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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Deciphering the Evolution of Current Distribution in Hybrid Silver Vanadium Oxide / Carbon Monofluoride Cathodes within Lithium Primary Batteries

For batteries to function effectively all active material must be accessible requiring both electron and ion transport to each particle. A common approach to generating the needed conductive network is the addition of carbon to create a composite electrode. An alternative approach is the electrochemically induced formation of conductive reaction products where the electrochemically generated materials are in intimate contact with the active material contributing to effective connection of each active particle. Furthermore, this study probes silver vanadium oxide (Ag 2 V 4 O 11 , SVO), carbon monofluoride (CF x ), and hybrid SVO/CF x electrodes in lithium batteries. Ex situ XRD identifies Ag 0 as a reduction product from SVO and LiF from CF x that can be followed as a function of depth-of-discharge (DOD). Spatially-resolved operando energy dispersive x-ray diffraction reveals that the presence of SVO alleviates reaction heterogeneity in the electrodes which are electron transfer limited in the absence of sufficient Ag 0 . Synchrotron X-ray tomography on discharged cathodes reveals the distribution of silver particles where the particles are more closely spaced near the current collector indicating multiple nucleation sites for their formation. Finally, operando isothermal microcalorimetry is used to determine the heat dissipation of the parent and hybrid battery types. Using material enthalpy potentials, we determine the current distribution between the two active materials for the discharging hybrid cathode adding further insight to the diffraction analysis. Taken together, these results provide a comprehensive understanding of hybrid SVO/CF x cathodes and give guidance on optimal compositions that balance power and energy density considerations.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Shifting Valencies and Magnetic Responses in La-Based High-Entropy Oxide Perovskite Thin Films with Variable Mn Presence

Chemical disorder in compositionally complex perovskite oxides generates a broad distribution of exchange pathways and spin states, but the microscopic origin and spatial homogeneity of the resulting magnetic phases remain debated. Here, we tune the Mn fraction (x = 0.2–0.6) in epitaxial La(Cr, Mn, Fe, Co, Ni)O3 thin films and resolve the coupled evolution of valence, spin state, and magnetism using element-specific x-ray absorption spectroscopy and x-ray magnetic circular dichroism (XMCD). Mn enrichment drives an internal redistribution of charge, in which Mn evolves toward a Mn3+-rich mixed valence, while Co converts from predominantly Co3+ to high-spin Co2+. This valence/spin-state coupling amplifies the Mn- and Co-derived ferromagnetic response by nearly an order of magnitude while increasing the magnetic onset temperature to at least 250 K, whereas Fe and Cr remain essentially trivalent with weak dichroism. Depth-resolved low-energy muon spin spectroscopy (LE-μSR) shows magnetic homogeneity through the film thickness, with a secondary relaxation maximum near 25 K indicating a low-temperature dynamical crossover consistent with frustrated magnetism in a strongly disordered spin lattice.

Miertschin, Duncan [Baylor University]↗
DOE OSTI2025

Amorphous zinc–molybdenum–sulfide chalcogel as a long-cycle, high-capacity electrode for lithium-ion batteries

The inherent limitations of intercalation-based electrodes in lithium-ion batteries have prompted the search for alternative materials with higher specific capacities and robust electrochemical stability. Sulfur-based electrodes, despite their high theoretical capacities (1672 mAh g −1 ), typically suffer from poor cycling performance. In this work, zinc molybdenum polysulfide (Zn x Mo 3 S 13 , 0.5 ≤ x), an amorphous semiconductor chalcogel, exhibits high specific capacity and excellent cycling stability. Synchrotron X-ray pair distribution function and extended X-ray absorption fine structure analyses reveal a short-range atomic structure comprising Mo–Mo, M–S (M = Mo, Zn), and S–S bonding motifs. The coordination environment of Mo and S closely resembles that of Mo 3 S 13 clusters, interconnected via S–S bridges and Zn 2+ cations. The Li/Zn x Mo 3 S 13 cell delivers an initial discharge capacity of 844 mAh g −1 at C/3, and retains 386.2 mAh g −1 after 1000 cycles with an average coulombic efficiency of 99.99%. The distribution of relaxation times analysis confirms the formation of a stable solid electrolyte interphase, which underpins the cell's long-term stability. In conclusion, this outstanding performance is attributed to the synergistic effects of the chalcogel's unique amorphous framework, semiconductive character, Zn-mediated polysulfide anchoring, and structural resilience, positioning Zn x Mo 3 S 13 chalcogel among the most durable pure metal sulfide cathodes reported for next-generation LIBs.

