Search NASA⌕ Search

SEARCH · Search NASA

Results for “Energy stable”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

Direct simulation of the stably stratified turbulent Ekman layer

The Navier-Stokes equations and the Boussinesq approximation were used to compute a 3D time-dependent turbulent flow in the stably stratified Ekman layer over a smooth surface. The simulation data are found to be in very good agreement with atmospheric measurements when nondimensionalized according to Nieuwstadt's local scaling scheme. Results suggest that, when Reynolds number effects are taken into account, the 'constant Froud number' stable layer model (Brost and Wyngaard, 1978) and the 'shearing length' stable layer model (Hunt, 1985) for the dissipitation rate of turbulent kinetic energy are both valid. It is concluded that there is good agreement between the direct numerical simulation results and large-eddy simulation results obtained by Mason and Derbyshire (1990).

Coleman, G. N.↗

Finite nucleus effects on relativistic energy corrections

The effect of using a finite nucleus model in quantum-chemical calculations is examined. Relativistic corrections from the first order Foldy-Wouthuysen terms are affected indirectly by the change in wavefunction, but also directly as a result of revised expressions for the Darwin and spin-orbit terms due to the change in nuclear potential. A calculation for the Rn atom indicates that the mass-velocity and Darwin corrections are much more sensitive to the finite nucleus than the non-relativistic total energy, but that the total contribution for these two terms is quite stable provided the revised form of the Darwin term is used. The spin-orbit interaction is not greatly affected by the choice of nuclear model.

Dyall, Kenneth G.↗

Crystallographic Stability of Metastable Phase Formed by Containerless Processing in REFeO3 (RE: Rare-Earth Element)

Undercooling a melt often facilitates a metastable phase to nucleate preferentially. Although the classical nucleation theory shows that the most critical factor for forming a metastable phase is the interface free energy, the crystallographic stability is also indispensable for the phase to be frozen at ambient temperature. In compound materials such as oxides, authors have suggested that the decisive factors for forming a critical nucleus are not only the free energy difference but also the difference of the entropy of fusion between stable and metastable phases. In the present study, using REFeO3 (RE: rare-earth element) as a model material, we investigate the formation of a metastable phase from undercooled melts with respect to the competitive nucleation and crystallographical stabilities of both phases.

Kuribayashi, Kazuhiko↗

Effect of Control Mode and Test Rate on the Measured Fracture Toughness of Advanced Ceramics

The effects of control mode and test rate on the measured fracture toughness of ceramics were evaluated by using chevron-notched flexure specimens in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% (statistically insignificant) variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or crack mouth opening displacement (CMOD) control gave approx. 5% (statistically significant) variation over a very wide range of rates (1 to 80 μm/m/s), with the measurements being a function of rate. However, the rate effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of a nitrogen environment during strain controlled tests, fracture toughness values were within about 1% over a wide range of rates (1 to 80 micons/m/s). CMOD or strain control did allow stable crack extension well past maximum force, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM Test Method C1421 on fracture toughness measurement.

silicon nitride↗

Effect of Control Mode and Load Rate on Fracture Toughness of Brittle Ceramics

The effects of control mode and rate on the fracture toughness of ceramics were measured by using chevron-notched flexure specimen in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or CMOD control gave an approximately 5% variation over a very wide range of rates, with the measurements being a function of rate. However, the effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of nitrogen for strain control, fracture toughness values were within about 1% over a wide range of rates (1 to 80 micro-epsilon/sec.). CMOD or strain control did allow stable crack extension well past maximum load, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM International standard C1421 on fracture toughness measurement.

control mode↗

Effect of Control Mode and Test Rate on Fracture Toughness of Advanced Ceramics

The effects of control mode and rate on the fracture toughness of ceramics were measured by using chevron-notched flexure specimen in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or CMOD control gave ~5% variation over a very wide range of rates, with the measurements being a function of rate. However, the effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of nitrogen for strain control, fracture toughness values were within about 1% over a wide range of rates (1 to 80 /s). CMOD or strain control did allow stable crack extension well past maximum load, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM International standard C1421 on fracture toughness measurement.

fracture toughness↗

Observations of low-energy /0.3- to 1.8-MeV/ differential spectrums of trapped protons.

Measurements of differential energy spectrums of trapped protons obtained from several passes during the period January to November 1969 using the polar orbiting, low-altitude Injun 5 satellite equipped with a special solid-state detector proton-electron telescope are presented. Results reveal the existence of a quasi-persistent peak in the differential energy spectrum in the McIlwain shell parameter (L) range 2 to 2.6 and in the energy range of approximately 0.32 to 0.72 MeV. The fact that the shape of the spectrum is stable for several days or can change with time scales as small as 4 hours suggests an impulsive acceleration mechanism deep in the radiation belts. Other features of the spectrum show that if the spectrum is represented by an exponential form in energy, the dependence of the spectral parameter is in general agreement with diffusion theory over the L range of approximately 2 to 4.

