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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Modernization of Insulative Reusable Thermal Protection Systems (IRTPS)

Insulative thermal protection systems, such as Flexible Reusable Surface Insulation blankets and High Temperature Reusable Surface Insulation tiles, were developed for the Shuttle Orbiter to enable reuse of the vehicle for low-earth orbit missions. Since reusability is essential to many new industry launch and space vehicles, Shuttle-derived thermal protection materials (TPMs) are being sought for their flight proven performance. Alumina Enhanced Thermal Barrier (AETB) is the state-of-the-art tile material that was developed in the 90’s. AETB along with associated coatings, reaction cured glass (RCG) and Toughened Unipiece Fibrous Insulation (TUFI), are currently made by NASA using heritage raw materials derived from lifetime purchases. Finding viable replacements for raw materials that have changed in nature or are obsolete is important for continuation of these TPMs. In some cases, the use of modern raw materials has been shown to yield tile with reduced performance, most notably in mechanical properties. ​ In this work, the production of AETB will be discussed to better understand the process-structure-property relationships and for allowing use of these modern alternatives. A small-scale tile casting system was developed for rapid and efficient exploration of the manufacturing variables such raw material selection and pre-processing, casting process parameters, and billet firing protocols. An optical transmission defect characterization technique was implemented to correlate process variables to structure. Comparisons between TUFI/RCG coated AETB derived from heritage and modern raw materials will be shown including AHF arc jet test results completed under a collaboration with Stratolaunch.

thermal protection materials↗

Thermal protective visor for entering high temperature areas

Chamber observer suit visor protects the eyes and ears of the wearer while he is performing rescue operations during a fire. The visor is a simple curved sandwich of selected glass plates, gold coated polyester plastic film, and a dead air space, all mounted in an aluminum frame.

Burgett, F. A.↗

Preliminary evaluation of Glass Resin materials for solar cell cover use

The glass resins were deposited by several techniques on 200 micron thick cells and on 50 microns thick wafers. The covered cells were exposed to ultraviolet light in vacuum to an intensity of 10 UV energy-equivalent solar constants at air mass zero for 728 hr. The exposure was followed by a single long thermal cycle from ambient temperature to -150 C. Visual inspection of the samples indicated that all samples had darkened to varying degrees. The loss in short-circuit current was found to range from 8 to 24%, depending on the resin formulation. In another test over 40 glass resin-coated silicon wafers withstood 15 thermal cycles from 100 to-196 C in one or more of the thicknesses tested. Several of the resin-coated wafers were tested at 65 C and 90% relative humidity for 170 hr. No change in physical appearance was detected.

Marsik, S. J.↗

High-efficiency module and array research

An outline is presented giving module high efficiency research activities and module technologies contributing to high efficiency. Some factors given on high efficiency are high cell packing factors, low optical losses, low electrical mismatch losses and low operating temperatures. Factors given which are associated with reliability of modules are high efficiency cells, narrow module borders, antisoiling coatings, and antireflection coatings on glass-air interfaces.

Ross, R. G., Jr.↗

Petrology and geochemistry of lunar dimict breccia 61015

The results of a petrological and geochemical study of the dimict breccia 61015 at the Apollo 16 site are presented and discussed. The breccia consists predominantly of granulated anorthosite and impact melt rock of very high aluminum-basalt composition. It probably formed in the floor of an expanding crater cavity when impact melt generated within the cavity was injected into underlying anorthositic bedrock and solidified rapidly, the anorthosite and melt rock being fragmented by deformation in the later stages of the impact. A possible source crater for the breccia is identified. The breccia has been affected by at least one recent small impact, which produced internal shock-induced melting of the breccia and injected and coated the rock with externally derived melts. The TiO2 content of the coating and vein glasses establish that they cannot be melted soils; their composition requires a mafic, low-TiO2 protolith component.

James, O. B.↗

Effect of thermal cycling on stress in metallic films on ceramic substrates

The hydrogen maser is the most stable frequency standard currently available for averaging intervals of hours to weeks. A major contributor to maser frequency variations is the maser's microwave resonant cavity: by means of the cavity pulling effect, a change in the cavity's resonance frequency produces a proportional change in the maser's output frequency. To minimize variations in the cavity's dimensions, and thus in its resonance frequency, maser cavities are often constructed of a low-expansivity glass-ceramic material coated on its surface with a conductive metallic film. It was previously shown that silver films like those used in SAO maser cavities develop tensile stress when cooled to room temperature after being fired onto the cavity, and that the stress in such films relaxes with time at a rate proportional to the level of stress. Stress relaxation in maser cavity coatings can alter the shape, and hence the resonance frequency, of the cavity, resulting in a slow variation in the maser's output frequency. The possibility was investigated of reversing the initial tensile stress by precooling the coated cavity material. It was hypothesized that cooling the material well below its normal working temperature and then warming it to its normal temperature would result in a lower tensile stress or even a compressive stress. Under such a condition stress relaxation, and thus any consequent frequency drifts, might be reduced or reversed.

