Phase studies of the systems Mn-S, Mn-Se, and MnS-MnSe
Phase equilibria in Mn-S, Mn-Se and MnS-MnSe systems by X ray diffraction after preparation by annealing
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Phase equilibria in Mn-S, Mn-Se and MnS-MnSe systems by X ray diffraction after preparation by annealing
Transport properties of high temperature gases compared with room temperature differences, considering chemical equilibria, heat conduction and atom-free radical forces
Phase equilibria and maximum melting compositions determinations for compound semiconductors by differential thermal analysis compared with vapor and high pressure techniques
Coronal condensation spectra during 4 February 1962 total eclipse, determining abundances, ionization equilibria, electron densities, etc, from Fe and Ca XV lines analysis
Equilibria stability of linear discrete dynamic systems involving elastic, nonconservative, dissipative and gyroscopic forces, using Liapunov-type energy method
Galactic evolutionary models using disklike Riemann ellipsoids with internal motions and gravitational gas equilibria
Co-Ge-Si alloys phase equilibria, evaluating long term stability of junctions between thermoelectric batteries conducting series connectors
Computer program is described for numerical solution of chemical equilibria in complex systems by using nonlinear algebraic equations. Free-energy minimization technique is used.
The equilibrium properties of the control moment gyroscopes of the Skylab are discussed. A rotation law is developed to produce gimbal rates which distribute the angular momentum contributions among the control moment gyroscopes to avoid gimbal stop encounters. The implications for gimbal angle management under various angular momentum situations are described. Conditions were obtained for the existence of equilibria and corresponding stability properties.
For single-phase media, the critical discharge velocity, the sonic velocity, and the pressure pulse propagation velocity can be expressed in the same form by assuming isentropic, equilibria processes. In two-phase mixtures, the same concept is not valid due to the existence of interfacial transports of momentum, heat, and mass. Thus, the three velocities should be treated differently and separately for each particular condition, taking into account the various transport processes involved under that condition. Various attempts are reviewed to predict the critical discharge rate or the propagation velocities by considering slip ratio (momentum change), evaporation (mass and heat transport), flow pattern, etc. Experimental data were compared with predictions based on various theorems. The importance is stressed of the time required to achieve equilibrium as compared with the time available during the process, for example, of passing a pressure pulse.
Review of some recent contributions of X-ray spectroscopy to knowledge about solar active regions and flares. As an example of the importance of X-ray spectroscopy, it is pointed out that, while there are no emission lines from highly ionized silicon in the visible spectrum, the XUV spectrum has emission lines from SiIX through SiXIV. Jordan's (1969) calculations of ionization equilibria for silicon and iron are illustrated by diagrams and discussed. The observation of SiXIV gives evidence for regions having electron temperatures from 5 to 20 million deg. The ability to record the corona against the disk of the sun has enabled Van Speybroeck et al. (1970) to identify many bright diffuse X-ray emitting regions with remnants of old active regions of the type giving rise to unipolar magnetic regions. The physical characteristics of the hot coronal plasma associated with chromospheric flares are outlined on the basis of current observations.
Attention is given to important astronomical observations, the source of atmospheric hydrogen, and the primordial abundance of the elements. The evolution of the earth's atmosphere is discussed together with some physical facts about Venus and Mars. The likelihood that Mars produced an atmosphere in the past is investigated, taking into account present equilibria between the surface and the atmosphere, and the evidence regarding a past atmosphere.
Generalized computer methods are developed for inferring details of the formation of cosmochemical systems. Compositions of ideal gas mixtures existing in equilibrium with multicomponent solid and liquid phases are calculated. A comparison of computed results with experimental data is made for the ternary system MgO-FeO-SiO2. While the ideal-solution approximation is shown to be inaccurate in dealing with the silicate melts, the stable phases and compositions can be accurately calculated in a system where there are only solids and gas. A model system containing the elements H, O, Si, Mg, S, C, Cl, and F is investigated over a range of compositions involving the gas and ten solid phases, to show the power of the technique in dealing with complex gas-solid equilibria. Systems close to cosmic composition are next considered, both with and without iron.
Single phase alpha-kamacite containing more than 3.2 wt % Co and gamma-taenite containing from 30 to 60 wt % Ni from the Apollo 15 soils - 15031, 15071, 15081, 15261, and 15271 - have been examined by metallographic and electron microprobe techniques. In addition two phase alpha + gamma particles from soils 14003, 15071, 15261, and 15271 with Ni and Co contents well outside the meteoritic range have also been examined. Two distinct types of alpha-gamma structure occur, one analogous to 'clear taenite' in ordinary chondrites, and the other analogous to a 'Widmanstaetten' structure in Ni-rich ataxites. The measured Ni gradients in the two-phase particles are very similar to those meteorites having the same structure. However the Co content is much higher than the meteoritic samples, up to 12 wt % in the alpha phase. Approximate phase equilibria data for the Fe-Ni-Co system indicate equilibration of the two-phase particles during cooling to approximately 350 C. Estimates of cooling rates and second-phase growth times indicate that the maximum time necessary for the development of the high-Co two-phase structures is roughly 25 to 100 m.y. These estimates argue for the development of the two-phase structures during formation of the lunar crust, at a depth of 10 to 20 km beneath the moon's surface.
One hundred seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvospinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO2-rich phase were also found. Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The Fe/(Fe + Mg) ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains. Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinz et al. (1973).
Experimental verification of the conclusions of Van Schmus and Koffman (1967) that the equilibration temperatures of ordinary chondrites are roughly the same regardless of classification, and that these temperatures range from 770 to 860 C. The higher average relative equilibrium temperatures found are attributed to improvements in microprobe techniques, and better standards and correction procedures introduced over the last six years. Agreement is expressed with their conclusion that ordinary chondrites embody equilibria achieved within the metamorphic temperature regime and not under igneous temperatures as postulated earlier by Craig (1964) and Mueller (1964).
Data published in the literature and original results of mineralogical and petrological analyses of Apollo 16 rocks and fines indicate that Apollo 16 and Luna 20 sites are dominated by plagioclase-rich rocks with minor olivine and/or pyroxene. Data suggest that shock, brecciation, and recrystallization have largely eliminated primary textures. In general, all data are consistent with derivation from ejecta blankets produced from plagioclase-rich rocks by impacts. The lunar crust is discussed as a product of an early differentiation of the entire moon, and Mg/Fe data for experimental olivine-liquid and olivine-orthopyroxene equilibria are used as constraints to examine compositional data for rocks, glasses, and fragments in the light of specific models for crystal-liquid differentiation.
The hydrostatic and steady laminar hydrodynamic equilibria of spatially varying electromechanical flow structures are investigated. Under certain conditions the relationship between the dielectric height of rise and the applied voltage is found to be double valued. It is found that one of the two equilibrium values is always unstable. This gives rise to the experimentally observed spontaneous rise of the fluid to the top of the structure, once a certain critical voltage is reached. Starting above this critical voltage with the structure completely filled and decreasing the applied voltage toward the critical value results in pinch-in failure at an intermediate point along the structure and trapping of dielectric fluid at the top. The simple mathematical model developed predicts all these phenomena, without recourse to tedious point-by-point surface force equilibrium determination. Experiments are reported which verify the results for the hydrostatic case.