Search NASA⌕ Search

SEARCH · Search NASA

Results for “Electron localization function”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

A theoretical study of the excited states of Ag3

Recently there was considerable interest in the properties and reactivities of small metal clusters. However, for the transition metal trimers, gas phase spectroscopy exists only for Cu3. Calculations are reported for the excited states of the Ag3 molecule. The excitation energies, geometries, derived harmonic frequencies, and transition moments are presented. The electronic structure of these states is very similar to the analogous states of Cu3. From the VCI wave functions transition moments were calculated between each of the Rydberg excited states and the ground state for an equilateral triangle geometry with R sub Ag-Ag = 5.3 a sub 0. One state was computed for the configuration 4d29 5sa sup prime 2 sub 1 5se sup prime 1 sub x 5se sup prime 1 sub y. This configuration was considered since the corresponding configuration for Cu3 is low-lying. Calculations were carried out for a quartet wavefunction in which the 4d hole was localized on the central Ag atom. The spectrum for Ag3 is expected to be simpler than for Cu3 since the 5s2 4d9 states are shifted to higher energy.

Walch, Stephen P.↗
NASA NTRS1997

Interfacing Relativistic and Nonrelativistic Methods: A Systematic Sequence of Approximations

A systematic sequence of approximations for the introduction of relativistic effects into nonrelativistic molecular finite-basis set calculations is described. The theoretical basis for the approximations is the normalized elimination of the small component (ESC) within the matrix representation of the modified Dirac equation. The key features of the normalized method are the retention of the relativistic metric and the ability to define a single matrix U relating the pseudo-large and large component coefficient matrices. This matrix is used to define a modified set of one- and two-electron integrals which have the same appearance as the integrals of the Breit-Pauli Hamiltonian. The first approximation fixes the ratios of the large and pseudo-large components to their atomic values, producing an expansion in atomic 4-spinors. The second approximation defines a local fine-structure constant on each atomic centre, which has the physical value for centres considered to be relativistic and zero for nonrelativistic centres. In the latter case, the 4-spinors are the positive-energy kinetic al ly-balanced solutions of the Levy-Leblond equation, and the integrals involving pseudo-large component basis functions on these centres, are set to zero. Some results are presented for test systems to illustrate the various approximations.

Dyall, Ken↗
NASA NTRS1990

Fairness problems at the media access level for high-speed networks

Most lower speed (approx. 10 Mbps) local area networks use adaptive or random access protocols like Ethernet. Others at higher speed use demand assignment like token or slotted rings. These include Cambridge ring and electronic token ring systems. Fairness issues in representatives of such protocols are discussed. In particular, Fiber Distributed Data Interface (FDDI) was selected as a demand access protocol using tokens, Carrier Sensed Multiple Access/Ring Network (CSMA/RN) a random access protocol, and Distributed Queue Dual Bus (DQDB) a demand access protocol using reservations. Fairness at the media access level was the focus, i.e., attaining access or being excessively delayed when a message is queued to be sent as a function of network location. Within that framework, the essential fairness of FDDI was observed along with severe fairness problems in DQDB and some problems for CSMA/RN. Several modifications were investigated and their ameliorative effect is shown. Finally, a unified presentation which allows comparisons of the three protocols' fairness when normalized to their capacity is given.

Maly, Kurt J.↗
NASA NTRS2018

Imaging Plasma Density Structures in the Soft X-Rays Generated by Solar Wind Charge Exchange with Neutrals

