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At least 199 records · Page 11

The Mineralogical Record of Ancient Fluvio-Lacustrine Environments in Gale Crater as Measured by the MSL CheMin Instrument

The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to investigate early Hesperian-aged sedimentary rocks on the lower slopes of Aeolis Mons (i.e., Mount Sharp) that show variations in phyllosilicates, hematite, and sulfates from orbital reflectance spectroscopy, suggesting changes in ancient aqueous environments. During the Eighth International Conference on Mars in July 2014, Curiosity was still traversing the Bradbury group on the plains of Gale crater (Aeolis Palus) and had only analyzed four samples in its internal laboratories. Soon after Mars 8, Curiosity began its investigation of Mount Sharp and has since driven through ~350 m of vertical stratigraphy, the majority of which is part of the Murray formation. The Murray fm is comprised primarily of laminated mudstone with occasional sandstone and heterolithic facies and represents a long-lived fluvio-lacustrine environment. Curiosity has analyzed 13 drilled rock samples from the Murray formation and 4 from the ancient eolian Stimson fm with the Chemistry and Mineralogy (CheMin) instrument. Here, we discuss the mineralogy of all fluvio-lacustrine samples analyzed to date and what these results tell us about sources of the sediments, aqueous environments, and habitability of ancient Gale crater.

Rampe, E. B.↗

Challenges of Building, Launching, and Operating The Curiosity SAM Instrument on Mars

The Sample Analysis at Mars (SAM) Suite Investigation onboard the Mars Science Laboratory (MSL) Curiosity rover is currently roving up Mt Sharp in Gale Crater on Mars. It is investigating the present and past habitability of Mars by exploring molecular and elemental chemistry relevant to life. SAM is a suite of three instruments, a Quadrupole Mass Spectrometer (QMS), a Gas Chromatograph (GC), and a Tunable Laser Spectrometer (TLS). As Curiosity climbs Mt. Sharp, SAM’s instrument suite search for and measure the abundances of carbon, oxygen, hydrogen, and nitrogen - elements that are associated with life as we know it. SAM quantitatively addresses the habitability of Mars, an essential step in the search for past or present life on Mars. This talk provides a behind-the-scenes look at the vignettes of the engineering challenges of building, integrating, testing, launching, and the SAM’s team’s initial experiences of operating SAM on Mars.

Florence Tan↗

Mineralogical Changes in a Predominantly Fluviolacustrine Succession at Gale Crater, Mars

The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to investigate the strata of lower Aeolis Mons (i.e., Mount Sharp) and characterize their depositional and diagenetic environments. Visible/short-wave infrared spectra from orbit of these strata show variations in phyllosilicate, sulfate, and Fe-oxide minerals, suggesting these units record environmental changes that occurred during the early Hesperian. Curiosity has traversed over 15 km and has climbed through Approx. 200 m of stratigraphic section, made up of predominantly fluviolacustrine (i.e., the Bradbury group and the Murray formation) and aeolian (i.e., the Stimson formation) units. Multiple geochemical and mineralogical instruments are onboard Curiosity to study these ancient rocks, including the Chemistry and Mineralogy (CheMin) instrument, which is an X-ray diffractometer (XRD) and X-ray fluorescence spectrometer, and the Alpha Particle X-ray Spectrometer (APXS).

Rampe, E. B.↗

Gravity Wave Observations by the Mars Science Laboratory REMS Pressure Sensor and Comparison with Mesoscale Atmospheric Modeling with MarsWRF

