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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Coherence mapping to identify the intermediates of multi-channel dissociative ionization

Identifying the short-lived intermediates and reaction mechanisms of multi-channel radical cation fragmentation processes remains a current and important challenge to understanding and predicting mass spectra. We find that coherent oscillations in the femtosecond time-dependent yields of several product ions following ultrafast strong-field ionization represent spectroscopic signatures that elucidate their mechanism of formation and identify the intermediate(s) they originate from. Experiments on endo-dicyclopentadiene show that vibrational frequencies from various intermediates are mapped onto their resulting products. Aided by ab initio methods, we identify the vibrational modes of both the cleaved and intact molecular ion intermediates. These results confirm stepwise and concerted fragmentation pathways of the dicyclopentadiene ion. This study highlights the power of tracking the femtosecond dynamics of all product ions simultaneously and sheds further light onto one of the fundamental reaction mechanisms in mass spectrometry, the retro-Diels Alder reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2004

A Glass Can Be Half Full: Even in Microgravity

When conducting physical science research in space, the smallest vibration or disturbance can disrupt sensitive experiments. Back in the 1990s we developed an instrument, the Space Acceleration Measurement System (SAMS) that flew on the shuttle to monitor the vibration environment - but it wasn't very flexible. It could only measure vibrations for three users and only at fixed frequency ranges, and it had to be disassembled after each two-week mission to be readied for reuse. Then the International Space Station came along. Our researchers needed a second-generation system, the SAMS-II, which would measure acceleration and vibrations for multiple payloads conducting experiments throughout the life of the station. Measurement requirements were all over the map with a variety of frequencies that needed measuring over a broad dynamic range, so it was essential to develop a robust system that would be flexible enough to accommodate all the particular users. We came up with a concept using the Space Station's Ethernet as the means to talk between multiple remote triaxial sensor systems and a remote controller box. Ultimately, our job was to acquire data within the existing constraints of the station and to quickly and effectively get that information to the scientists. In 1994 we had a $2.1-million budget and a four-year development schedule aimed at achieving these goals. Technical risks were few and primarily resulted from uncertainty of ISS capabilities. At that point, we didn't worry about a thing programmatically; our cup runneth over.

Sutliff, Thomas↗
NASA NTRS1974

An analysis of fracture trace patterns in areas of flat-lying sedimentary rocks for the detection of buried geologic structure

Two study areas in a cratonic platform underlain by flat-lying sedimentary rocks were analyzed to determine if a quantitative relationship exists between fracture trace patterns and their frequency distributions and subsurface structural closures which might contain petroleum. Fracture trace lengths and frequency (number of fracture traces per unit area) were analyzed by trend surface analysis and length frequency distributions also were compared to a standard Gaussian distribution. Composite rose diagrams of fracture traces were analyzed using a multivariate analysis method which grouped or clustered the rose diagrams and their respective areas on the basis of the behavior of the rays of the rose diagram. Analysis indicates that the lengths of fracture traces are log-normally distributed according to the mapping technique used. Fracture trace frequency appeared higher on the flanks of active structures and lower around passive reef structures. Fracture trace log-mean lengths were shorter over several types of structures, perhaps due to increased fracturing and subsequent erosion. Analysis of rose diagrams using a multivariate technique indicated lithology as the primary control for the lower grouping levels. Groupings at higher levels indicated that areas overlying active structures may be isolated from their neighbors by this technique while passive structures showed no differences which could be isolated.