Both heliophysics and planetary physics seek to understand the complex nature of the solar wind's interaction with solar system obstacles like Earth's magnetosphere, the ionospheres of Venus and Mars, and comets. Studies with this objective are frequently conducted with the help of single or multipoint in situ electromagnetic field and particle observations, guided by the predictions of both local and global numerical simulations, and placed in context by observations from far and extreme ultraviolet (FUV, EUV), hard X-ray, and energetic neutral atom imagers (ENA). Each proposed interaction mechanism (e.g., steady or transient magnetic reconnection, local or global magnetic reconnection, ion pick-up, or the Kelvin- Helmholtz instability) generates diagnostic plasma density structures. The significance of each mechanism to the overall interaction (as measured in terms of atmospheric/ionospheric loss at comets, Venus, and Mars or global magnetospheric/ionospheric convection at Earth) remains to be determined but can be evaluated on the basis of how often the density signatures that it generates are observed as a function of solar wind conditions. This paper reviews efforts to image the diagnostic plasma density structures in the soft (low energy, 0.1-2.0 keV) X-rays produced when high charge state solar wind ions exchange electrons with the exospheric neutrals surrounding solar system obstacles.

Sibeck, David G.↗
NASA NTRS2015

Insulation Resistance Degradation in Ni-BaTiO3 Multilayer Ceramic Capacitors

Insulation resistance (IR) degradation in Ni-BaTiO3 multilayer ceramic capacitors has been characterized by the measurement of both time to failure and direct-current (DC) leakage current as a function of stress time under highly accelerated life test conditions. The measured leakage current-time dependence data fit well to an exponential form, and a characteristic growth time SD can be determined. A greater value of tau(sub SD) represents a slower IR degradation process. Oxygen vacancy migration and localization at the grain boundary region results in the reduction of the Schottky barrier height and has been found to be the main reason for IR degradation in Ni-BaTiO3 capacitors. The reduction of barrier height as a function of time follows an exponential relation of phi (𝑡)=phi (0)e(exp -2Κt), where the degradation rate constant 𝐾=𝐾o𝑒(𝐸𝑘/𝑘𝑇) is inversely proportional to the mean time to failure (MTTF) and can be determined using an Arrhenius plot. For oxygen vacancy electromigration, a lower barrier height phi(0) will favor a slow IR degradation process, but a lower phi(0) will also promote electronic carrier conduction across the barrier and decrease the insulation resistance. As a result, a moderate barrier height phi(0) (and therefore a moderate IR value) with a longer MTTF (smaller degradation rate constant 𝐾) will result in a minimized IR degradation process and the most improved reliability in Ni-BaTiO3 multilayer ceramic capacitors.

dielectric degradation↗
NASA NTRS1973

Plasma and potential at the lunar surface

The various plasma environments of the moon are described for the lunar orbit through the solar wind and geomagnetic tail. The sources of lunar surface charge, including plasma, photo, and secondary currents, are compared for their expected range of values. The electric potential is calculated from probe theory as a function of local position on the lunar surface; the theory includes plasma environments which are both stationary and flowing. In agreement with several other calculations, the potential at the subsolar point is likely to be a few volts positive. However, for the case when the moon is in the solar wind, the potential is calculated to be a few tens of volts negative at the terminator, and is expected to go to larger negative values on the dark side. If the moon traverses a significant plasma sheet in the geomagnetic tail, then the dark side potential tends toward several kilovolts negative but may be strongly limited by the secondary electron current. Associated surface electric fields are estimated.

Manka, R. H.↗
NASA NTRS1988

A mathematical model of the middle and high latitude ionosphere

A time-dependent three-dimensional model of the middle and high latitude ionosphere is described. The density distributions of six ion species NO(+), O(2+), N(2+), O(+), N(+), He(+), and the electron and ion temperatures are obtained from a numerical solution of the appropriate continuity, momentum, and energy equations. The equations are solved as a function of height for an inclined magnetic field at E and F region altitudes. The three-dimensional nature of the model is obtained by following flux tubes of plasma as they convect or corotate through a moving neutral atmosphere. The model takes account of field-aligned diffusion, cross-field electrodynamic drifts, thermospheric winds, polar wind escape, energy-dependent chemical reactions, neutral composition changes, ion production due to solar EUV radiation and auroral precipitation, thermal conduction, diffusion-thermal heat flow and local heating and cooling processes. The model also takes account of the offset between the geomagnetic and geographic poles.