Mattison, Edward M.↗

NASA/GSFC reliability evaluation of high temperature fiber optic cables

A high temperature (200 C rating) fiber-optic cable of fluorocarbon, silica-based glass, and polyimide coating, 100-micron core was evaluated for Goddard Space Flight Center applications. Testing was performed to evaluate attenuation characteristics of the cables during environmental stresses and exposure to Co-60 gamma radiation. The cables passed environmental tests, but after irradiation failed the established delta limit of 3 dB at 10 krads for a wavelength of 850 nm and 100 krads for a wavelength of 1300 nm.

Sharma, A. K.↗

The Long Duration Exposure Facility (LDEF) annotated bibliography

A major objective of the Space Act of 1958 which led to the establishment of the National Aeronautics and Space Administration (NASA) was the dissemination of science and technology. Today, under NASA administrator Daniel Goldin and the White House, there is a reemphasis on the dissemination and transfer of NASA science and technology to U.S. industry: both aerospace and non aerospace. The goal of this transfer of science and technology is to aid U.S. industries, making them more competitive in the global economy. After 69 months in space, LDEF provided new and important information on the space environment and how this hostile environment impacts spacecraft materials and systems. The space environment investigated by the LDEF researchers included: ionizing radiation, ultraviolet radiation, meteoroid and debris, atomic oxygen, thermal cycling, vacuum, microgravity, induced contamination and various synergistic effects. The materials used as part of LDEF and its experiments include polymers, metals, glass, paints and coatings. Fiber optic, mechanical, electrical, and optical systems were also used on LDEF. As part of the effort to disseminate and transfer LDEF science and technology, an annotated bibliographic database is being developed. This bibliography will be available electronically, as well as in hard copy. All LDEF domestic and foreign publications in the open literature, including scientific journals, the NASA LDEF Symposia volumes, books, technical reports and unrestricted contractor reports will be included in this database. The hard copy, as well as the electronic database, will be categorized by section in the scientific and technical discipline.

Levine, Arlene S.↗

A Roof for the Lions' House

Fans of the National Football League s Detroit Lions don't worry about game day weather. Their magnificent new Pontiac Stadium has a domed, air-supported, fabric roof that admits light but protects the playing field and patrons from the elements. The 80,000-seat Silverdome is the world s largest fabric-covered structure-and aerospace technology played an important part in its construction. The key to economical construction of the Silverdome--and many other types of buildings--is a spinoff of fiber glass Beta yarn coated with Teflon TFE fluorocarbon resin. The big advance it offers is permanency.The team of DuPont, Chemical Fabrics and Birdair have collaborated on a number of fabric structures. Some are supported by air pressure, others by cables alone. Most of the structures are in the recreational category. With conventional construction costs still on the upswing, you're likely to see a great many more permanent facilities enclosed by the aerospace spinoff fabric.

Source record↗

A Roof for the Lion's House

Fans of the National Football League's Detroit Lions don't worry about gameday weather. Their magnificent new Pontiac Stadium has a domed, air-supported, fabric roof that admits light but protects the playing field and patrons from the elements. The 80,000-seat "Silverdome" is the world's largest fabric-covered structure-and aerospace technology played an important part in its construction. The key to economical construction of the Silverdome-and many other types of buildings-is a spinoff of fiber glass Beta yarn coated with Teflon TFE fluorocarbon resin. The big advance it offers is permanency. Fabric structures-tents, for example have been around since the earliest years of human civilization. But their coverings-hides, canvas and more recently plastics-were considered temporary; though tough, these fabrics were subject to weather deterioration. Teflon TFE-coated Beta Fiberglas is virtually impervious to the effects of weather and sunlight and it won't stretch, shrink, mildew or rot, thus has exceptional longevity; it is also very strong, lightweight, flame resistant and requires no periodic cleaning, because dirt will not stick to the surface of Teflon TFE. And to top all that, it costs only 30 to 40 percent as much as conventional roofing.

