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At least 199 records · Page 11

Environmental fatigue of an Al-Li-Cu alloy. Part 3: Modeling of crack tip hydrogen damage

Environmental fatigue crack propagation rates and microscopic damage modes in Al-Li-Cu alloy 2090 (Parts 1 and 2) are described by a crack tip process zone model based on hydrogen embrittlement. Da/dN sub ENV equates to discontinuous crack advance over a distance, delta a, determined by dislocation transport of dissolved hydrogen at plastic strains above a critical value; and to the number of load cycles, delta N, required to hydrogenate process zone trap sites that fracture according to a local hydrogen concentration-tensile stress criterion. Transgranular (100) cracking occurs for process zones smaller than the subgrain size, and due to lattice decohesion or hydride formation. Intersubgranular cracking dominates when the process zone encompasses one or more subgrains so that dislocation transport provides hydrogen to strong boundary trapping sites. Multi-sloped log da/dN-log delta K behavior is produced by process zone plastic strain-hydrogen-microstructure interactions, and is determined by the DK dependent rates and proportions of each parallel cracking mode. Absolute values of the exponents and the preexponential coefficients are not predictable; however, fractographic measurements theta sub i coupled with fatigue crack propagation data for alloy 2090 established that the process zone model correctly describes fatigue crack propagation kinetics. Crack surface films hinder hydrogen uptake and reduce da/dN and alter the proportions of each fatigue crack propagation mode.

Piascik, Robert S.↗

Experimental detailed power distribution in a fast spectrum thermionic reactor fuel element at the core/BeO reflector interface region

A zero-power critical assembly was designed, constructed, and operated for the prupose of conducting a series of benchmark experiments dealing with the physics characteristics of a UN-fueled, Li-7-cooled, Mo-reflected, drum-controlled compact fast reactor for use with a space-power conversion system. The critical assembly was modified to simulate a fast spectrum advanced thermionics reactor by: (1) using BeO as a reflector in place of some of the existing molybdenum, (2) substituting Nb-1Zr tubing for some of the existing Ta tubing, and (3) inserting four full-scale mockups of thermionic type fuel elements near the core and BeO reflector boundary. These mockups were surrounded with a buffer zone having the equivalent thermionic core composition. In addition to measuring the critical mass of this thermionic configuration, a detailed power distribution in one of the thermionic element stages in the mixed spectrum region was measured. A power peak to average ratio of two was observed for this fuel stage at the midplane of the core and adjacent to the reflector. Also, the power on the outer surface adjacent to the BeO was slightly more than a factor of two larger than the power on the inside surface of a 5.08 cm (2.0 in.) high annular fuel segment with a 2.52 cm (0.993 in. ) o.d. and a 1.86 cm (0.731 in.) i.d.

Klann, P. G.↗

Assessing Bare-Ice Albedo Simulated By MAR Over the Greenland Ice Sheet (2000–2021) and Implications for Meltwater Production Estimates

Surface mass loss from the Greenland ice sheet (GrIS) has accelerated over the past decades, mainly due to enhanced surface melting and liquid water runoff in response to atmospheric warming. A large portion of runoff from the GrIS originates from exposure of the darker bare ice in the ablation zone when the overlying snow melts, where surface albedo plays a critical role in modulating the energy available for melting. In this regard, it is imperative to understand the processes governing albedo variability to accurately project future mass loss from the GrIS. Bare-ice albedo is spatially and temporally variable and contingent on non-linear feedbacks and the presence of light-absorbing constituents. An assessment of models aiming at simulating albedo variability and associated impacts on meltwater production is crucial for improving our understanding of the processes governing these feedbacks and, in turn, surface mass loss from Greenland. Here, we report the results of a comparison of the bare-ice extent and albedo simulated by the regional climate model Modèle Atmosphérique Régional (MAR) with satellite imagery from the Moderate Resolution Imaging Spectroradiometer (MODIS) for the GrIS below 70∘ N. Our findings suggest that MAR overestimates bare-ice albedo by 22.8 % on average in this area during the 2000–2021 period with respect to the estimates obtained from MODIS. Using an energy balance model to parameterize meltwater production, we find this bare-ice albedo bias can lead to an underestimation of total meltwater production from the bare-ice zone below 70∘ N of 42.8 % during the summers of 2000–2021.