Surface pressure measurements on Mars have revealed a wide variety of atmospheric phenomena. The Mars Science Laboratory Rover Environmental Monitoring Station pressure sensor dataset is now the longest duration record of surface pressure on Mars. We use the first 2580 martian sols, nearly 4 Mars years,of measurements to identify atmospheric pressure waves with periods of tens of minutes to hours using wavelet analysis on residual pressure after the tidal harmonics are removed. We find these waves have a clear diurnal cycle with strongest activity in the early morning and late evening and a seasonal cycle with the strongest waves in the second half of the martian year (Ls= 180-360°). The strongest such waves of the entire mission occurred during the Mars Year 34 global dust storm. Comparable atmospheric waves are identified using atmospheric modeling with the MarsWRF general circulation model in a “nested” high spatial resolution mode. With the support of the modeling, we find these waves best fit the expected properties of inertia-gravity waves with horizontal wavelengths of O(100s) of km. PLAIN LANGUAGE SUMMARY Measuring air pressure from the surface of Mars has revealed a wide variety of atmospheric phenomena. The Curiosity rover's record or surface air pressure is now the longest yet made on Mars.We use the first ~8 years of Curiosity's pressure observations to look for atmospheric waves with periods of tens of minutes to hours. We find these waves have a clear pattern in their daily behavior with the strongest activity in the early morning and late evening and a seasonal cycle with the strongest waves in the second half of the martian year (Northern hemisphere fall and winter). The strongest such waves occurred in 2018 during a global dust storm. We find comparable waves in atmospheric modeling. With the support of modeling, we find these waves best fit the expected properties of buoyancy waves forced by airflow over topography with horizontal wavelengths of 100-1000 km.

Scott D Guzewich↗

Precision Instrument Targeting via Image Registration for the Mars 2020 Rover

A key component of Mars exploration is the operation of robotic instruments on the surface, such as those on board the Mars Exploration Rovers, the Mars Science Laboratory (MSL), and the planned Mars 2020 Rover. As the instruments carried by these rovers have become more advanced, the area targeted by some instruments becomes smaller, revealing more fine-grained details about the geology and chemistry of rocks on the surface. However, thermal fluctuations, rover settling or slipping, and inherent inaccuracies in pointing mechanisms all lead to pointing error that is on the order of the target size (several millimeters) or larger. We show that given a target located on a previously acquired image, the rover can align this with a new image to visually locate the target and refine the current pointing. Due to round-trip communication constraints, this visual targeting must be done efficiently on board the rover using relatively limited computing hardware. We employ existing ORB features for landmark-based image registration, describe and theoretically justify a novel approach to filtering false landmark matches, and employ a random forest classifier to automatically reject failed alignments. We demonstrate the efficacy of our approach using over 3,800 images acquired by Remote Micro-Imager on board the “Curiosity” rover.

Doran, Gary↗

Mineral Trends in Early Hesperian Lacustrine Mudstone at Gale Crater, Mars

The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to study the layered sediments of lower Aeolis Mons (i.e., Mount Sharp), which have signatures of phyllosilicates, hydrated sulfates, and iron oxides in orbital visible/near-infrared observations. The observed mineralogy within the stratigraphy, from phyllosilicates in lower units to sulfates in higher units, suggests an evolution in the environments in which these secondary phases formed. Curiosity is currently investigating the sedimentary structures, geochemistry, and mineralogy of the Murray formation, the lowest exposed unit of Mount Sharp. The Murray formation is dominated by laminated lacustrine mudstone and is approx.200 m thick. Curiosity previously investigated lacustrine mudstone early in the mission at Yellowknife Bay, which represents the lowest studied stratigraphic unit. Here, we present the minerals identified in lacus-trine mudstone from Yellowknife Bay and the Murray formation. We discuss trends in mineralogy within the stratigraphy and the implications for ancient lacustrine environments, diagenesis, and sediment sources.

Rampe, E. B.↗

Bulk Hydrogen Content OF High-Silica Rocks in Gale Crater With the Active Dynamic Albedo of Neutrons Experiment

The Mars Science Laboratory (MSL) Curiosity rover recently traversed over plateaus of mafic aeolian sandstones (the 'Stimson' formation) that overlie mudstones (the 'Murray' formation). Within the Stimson formation we observed many lighter-toned, halo-forming features, that are potentially indicative of fluid alteration (see Fig. 1). These halo features extend for tens of meters laterally and are approx.1 meter wide. The halo features were characterized by Curiosity's geochemical instruments: Alpha Proton X-Ray Spectrometer (APXS), Chemin, Chemcam and Sample Analysis at Mars (SAM). With respect to the host (unaltered) Stimson rocks, fracture halos were significantly enriched in silicon and low in iron [1]. Changes in hydrogen abundance (due to its large neutron scattering cross section) greatly influence the magnitude of the thermal neutron response from the Dynamic Albedo of Neutrons (DAN) instrument [2]. There are also some elemental species, e.g. chlorine, iron, and nickel, that have significant microscopic neutron absorption cross sections. These elements can be abundant and variable results provide a useful estimate of the lower bound for bulk hydrogen content (assuming a homogeneous distribution).