Source record↗

Using Indium Tin Oxide To Mitigate Dust on Viewing Ports

NASA plans to use a number of onboard viewing ports to measure lunar regolith in situ and to monitor robotic and human activities on the lunar or Martian surface. Because of the size and abundance of dust particles on these bodies, the potential for dust to occlude viewing ports and windows is high enough to threaten system lifetime and reliability, especially when activities rely on relaying video to either a habitat module or controllers on Earth. This project uses a technology being developed by KSC's Electrostatics and Surface Physics Laboratory to remove dust from windowlike surfaces. The technology applies an alternating electric potential to interlaced electrodes. In this application, we use indium tin oxide (ITO) to create various electrode patterns in order to determine the most reliable pattern for dust removal. This technology has application to systems where optical clarity is important. Specifically, this project considers the in situ resource utilization (ISRU) application of a viewing port for Raman spectroscopy, where the electrode pattern on glass would be coated with a scratch-resistant sapphire film (Al2O3).

Source record↗

Dusty Environment Classification and Testing: Dust Mitigation Slide Cleaning Material Study

During the Apollo missions many mechanisms, equipment, and surfaces were contaminated by lunar dust and often negatively affected. The methods used to clear these devices of dust proved ineffective, which led to premature failure in some cases. Systems being designed for upcoming missions to the Moon will need to address the performance degradation risk of dust contamination. Surfaces at risk include thermal control surfaces, solar cells, camera and sensor optics, seals, metal joints and tools, and space suit assemblies. To improve state of the art dust mitigation approaches, the dust mitigation team at NASA Glenn Re-search Center (GRC) explored the effects imposed on substrates during cleaning activities in the presence of lunar dust. The Uniform Dust Deposition System (UDDS) was used to conduct a study of various cleaning techniques on different substrates. Test substrates and cleaning media were selected to represent a wide range of structural and functional materials. Substrates included orthofabric, thermal radiator coating, aluminum, quartz glass, silicone rubber, aluminized Mylar, and FEP. Cleaning materials included cloth wipes, tapes, a brush, and a pliable cleaner concept. Cleaning material / substrate pairs were rated on cleaning efficiency, substrate damage, cleaning material longevity, and ease of use. The best performing cleaning method varied based on application.

dust mitigation↗

Dusty Environment Classification and Testing: Dust Mitigation Slide Wipes & Tapes

During the Apollo missions many mechanisms, equipment, and surfaces were contaminated by lunar dust and often negatively affected. The methods used to clear these devices of dust proved ineffective, which led to premature failure in some cases. Systems being designed for upcoming missions to the Moon will need to address the performance degradation risk of dust contamination. Surfaces at risk include thermal control surfaces, solar cells, camera and sensor optics, seals, metal joints and tools, and space suit assemblies. To improve state of the art dust mitigation approaches, the dust mitigation team at NASA Glenn Research Center (GRC) explored the effects imposed on substrates during cleaning activities in the presence of lunar dust. The Uniform Dust Deposition System (UDDS) was used to conduct a study of various cleaning techniques on different substrates. Test substrates and cleaning media were selected to represent a wide range of structural and functional materials. Substrates included orthofabric, thermal radiator coating, aluminum, quartz glass, silicone rubber, aluminized Mylar, and FEP. Cleaning materials included cloth wipes, tapes, a brush, and a pliable cleaner concept. Cleaning material / substrate pairs were rated on cleaning efficiency, substrate damage, cleaning material longevity, and ease of use. The best performing cleaning method varied based on application.

lunar simulant↗

An LED Approach for Measuring the Photocatalytic Breakdown of Crystal Violet Dye

A simple technique to assess the reactivity of photocatalytic coatings sprayed onto transmissive glass surfaces was developed. This new method uses ultraviolet (UV) gallium nitride (GaN) light-emitting diodes (LEDs) to drive a photocatalytic reaction (the photocatalytic breakdown of a UV-resistant dye applied to a surface coated with the semiconductor titanium dioxide); and then a combination of a stabilized white light LED and a spectrometer to track the dye degradation as a function of time. Simple, standardized evaluation techniques that assess photocatalytic materials over a variety of environmental conditions, including illumination level, are not generally available and are greatly needed prior to in situ application of photocatalytic technologies. To date, much research pertaining to this aspect of photocatalysis has been limited and has focused primarily on laboratory experiments using mercury lamps. Mercury lamp illumination levels are difficult to control over large ranges and are temporally modulated by line power, limiting their use in helping to understand and predict how photocatalytic materials will behave in natural environmental settings and conditions. The methodology described here, using steady-state LEDs and time series spectroradiometric techniques, is a novel approach to explore the effect of UV light on the photocatalytic degradation of a UV resistant dye (crystal violet). GaN UV LED arrays, centered around 365 nm with an adjustable DC power supply, are used to create a small, spatially uniform light field where the steady state light level can be varied over three to four orders of magnitude. For this study, a set of glass microscope slides was custom coated with a thinly sprayed layer of photocatalytic titanium dioxide. Crystal violet was then applied to these titanium-dioxide coated slides and to uncoated control slides. The slides were then illuminated at various light levels from the dye side of the slide by the UV LED array. To monitor dye degradation on the slides over time, a temperature-stabilized white light LED was used to illuminate the opposite side of the slides. As the dye degraded, the amount of light from the white light LED transmitted through the slide was monitored with a spectrometer and subsequently analyzed to determine and compare the rate of dye degradation for photocatalytically coated versus uncoated slide surfaces. The long-term stability of the spectrometer/white light LED combination, which required only a single reference spectra to be taken for a time series sequence of several hours, enabled accurate measurements of transmitted light over time. Time series transmission curves were generated and results demonstrated that over time the transmission increased much more rapidly on the coated slides than on the control slides. This experimental configuration and methodology for photocatalytic activity measurement minimizes many external variable effects and allows low light level studies to be performed. This study also compares the advantages of this novel LED light source design to traditional mercury lamp systems and non-LED lamp approaches that have conventionally been used. The methodology and experimental design research summarized in this abstract is partly funded by the Department of Homeland Security, Science and Technology Directorate, and by the NASA Stennis Space Center Innovative Partnerships Program.

