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At least 199 records · Page 11

Space Cooling: Recovery, Reuse, Recycling and Supply Chain Impacts

The global cooling sector has undergone tremendous growth in recent years, and cooling demand is projected to double or triple by 2050. Surging air conditioning demand will continue to be driven by increased populations, incomes and occurrences of extreme heat and humidity events. Cooling equipment growth has important pollution and material implications as they are made up of critical metals and precious raw materials - including ferrous metals, copper, aluminum and printed circuit boards composed of copper, silver, gold and palladium - that generate significant electronic waste at end-of-life. Air conditioning equipment also contains fluorinated gas (F-gas) refrigerants, which are potent gases that are thousands of times more heat-trapping than carbon dioxide (CO2). While recovery, reuse, and recycling strategies have been assessed for cold chain and refrigeration, there is currently limited analysis on how these strategies could be adopted for the global space cooling industry and potential supply chain implications. This paper aims to address this research gap by qualitatively evaluating product and material recovery, reuse and recycling frameworks from both demand and supply-side perspectives and with the support of cooling-specific case studies. It also focuses on quantitatively assessing potential energy, emissions and resource benefits of such strategies for space cooling equipment. This paper first analyzes how existing recovery, reuse and recycling frameworks can be applied to space cooling, with emphasis on the demand-side enablers (e.g., innovative business models, supporting policies and regulations) and changes in supply-side production network throughout the supply chain (e.g., design, production and distribution, end-of-life recovery) needed to overcome existing barriers. It will present case studies of innovative business models for space cooling technologies, including reuse and recycling, and how effective refrigerant reclamation and recovery programs have been operationalized. Lastly, the paper will highlight global modeling results of energy, emissions and material recovery from scenario analysis of selected strategies for air conditioners. The findings of this paper are intended to inform the development of product and material recovery, reuse and recycling strategies for a rapidly growing stock of space conditioning equipment by addressing existing organizational, economic and regulatory barriers and potential supply-chain bottlenecks.

Khanna, Nina↗

Upcycling Polynorbornene Derivatives into Chemically Recyclable Multiblock Linear and Thermoset Plastics

Synthetic polymers have found widespread use, but their ineffective end-of-life treatment is causing a significant environmental and human health crisis. Here, we demonstrate the upcycling of polynorbornene derivatives (pNBEs) through their deconstruction into distinct oligomeric buildings blocks that can be repolymerized into chemically recyclable pNBEs-like multiblock polymers via dehydrogenative polymerization. The resulting materials exhibit diverse mechanical properties, while integrating high melting temperatures (T m as high as 133 °C). Notably, this method could also enable the selective deconstruction of permanently cross-linked polydicyclopentadiene (pDCPD) thermosets into telechelic-OH functionalized oligomers, overcoming the significant challenges posed by their robust network structure in recycling and degradation. The resulting pDCPD oligomers can subsequently be repolymerized with macrodiols to create multiblock thermosets with tunable mechanical properties, including Young's modulus and tensile elongation. After use, upcycled plastics could be effectively deconstructed back to the oligomers for recovery and repolymerization. Overall, this work establishes an approach that can be utilized to upcycle pNBEs into previously inaccessible multiblock thermosets and thermoplastics with full recyclability, and may be generalizable to a range of polymers to shift their end-of-life waste disposal toward sustainable recovery and reuse.