Venkatesan, D.↗

A hot wire radiant energy source for mapping the field of view of a radiometer

The design and performance of a calibration device that allows the measurement of a radiometer's field of view are described. The heart of the device is a heated 0.0254-mm (0.001-inch) diameter filament that provides a variable, isothermal line source of radiant energy against a cold background. By moving this discrete line source across the field of view of a radiometer, the radiometer's spatial response can be completely mapped. The use of a platinum filament provides a durable radiation source whose temperature is stable and repeatable to 10 K over the range of 600 to 1200 K. By varying the energy emitted by the filament, the field of view of radiometers with different sensitivities (or multiple channel radiometers) can be totally mapped.

Edwards, S. F.↗

Energy Requirements of Hydrogen-Utilizing Microbes: Boundary Condition for Subsurface Life

For planetary bodies with surface conditions that are too harsh to permit continuous occupation by life, the deep subsurface offers a potentially stable and habitable niche. For organisms occupying this niche, the spectrum of possible metabolisms must be limited to those which do not include sunlight as an energy source or oxygen as a chemical reagent - generally, low-energy anaerobic oxidation-reduction processes. The quantity of energy released in such processes is critical, because currently understood mechanisms of biological energy conservation indicate that energy is only 'useful' to an organism when it is available at a certain minimum level - the 'biological energy quantum'. The mere existence of a BEQ implies that a significant fraction of the chemical energy present in the environment cannot be exploited by life; similarly, the absolute magnitude of the BEQ must be a key variable in determining the potential viability and distribution of subsurface microbial communities. Laboratory culture studies suggest that organisms require an energy of about -20 kJ/mol to grow. However, we find that hydrogen-utilizing microorganisms in an energy-limited natural ecosystem are active with energy yields as low as -10 kJ/mol. A lower BEQ would mean a significantly expanded range of energetically viable subsurface habitat for life.

Hoehler, Tori M.↗

Study of Stable Cathodes and Electrolytes for High Specific Density Lithium-Air Battery

Future NASA missions require high specific energy battery technologies, greater than 400 Wh/kg. Current NASA missions are using "state-of-the-art" (SOA) Li-ion batteries (LIB), which consist of a metal oxide cathode, a graphite anode and an organic electrolyte. NASA Glenn Research Center is currently studying the physical and electrochemical properties of the anode-electrolyte interface for ionic liquid based Li-air batteries. The voltage-time profiles for Pyr13FSI and Pyr14TFSI ionic liquids electrolytes studies on symmetric cells show low over-potentials and no dendritic lithium morphology. Cyclic voltammetry measurements indicate that these ionic liquids have a wide electrochemical window. As a continuation of this work, sp2 carbon cathode and these low flammability electrolytes were paired and the physical and electrochemical properties were studied in a Li-air battery system under an oxygen environment.

cathodes↗

Energy Requirements of Hydrogen-utilizing Microbes: A Boundary Condition for Subsurface Life

Microbial ecosystems based on the energy supplied by water-rock chemistry carry particular significance in the context of geo- and astrobiology. With no direct dependence on solar energy, lithotrophic microbes could conceivably penetrate a planetary crust to a depth limited only by temperature or pressure constraints (several kilometers or more). The deep lithospheric habitat is thereby potentially much greater in volume than its surface counterpart, and in addition offers a stable refuge against inhospitable surface conditions related to climatic or atmospheric evolution (e.g., Mars) or even high-energy impacts (e.g., early in Earth's history). The possibilities for a deep microbial biosphere are, however, greatly constrained by life s need to obtain energy at a certain minimum rate (the maintenance energy requirement) and of a certain minimum magnitude (the energy quantum requirement). The mere existence of these requirements implies that a significant fraction of the chemical free energy available in the subsurface environment cannot be exploited by life. Similar limits may also apply to the usefulness of light energy at very low intensities or long wavelengths. Quantification of these minimum energy requirements in terrestrial microbial ecosystems will help to establish a criterion of energetic habitability that can significantly constrain the prospects for life in Earth's subsurface, or on other bodies in the solar system. Our early work has focused on quantifying the biological energy quantum requirement for methanogenic archaea, as representatives of a plausible subsurface metabolism, in anoxic sediments (where energy availability is among the most limiting factors in microbial population growth). In both field and laboratory experiments utilizing these sediments, methanogens retain a remarkably consistent free energy intake, in the face of fluctuating environmental conditions that affect energy availability. The energy yields apparently required by methanogens in these sediment systems for sustained metabolism are about half that previously thought necessary. Lowered energy requirements would imply that a correspondingly greater proportion of the planetary subsurface could represent viable habitat for microorganisms.

Hoehler, Tori M.↗

COMOC: Thermal analysis variant. User's manual

The Thermal Analysis Variant of the COMOC (computational continuum mechanics) computer system solves problems involving transient heat conduction and convection in stationary continua spanning arbitrarily irregular two-dimensional and axisymmetric solution domains. COMOC is based upon a finite element solution algorithm for the energy equation, and solves for the transient nodal temperature distribution using a highly stable and automatic explicit integration procedure. COMOC is extensively user-oriented, requires minimal input, and no a priori knowledge concerning the stability character of the differential equation system. It can readily output computed data in user-specified format fields, that geometrically resemble the solution domain discretization (for rapid engineering evaluation). Complete information is provided for applying COMOC to a specific problem.