Gabriel, T. S. J.↗

Large Sulphur Isotope Fractionations in Martian Sediments at Gale Crater

Variability in the sulfur isotopic composition in sediments can reflect atmospheric, geologic and biological processes. Evidence for ancient fluvio-lacustrine environments at Gale crater on Mars and a lack of efficient crustal recycling mechanisms on the planet suggests a surface environment that was once warm enough to allow the presence of liquid water, at least for discrete periods of time, and implies a greenhouse effect that may have been influenced by sulfur-bearing volcanic gases. Here we report in situ analyses of the sulfur isotopic compositions of SO2 volatilized from ten sediment samples acquired by NASA's Curiosity rover along a 13 km traverse of Gale crater. We find large variations in sulfur isotopic composition that exceed those measured for Martian meteorites and show both depletion and enrichment in S-34. Measured values of δS-34 range from -47 +/- 14% to 28 +/- 7%, similar to the range typical of terrestrial environments. Although limited geochronological constraints on the stratigraphy traversed by Curiosity are available, we propose that the observed sulfur isotopic signatures at Gale crater can be explained by equilibrium fractionation between sulfate and sulfide in an impact-driven hydrothermal system and atmospheric processing of sulfur-bearing gases during transient warm periods.

Curiosity↗

Mineralogical Evidence for Environmental Change in the Clay-Sulfate Transition at Gale Crater, Mars

A primary reason for selecting Gale crater as the Mars Science Laboratory (MSL) Curiosity rover landing site was a clear mineralogical transition from Fe/Mg smectite in older strata to hydrated Mg sulfate salts in younger strata observed in orbital visible/shortwave-infrared reflectance data. This transition has been observed in other early-Hesperian terrains on Mars and has been hypothesized to signal a planet-wide change in climate from relatively warm and wet to cold and dry. Curiosity studied the sedimentology and geochemical and mineralogical composition of rocks in this “clay-sulfate transition” region from sols 3052 to 3572 (i.e., March 2021 to August 2022), with arrival at the sulfate unit on sol 3574. Here, we report on the mineralogical measurements made by the CheMin X-ray diffractometer of the six drill targets in the clay-sulfate transition and the first drill target in the sulfate unit. We use compositional data and sedimentological observations to interpret depositional and diagenetic environments and present hypotheses to explain the transition from clay minerals to hydrated Mg sulfates.

E. B. Rampe↗

Data from the Mars Science Laboratory CheMin XRD/XRF Instrument

The CheMin instrument on the Mars Science Laboratory (MSL) rover Curiosity uses a Co tube source and a CCD detector to acquire mineralogy from diffracted primary X-rays and chemical information from fluoresced X-rays. CheMin has been operating at the MSL Gale Crater field site since August 5, 2012 and has provided the first X-ray diffraction (XRD) analyses in situ on a body beyond Earth. Data from the first sample collected, the Rocknest eolian soil, identify a basaltic mineral suite, predominantly plagioclase (approx.An50), forsteritic olivine (approx.Fo58), augite and pigeonite, consistent with expectation that detrital grains on Mars would reflect widespread basaltic sources. Minor phases (each <2 wt% of the crystalline component) include sanidine, magnetite, quartz, anhydrite, hematite and ilmenite. Significantly, about a third of the sample is amorphous or poorly ordered in XRD. This amorphous component is attested to by a broad rise in background centered at approx.27deg 2(theta) (Co K(alpha)) and may include volcanic glass, impact glass, and poorly crystalline phases including iron oxyhydroxides; a rise at lower 2(theta) may indicate allophane or hisingerite. Constraints from phase chemistry of the crystalline components, compared with a Rocknest bulk composition from the APXS instrument on Curiosity, indicate that in sum the amorphous or poorly crystalline components are relatively Si, Al, Mg-poor and enriched in Ti, Cr, Fe, K, P, S, and Cl. All of the identified crystalline phases are volatile-free; H2O, SO2 and CO2 volatile releases from a split of this sample analyzed by the SAM instrument on Curiosity are associated with the amorphous or poorly ordered materials. The Rocknest eolian soil may be a mixture of local detritus, mostly crystalline, with a regional or global set of dominantly amorphous or poorly ordered components. The Rocknest sample was targeted by MSL for "first time analysis" to demonstrate that a loose deposit could be scooped, sieved to <150 microns, and delivered to instruments in the body of the rover. A drilled sample of sediment in outcrop is anticipated. At the time of writing this abstract, promising outcrops are in range and this talk will provide an update on data collected with the CheMin instrument.