36 MATERIALS SCIENCE↗
DOE OSTI2026

In situ electric field X-ray total scattering reveals composition-dependent electromechanical strain mechanisms in (1 − x )BiFe 2/8 Ti 3/8 Mg 3/8 O 3 – x PbTiO 3 ceramics

Ferroelectric materials find many applications in energy and aerospace industries. A major challenge for ferroelectric materials is maintaining their properties at elevated temperatures. The (1 − x )BiFe 2/8 Ti 3/8 Mg 3/8 O 3 – x PbTiO 3 (BFTM–xPT) ferroelectric solid solution is a promising candidate for high-temperature applications as it has a high piezoelectric response while also maintaining its ferroelectric phase until a high Curie temperature (T C ) of 650 °C. In this work, we investigate the piezoelectric mechanism in BFTM–xPT, a novel high-T C ferroelectric ceramic. To elucidate the origin of its enhanced piezoelectric performance, relative to other piezoceramics of similar T C , in situ electric field X-ray total scattering experiments were performed. Total scattering combines Bragg scattering (diffraction) and diffuse scattering (pair distribution function), providing insight on various length scales. With information spanning different length scales, extrinsic contributions (i.e., domain wall motion and interphase boundary motion) can be separated from intrinsic contributions (i.e., piezoelectric lattice strain). We show that, for compositions within the morphotropic phase boundary (MPB, x = 0.325), the piezoelectric response is dominated by intrinsic piezoelectric lattice strain, whereas outside the MPB (x = 0.375) the major component of the piezoelectric response is from extrinsic mechanisms including an electric-field-induced phase transition and tetragonal domain wall motion. This article reveals that the origin of piezoelectric response in BFTM–xPT is composition-dependent and shows that high-performance materials may also be located outside the MPB. These findings can help guide material design to optimize properties for specific applications.

Richtik, Brooke N. [University of Calgary, AB (Can↗
DOE OSTI2025

Structure–property relations of binary ferrite melts

Molten ferrite systems are used in the smelting and refining processes in steelmaking, to reduce the loss of metals in slags and to accelerate reaction rates. Here, high-energy x-ray diffraction experiments have been performed on aerodynamically levitated molten spheres of 43BaO–57FeO X and 43SrO–57FeO X at 1873 K using laser beam heating. The composition was varied within the range of x = 1–1.5 by changing the oxygen partial pressure of the levitation gas. The corresponding x-ray pair distribution functions have been interpreted using empirical potential structure refinement (EPSR) modeling. In oxygen-rich melts (x = 1.5), our EPSR models indicate very similar structures for the different alkaline-earth liquids, with both the Ba–O and Sr–O coordination numbers to be ∼8.4 and the total Fe–O coordination numbers ∼5.7. However, our models show that in reducing environments, the Fe 3+ and Fe 2+ ions exhibit very different behaviors in the Ba- and Sr-ferrite liquids. In the Ba-ferrite melt, the Fe 3+ –O coordination number decreases from 5.7 (at x = 1.5) to 5.2 (at x = 1.07), whereas Fe 2+ –O remains constant at ∼5.0 across the same compositional range. In the Sr melts, both the Fe 2+ –O and Fe 3+ –O coordination numbers rise from ∼5.7 (at x = 1.5) to 6.3 (at x = 1.07). All models show the structures to be heterogeneous with intertwined nanometer sized clusters or channels of Ba/Sr–O and Fe–O polyhedra that grow as oxygen content is reduced. Changes in the viscosity and electrical properties are interpreted in terms of the number of bridging and non-bridging oxygens associated with FeO 4 tetrahedra and concentration of charge carriers, respectively.