albedo↗

Paramagnon dispersion and damping in doped Na x Ca 2 – x CuO 2 Cl 2

Here, using resonant inelastic x-ray scattering, we measure the paramagnon dispersion and damping of undoped, antiferromagnetic Ca 2 CuO 2 Cl 2 as well as doped, superconducting Na x Ca 2–x CuO 2 Cl 2 . Our estimation of the spin-exchange parameter and width of the paramagnon peak at the zone boundary X=(0.5, 0) confirms that no simple relation can be drawn between these parameters and the critical temperature T c . Consistently with other cuprate compounds, we show that upon doping there is a slight softening at (0.25,0) but not at the zone boundary X. In combination with these measurements we perform calculations of the dynamical spin structure factor of the one-band Hubbard model using cluster dynamical mean-field theory. The calculations are in excellent agreement with the experiment in the undoped case, both in terms of energy position and width. While the increase in width is also captured upon doping, the dynamical spin structure factor shows a sizable softening at X, which provides insightful information on the length-scale of the spin fluctuations in doped cuprates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Microgravity silicon zoning investigation

The flow instabilities in floating zones of silicon were investigated and methods for investigation of these instabilities in microgravity were defined. Three principal tasks were involved: (1) characterization of the float zone in small diameter rods; (2) investigation of melt flow instabilities in circular melts in silicon disks; and (3) the development of a prototype of an apparatus that could be used in near term space experiments to investigate flow instabilities in a molten zone. It is shown that in a resistance heated zoner with 4 to 7 mm diameter silicon rods that the critical Marangoni number is about 1480 compared to a predicted value of 14 indicative that viable space experiments might be performed. The prototype float zone apparatus is built and specifications are prepared for a flight zoner should a decision be reached to proceed with a space flight experimental investigation.

Kern, E. L.↗

Tape-in-tape-out (TITO): a new approach for in-situ contact resistance measurements in high temperature superconducting CORC® cables

One of the ongoing development challenges with ReBCO high-temperature superconducting (HTS) cables is normal zone initiation and local heating, which is associated with over-critical current flowing through and around local performance reductions in individual tapes. Although inter-tape contact resistances are well-reported for individual tapes and HTS cables, these measurements are a challenge in CORC® cables as current percolates through much of the cable. In this work, developments in tape-in-tape-out (TITO) automated individual tape powering experiments are presented, and a simplified modeling approach for current percolation in CORC® cables is developed. An optimization is formulated to fit the model parameters to a large set of TITO experiments on a single cable, allowing the layer-dependent inter-tape contact resistance to be extracted. Measurements are presented and discussed for a straight CORC® cable and a cable bent to a 152 mm and 76 mm radius. The approach provides both quantitative insight and facilitates better understanding of current sharing phenomena in HTS cables.

Teyber, Reed↗

Magnetostrictive EMAT for Nuclear Spent Fuel Canisters

One approach for mitigation of stainless steel (SS) spent fuel canisters (SFCs) is to coat the welds or even the entire SFC with a cold-sprayed nickel coating. The coating can serve as a magnetostrictive interface between an electromagnetic acoustic transducer (EMAT) and the SS plate material. The EMAT can send ultrasound into the canister and “listen” for reflections caused by chloride-initiated stress corrosion cracking (CISCC) or other damage mechanisms that may lead to leaks if undetected and unmitigated. Here, this project outlines an approach for monitoring the integrity of SFCs using magnetostrictive EMAT sensors, which emit and detect discontinuity-initiated reflections indicative of pits or cracks likely arising from CISCC. Flat 13 mm SS plates with welds similar to actual canister welds were prepared, with flat-bottom holes 3 mm and 6 mm deep and 6 mm in diameter placed within the weld heat-affected zone (HAZ). The most effective sensor configurations were able to detect critical discontinuities more than 2 m away. Although a single sensor could be robotically deployed, the large volume covered by each sensor could support a small number of permanently mounted sensors, equipped with an external connector for periodic interrogation. The HAZ of a hypothetical SFC cylindrical surface could be effectively monitored with just 16 sensors.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Ultrastable environment control for the NEID spectrometer: design and performance demonstration