Podwysocki, M. H.↗
NASA NTRS2009

90 GHz and 150 GHz Observations of the Orion M42 Region. A Submillimeter to Radio Analysis

We have used the new 90GHz MUSTANG camera on the Robert C. Green Bank Telescope (GBT)to map the bright Huygens region of the star-forming region M42 with a resolution of 9" and a sensitivity of 2.8 mJy/beam. Ninety GHz is an interesting transition frequency, as MUSTANG detects both the free-free emission characteristic of the H II region created by the Trapezium stars, normally seen at lower frequencies, and thermal dust emission from the background OMCI molecular cloud, normally mapped at higher frequencies. We also present similar data from the 150 GHz GISMO camera taken on the IRAM 30 m telescope. This map has 15" resolution. By combining the MUSTANG data with 1.4, 8. and 31 GHz radio data from the VLA and GBT, we derive a new estimate of the emission measure averaged electron temperature of T(sub e) = 11376+/-1050 K by an original method relating free-free emission intensities at optically thin and optically thick frequencies. Combining Infrared Space Observatory-long wavelength spectrometer (ISO-LWS) data with our data, we derive a new estimate of the dust temperature and spectral emissivity index within the 80" ISO-LWS beam toward Orion KL/BN, T(sub d) = 42+/-3 K and Beta(sub d) = 1.3+/-0.1. We show that both T(sub d) and Beta(sub d) decrease when going from the H II region and excited OMCI interface to the denser UV shielded part OMCI (Orion KL/BN, Orion S). With a model consisting of only free-free and thermal dust emission, we are able to fit data taken at frequencies from 1.5 GHz to 854 GHz (350 micrometers).

Dicker, S. R.↗
NASA NTRS1996

An Acoustic Emission and Acousto-Ultrasonic Analysis of Impact Damaged Composite Pressure Vessels

The research presented herein summarizes the development of acoustic emission (AE) and acousto-ultrasonic (AU) techniques for the nondestructive evaluation of filament wound composite pressure vessels. Vessels fabricated from both graphite and kevlar fibers with an epoxy matrix were examined prior to hydroburst using AU and during hydroburst using AE. A dead weight drop apparatus featuring both blunt and sharp impactor tips was utilized to produce a single known energy 'damage' level in each of the vessels so that the degree to which the effects of impact damage could be measured. The damage levels ranged from barely visible to obvious fiber breakage and delamination. Independent neural network burst pressure prediction models were developed from a sample of each fiber/resin material system. Here, the cumulative AE amplitude distribution data collected from low level proof test (25% of the expected burst for undamaged vessels) were used to measure the effects of the impact on the residual burst pressure of the vessels. The results of the AE/neural network model for the inert propellant filled graphite/epoxy vessels 'IM7/3501-6, IM7/977-2 and IM7/8553-45' demonstrated that burst pressures can be predicted from low level AE proof test data, yielding an average error of 5.0%. The trained network for the IM7/977-2 class vessels was also able to predict the expected burst pressure of taller vessels (three times longer hoop region length) constructed of the same material and using the same manufacturing technique, with an average error of 4.9%. To a lesser extent, the burst pressure prediction models could also measure the effects of impact damage to the kevlar/epoxy 'Kevlar 49/ DPL862' vessels. Here though, due to the higher attenuation of the material, an insufficient amount of AE amplitude information was collected to generate robust network models. Although, the worst case trial errors were less than 6%, when additional blind predictions were attempted, errors as high as 50% were produced. An acousto-ultrasonic robotic evaluation system (AURES) was developed for mapping the effects of damage on filament wound pressure vessels prior to hydroproof testing. The AURES injects a single broadband ultrasonic pulse into each vessel at preprogrammed positions and records the effects of the interaction of that pulse on the material volume with a broadband receiver. A stress wave factor in the form of the energy associated with the 750 to 1000 kHz and 1000 to 1250 kHz frequency bands were used to map the potential failure sites for each vessel. The energy map associated with the graphite/epoxy vessels was found to decrease in the region of the impact damage. The kevlar vessels showed the opposite trend, with the energy values increasing around the damage/failure sites.