36 MATERIALS SCIENCE↗

Summary of EOS flight dynamics analysis

From a flight dynamics perspective, the Earth Observing System (EOS) spacecraft present a number of challenges to mission designers. The Flight Dynamics Support Branch of NASA GSFC has examined a number of these challenges, including managing the EOS constellation, disposing of the spacecraft at the end-of-life (EOL), and achieving the appropriate mission orbit given launch vehicle and ascent propulsion constraints. The EOS program consists of a number of spacecraft including EOS-AM, an ascending node spacecraft, EOS-PM, a descending node spacecraft, the EOS Chemistry mission (EOS-CHEM), the EOS Altimetry Laser (EOS-LALT), and the EOS-Altimetry Radar (EOS-RALT). The orbit characteristics of these missions are presented. In order to assure that downlinking data from each spacecraft will be possible without interference between any two spacecraft, a careful examination of the relationships between spacecraft and how to maintain the spacecraft in a configuration which would minimize these communications problems must be made. The FDSB has performed various analyses to determine whether the spacecraft will be in a position to interfere with each other, how the orbit dynamics will change the relative positioning of the spacecraft over their lifetimes, and how maintenance maneuvers could be performed, if needed, to minimize communications problems. Prompted by an activity at NASA HQ to set guidelines for spacecraft regarding their end-of-life dispositions, much analysis has also been performed to determine the spacecraft lifetime of EOS-AM1 under various conditions, and to make suggestions regarding the spacecraft disposal. In performing this analysis, some general trends have been observed in lifetime calculations. The paper will present the EOS-AM1 lifetime results, comment on general reentry conclusions, and discuss how these analyses reflect on the HQ NMI. Placing the EOS spacecraft into their respective mission orbits involves some intricate maneuver planning to assure that all mission orbit requirements are met, given the initial conditions supplied by the launch vehicle at injection. The FDSB has developed an ascent scenario to meet the mission requirements. This paper presents results of the ascent analysis.

Newman, Lauri Kraft↗

Electrode Separation and Froth Flotation for the Recovery of Li-ion Battery Cathode Materials

Increasing use of Li-ion batteries (LIBs) will significantly increase the quantity of LIB waste generated from end-of-life batteries. Spent LiCoO 2 (LCO) battery cathodes contain significant quantities of valuable metals, making them good candidates for recycling. Typical recycling processes rely on high temperatures (pyrometallurgy) and chemical leachants (hydrometallurgy) to completely decompose the cathode and enable material recovery. Direct recycling processes and recovery of active material from electrode scrap do not benefit from such destructive recycling, and an efficient means of separating the cathode active material from the inactive components (e.g., polyvinylidene fluoride (PVDF) binder, conductive carbon) is needed. Here, we explore PVDF removal from LCO cathodes by two separate methods, evaluating their suitability for coupling to subsequent separation by froth flotation (FF). We show that washing electrodes in the solvent PolarClean (PC) dissolves PVDF away from LCO cathodes, enabling separation of the remaining LCO and conductive carbon by FF. The process is suitable for use with both pristine and cycled LCO electrodes, and the pristine recovered material can be used to prepare electrodes capable of cycling at 140 mAh/g. In conclusion, this demonstrates the suitability of coupled PC washing and FF separation for recycling both end-of-life batteries and scrap electrode material.

Batteries↗

Towards a Circular Economy for PET Bottles in the U.S. - 4P Model

The United States generates the most plastic waste of any country. Along with that GHG emissions from the global plastic economy are expected to increase to 15% of the global carbon budget by 2050. It is imperative that plastic recycling is made a reality to reduce both plastic pollution in the environment and GHG emissions. A portfolio of end-of-life strategies must be implemented to minimize environmental impacts and retain valuable plastic material, but it is challenging to compare options that generate products with different utility and lifetime. Plastic use reduction, reuse and recycling are thus increasingly important, but making informed policy and research decisions within this space can be challenging given the diverse range of available solutions. The novel analysis framework, Plastic Parallel Pathways Platform (4P) has been equipped with consequential life cycle assessment, techno-economic analysis, and a plastic circularity indicator to estimate the greenhouse gas (GHG) emissions, circularity, and cost of polyethylene terephthalate (PET) down-cycling to lower-quality resin, closed-loop recycling to food-grade PET bottles, up-cycling to fiber-reinforced plastic (FRP), and conversion to non-plastic products (electricity, oil) on a United States economy-wide basis. Integrating system dynamics into this robust plastics model that already incorporates techno-economics, circularity, and environmental impacts will enable identification of key bottlenecks between manufacturers, waste sorters, and reclaimers that currently prevent rapid decarbonization of the plastics economy. System dynamics (SD) explore the evolution of activities and technologies based on changed macro parameters such as plastic demand and supply, market shifts, and cross-sectoral interactions. This project particularly aims to explore the interplay between, waste collection, plastic waste sorting, recycling, and manufacturing, as well as the effect of plastic bale quality and plastic reuse initiatives on the surrounding process stages. This functionality will facilitate combinatory analysis in which a portfolio of end-of-life pathways are assessed simultaneously, with the exact makeup of that portfolio affected by parameters such as technology scales, resource constraints, and waste mitigation efforts. Integrating SD with the 4P framework enables analyzing the effect of increased revenue and reinvestment into improving process efficiencies, sorting and collection quantities. Through that, market effects of increased recycled resin availability can be studied for the plastics systems model for the US. The results will help identify technical or economic bottlenecks that currently limit efforts to decarbonize the U.S. plastics economy.