Two key areas of emphasis in contemporary experimental exoplanet science are the detailed characterization of transiting terrestrial planets and the search for Earth analog planets to be targeted by future imaging missions. Both of these pursuits are dependent on an order-of-magnitude improvement in the measurement of stellar radial velocities (RV), setting a requirement on single-measurement instrumental uncertainty of order 10 cm∕s. Achieving such extraordinary precision on a high-resolution spectrometer requires thermomechanically stabilizing the instrument to unprecedented levels. We describe the environment control system (ECS) of the NEID spectrometer, which will be commissioned on the 3.5-m WIYN Telescope at Kitt Peak National Observatory in 2019, and has a performance specification of on-sky RV precision <50 cm/s. Because NEID’s optical table and mounts are made from aluminum, which has a high coefficient of thermal expansion, sub-milliKelvin temperature control is especially critical. NEID inherits its ECS from that of the Habitable-Zone Planet Finder (HPF), but with modifications for improved performance and operation near room temperature. Our full-system stability test shows the NEID system exceeds the already impressive performance of HPF, maintaining vacuum pressures below 10(exp −6) Torr and a root mean square (RMS) temperature stability better than 0.4 mK over 30 days. Our ECS design is fully open-source; the design of our temperature-controlled vacuum chamber has already been made public, and here we release the electrical schematics for our custom temperature monitoring and control system.

Paul Robertson↗

Field retrieved photovoltaic backsheet survey from diverse climate zones: Analysis of degradation patterns and phenomena

Understanding the impact of climate stressors on photovoltaic (PV) backsheet degradation in real-use conditions is critical to improve the accelerated testing exposures, extend the backsheet lifetime, and increase the confidence in PV reliability. Here, in this work, a total of 33 PV module backsheets were retrieved from six climatic zones worldwide with 2 - 28 years of exposure. These modules included five types of backsheet air-side materials (or outer layer): poly(vinylidene fluoride) (PVDF), poly(tetrafluoroethylene-co-hexafluoropropylene-co-vinylidene fluoride) (THV), poly(vinyl fluoride) (PVF), poly(ethylene terephthalate) (PET), and polyamide (PA). Attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR) was used to identify air-side materials. The degradation induced color change, gloss loss, and chemical material changes analyzed using optical microscopy, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), colorimetry (yellowness index (YI)), and gloss measurements. PVDF, THV, and PVF air-side layer backsheets, in particular PVF, had minimal degradation in the air-side layer appearance and chemical structures after exposure in different climatic zones. The PET air-side backsheets exhibited obvious color increase (22.55 YI units after about 9 years exposure) and the PA/PA/PA backsheets showed large gloss loss (up to 76.4 %) relative to the unexposed backsheets. Severe cracks between cells that penetrated through the entire thickness of backsheets are observed on PA/PA/PA backsheets after 4-6 years of exposure in 6 climatic zones. The current indoor exposure standards were not sufficient to identify this degradation type. However, fluoropolymer based PV backsheets showed lower levels of degradation predictors and increased climatic resistance. Specific samples (PVF) showed little change from baseline after 28 years of outdoor exposure.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Global Patterns and Controls of Nutrient Immobilization on Decomposing Cellulose in Riverine Ecosystems

Microbes play a critical role in plant litter decomposition and influence the fate of carbon in rivers and riparian zones. When decomposing low-nutrient plant litter, microbes acquire nitrogen (N) and phosphorus (P) from the environment (i.e., nutrient immobilization), and this process is potentially sensitive to nutrient loading and changing climate. Nonetheless, environmental controls on immobilization are poorly understood because rates are also influenced by plant litter chemistry, which is coupled to the same environmental factors. Here we used a standardized, low-nutrient organic matter substrate (cotton strips) to quantify nutrient immobilization at 100 paired stream and riparian sites representing 11 biomes worldwide. Immobilization rates varied by three orders of magnitude, were greater in rivers than riparian zones, and were strongly correlated to decomposition rates. In rivers, P immobilization rates were controlled by surface water phosphate concentrations, but N immobilization rates were not related to inorganic N. The N:P of immobilized nutrients was tightly constrained to a molar ratio of 10:1 despite wide variation in surface water N:P. Immobilization rates were temperature-dependent in riparian zones but not related to temperature in rivers. However, in rivers nutrient supply ultimately controlled whether microbes could achieve the maximum expected decomposition rate at a given temperature. Collectively, we demonstrated that exogenous nutrient supply and immobilization are critical control points for decomposition of organic matter.