Walker, James L.↗
NASA NTRS2012

The Atacama Cosmology Telescope: Data Characterization and Map Making

We present a description of the data reduction and mapmaking pipeline used for the 2008 observing season of the Atacama Cosmology Telescope (ACT). The data presented here at 148 GHz represent 12% or the 90 TB collected by ACT from 2007 to 2010. In 2008 we observed for 136 days, producing a total of 142h of data (11 TB for the 148 GHz band only), with a daily average of 10.5 h of observation. From these, 108.5 h were devoted to 850 sq deg stripe (11.2 h by 9 deg.1) centered on a declination of -52 deg.7, while 175 h were devoted to a 280 square deg stripe (4.5 h by 4 deg.8) centered at the celestial equator. We discuss sources of statistical and systematic noise, calibration, telescope pointing and data selection. Out of 1260 survey hours and 1024 detectors per array, 816 h and 593 effective detectors remain after data selection for this frequency band, yielding a 38 % survey efficiency. The total sensitivity in 2008, determined from the noise level between 5 Hz and 20 Hz in the time-ordered data stream (TOD), is 32 muK square root of s in CMB units. Atmospheric brightness fluctuations constitute the main contaminant in the data and dominate the detector and noise covariance at low frequencies in the TOD. The maps were made by solving the lease squares problem using the Preconditioned Conjugate Gradient method, incorporating the details of the detector and noise correlations. Cross-correlation with WMAP sky maps as well as analysis from simulations reveal the our maps are unbiased at l > 300. This paper accompanies the public release of the 148 GHz southern stripe maps from 2008. The techniques described here will be applied to future maps and data releases.

Duenner, Rolando↗
NASA NTRS1996

(abstract) Topographic Signatures in Geology

Topographic information is required for many Earth Science investigations. For example, topography is an important element in regional and global geomorphic studies because it reflects the interplay between the climate-driven processes of erosion and the tectonic processes of uplift. A number of techniques have been developed to analyze digital topographic data, including Fourier texture analysis. A Fourier transform of the topography of an area allows the spatial frequency content of the topography to be analyzed. Band-pass filtering of the transform produces images representing the amplitude of different spatial wavelengths. These are then used in a multi-band classification to map units based on their spatial frequency content. The results using a radar image instead of digital topography showed good correspondence to a geologic map, however brightness variations in the image unrelated to topography caused errors. An additional benefit to the use of Fourier band-pass images for the classification is that the textural signatures of the units are quantative measures of the spatial characteristics of the units that may be used to map similar units in similar environments.

topography geology texture Fourier analysis↗
NASA NTRSDate not supplied

Improvements to the Simulated CubeSpark Satellite Constellation and Their Effects on Lightning Geolocation Accuracy from Orbit

The CubeSpark mission concept is being developed as a constellation of up to six satellites in low-Earth orbit (LEO) for high resolution 3D lightning mapping using optical and radio frequency (RF) sensors. Individual lightning VHF signals are simulated from Earth’s atmosphere through the ionosphere to each satellite, using their arrival times to reconstruct source locations. Here we present recent updates to these simulations based on improved ionospheric modeling, with a focus on the expected three-dimensional resolution. These studies include testing from the equator up to high latitudes, with varying vertical total electron content (vTEC), and using between one and six orbiting stations. In addition to the more robust ionosphere model, the constellation formation has also been updated to reduce its resulting errors and increase the effective range of VHF geolocation from space. The goals of CubeSpark include mapping thundercloud charge structure as well as lightning channel lengths relevant to climatology, meteorology, and more. These applications require location uncertainty less than 1-2 km in each dimension. This improved algorithm shows sufficient resolution up to high latitudes, including significantly larger areas having 3D resolution less than 1 km. Analysis of the distributions of biases in simulated arrival times has also revealed the unexpected relationship between the shape of those distributions and the resulting uncertainties. This work helps to refine our understanding of the sources of error in lightning geolocation and reinforces the potential for post-processing improvements in this and other similar systems.

Lightning↗
NASA NTRS1992

Mapping the sky with the COBE differential microwave radiometers

The Differential Microwave Radiometers (DMR) instrument on COBE is designed to determine the anisotropy of the Cosmic Microwave Background by providing all-sky maps of the diffuse sky brightness at microwave frequencies. The principal intent of this lecture is to show how these maps are generated from differential measurements.