carbon↗

Towards a Circular Economy for PET Bottles in the U.S. - 4P Framework

The United States generates the most plastic waste of any country. Along with that GHG emissions from the global plastic economy are expected to increase to 15% of the global carbon budget by 2050. It is imperative that plastic recycling is made a reality to reduce both plastic pollution in the environment and GHG emissions. A portfolio of end-of-life strategies must be implemented to minimize environmental impacts and retain valuable plastic material, but it is challenging to compare options that generate products with different utility and lifetime. Plastic use reduction, reuse and recycling are thus increasingly important, but making informed policy and research decisions within this space can be challenging given the diverse range of available solutions. The novel analysis framework, Plastic Parallel Pathways Platform (4P) has been equipped with consequential life cycle assessment, techno-economic analysis, and a plastic circularity indicator to estimate the greenhouse gas (GHG) emissions, circularity, and cost of polyethylene terephthalate (PET) down-cycling to lower-quality resin, closed-loop recycling to food-grade PET bottles, up-cycling to fiber-reinforced plastic (FRP), and conversion to non-plastic products (electricity, oil) on a United States economy-wide basis. Integrating system dynamics into this robust plastics model that already incorporates techno-economics, circularity, and environmental impacts will enable identification of key bottlenecks between manufacturers, waste sorters, and reclaimers that currently prevent rapid decarbonization of the plastics economy. System dynamics (SD) explore the evolution of activities and technologies based on changed macro parameters such as plastic demand and supply, market shifts, and cross-sectoral interactions. This project particularly aims to explore the interplay between, waste collection, plastic waste sorting, recycling, and manufacturing, as well as the effect of plastic bale quality and plastic reuse initiatives on the surrounding process stages. This functionality will facilitate combinatory analysis in which a portfolio of end-of-life pathways are assessed simultaneously, with the exact makeup of that portfolio affected by parameters such as technology scales, resource constraints, and waste mitigation efforts. Integrating SD with the 4P framework enables analyzing the effect of increased revenue and reinvestment into improving process efficiencies, sorting and collection quantities. Through that, market effects of increased recycled resin availability can be studied for the plastics systems model for the US. The results will help identify technical or economic bottlenecks that currently limit efforts to decarbonize the U.S. plastics economy.

circular economy↗

Reman Co-Design: A Combined Design and Remanufacturing Optimization Framework for the Sustainable Design of High-Value Components