Ryan, Robert E.↗

Morphology of gold and copper ion-plated coatings

Copper and gold films (0.2 to 2 microns thick) were ion plated onto polished 304-stainless-steel, glass, mica surfaces. These coatings were examined by SEM for defects in their morphological growth. Three types of defects were distinguished: nodular growth, abnormal or runaway growth, and spits. The cause for each type of defect was investigated. Nodular growth is due to inherent substrate microdefects, abnormal or runaway growth is due to external surface inclusions, and spits are due to nonuniform evaporation (ejection of droplets). All these defects induce stresses and produce porosity in the coatings and thus weaken their mechanical properties. During surface rubbing, large nodules are pulled out, leaving vacancies in the coatings.

Spalvins, T.↗

Effects of long term space environment exposure on optical substrates and coatings (S0050-2)

The experiment consisted of Fused Silica and Ultra Low Expansion (ULE(tm)) glass samples which were either uncoated or had high reflectance silver, antireflectance, or solar rejection coatings. A set of duplicate control samples was manufactured and stored in a controlled environment for comparison purposes. We will present spectral curves for the glass and coatings which define preflight, postflight, and post-cleaning performance. Data on the analysis of the contaminate deposited on the samples and stress measurements in the glass will also be presented. Some results of particular interest are that the contaminate composition varied between different types of samples, and no darkening of the ULE(tm) glass occurred due to the radiation exposure.

Vallimont, John↗

Advanced Al Mirrors Protected with LiF Overcoat to Realize Stable Mirror Coatings for Astronomical Telescopes

Pure Aluminum (Al) exhibits intrinsic high reflectance over the proposed Large UV/Optical/IR (LUVOIR) Surveyor observatory target spectral range (90-2500 nm). However, Al coatings have to be protected from oxygen exposure in order to prevent the formation of the naturally occurring Al2O3 oxide layer, which limit performance for use only above 160 nm. Aluminum protected with fluorides such as LiF or MgF2 have been the most commonly used solutions. But below 102 nm and down to 90 nm, no transparent material is available to protect Al and coating mirror reflectance stays below 40%. But even above 102 nm, the reflectance of protected Al is limited by the residual absorption of the fluoride overcoats. Hence, this paper will report on recent advances in producing enhanced Al-based mirror coatings with the highest possible far-ultraviolet (FUV) reflectance, while exhibiting a more stable LiF protection layer. The process starts with a bare optically smooth glass substrate that is coated with Al in an ultra-high vacuum chamber by using the physical vapor deposition (PVD) process, which has been shown to provide the best aluminum thin-films when compared to other approaches. The next step is done by in-situ exposure of the freshly made Al film to a reactive XeF2 gas that will grant a thin AlF3 overcoat (2-3 nm) to the Al film that prevents further oxidation. This fluorinated Al film is then coated with a final layer of a LiF metal-fluoride overcoat. The coating process is finalized with a second exposure to the XeF2 precursor gas. The preparation of these mirror coatings will be studied and analyzed as a function of the XeF2 exposure time and deposition rate of the LiF layer during the PVD process. This paper will present and discuss characterization of a number of Al+XeLiF witness coupons produced with this reactive PVD (rPVD) process. These studies include characterization of specular reflectance in the 90-2500 nm spectral range, micro-roughness, long-term stability, as well as polarization characteristics in the visible and near-infrared spectral regions. These studies have been performed in order to demonstrate the improved reflectance performance, longer durability, and less hygroscopic nature of protected Al mirrors produced with the rPVD process (through exposure to XeF2) and in comparison with the standard PVD process.

optics↗