Vaniman, David↗

Curiosity's Investigation at Vera Rubin Ridge

The Curiosity rover is exploring Vera Rubin Ridge (VRR), a ~6.5 km long and ~200 m wide topographic feature trending northeast-southwest across Aeolis Mons (informally known as Mt. Sharp) (Fig 1). In orbital data, VRR is distinct from the underlying Murray formation due to its relative erosional resistance and greater exposure of bedrock. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) orbital data show a hematite spectral signature over much of the ridge (Fig. 2). On the ground, Curiosity also observed hematite associated with the sedimentary rocks of the underlying Murray formation, although these detections are difficult to see with CRISM due to mixing with sand and dust.

Fraeman, A. A.↗

Mineralogy of Vera Rubin Ridge in Gale Crater from the Mars Science Laboratory CheMin instrument

Gale crater was selected as the landing site for the Mars Science Laboratory Curiosity rover because of orbital evidence for a variety of secondary minerals in the lower slopes of Aeolis Mons (aka Mount Sharp) that indicate changes in aqueous conditions over time. Distinct units demonstrate orbital spectral signatures of hematite, phyllosilicate (smectite), and sulfate minerals, which suggest that ancient aqueous environments in Gale crater varied in oxidation potential, pH, and water activity. Vera Rubin ridge (VRR) is the first of these units identified from orbit to have been studied by Curiosity. Orbital near-infrared data from VRR show a strong band at 860 nm indicative of hematite. Before Curiosity arrived at VRR, the hypotheses to explain the formation of hematite included (1) precipitation at a redox interface where aqueous Fe2+ was oxidized to Fe3+, and (2) acidic alteration of olivine in oxic fluids. Studying the composition and sedimentology of the rocks on VRR allow us to test and refine these hypotheses and flesh out the depositional and diagenetic history of the ridge. Here, we focus on the mineralogical results of four rock powders drilled from and immediately below VRR as determined by CheMin.

Rampe, E. B.↗

New Mastcam Multispectral Rock Classes in Sulfate-Bearing Strata, Gale Crater, Mars

Orbital data of Gale Crater, Mars has identified a transition in the stratigraphy of Mt. Sharp indicating an environmental change from a wetter one that accommodated clay mineral formation to a drier environment that led to the precipitation of sulfates. Mt. Sharp is not the only location on Mars for which this transition has been observed which suggests a global environmental change around the Noachian-Hesperian transition. Also visible from orbit is a dark-toned marker band that lies within the sulfate-bearing strata hypothesized to be a volcanic ash deposit. The Mars Science Laboratory (MSL) Curiosity rover is currently exploring this region of Mt. Sharp. In-situ analyses by the rover show changes in morphology and chemistry between the sulfate-bearing layers below and above the marker band and the marker band itself. The MSL instrument payload includes the Mast Camera (Mastcam), which collects multispectral images to provide context for other instruments and broad mineralogic interpretations. In addition to mafic Fe-bearing minerals, Mastcam is sensitive to oxides and some hydrated minerals, important indicators of alteration. In our previous work, we compiled a database of Mastcam spectra through Curiosity’s exploration of Vera Rubin ridge (sols 0-2302), from which 9 spectral classes of rocks were identified (Fig. 1D). Each class has diagnostic spectral features that reflect a common mineralogic interpretation. More recently, as Curiosity traversed through the clay-rich region, Glen Torridon (GT), there was some variation in the rock spectral classes potentially due to nontronite and other phyllosilicates, but not enough to warrant new spectral classes (Fig. 1B). We hypothesize that new classes will appear in accordance with sulfate-bearing strata and the marker band, specifically appearing as a ‘downturn’ in the last two wavelength filters that is inherent, but not unique, to polyhydrated Mg-sulfates. Here, we expand upon our analysis of Mastcam multispectral observations through Curiosity’s second encounter with the marker band (up to sol 3672), comparing the spectral diversity within the sulfate-bearing unit and the marker band to the spectral classes encountered previously in the traverse. These analyses will provide a basis for comparison and aid in selecting targets for in-situ investigations as Curiosity continues its ascent of Mt. Sharp.