Bauer, A. M.↗

Control of spin ambiguity during reorientation of an energy dissipating body

A quasi-rigid body initially spinning about its minor principal axis and experiencing energy dissipation will enter a tumbling mode and eventually reorient itself such that stable spin about its major principal axis is achieved. However, in this final state the body may be spinning in a positive or negative sense with respect to its major axis and aligned in a positive or negative sense with the inertially fixed angular momentum vector. This ambiguity can be controlled only through an active system. The associated dynamical formulations and simulations of uncontrolled reorientations are presented. Three control schemes are discussed and results offered for specific examples. These schemes include displacement of internal masses, spinning up of internal inertia, and reaction jets, all of which have demonstrated the ability to control spin ambiguity.

Kaplan, M. H.↗

A case of elasto-plastic flow using a new special element

Using a new special element for elasto-plastic flow, a nearly square, center-cracked plate of simulated A533 steel is analyzed. Selected results are examined locally to the crack's tip. It is found that a sharp transition in the distribution of deformation and stress occurs after the initial elastic response, and that this state is followed by fairly stable behavior over a considerable portion of the load range. Distribution of strain energy density is noted, and implications for use of the parameter J and for additional work are discussed briefly.

Swedlow, J. L.↗

Theoretical study of miscibility and glass-forming trends in mixtures of polystyrene spheres

A theoretical study of glass-forming trends and miscibility in mixtures of polystyrene spheres (polyballs) of different diameters, suspended in an aqueous solution, is presented. The polyballs are assumed to be charged and to interact via a Debye-Hueckel screened Coulomb potential. The Helmholtz free energy is calculated from a variational principle based on the Gibbs-Bogoliubov inequality, in which a mixture of hard spheres of different diameters is chosen as the reference system. It is found that when the charges of the two types of polyballs are sufficiently different, the variationally determined ratio of hard-sphere diameters differs substantially, leading to packing difficulties characteristic of glass formation. The experimentally observed range of glass formation corresponds to a ratio of hard-sphere diameters of 0.8 or less. Calculations of the free energy as a function of concentration indicate that the liquid polyball mixture is stable against the phase separation, even for widely different polyball charges.

Shih, W.-H.↗

Ab initio study of BeCN, MgCN, CaCN and BaCN

The structure and energetics of the BeCN, MgCN, CaCN and BaCN molecules are studied at both the Hartree-Fock and singles plus doubles configuration-interaction level using Gaussian basis sets of at least triple-zeta plus double polarization quality. All molecules are predicted to be linear, with the isocyanide structures more stable by 0.3 to 0.5 eV than the corresponding cyanides. The theoretical dissociation energies (De) in eV with an estimated uncertainty are (with the experimental values in parentheses): Be-NC 4.2 + or - 0.1 (4.46 + or - 0.29), Mg-NC 3.45 + or - 0.1 (4.21 + or - 0.22), Ca-NC 4.2 + or - 0.1 (4.46 + or - 0.22) and Ba-NC 4.5 + or 0.2 (4.87 + or - 0.26).

Bauschlicher, C. W., Jr.↗

Composite interlaminar fracture toughness: Three-dimensional finite element modeling for mixed mode 1, 2 and 3 fracture

A computational method/procedure is described which can be used to simulate individual and mixed mode interlaminar fracture progression in fiber composite laminates. Different combinations of Modes 1, 2, and 3 fracture are simulated by varying the crack location through the specimen thickness and by selecting appropriate unsymmetric laminate configurations. The contribution of each fracture mode to strain energy release rate is determined by the local crack closure methods while the mixed mode is determined by global variables. The strain energy release rates are plotted versus extending crack length, where slow crack growth, stable crack growth, and rapid crack growth regions are easily identified. Graphical results are presented to illustrate the effectiveness and versatility of the computational simulation for: (1) evaluating mixed-mode interlaminar fracture, (2) for identifying respective dominant parameters, and (3) for selecting possible simple test methods.

Murthy, P. L. N.↗

Composite interlaminar fracture toughness - Three-dimensional finite-element modeling for mixed mode I, II, and fracture

A computational method/procedure is described which can be used to simulate individual and mixed mode interlaminar fracture progression in fiber composite laminates. Different combinations of Modes 1, 2, and 3 fracture are simulated by varying the crack location through the specimen thickness and by selecting appropriate unsymmetric laminate configurations. The contribution of each fracture mode to strain energy release rate is determined by the local crack closure methods while the mixed mode is determined by global variables. The strain energy release rates are plotted versus extending crack length, where slow crack growth, stable crack growth, and rapid crack growth regions are easily identified. Graphical results are presented to illustrate the effectiveness and versatility of the computational simulation for: (1) evaluating mixed-mode interlaminar fracture, (2) for identifying respective dominant parameters, and (3) for selecting possible simple test methods.

Murthy, Pappu L. N.↗