Schunk, R. W.↗
NASA NTRS1978

Pitch angle dispersion of drifting energetic protons at synchronous orbit

The time of arrival at ATS 6 of substorm-associated energetic proton flux enhancements has been examined as a function of both energy and pitch angle by using electron-proton spectrometer data. The protons exhibit energy dispersion with the particles with the highest energy arriving first. This has generally been interpreted as evidence that these particles have gradient- and curvature-drifted to the spacecraft from an acceleration region on the nightside. In the evening quadrant, proton enhancements at 90 deg pitch angle arrived at the spacecraft prior to those at small pitch angles. However, on the dayside the increase occurs first at the smallest pitch angle (about 30 degrees). The difference between the arrival times of the 30 deg and 90 deg protons increases for more westward local times. For the highest energy range observed, drifting protons are rarely seen at large pitch angles. These observations place severe restrictions on the simple drift models. Since the pitch angle dependence of the particle drift velocity is a field geometric quantity, the observations require the modification of present magnetospheric magnetic field models. In particular, the models need to reproduce better the enhanced field observed on the dayside near synchronous orbit.

Walker, R. J.↗
NASA NTRS2022

Solar Flare Heating with Turbulent Suppression of Thermal Conduction

During solar flares plasma is typically heated to very high temperatures, and the resulting redistribution of energy via thermal conduction is a primary mechanism transporting energy throughout the flaring solar atmosphere. The thermal flux is usually modeled using Spitzer’s theory, which is based on local Coulomb collisions between the electrons carrying the thermal flux and those in the background. However, often during flares, temperature gradients become sufficiently steep that the collisional mean free path exceeds the temperature gradient scale size, so that thermal conduction becomes inherently non-local. Further, turbulent angular scattering, which is detectable in nonthermal widths of atomic emission lines, can also act to increase the collision frequency and so suppress the heat flux. Recent work by Emslie & Bian (2018) extended Spitzer’s theory of thermal conduction to account for both non-locality and turbulent suppression. We have implemented their theoretical expression for the heat flux (which is a convolution of the Spitzer flux with a kernel function) into the RADYN flare-modeling code and performed a parameter study to understand how the resulting changes in thermal conduction affect flare dynamics and hence the radiation produced. We find that models with reduced heat fluxes predict slower bulk flows, less intense line emission, and longer cooling times. By comparing features of atomic emission lines predicted by the models with Doppler velocities and nonthermal line widths deduced from a particular flare observation, we find that models with suppression factors between 0.3 to 0.5 relative to the Spitzer value best reproduce observed Doppmission lines forming over a wide range of temperatures. Interestingly, the model that best matches observed nonthermal line widths has a kappa-type velocity distribution function.

Joel C. Allred↗
NASA NTRS2022

Solar Flare Heating with Turbulent Suppression of Thermal Conduction

During solar flares plasma is typically heated to very high temperatures, and the resulting redistribution of energy via thermal conduction is a primary mechanism transporting energy throughout the flaring solar atmosphere. The thermal flux is usually modeled using Spitzer’s theory, which is based on local Coulomb collisions between the electrons carrying the thermal flux and those in the background. However, often during flares, temperature gradients become sufficiently steep that the collisional mean free path exceeds the temperature gradient scale size, so that thermal conduction becomes inherently non-local. Further, turbulent angular scattering, which is detectable in nonthermal widths of atomic emission lines, can also act to increase the collision frequency and so suppress the heat flux. Recent work by Emslie & Bian (2018) extended Spitzer’s theory of thermal conduction to account for both non-locality and turbulent suppression. We have implemented their theoretical expression for the heat flux (which is a convolution of the Spitzer flux with a kernel function) into the RADYN flare-modeling code and performed a parameter study to understand how the resulting changes in thermal conduction affect flare dynamics and hence the radiation produced. We find that models with reduced heat fluxes predict slower bulk flows, less intense line emission, and longer cooling times. By comparing features of atomic emission lines predicted by the models with Doppler velocities and nonthermal line widths deduced from a particular flare observation, we find that models with suppression factors between 0.3 to 0.5 relative to the Spitzer value best reproduce observed Doppler velocities across emission lines forming over a wide range of temperatures. Interestingly, the model that best matches observed nonthermal line widths has a kappa-type velocity distribution function