A M Eng↗

Cementation and Aqueous Alteration of a Sandstone Unit Under Acidic Conditions in Gale Crater, Mars

The Curiosity rover landed on Mars in August 2012 to explore the sedimentary history and to assess the habitability of Gale Crater. After 1200 sols of surface operations and over 12 km of traverse distance, the mineralogy of 10 samples has been determined by the CheMin X-ray diffractometer (XRD) and the chemical composition of nearly 300 targets has been established by the Alpha Particle X-ray Spectrometer (APXS). Light-toned fracture zones containing elevated concentrations of silica have been studied by Curiosity's instruments to determine the nature of the fluids that resulted in the enrichment of SiO2. Multiple fluid exposures are evident, and the chemistry and mineralogy data indicate at least two aqueous episodes may have occurred under acidic conditions.

Yen, A. S.↗

Qualification of UHF Antenna for Extreme Martian Thermal Environments

The purpose of this development was to validate the use of the external Rover Ultra High Frequency (RUHF) antenna for space under extreme thermal environments to be encountered during the surface operations of the Mars Science Laboratory (MSL) mission. The antenna must survive all ground operations plus the nominal 670 Martian sol mission that includes summer and winter seasons of the Mars thermal environment.The qualification effort was to verify that the RUHF antenna design and its bonding and packaging processes are adequate to survive the harsh environmental conditions. The RUHF is a quadrifilar helix antenna mounted on the MSL Curiosity rover deck. The main components of the RUHF antenna are the helix structure, feed cables, and hybrid coupler, and the high-power termination load. In the case of MSL rover externally mounted hardware, not only are the expected thermal cycle depths severe, but there are temperature offsets between the Mars summer and winter seasons. The total number of temperature cycles needed to be split into two regimes of summer cycles and winter cycles. The qualification test was designed to demonstrate a survival life of three times more than all expected ground testing, plus a nominal 670 Martian sol missions. Baseline RF tests and a visual inspection were performed prior to the start of the qualification test. Functional RF tests were performed intermittently during chamber breaks over the course of the qualification test. For the RF return loss measurements, the antenna was tested in a controlled environment outside the thermal chamber with a vector network analyzer that was calibrated over the antenna s operational frequency range. A total of 2,010 thermal cycles were performed. Visual inspection showed a dulling of the solder material. This change will not affect the performance of the antenna. No other changes were observed. RF tests were performed on the RUHF helix antenna, hybrid, and load after the 2,010 qualification cycles test. The RF performance of the RUHF antenna, hybrid, and load were almost identical before and after the complete test. Therefore, the developed design of RUHF is qualified for a long-duration MSL mission. The RUHF antenna has not been used for long-duration missions such as MSL in the past. The state-of-the-art technology of the RUHF antenna is used to develop the antennas for MSL mission survivability. This developmental test data provides the confidence in using this RUHF antenna for future NASA missions to Mars.

Ramesham, Rajeshuni↗

Fluids During Diagenesis and Sulfate Vein Formation in Sediments at Gale Crater, Mars

We model the fluids involved in the alteration processes recorded in the Sheep bed Member mudstones of Yellowknife Bay (YKB), Gale crater, Mars, as revealed by the Mars Science Laboratory Curiosity rover investigations. We compare the Gale crater waters with fluids modeled for shergottites, nakhlites, and the ancient meteorite ALH 84001, as well as rocks analyzed by the Mars Exploration rovers, and with terrestrial ground and surface waters. The aqueous solution present during sediment alteration associated with phyllosilicate formation at Gale was high in Na, K, and Si; had low Mg, Fe, and Al concentrations relative to terrestrial ground waters such as the Deccan Traps and other modeled Mars fluids; and had near neutral to alkaline pH. Ca and S species were present in the 10(exp -3) to 10(exp -2) concentration range. A fluid local to Gale crater strata produced the alteration products observed by Curiosity and subsequent evaporation of this ground water- type fluid formed impure sulfate- and silica-rich deposits veins or horizons. In a second, separate stage of alteration, partial dissolution of this sulfate-rich layer in Yellowknife Bay,or beyond, led to the pure sulfate veins observed in YKB. This scenario is analogous to similar processes identified at a terrestrial site in Triassic sediments with gypsum veins of the Mercia Mudstone Group in Watchet Bay, UK.