Benmore, Chris J. [Argonne National Laboratory (AN↗
DOE OSTI2025

Nanodiffraction imaging of ionically driven phase separation in cobaltite heterostructures

Controlling the anionic stoichiometry and distribution of perovskite cobaltites presents a powerful method for tailoring the magnetic and electronic properties for magneto-ionic applications. Nevertheless, the influence of nanoscale morphology, including phase separation and defects in cobaltite heterostructures, remains largely unexplored. We used x-ray nanodiffraction to directly image the nanoscale topotactic phase transformation in La 1−x Sr x CoO 3 (LSCO) heterostructures capped with a reactive aluminum (Al) layer (i.e., oxygen “getter”) of varying thicknesses (0.5, 3, and 7 nm). Nanodiffraction images reveal the formation of highly elongated BM filaments extending over mesoscopic lengths (>67 μm), indicating a strong tendency toward oxygen vacancy ordering in both P and BM phases in all heterostructures. Local strain and strain gradient analysis shows a strong correlation between the depletion of the P phase and strain gradients. Our measurements suggest that elongation of the BM filaments is the predominant mechanism for topotactic transformation in LSCO/Al heterostructures, preferred over coarsening, branching, and fractal growth. Our study provides a detailed nanoscale analysis of ionically driven phase transitions in LSCO/Al heterostructures, which is crucial for tailoring the functional properties of cobaltites for magneto-ionic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Foliar elemental distribution in Blepharidium guatemalense assessed by synchrotron X-ray fluorescence spectroscopy and colorimetric optical microscopy

The hyperaccumulation phenomenon holds significant potential for Ni agromining in ultramafic areas; however, data on tropical hyperaccumulator species, particularly regarding metal distribution and tolerance mechanisms, remain scarce. Here, this study characterized the foliar elemental distribution of Blepharidium guatemalense, analyzed its metal localization at both tissue and cellular levels, and quantified its Ni accumulation when grown in Brazilian ultramafic soil. Plants were grown in pots for 90 days, and Ni concentrations in the aerial biomass and bio-ore were determined. Synchrotron-based micro-X-ray fluorescence (S-µXRF) was used to assess metal distribution in tissues, supplemented by microscopic examination with dimethylglyoxime (DMG) to visualize Ni accumulation in specific cell types. B. guatemalense reached 19,000 mg kg −1 Ni in leaves. Processing leaf biomass produced ash containing 24 wt% Ni, indicating promising metal-recovery potential for the species. S-µXRF revealed that Ni was predominantly localized in the central and secondary veins of the leaves, suggesting efficient vascular transport. Microscopic analysis using the colorimetric reagent DMG further showed that Ni accumulation occurs near the epidermis and phloem, suggesting that B. guatemalense employs specific physiological mechanisms for Ni translocation, potentially supporting both defense and growth functions. These results establish B. guatemalense as a promising candidate for large-scale Ni agromining in tropical regions.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Evidence of distinct nonpolar/polar ordering at long/short ranges in relaxor ferroelectrics

Distinct atomic nonpolar/polar ordering is determined at long, intermediate, and short ranges using synchrotron x-ray diffraction, Raman scattering, and pair distribution function data in K 0.5 Na 0.5 NbO 3 -doped BaTiO 3 -based relaxor ferroelectrics, viz., (1 - x) Ba 0.9 Sr 0.1 TiO 3 -x KNN 50. Two different polar phases with distinct symmetries are identified at short/intermediate ranges for x = 0.10, where a monoclinic phase at short ranges gradually transforms into a rhombohedral phase at intermediate ranges. Here, in contrast, a nonpolar phase with average cubic symmetry is found to be stable at long ranges for a wide temperature range (100 ≤ T ≤ 500 K). The polar behavior of short/intermediate-range ordering is quantified in terms of the amplitude of ferroelectric phonon mode $Γ^-_4$ (q = 0, 0, 0) (which corresponds to the zone center of the cubic Brillouin zone). The amplitude of the $Γ^-_4$ phonon mode increases with decreasing temperature, suggesting the enhancement of ferroelectric polarization at short/intermediate ranges on lowering temperatures. Enhanced ferroelectric polarization at low temperature is also visible and evident by ferroelectrostriction and is quantified by the increase in magnitude of spontaneous volume ferroelectrostriction. Consequently, Zero thermal expansion is observed at low temperatures.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Inference of Multichannel r -process Element Enrichment in the Milky Way Using Binary Neutron Star Merger Observations