Solar flares↗
NASA NTRS1994

Dielectric Properties of Poly(ethylene oxide) from Molecular Dynamics Simulations

The order, conformations and dynamics of poly(oxyethylene) (POE) melts have been investigated through molecular dynamics simulations. The potential energy functions were determined from detailed ab initio electronic structure calculations of the conformational energies of the model molecules 1,2-dimethoxyethane (DME) and diethylether. The x-ray structure factor for POE from simulation will be compared to experiment. In terms of conformation, simulations reveal that chains are extended in the melt relative to isolated chains due to the presence of strong intermolecular O...H interactions, which occur at the expense of intramolecular O...H interactions. Conformational dynamics about the C-C bond were found to be significantly faster than in polymethylene, while conformational dynamics about the C-O bond even faster than the C-C dynamics. The faster local dynamics in POE relative to polymethylene is consistent with C-13 NMR spin-lattice relaxation experiments. Conformational transitions showed significant second-neighbor correlation, as was found for polymethylene. This correlation of transitions with C-C neighbors was found to be reduced relative to C-O neighbors. Dielectric relaxation from simulation will also be compared with experiment.

Smith, Grant D.↗
NASA NTRS1990

Beam-generated upper hybrid noise in Jupiter's outer magnetosphere

A model for generation of upper hybrid waves in Jupiter's outer magnetosphere is presented. Energetic electrons accelerated on high-latitude auroral field lines at 1 R(J) altitudes are assumed to stream outwards to the distant magnetosphere. The large decrease in the local magnetic field strength results in a highly collimated, field-aligned electron beam due to conservation of the particle's magnetic moment. As the beam travels outward it passes through the plasma sheet boundary layer region located on the edges of the plasma sheet. Because of the large field-aligned anisotropy of the beam, the distribution is unstable to the excitation of the upper hybrid waves which amplify and then undergo mode conversion at the f(p) layer to generate the Jovian continuum radiation. A novel feature of the model is the beam-anisotropic heat flux instability which drives UH waves unstable without the need for any positive slope on the electron distribution function.

Barbosa, D. D.↗
NASA NTRS1990

Potential for integrated optical circuits in advanced aircraft with fiber optic control and monitoring systems

Fiber optic technology is expected to be used in future advanced weapons platforms as well as commercial aerospace applications. Fiber optic waveguides will be used to transmit noise free, high speed data between a multitude of computers as well as audio and video information to the flight crew. Passive optical sensors connected to control computers with optical fiber interconnects will serve both control and monitoring functions. Implementation of fiber optic technology has already begun. Both the military and NASA have several programs in place. A cooperative program, called FOCSI (Fiber Optic Control System Integration), between NASA Lewis and the NAVY to build, environmentally test and flight demonstrate sensor systems for propulsion and flight control systems is currently underway. Integrated Optical Circuits (IOC's) are also being given serious consideration for use in advanced aircraft systems. IOC's will result in miniaturization and localization of components to generate, detect optical signals and process them for use by the control computers. In some complex systems IOC's may be required to perform calculations optically if the technology is ready, replacing some of the electronic systems used today. IOC's are attractive because they will result in rugged components capable of withstanding severe environments in advanced aerospace vehicles. Manufacturing technology developed for microelectronic integrated circuits applied to IOC's will result in cost effective manufacturing. This paper reviews the current FOCSI program and describes the potential role of IOC's in FOCSI applications.