Remanufacturing is a process that returns end-of-life equipment to as-new conditions and offers numerous environmental and economic benefits. To fully capitalize on remanufacturing, its synergistic interactions with design must be fully realized and addressed during the design stage. Although this fact is widely recognized in the literature, most of the current studies focus primarily either on the design or remanufacturing aspects of design for remanufacturing (DfRem). In an effort to offer a more integrated DfRem approach than those reported in the literature, we propose a new combined design and remanufacturing optimization (reman co-design) framework that takes a holistic approach by leveraging the intricate interplay between design and remanufacturing. Here, the aim of this formulation is to identify the optimal decisions that maximize the benefits of remanufacturing throughout the entire lifespan of a product. To showcase the utility of the new formulation, we are using a case study of a hydraulic manifold, (re)manufactured by John Deere. Using this industry example, we compare the results of reman co-design to the ones from a decoupled remanufacturing design approach. Results reveal that remanufacturing benefits are better realized and improved upon when using the developed reman co-design approach.

design for X↗

Ghostbusters for Batteries

End-of-life lithium-ion batteries are Class 9 hazardous materials due to flammability of electrolyte and lithium. It is why the transportation cost ranges from $2.49/kg - $7.20/kg for civilian and defense disposition, that is over 50% of the cost of recycling. Damaged batteries have many times greater transportation cost. Dead batteries require costly bunker-storage that occupies real estate and personnel that could be used for productive purposes. Insurance is expensive and accidents are almost assured even with relatively low volumes of waste. Tipping fees on top of this adds an unpredictable, inflated cost for the EV industry, which is very cost sensitive for survival. Transforming lithium-ion into a class of non-hazardous material reduces transportation cost to $0.10/kg, providing a value opportunity of ~$2/kg to ~$6/kg for civilian and defense disposition respectively. OnTo can eliminate the risk of thermal runaway with a brief, non-toxic treatment to eliminate flammability and toxic risks in most any battery, except Pb, which is inherently toxic. With the service, OnTo also can provide rigorous certainty that cells are rendered inert. OnTo’s patented and patent pending deactivation technology improves the cost and safety for disposition of end-of-life lithium-ion battery packs and cells. Deactivation uses non-toxic chemical processing to remove inherent risks in lithium-ion and other primary and secondary chemistries. The technology has been demonstrated and developed through DOE contract with OnTo Technology LLC (EE0008475).

25 ENERGY STORAGE↗

Predicting Maximum Temperatures of a Li-ion Battery on a Simulated Flight Profile using a Model-based Prognostics

One of the challenges in using Li-ion packs in aeronautics is their safety, and thermal runaway (TR) is a major concern. The current engineering solutions to prevent a Li-ion pack from a catastrophic TR require additional mass and volume to isolate cells. The excess mass could be reduced by improving detection and, thus, preventing a TR event. One of the possible early warning indicators of a TR is crossing a threshold temperature. We have developed an approach, based on the Unscented Kalman Filter (UKF), to predict the likelihood of reaching the threshold temperature for simulated flight profiles. The current battery prognostics algorithms for aerospace predict state-of-charge (SOC) and end-of-life (EOL) [1]. We extended this two-level algorithm to predict the maximum temperature during discharge. The amount of heat generated in a cell depends on factors such as cell chemistry, cell packaging, total cycles, operating temperature, and abuse history [2]. Our semi-empirical thermal model depends on three phenomenological parameters which account for those factors. In addition, a two-parameter reduced-order model is developed to predict the temperature rise for short bursts of “random-walk” (RW) discharge current sequence, which simulates a flight's current-loading profile. The performance of these models on different datasets and types of current loading will be presented. To predict the maximal temperatures for future cycles we must estimate the evolution of thermal parameters as the batteries age. It is found that the parameters of the 3-parametric thermal model cannot be estimated only from the RW data. To address the issue, we will present two alternative approaches: i) expanding the datasets to include discharge profiles beyond RWs; ii) model reduction to a two-parametric model. The two approaches will be illustrated by an application to the cycling data from a commercial LG 18650 cell. References: 1. M. Daigle, C.S. Kulkarni, End-of-discharge and End-of-life Prediction in Lithium-ion Batteries with Electrochemistry-based Aging Models, in: AIAA Infotech @ Aerospace, American Institute of Aeronautics and Astronautics, San Diego, California, USA, 2016. 2. M. Börner, et. al, Correlation of aging and thermal stability of commercial 18650-type lithium ion batteries, Journal of Power Sources. 342 (2017) 382–392.