Observations of GW170817 strongly suggest that binary neutron star (BNS) mergers produce rapid neutron-capture nucleosynthesis ( r -process) elements. However, it remains an open question whether these mergers can account for all the r -process element enrichment in the Milky Way’s history. Here, we constrain the contributions of the BNS channel using astrophysical neutron star observations. The rate and mass distributions are constrained by LIGO/Virgo/Kagra through the latest catalog GWTC-3, the neutron star equation of state by gravitational-wave, radio, and X-ray observations, and the delay time distribution by short gamma-ray burst (GRB) host galaxy associations. We present a Bayesian framework to consistently combine these observations with abundance information to quantify the contribution and uncertainties of single and multiple astrophysical enrichment sources, and obtain a distribution of per-event BNS r -process element yields consistent with geophysical and astrophysical abundance constraints. We then adopt a Galactic chemical evolution model assuming an instantaneous and fixed amount of Fe enrichment from core-collapse supernovae, and show that BNS-only enrichment scenarios remain inconsistent with the observed r-process abundance trend of disk stars in the Galaxy even with the uncertainties in BNS merger observations. Using stellar abundance observations instead of the short GRB constraints, we can infer a shorter BNS delay time distribution with power-law index α ≤ −2.0 and minimum delay time ${t}_{{\rm{\min }}}\leqslant 40$ Myr at 90% confidence, consistent with detailed Galactic chemical evolution models. Such delay times are in tension with those predicted by standard BNS formation models. Alternatively, we confirm that a two-channel scenario, in which the second channel tracks the star formation history without significant delay, can account for both Galactic stellar and short GRB observations. We estimate that 45%–90% of the r -process abundance in the Milky Way today would have been produced by this star formation-tracking channel, rather than BNS mergers with significant delay times.

gravitational wave astronomy↗
NASA NTRS1971

Plasma model for thermal X-ray sources

Thermal X ray sources associated with rotating collapsed stars with surrounding plasma shells, discussing plasma density profile and electron distribution in stellar magnetosphere

Coppi, B.↗
NASA NTRS1971

Interaction of fast particles with intergalactic matter.

A discussion is given of the relaxation of power-law cosmic-ray spectra in the intergalactic medium. The theoretical time-dependent spectra obtained are used to calculate the nonthermal radiation produced by bremsstrahlung of subcosmic-ray electrons colliding with ambient protons of the intergalactic gas. A comparison is made between the theory and the observations of the diffuse X-ray and gamma-ray background. The calculated cosmic-ray proton spectra are applied to a computation of the heating of the intergalactic medium, and the resulting thermal bremsstrahlung radiation is compared with the suprathermal proton bremsstrahlung flux. We conclude that nonthermal bremsstrahlung is unlikely to be an important contributor to the isotropic X- and gamma-ray background. However, cosmic-ray heating can provide a plausible heat source for maintaining a hot intergalactic gas, especially when evolutionary effects are included in the distribution of cosmic-ray sources.

Arons, J.↗
NASA NTRS1977

Backscatter of hard X-rays in the solar atmosphere

The solar photosphere backscatters a substantial fraction of the hard X rays from solar flares incident upon it. This reflection was studied using a Monte Carlo simulation which takes into account Compton scattering and photo-electric absorption. Both isotropic and anisotropic X ray sources are considered. The bremsstrahlung from an anisotropic distribution of electrons are evaluated. By taking the reflection into account, the inconsistency is removed between recent observational data regarding the center-to-limb variation of solar X ray emission and the predictions of models in which accelerated electrons are moving down toward the photosphere.