54 ENVIRONMENTAL SCIENCES↗

Design of Zone-Based Hierarchical Protection System for 100% Renewable Microgrids

Design of a reliable and secure protection system for a 100% renewable microgrid with only inverter-based resources (IBRs), is quite challenging. Most of the existing protection schemes in the state-of-the-art are suitable for microgrids with mixed-type of distributed energy resources (DERs) that covers both rotating machine-based DERs as well as IBR-based DERs, where the fault current level is moderately high. Due to drastic reduction in fault current level based on mode of operation and the variation of the low fault current level based on the operating level of the IBRs, the existing protection schemes face critical challenges, in case of a 100% renewable microgrid. This article proposes a zone-based hierarchical protection scheme that partitions a microgrid into various zones-of-protection and assigns speed-based hierarchical protection schemes in order to address the fundamental challenges of such microgrids. The performance of the proposed scheme is evaluated using time-domain simulation study on a microgrid test system. The results corroborates that the proposed hierarchical zone-based protection scheme exhibits enhanced reliability, security and dependability while tested with various fault cases (fault types, locations, and impedances), and non-fault cases during both grid-tied and islanded mode.

grid-forming inverter↗

Design of Zone-Based Hierarchical Protection System for 100% Renewable Microgrids: Preprint

Design of a reliable and secure protection system for a 100% renewable microgrid with only inverter-based resources (IBRs), is quite challenging. Most of the existing protection schemes in the state-of-the-art are suitable for microgrids with mixed-type of distributed energy resources (DERs) that covers both rotating machine-based DERs as well as IBR-based DERs, where the fault current level is moderately high. Due to drastic reduction in fault current level based on mode of operation and the variation of the low fault current level based on the operating level of the IBRs, the existing protection schemes face critical challenges, in case of a 100% renewable microgrid. This article proposes a zone-based hierarchical protection scheme that partitions a microgrid into various zones-of-protection and assigns speed-based hierarchical protection schemes in order to address the fundamental challenges of such microgrids. The performance of the proposed scheme is evaluated using time-domain simulation study on a microgrid test system. The results corroborates that the proposed hierarchical zone-based protection scheme exhibits enhanced reliability, security and dependability while tested with various fault cases (fault types, locations, and impedances), and non-fault cases during both grid-tied and islanded mode.

grid-forming inverter↗

Thermochromic Halide Perovskite Windows with Ideal Transition Temperatures

Abstract Urban centers across the globe are responsible for a significant fraction of energy consumption and CO 2 emission. As urban centers continue to grow, the popularity of glass as cladding material in urban buildings is an alarming trend. Dynamic windows reduce heating and cooling loads in buildings by passive heating in cold seasons and mitigating solar heat gain in hot seasons. Here, reduced energy consumption in highly glazed buildings in a mesoscopic building energy model is demonstrated when thermochromic windows are employed. Savings are realized across eight disparate climate zones of the United States. The model is used to determine ideal critical transition temperatures of 20–27.5 °C for thermochromic windows based on metal halide perovskite materials. Ideal transition temperatures are realized experimentally in composite metal halide perovskite films composed of perovskite crystals and an adjacent reservoir phase. The transition temperature is controlled by cointercalating methanol, instead of water, with methylammonium iodide and tailoring the hydrogen‐bonding chemistry of the reservoir phase. Thermochromic windows based on metal halide perovskites represent a clear opportunity to mitigate the effects of energy‐hungry buildings.

14 SOLAR ENERGY↗

Comprehensive Characterization of Water Group Ion Composition and Distributions in Saturn's Magnetosphere With Cassini Plasma Spectrometer Data

Saturn's magnetosphere is continuously supplied with neutrals from the Enceladus plume and the icy rings, which undergo ionization and charge-exchange to form a complex water-group plasma environment. While the Cassini Plasma Spectrometer (CAPS) instrument has provided extensive compositional information, detailed separation of individual water-group ion species in time-of-flight (TOF) data has not previously been achieved. In this study, we perform forward modeling of CAPS-IMS energy-per-charge (E/Q) and TOF spectra obtained between 2004 and 2012 to resolve O + , OH + , H 2 O + , and H 3 O + and to characterize their plasma properties, including number density, temperature, and thermodynamic κ. Our results demonstrate that O + is the dominant thermal ion species throughout Saturn's magnetosphere, comprising up to ∼70% of the total ion population beyond ∼5 Saturn radii (R S ). In contrast, molecular ions such as OH + , H 2 O + , and H 3 O + dominate closer to Enceladus but rapidly dissociate into atomic ions between ∼5 and 10 R S . This radial region is also characterized by the steepest increase in plasma flow speed, which rises from ∼40% to ∼80% of rigid corotation. Simultaneously, ion velocity distributions approach Maxwell–Boltzmann equilibrium, as indicated by high kappa values. These findings provide new constraints on the ion–neutral chemistry that regulates the balance between molecular and atomic ions in Saturn's magnetosphere. They also emphasize the critical role of the 5–10 R S region as a transition zone for both plasma composition and dynamics. Our results refine previous CAPS-based studies and underscore the need to incorporate seasonal variability and ionospheric coupling into future global models of Saturn's plasma environment.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Atmospheric electricity