Robert Baumbick↗
NASA NTRS2004

Advanced Signal Conditioners for Data-Acquisition Systems

Signal conditioners embodying advanced concepts in analog and digital electronic circuitry and software have been developed for use in data-acquisition systems that are required to be compact and lightweight, to utilize electric energy efficiently, and to operate with high reliability, high accuracy, and high power efficiency, without intervention by human technicians. These signal conditioners were originally intended for use aboard spacecraft. There are also numerous potential terrestrial uses - especially in the fields of aeronautics and medicine, wherein it is necessary to monitor critical functions. Going beyond the usual analog and digital signal-processing functions of prior signal conditioners, the new signal conditioner performs the following additional functions: It continuously diagnoses its own electronic circuitry, so that it can detect failures and repair itself (as described below) within seconds. It continuously calibrates itself on the basis of a highly accurate and stable voltage reference, so that it can continue to generate accurate measurement data, even under extreme environmental conditions. It repairs itself in the sense that it contains a micro-controller that reroutes signals among redundant components as needed to maintain the ability to perform accurate and stable measurements. It detects deterioration of components, predicts future failures, and/or detects imminent failures by means of a real-time analysis in which, among other things, data on its present state are continuously compared with locally stored historical data. It minimizes unnecessary consumption of electric energy. The design architecture divides the signal conditioner into three main sections: an analog signal section, a digital module, and a power-management section. The design of the analog signal section does not follow the traditional approach of ensuring reliability through total redundancy of hardware: Instead, following an approach called spare parts tool box, the reliability of each component is assessed in terms of such considerations as risks of damage, mean times between failures, and the effects of certain failures on the performance of the signal conditioner as a whole system. Then, fewer or more spares are assigned for each affected component, pursuant to the results of this analysis, in order to obtain the required degree of reliability of the signal conditioner as a whole system. The digital module comprises one or more processors and field-programmable gate arrays, the number of each depending on the results of the aforementioned analysis. The digital module provides redundant control, monitoring, and processing of several analog signals. It is designed to minimize unnecessary consumption of electric energy, including, when possible, going into a low-power "sleep" mode that is implemented in firmware. The digital module communicates with external equipment via a personal-computer serial port. The digital module monitors the "health" of the rest of the signal conditioner by processing defined measurements and/or trends. It automatically makes adjustments to respond to channel failures, compensate for effects of temperature, and maintain calibration.

Lucena, Angel↗
NASA NTRS1990

The 60 micron to 20 centimeter infrared-to-radio ratio within spiral galaxies

A detailed comparison is presented of the distribution of 60 micron IR and 20 cm radio continuum emission within 25 galaxies, mostly disk spirals. Local maxima in the thermal IR and nonthermal radio emission are found to be spatially coincident on scales of less than about 0.4 kpc in the nearest sample galaxies. The IR-red disk in normal spirals appears to be characterized by a shorter scale length than that of the radio continuum disk, suggesting that the IR-to-radio ratio should decrease as a function of radius. A model that successfully accounts for the observations is introduced which is based on the assumptions of steady-state star formation activity within the disk on kpc scales and a tight coupling between the origins of the dust-heating radiation and the radio-emitting cosmic-ray electrons. The underlying source is described as an exponential disk. The results also suggest that a random walk process cannot by itself describe the temporal evolution of cosmic rays.

Bicay, M. D.↗
NASA NTRS1981

Diagnostic system design for the Ion Auxiliary Propulsion System /IAPS/ - Flight test of two 8 cm mercury ion thrusters

The experimental design of a Diagnostic Subsystem (DSS) as part of an Ion Auxiliary Propulsion System (IAPS) to be flown on P80-1 spacecraft in May 1983, is discussed. The DSS is composed of several detectors measuring thruster efflux, material deposition and spacecraft potential relative to the local space plasma in the vicinity of two 8 cm mercury ion thrusters. The detectors consist of two QCM units measuring frequency in the range of two to 65 KHz. Nine solar cell arrays have the capability of measuring current and voltage from 0-600 mA and 0-0.9 V. Seven ion collectors can measure ion currents with bias voltages of 0, 25, 55 and 96 V. The potential probe can measure current at 16 different commandible levels varying from one to 5 K microamperes within a voltage range of -25 to 175 V. The analysis of the ground-based data indicates that the hardware is qualified for flight, with the detectors and electronic units having passed all functional and environmental tests. Block diagrams are given and the functional parameters of the different design configurations are described.