Gale Crater↗

From Concept-to-Flight: An Active Active Fluid Loop Based Thermal Control System for Mars Science Laboratory Rover

The Mars Science Laboratory (MSL) rover, Curiosity, which was launched on November 26, 2011, incorporates a novel active thermal control system to keep the sensitive electronics and science instruments at safe operating and survival temperatures. While the diurnal temperature variations on the Mars surface range from -120 C to +30 C, the sensitive equipment are kept within -40 C to +50 C. The active thermal control system is based on a single-phase mechanically pumped fluid loop (MPFL) system which removes or recovers excess waste heat and manages it to maintain the sensitive equipment inside the rover at safe temperatures. This paper will describe the entire process of developing this active thermal control system for the MSL rover from concept to flight implementation. The development of the rover thermal control system during its architecture, design, fabrication, integration, testing, and launch is described.

heat rejection systems↗

Exploring Mars for Evidence of Habitable Environments and Life

The climate of Mars has been more similar to that of Earth than has the climate of any other planet in our Solar System. But Mars still provides a valuable alternative example of how planetary processes and environments can affect the potential presence of life elsewhere. For example, although Mars also differentiated very early into a core, mantle and crust, it then evolved mostly if not completely without plate tectonics and has lost most of its early atmosphere. The Martian crust has been more stable than that of Earth, thus it has probably preserved a more complete record of its earliest history. Orbital observations determined that near-surface water was once pervasive. Orbiters have identified the following diverse aqueous sedimentary deposits: layered phyllosilicates, phyllosilicates in intracrater fans, plains sediments potentially harboring evaporitic minerals, deep phyllosilicates, carbonate-bearing deposits, intracrater clay-sulfate deposits, Meridiani-type layered deposits, valles-type layered deposits, hydrated silica-bearing deposits, and gypsum plains. These features, together with evidence of more vigorous past geologic activity, indicate that early climates were wetter and perhaps also somewhat warmer. The denser atmosphere that was required for liquid water to be stable on the surface also provided more substantial protection from radiation. Whereas ancient climates might have favored habitable environments at least in some localities, clearly much of the Martian surface for most of its history has been markedly less favorable for life. The combination of dry conditions, oxidizing surface environments and typically low rates of sedimentation are not conducive to the preservation of evidence of ancient environments and any biota. Thus a strategy is required whereby candidate sites are first identified and then characterized for their potential to preserve evidence of past habitable environments. Rovers are then sent to explore the most promising candidates. The Mars Exploration Rover (MER) Opportunity revealed that water once flowed to the surface across the vast Meridiani plains, creating saline lakes whose waters were roiled by ancient winds that also sculptured their salt deposits into sand dunes. Opportunity then drove more than 30 km to explore even older deposits on a crater rim. MER Spirit found evidence that thermal waters (heated by volcanism or by impacts?) altered rocks to create sulfate salts, and siliceous sinters. These discoveries indicate that an early hydrological cycle apparently sustained precipitation, streams and lakes. Liquid water participated in rock weathering reactions, such as iron and sulfur oxidation, that created distinctive weathering regimes. Volcanism, impacts, groundwater and ice interacted at least locally. Redox chemical energy from volcanism, hydrothermal activity and weathering of crustal materials would have been available for any life. Thus conditions might have supported life in the past, at least locally. The main objective of the Mars Science Laboratory (MSL) Curiosity rover is to determine the extent to which Gale crater hosted environments capable of supporting microbial life. The rover has already found stream gravels as well as sediments that might have been deposited in an ancient lake. The rover is now traversing to Mt. Sharp, a 5 km-high mound that is located on the crater floor and that exhibits layered sedimentary rocks having diverse minerals (sulfates and clays) that apparently formed in the presence of liquid water. This rock sequence was deposited over an extended time period in diverse potentially habitable watery environments. Curiosity is poised to characterize a a well-preserved rock record of hundreds of millions of years of diverse environments and profound climate change.

layered phyllosilicates↗