the cluster. Weak-lensing mass measurements of these shear-selected subhalos enable us to investigate subhalo properties and the correlation between subhalo masses and galaxy luminosities for the first time. The mean distortion profiles stacked over subhalos show a sharply truncated feature which is well-fitted by a Navarro-Frenk-White (NFW) mass model with the truncation radius, as expected due to tidal destruction by the main cluster. We also found that subhalo masses, truncation radii, and mass-to-light ratios decrease toward the cluster center. The subhalo mass function, dn/dln M {sub sub}, in the range of 2 orders of magnitude in mass, is well described by a single power law or a Schechter function. Best-fit power indices of 1.09{sub −0.32}{sup +0.42} for the former model and 0.99{sub −0.23}{sup +0.34} for the latter, are in remarkable agreement with slopes of ∼0.9-1.0 predicted by the cold dark matter paradigm. The tangential distortion signals in the radial range of 0.02-2 h {sup –1} Mpc from the cluster center show a complex structure which is well described by a composition of three mass components of subhalos, the NFW mass distribution as a smooth component of the main cluster, and a lensing model from a large scale structure behind the cluster. Although the lensing signals are 1 order of magnitude lower than those for clusters at z ∼ 0.2, the total signal-to-noise ratio, S/N = 13.3, is comparable, or higher, because the enormous number of background source galaxies compensates for the low lensing efficiency of the nearby cluster.

79 ASTRONOMY AND ASTROPHYSICS↗

Extremely organic-rich coma of comet C/2010 G2 (Hill) during its outburst in 2012

We performed high-dispersion near-infrared spectroscopic observations of comet C/2010 G2 (Hill) at 2.5 AU from the Sun using NIRSPEC (R ≈ 25,000) at the Keck II Telescope on UT 2012 January 9 and 10, about a week after an outburst had occurred. Over the two nights of our observations, prominent emission lines of CH{sub 4} and C{sub 2}H{sub 6}, along with weaker emission lines of H{sub 2}O, HCN, CH{sub 3}OH, and CO were detected. The gas production rate of CO was comparable to that of H{sub 2}O during the outburst. The mixing ratios of CO, HCN, CH{sub 4}, C{sub 2}H{sub 6}, and CH{sub 3}OH with respect to H{sub 2}O were higher than those for normal comets by a factor of five or more. The enrichment of CO and CH{sub 4} in comet Hill suggests that the sublimation of these hypervolatiles sustained the outburst of the comet. Some fraction of water in the inner coma might exist as icy grains that were likely ejected from nucleus by the sublimation of hypervolatiles. Mixing ratios of volatiles in comet Hill are indicative of the interstellar heritage without significant alteration in the solar nebula.

79 ASTRONOMY AND ASTROPHYSICS↗