Bai, T.↗
NASA NTRS1978

Hard X-ray imaging from the solar probe

The solar probe offers a platform with particular advantages for studying solar nonthermal plasma processes via the observations of hard X-radiation from energetic electrons in the chromosphere and corona, these include (1) high sensitivity, (2) a second line of sign (in addition to the earth's) that can aid in three dimensional reconstruction of the source distribution, and, (3) the possibility of correlation with direct measurements of the nonthermal particles from the probe itself.

Hudson, H. S.↗
NASA NTRS1977

Recent high energy gamma-ray results from SAS-2

Recent developments in gamma-ray astronomy due to the results from SAS-2 have focused on two areas. First, the emission from the plane of the Galaxy is the dominant feature in the gamma-ray sky. The galactic latitude and longitude distributions are consistent with the concept that the high-energy radiation originates from cosmic rays interacting with interstellar matter, and the measurements support a galactic origin for cosmic rays. Second, searches of the SAS-2 data for emission from localized sources have shown three strong discrete gamma-ray sources: the Crab nebula and PSR 0531 + 21, the Vela supernova remnant and PSR 0833-45, and a source near galactic coordinates 193 deg longitude, +3 deg latitude, which does not appear to be associated with other known celestial objects. Evidence has also been found for pulsed gamma-ray emission from two other radio pulsars, PSR 1818-04 and PSR 1747-46. A localized source near longitudes 76-80 deg may be associated with the X-ray source Cyg X-3.

Thompson, D. J.↗
NASA NTRS1978

Imaging of X-ray aurorae from Spacelab

The Atmospheric X-ray Emission Telescope (AXET) is designed to image and measure the spatial, temporal, and spectral distributions of X-ray aurorae produced in the upper atmosphere by precipitating energetic electrons. The bremsstrahlung-produced X radiation penetrates to stratospheric depths where it can modify ozone, conductivity, and other critical atmospheric parameters. Remote sensing of this radiation from topside will provide vital data on solar-terrestrial relationships and mechanisms that could help trigger tropospheric response to solar activity. The X rays also provide direct information concerning the dynamics of radiation-belt processes within the magnetosphere. AXET is designed to detect sources up to 50 keV and to image them below 25 keV by means of directionally sensitive proportional counters with passive collimators. It will be mounted in the Space Shuttle on a single fixed platform designed to optimize viewing conditions for the anticipated orbits and aspects of early Spacelab missions.

Goldberg, R. A.↗
NASA NTRS1979

Ultraviolet spectroscopic measurements of globular clusters

Ultraviolet spectra of six globular clusters (M15, M92, NGC 1851, NGC 6624, 47 Tuc, and NGC 6752) have been taken with the International Ultraviolet Explorer satellite in order to investigate the surface brightness distributions in the central regions. The ultraviolet emission indicates composite stellar spectra. Short-wavelength emission (1200-1900 A) arises from blue horizontal-branch stars; long-wavelength emission (2100-3000 A) is characteristic of late-type horizontal-branch and giant stars. The surface brightness distribution is more compact at short wavelengths than at long wavelengths, suggesting a segregation of horizontal-branch stars. A dense core appears to be present in X-ray-emitting clusters and absent in those clusters without X-ray sources. The X-ray source in NGC 6624 may have been detected at short wavelengths (1300-1900 A).

Dupree, A. K.↗
NASA NTRS1979

Einstein observations of the Orion Nebula

A single 3.5 hour observation on 1979 March 6 with the imaging proportional counter aboard the Einstein Observatory has revealed the presence of numerous low-luminosity (10 to the 31st ergs/s) X-ray sources in a region centered near the Trapezium in the Orion Nebula. In addition to the Trapezium, 22 discrete sources have been detected in a 1 x 1 deg field at or above the 4 sigma level. These sources are clearly associated with star formation, as indicated by the similarity of their spatial distribution with that of the nebular variables, a class of pre-main-sequence stars. Because the field is quite crowded, however, individual identifications of these sources are difficult. In addition to the discrete sources, there is evidence for diffuse or unresolved emission from two ridges extending 16 deg to the north and 15 deg to the west of the Trapezium. The nature of the discrete sources and of the diffuse emission is discussed.

Ku, W. H.-M.↗