Janssen, M. A.↗
NASA NTRS1990

Martian crater counts on Elysium Mons

Without returned samples from the Martian surface, relative age chronologies and stratigraphic relationships provide the best information for determining the ages of geomorphic features and surface regions. Crater-size frequency distributions of six recently mapped geological units of Elysium Mons were measured to establish their relative ages. Most of the craters on Elysium Mons and the adjacent plains units are between 500 and 1000 meters in diameter. However, only craters 1 km in diameter or larger were used because of inadequate spatial resolution of some of the Viking images and to reduce probability of counting secondary craters. The six geologic units include all of the Elysium Mons construct and a portion of the plains units west of the volcano. The surface area of the units studied is approximately 128,000 sq km. Four of the geologic units were used to create crater distribution curves. There are no craters larger than 1 km within the Elysium Mons caldera. Craters that lacked raised rims, were irregularly shaped, or were arranged in a linear pattern were assumed to be endogenic in origin and not counted. A crater frequency distribution analysis is presented.

Mcbride, Kathleen↗
DOE OSTI2021

Development of in-use engine speed/torque heat maps across multiple heavy-duty commercial vehicle vocations

The U.S. Department of Energy (DOE) established the SuperTruck program with the goal of achieving brake thermal efficiency (BTE) greater than or equal to 55% as demonstrated in an operational heavy-duty (HD) diesel engine at a 65-miles-per-hour (mph) cruise point. Beyond the line-haul application, HD engines operate in a wide range of speed and torque conditions that are unlikely to yield the same efficiency under real-world operation. Thereby, the in-use engine heat maps described in this paper are a valuable tool to illustrate whether the engine-efficiency “sweet spot” matches the most frequent operating conditions. In this study, NREL developed engine heat maps to quantify the important operating points for various vocations using our Fleet DNA database of commercial fleet vehicle operations data. These heat maps clearly show that high-frequency operating points vary significantly according to vehicle vocation, while only a few of them match the sweet spot. Beyond the illustration, engine in-use heat maps can also be leveraged to build up reduced-order engine-efficiency models, needed by many rapid powertrain simulations. As case studies, nine reduced-order models – including line-haul truck, transfer truck, transit bus, transit bus with compressed natural gas (CNG) engine, drayage, refuse pickup, local delivery, utility truck, and school bus with CNG engine – using a trust-region reflective algorithm to fit the on-road data extracted based on the engine in-use heat maps.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1991

Lightning mapping system

A Lightning Detection and Ranging (LDAR) System is being implemented at KSC in Florida. The first operational use is expected in the late summer of 1991. The system is designed to map the location of in-cloud and cloud-to-ground lightning based on the time of arrival (TOA) of electromagnetic radiation. The system detects very high frequency (VHF) radiation and designed to map the volumetric extent of lightning. The system implements two independent antenna arrays to provide a fast data quality check, as necessary for a real-time warning system. The system performance goals and a comparison with a similar system implemented in the mid-1970's is made.

Lennon, C.↗
NASA NTRS2020

Small Aperture Telescopes for the Simons Observatory

The Simons Observatory (SO) is an upcoming cosmic microwave background(CMB) experiment located on Cerro Toco, Chile, that will map the microwave sky in temperature and polarization in six frequency bands spanning 27 to 285 GHz. SO will consist of one 6-meter Large Aperture Telescope (LAT) fielding∼30,000 detectors and an array of three 0.42-meter Small Aperture Telescopes (SATs) fielding an additional 30,000 detectors. This synergy will allow for the extremely sensitive characterization of the CMB over an-gular scales ranging from an arcmin to tens of degrees, enabling a wide range of scientific output. Here we focus on the SATs targeting degree angular scales with successive dichroic instruments observing at Mid-Frequency (MF: 93/145 GHz), Ultra-High-Frequency (UHF:225/285 GHz), and Low-Frequency (LF: 27/39 GHz). The three SATs will be able to map∼10% of the sky to a noise level of∼2 μK-arcmin when combining 93 and 145 GHz. The multiple frequency bands will allow the CMB to be separated from galactic foregrounds (primarily synchrotron and dust), with the primary science goal of characterizing the primordial tensor-to-scalar ratio, r, at a target level ofσ(r)≈0.003.

Small aperature telescope↗
NASA NTRS1999

Assessment of Global TEC Mapping Using a Three-Dimensional Electron Density Model

Dual-frequency transmissions from the Global Positioning System satellites can be used to measure and map ionospheric total electron content (TEC) on global scales. Using data exclusively from ground-based GPS networks, global ionosphere mapping has been successfully applied using either two or three dimensional techniques.