Thermal runaway↗

Atmospheric reentry of the in-core thermionic SP-100 reactor system

Presumed end-of-life atmospheric reentry of the GA SP-100 system was studied to assess dispersal feasibility and associated hazards. Reentry was studied by sequential use of an orbital trajectory and a heat analysis computer program. Two heating models were used. The first model assumed a thermal equilibrium condition between the stagnation point aerodynamic heating and the radiative cooling of the skin material surface. The second model allowed for infinite conductivity of the skin material. Four reentering configurations were studied representing stages of increased SP-100 breakup: (1) radiator, shield and reactor, (2) shield and reactor, (3) reactor with control drums, and (4) reactor without control drums. Each reentering configuration was started from a circular orbit at 116 km having an inertial velocity near Mach 25. The assumed failing criterion was the attainment of melting temperature of a critical system component. The reentry analysis revealed breakup of the vessel in the neighborhood of 61 km altitude and scattering of the fuel elements. Subsequent breakup of the fuel elements was not predicted. Oxidation of the niobium skin material was calculated to cause an increase in surface temperature of less than ten percent. The concept of thermite analogs for enhancing reactor reentry dispersal was assessed and found to be feasible in principle. A conservative worst-case hazards analysis was performed for radioactive and nonradioactive toxic SP-100 materials assumed to be dispersed during end-of-life reentry. The hazards associated with this phase of the SP-100 mission were calculated to be insignificant.

Stamatelatos, M. G.↗

Integrity Monitoring of Mercury Discharge Lamps

Mercury discharge lamps are critical in many trapped ion frequency standard applications. An integrity monitoring system can be implemented using end-of-life signatures observed in operational mercury discharge lamps, making it possible to forecast imminent failure and to take action to mitigate the consequences (such as switching to a redundant system). Mercury lamps are used as a source of 194-nm ultraviolet radiation for optical pumping and state selection of mercury trapped ion frequency standards. Lamps are typically fabricated using 202Hg distilled into high-purity quartz, or other 194-nm transmitting material (e.g., sapphire). A buffer gas is also placed into the bulb, typically a noble gas such as argon, neon, or krypton. The bulbs are driven by strong RF fields oscillating at .200 MHz. The lamp output may age over time by two internal mechanisms: (1) the darkening of the bulb that attenuates light transmission and (2) the loss of mercury due to migration or chemical interactions with the bulb surface. During fabrication, excess mercury is placed into a bulb, so that the loss rate is compensated with new mercury emanating from a cool tip or adjacent reservoir. The light output is nearly constant or varies slightly at a constant rate for many months/years until the mercury source is depleted. At this point, the vapor pressure abruptly falls and the total light output and atomic clock SNR (signal-to-noise ratio) decrease. After several days to weeks, the light levels decrease to a point where the atomic clock SNR is no longer sufficient to stay in lock, or the lamp self-extinguishes. This signature has been observed in four separate end-of-life lamp failures while operating in the Deep Space Network (DSN). A simple integrator circuit can observe and document steady-state lamp behavior. When the light levels drop over a predetermined time interval by a specified amount (e.g., 20 percent), an alarm is set. For critical operational applications, such as the DSN or in space flight, this warning provides notice that a failure may be imminent, and for operators or control algorithm to take action.