Hurst, E. B.↗
NASA NTRS2007

Miniature L-Band Radar Transceiver

A miniature L-band transceiver that operates at a carrier frequency of 1.25 GHz has been developed as part of a generic radar electronics module (REM) that would constitute one unit in an array of many identical units in a very-large-aperture phased-array antenna. NASA and the Department of Defense are considering the deployment of such antennas in outer space; the underlying principles of operation, and some of those of design, also are applicable on Earth. The large dimensions of the antennas make it advantageous to distribute radio-frequency electronic circuitry into elements of the arrays. The design of the REM is intended to implement the distribution. The design also reflects a requirement to minimize the size and weight of the circuitry in order to minimize the weight of any such antenna. Other requirements include making the transceiver robust and radiation-hard and minimizing power demand. Figure 1 depicts the functional blocks of the REM, including the L-band transceiver. The key functions of the REM include signal generation, frequency translation, amplification, detection, handling of data, and radar control and timing. An arbitrary-waveform generator that includes logic circuitry and a digital-to-analog converter (DAC) generates a linear-frequency-modulation chirp waveform. A frequency synthesizer produces local-oscillator signals used for frequency conversion and clock signals for the arbitrary-waveform generator, for a digitizer [that is, an analog-to-digital converter (ADC)], and for a control and timing unit. Digital functions include command, timing, telemetry, filtering, and high-rate framing and serialization of data for a high-speed scientific-data interface. The aforementioned digital implementation of filtering is a key feature of the REM architecture. Digital filters, in contradistinction to analog ones, provide consistent and temperature-independent performance, which is particularly important when REMs are distributed throughout a large array. Digital filtering also enables selection among multiple filter parameters as required for different radar operating modes. After digital filtering, data are decimated appropriately in order to minimize the data rate out of an antenna panel. The L-band transceiver (see Figure 2) includes a radio-frequency (RF)-to-baseband down-converter chain and an intermediate- frequency (IF)-to-RF up-converter chain. Transmit/receive (T/R) switches enable the use of a single feed to the antenna for both transmission and reception. The T/R switches also afford a built-in test capability by enabling injection of a calibration signal into the receiver chain. In order of decreasing priority, components of the transceiver were selected according to requirements of radiation hardness, then compactness, then low power. All of the RF components are radiation-hard. The noise figure (NF) was optimized to the extent that (1) a low-noise amplifier (LNA) (characterized by NF < 2 dB) was selected but (2) the receiver front-end T/R switches were selected for a high degree of isolation and acceptably low loss, regardless of the requirement to minimize noise.

McWatters, Dalia↗
NASA NTRS1998

Observations of Ion Signatures of Magnetic Reconnection for Northward IMF

Magnetic merging at Earth's magnetopause produces distinct mixtures of ions and electrons as well as signatures in their distribution functions. High resolution measurements allow for the separation of the different distributions and quantification of their characteristics. This provides details on the temporal and spatial nature of the merging site and the resulting history of the merged fields. The event of May 29, 1996 resulted in remote observations of the effects of reconnection on both magnetosheath and magnetosphere populations for a period of approximately three hours. Three-dimensional ion distributions obtained by the Thermal Ion Dynamics Experiment on the Polar spacecraft show that field lines threading the spacecraft's location in the northern cusp region contained a mix of D-shaped ions from the magnetosheath and accelerated magnetospheric ions both moving parallel to the local magnetic field. This mix of ions resulted from transmission of magnetosheath ions across the magnetopause at speeds greater than the de-Hoffman-Teller speed and the reflection of cold, slow-moving plasmasphere-like ions at the magnetopause. These observations are used to conclude that these field lines were connected to the ionosphere in the northern hemisphere and, southward of the spacecraft, the interplanetary magnetic field and crossed the magnetopause in the equatorial region southward of the spacecraft.

Chandler, Michael O.↗