Global↗
DOE OSTI2025

Evidence for Ga clusters in β-Ga 2 O 3 from Raman spectroscopy and density functional theory

Monoclinic gallium oxide (β-Ga 2 O 3 ) single crystals have a Raman mode at ∼250 cm −1 that is strongly correlated with free-electron density. Prior work attributed this peak to an electronic excitation of a shallow donor impurity band. However, heavily n-type thin films grown by metalorganic chemical vapor deposition or molecular beam epitaxy do not have the peak. In the present work, an alternate model is proposed: the 250 cm −1 Raman peak arises from Ga clusters, defined as two or more Ga atoms that form Ga–Ga bonds. Raman mapping reveals variations in the frequency that are consistent with a distribution of cluster sizes. The intensity of the peak decreases as the temperature is raised, attributed to melting of the Ga clusters. First-principles calculations indicate that the 250 cm −1 mode is due to Ga–Ga bond-stretching vibrations. As the Fermi energy is raised, the formation of Ga–Ga dimers becomes energetically favorable, explaining the correlation between n-type conductivity and the appearance of the Raman peak.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Integrated Modeling Driven Evaluation of Opportunities for Climate‐Resilient Perennial Biomass Crop Plantings in Flood‐Prone Agricultural Landscapes

Adapting to future climate change in flood-prone landscapes will require climate-resilient agricultural systems. Planting perennial crops, like switchgrass and willow, along river corridors can mitigate future flooding while supporting bioenergy markets. We developed an integrated assessment linking climate, hydrologic, and inundation model results to assess future flood risk to river-adjacent agricultural lands in the Mid-Atlantic Region (MAR) and explore this opportunity. We produced ensemble streamflow projections for every MAR stream using a hydrologic model driven by a suite of downscaled and bias-corrected Coupled Model Intercomparison Project Phase 6 climate projections. We then conducted high-resolution inundation mapping based on projected flood frequencies for baseline and future periods. Results show that in the near-term future, at least two-thirds of the streams will experience 100-year floods more severe than the baseline 200-year floods. Riparian zones are projected to face a median rise of inundation by 9.5%–24.1%. Results show that there is an opportunity to mitigate flooding in over half of MAR's counties with the quantities of switchgrass and willow plantings anticipated for mature bioenergy markets, even under the most extreme (200-year) flood events. Our integrated modeling framework can guide similar regions to evaluate opportunities for flood-resilient agricultural systems under climate change.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2023

Machine learning-based inversion for acoustic impedance with large synthetic training data: Workflow and data characterization

Where wells are sparse or training data are difficult to label with high-quality wireline-derived impedance logs, machine learning (ML)-based inversion of acoustic impedance typically depends on small training data sets, leading to biased prediction. We have advanced a novel workflow that applies large synthetic seismic training data to reduce facies-related bias. Using a geologically realistic model as the truth model, we randomly select sparse seed wells to perform sequential Gaussian simulation (SGS) for impedance models of the same geometry and simulate facies variability. We implement random forest regression on 30 features extracted from the synthetic volume. We observe that more seed wells tend to reduce facies-induced bias by sampling more types of facies, resulting in a better prediction. We then focus on the responses of SGS models to facies changes, the number of seed wells necessary for a useful synthetic model, and how much a synthetic model can help ML-based inversion. Here, we observe that the SGS synthetic training model outperforms well-direct training in general. For modeled clastic shore-zone systems in Miocene Gulf of Mexico, two or more seed wells are necessary for a significant reduction of root-mean-square error and outliners, and improvement of facies imaging. In a field-data test, we apply a similar workflow to quantitatively predict acoustic impedance, which is then converted to a sand-volume map at a high-frequency sequence (10–100 m), revealing detailed facies and sandstone patterns. Such results are valuable in many geologic and engineering applications, such as hydrocarbon and CO 2 reservoir prospecting, reserve estimation, simulation, etc.

3D seismic↗