Tjoelker, Robert L.↗

Solar and Drag Sail Propulsion: From Theory to Mission Implementation

Solar and drag sail technology is entering the mainstream for space propulsion applications within NASA and around the world. Solar sails derive propulsion by reflecting sunlight from a large, mirror- like sail made of a lightweight, reflective material. The continuous sunlight pressure provides efficient primary propulsion, without the expenditure of propellant or any other consumable, allowing for very high V maneuvers and long-duration deep space exploration. Drag sails increase the aerodynamic drag on Low Earth Orbit (LEO) spacecraft, providing a lightweight and relatively inexpensive approach for end-of-life deorbit and reentry. Since NASA began investing in the technology in the late 1990's, significant progress has been made toward their demonstration and implementation in space. NASA's Marshall Space Flight Center (MSFC) managed the development and testing of two different 20-m solar sail systems and rigorously tested them under simulated space conditions in the Glenn Research Center's Space Power Facility at Plum Brook Station, Ohio. One of these systems, developed by L'Garde, Inc., is planned for flight in 2015. Called Sunjammer, the 38m sailcraft will unfurl in deep space and demonstrate solar sail propulsion and navigation as it flies to Earth-Sun L1. In the Flight Center (MSFC) managed the development and testing of two different 20-m solar sail systems and rigorously tested them under simulated space conditions in the Glenn Research Center's Space Power Facility at Plum Brook Station, Ohio. One of these systems, developed by L'Garde, Inc., is planned for flight in 2015. Called Sunjammer, the 38m sailcraft will unfurl in deep space and demonstrate solar sail propulsion and navigation as it flies to Earth-Sun L1. In the interim, NASA MSFC funded the NanoSail-D, a subscale drag sail system designed for small spacecraft applications. The NanoSail-D flew aboard the Fast Affordable Science and Technology SATellite (FASTSAT) in 2010, also developed by MSFC, and began its mission after it was ejected from the FASTSAT into Earth orbit, where it remained for several weeks before deorbiting as planned. NASA recently selected two small satellite missions for study as part of the Advanced Exploration Systems (AES) Program, both of which will use solar sails to enable their scientific objectives. Lunar Flashlight, managed by JPL, will search for and map volatiles in permanently shadowed Lunar craters using a solar sail as a gigantic mirror to steer sunlight into the shaded craters. The Near Earth Asteroid (NEA) Scout mission will use the sail as primary propulsion allowing it to survey and image one or more NEA's of interests for possible future human exploration. Both are being studied for possible launch in 2017. The Planetary Society's privately funded LightSail-A and -B cubesat-class spacecraft are nearly complete and scheduled for launch in 2015 and 2016, respectively. MMA Design launched their DragNet deorbit system in November 2013, which will deploy from the STPSat-3 spacecraft as an end of life deorbit system. The University of Surrey is building a suite of cubesat class drag and solar sail systems that will be launched beginning in 2015. As the technology matures, solar sails will increasingly be used to enable science and exploration missions that are currently impossible or prohibitively expensive using traditional chemical and electric rockets. For example, the NASA Heliophysics Decadal Survey identifies no less than three such missions for possible flight before the mid-2020's. Solar and drag sail propulsion technology is no longer merely an interesting theoretical possibility; it has been demonstrated in space and is now a critical technology for science and solar system exploration.

Johnson, Les↗

Rechargeable Micro-Batteries

The quest for efficient power sources for small sensors has led to a growing interest in rechargeable micro-batteries, offering the potential to harness energy from various sources for extended periods. This project delves into a multifaceted project aimed at enhancing the performance and viability of rechargeable micro-batteries in this context. The Pacific Northwest National Laboratory (PNNL) has leveraged its expertise in primary micro-battery development, evolving into a software-driven approach for designing cylindrical micro-batteries. This project addresses the cycle life issue through innovative cell design, electrode optimization, and electrolyte refinement. A case study of the MB1842 rechargeable micro-battery demonstrates the promising outcomes of these advancements, showcasing a capacity of 0.32 mAh at ~1C (0.35 mA) and remarkable cycle performance, extending the cycle life to 510-570 cycles at 80% end-of-life (EOL), 710-760 cycles at 70% EOL and 840-940 cycles at 60% EOL, thereby ensuring a service life of 10 years for these rechargeable micro-batteries. This endeavor represents a significant stride towards unlocking the full potential of rechargeable micro-batteries, paving the way for their widespread application in small sensor technologies. The outcome from this project also successfully supports the award of a new project: 80621 - Self-Powered Modular Acoustic Telemetry System with Sensing.