Atmospheric electricity must be considered in the design, transportation, and operation of aerospace vehicles. The effect of the atmosphere as an insulator and conductor of high voltage electricity, at various atmospheric pressures, must also be considered. The vehicle can be protected as follows: (1) By insuring that all metallic sections are connected by electrical bonding so that the current flow from a lightning stroke is conducted over the skin without any gaps where sparking would occur or current would be carried inside; (2) by protecting buildings and other structures on the ground with a system of lightning rods and wires over the outside to carry the lightning stroke into the ground; (3) by providing a zone of protection for launch complexes; (4) by providing protection devices in critical circuits; (5) by using systems which have no single failure mode; and (6) by appropriate shielding of units sensitive to electromagnetic radiation.

Daniels, G. E.↗

Beryllium reflected cavity reactor for UF6 critical experiments

Experiments and theoretical studies are being conducted for NASA on critical assemblies with one-meter diam by one-meter long low-density cores surrounded by a thick beryllium reflector. These assemblies make extensive use of existing nuclear propulsion reactor components, facilities, and instrumentation. Due to excessive porosity in the reflector, the initial critical mass was 19 kg U(93.2). Addition of a 17-cm-thick by 89-cm-diam beryllium flux trap in the cavity reduced the critical mass to 7 kg when all the uranium was in the zone just outside the flux trap. A mockup aluminum UF6 container was placed inside the flux trap and fueled with uranium-graphite elements. Fission distributions and reactivity worths of fuel and structural materials are available. These results will be used to guide the design of a prototype plasma core reactor which will test energy removal by optical radiation.

Jarvis, G. A.↗

Research on plasma core reactors

Experiments and theoretical studies are being conducted for NASA on critical assemblies with one-meter diameter by one-meter long low-density cores surrounded by a thick beryllium reflector. These assemblies make extensive use of existing nuclear propulsion reactor components, facilities, and instrumentation. Due to excessive porosity in the reflector, the initial critical mass was 19 kg U(93.2). Addition of a 17 cm thick by 89 cm diameter beryllium flux trap in the cavity reduced the critical mass to 7 kg when all the uranium was in the zone just outside the flux trap. A mockup aluminum UF6 container was placed inside the flux trap and fueled with uranium-graphite elements. Fission distributions and reactivity worths of fuel and structural materials were measured. Finally, an 85,000 cu cm aluminum canister in the central region was fueled with UF6 gas and fission density distributions determined. These results are to be used to guide the design of a prototype plasma core reactor which will test energy removal by optical radiation.

Jarvis, G. A.↗

Numerical evaluation of photosensitive tracers as a strategy for separating surface and subsurface transient storage in streams

For this work, we numerically evaluated photosensitive tracers as a potential strategy for separating the effects of surface and hyporheic storage zones (SSZs and HSZs, respectively) on stream corridor transport. Correctly separating HSZ and SSZ effects is critical to estimating the hydro-biogeochemical function of a stream because HSZs and SSZs expose solutes to significantly different biogeochemical conditions, like sunlight exposure, microbial processes, and oxygen availability. Our numerical experiments used a multiscale river-corridor transport model implemented in the ATS code, which accommodates multiple storage zones with distinct travel time distributions and biogeochemical reactions. For parameter inferences, we used Bayesian inverse modeling. We found that breakthrough curves for photo-decaying tracers from day and night injection can delineate surface and hyporheic transient storage contributions, but only when interpreted jointly through a two-storage zone model. Numerical experiments that used only daytime injection or interpreted breakthrough curves with a single storage zone model yielded good fit to breakthrough curves, but parameter estimates were biased and controlling processes misattributed, examples of good model fits for the wrong reasons. Using those biased parameter estimates in reactive transport simulations resulted in significantly different projections of denitrification, which underscores the potential for stream function to be mischaracterized if tracer tests are interpreted through an inappropriately simplified model for transient storage. More generally, this study highlights the role of modeling in evaluating the experimental design and identifying the potential of system mischaracterization and its implications.

54 ENVIRONMENTAL SCIENCES↗