25 ENERGY STORAGE↗

Response of thick, notched laminates subjected to tension-compression cyclic loads

The fatigue response of a (0/24/90/-45)s4 T300-5208 graphite-epoxy laminate with a drilled centerhole subjected to fully reversed tension-compression (R=-1, T-C) constant amplitude loading was investigated. Damage evaluation techniques such as stiffness monitoring, penetrant-enchanced X-ray radiography, C-scan, laminate deeply and residual strength were used to establish the mechanisms of damage development as well as the relations between this damage and the stiffness, strength and life of the laminate. Damage initiated at the hole as matrix cracking parallel to the fibers in all plies. Matrix cracks had a significant effect on delamination initiation and growth. Delaminations initiated near the surface in the densely cracked region at the hole and grew along major matrix cracks. Compressive properties degraded more rapidly than tensile properties. At the stress levels used, residual tensile strength increased early in the fatigue life and remained approximately constant to near the end of life, when failure was precipitated by excessive laminate instability during the compressive portion of the loading.

Bakis, C. E.↗

Response of thick, notched laminates subjected to tension-compression cyclic loads

The fatigue response of a (0/24/90/-45)s4 T300-5208 graphite-epoxy laminate with a drilled centerhole subjected to fully reversed tension-compression (R=-1, T-C) constant amplitude loading was investigated. Damage evaluation techniques such as stiffness monitoring, penetrant-enhanced X-ray radiography, C-scan, laminate deply and residual strength were used to establish the mechanisms of damage development as well as the relations between this damage and the stiffness, strength and life of the laminate. Damage initiated at the hole as matrix cracking parallel to the fibers in all plies. Matrix cracks had a significant effect on delamination initiation and growth. Delaminations initiated near the surface in the densely cracked region at the hole and grew along major matrix cracks. Compressive properties degraded more rapidly than tensile properties. At the stress levels used, residual tensile strength increased early in the fatigue life and remained approximately constant to near the end of life, when failure was precipitated by excessive laminate instability during the compressive portion of the loading.

Bakis, C. E.↗

Fatigue response of notched laminates subjected to tension-compression cyclic loads

The fatigue response of a ((0/45/90/-45)(sub s))(sub 4) T300-5208 graphite-epoxy laminate with a drilled center-hole subjected to various components of tensile and compressive cyclic loads was investigated. Damage evaluation techniques such as stiffness monitoring, penetrant-enhanced X-ray radiography, C-scan, laminate deply and residual strength measurement were used to establish the mechanisms of damage development as well as the effect of such damage on the laminate strength, stiffness and life. Damage modes consisted of transverse matrix cracks, initiating at the hole, in all plies, followed by delamination between plies of different orientation. A characteristic stiffness repsonse during cyclic loading at two load levels was identified and utilized a more reliable indicator of material and residual properties than accumulated cycles. For the load ratios of tension-compression loading, residual tensile strength increased significantly above the virgin strength early in the fatigue life and remained approximately constant to near the end of life. A technique developed for predicting delamination initiation sites along the hole boundary correlated well with experimental evidence.

Bakis, C. E.↗

Acid electrolyte fuel cell technology program

The development of an acid electrolyte fuel cell was investigated to provide a cost effective electrical power system for the space shuttle orbiter. Previous investigation showed the life capability of the fuel cell was improved by proper prehumidification of the reactant gases. Breadboard models were developed which incorporate reactant prehumidification and have a life duration time of 2000 hours. Fuel cell performance was found to be invariant with cell life, and reactant consumption was unchanged from start to end of life. Satisfactory start and stop procedures are demonstrated along with scale-up capabilities for the number of cells in a stack, and for cell active areas. Safety design features, which operate to isolate the affected module from the remainder of the system, to eliminate single point failure modes from affecting the entire electrical power system are included.

Source record↗