Spatially resolved gas-phase metallicity in FIRE-2 dwarfs: late-time evolution of metallicity relations in simulations with feedback and mergers
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In Titan's atmosphere, composed mainly of N2 (95-98%) and CH4 (2-5%), a complex chemistry occurs at low temperature, and leads to the production of heavy organic molecules and subsequently solid aerosols. Here, we used the Titan Haze Simulation (THS) experiment, an experimental setup developed at the NASA Ames COSmIC simulation facility to study Titan's atmospheric chemistry at low temperature. In the THS, the chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas is cooled to Titan-like temperature ( approximately 150K) before inducing the chemistry by plasma, and remains at low temperature in the plasma discharge (approximately 200K). Different N2-CH4-based gas mixtures can be injected in the plasma, with or without the addition of heavier precursors present as trace elements on Titan, in order to monitor the evolution of the chemical growth. Both the gas- and solid phase products resulting from the plasma-induced chemistry can be monitored and analyzed using a combination of complementary in situ and ex situ diagnostics. A recent mass spectrometry[1] study of the gas phase has demonstrated that the THS is a unique tool to probe the first and intermediate steps of Titan's atmospheric chemistry at Titan-like temperature. In particular, the mass spectra obtained in a N2-CH4-C2H2-C6H6 mixture are relevant for comparison to Cassini's CAPS-IBS instrument. The results of a complementary study of the solid phase are consistent with the chemical growth evolution observed in the gas phase. Grains and aggregates form in the gas phase and can be jet deposited on various substrates for ex situ analysis. Scanning Electron Microscopy images show that more complex mixtures produce larger aggregates. A mass spectrometry analysis of the solid phase has detected the presence of aminoacetonitrile, a precursor of glycine, in the THS aerosols. X-ray Absorption Near Edge Structure (XANES) measurements also show the presence of imine and nitrile functional groups, showing evidence of nitrogen chemistry. These complementary studies show the high potential of THS to better understand Titan's chemistry and the origin of aerosol formation.
From far-ultraviolet (FUV) spectra of B stars taken with the Hopkins Ultraviolet Telescope (HUT) and Voyager space observations, we determine the far-ultraviolet extinction by Galactic dust and hydrogen absorption in the local spiral-arm clouds towards HD 25443 (B0.5 III), HD 37903 (B1.5 V), and HD 200775 (B3 Ve). We find that the (n (H)) = 1.3 cu cm and number fraction (f = 0.31) of H atoms in molecular hydrogen relative to the total hydrogen indicates a mostly diffuse medium toward HD 25443. We also determine f = 0.56 for the gas in the photodissociation region (PDR) in front of HD 37903 and f approximately equals 0.36 for the HD 200775 PDR. The inferred ratios of N(H2)/I(CO) = 2.4 to 2.8 x 10(exp 20)/K(km/s)/sq cm for cool gas in dark clouds agree with previous canonical estimates of N(H2)/I(CO) = 2 to 3 x 10(exp 20)/K(km/s)/sq cm and support the use of the ratio for determining masses of molecular clouds. We find that the shape and strength of the HD 25443 FUV extinction is the same as a diffuse-medium mean extinction (R(sub nu) = 2.95) extrapolated from mid-UV wavelengths (normal). The HD 37903 FUV extinction through a bright H2 photodissociation region is higher than a mean FUV extinction(R(sub nu) = 4.11), as is the HD 200775 extinction. Another star from the literature rho Oph, probes the dense medium and exhibits an FUV extinction of normal mean strength (R(sub nu) = 4.55) but steeper shape. The normal FUV -extinction of HD 25443 implies that the small FUV-extinction dust in the diffuse medium forms in p art from larger grains as the grains shatter under shocks. The normal strength of the rho Oph FUV-extinction indicates that the minute dust condenses onto or coagulates into larger grains in the dense medium. The high extinction deviation of the HD 37903 PDR (and HD 200775 PDR) shows that FUV radiation from hot stars with T(sub eff) approximately equals 20,000 to 23,000 K in PDRs can evaporate some of the FUV-extinction dust from grain surfaces. In contrast, previously measured extinctions in Galactic H(+) (H II) regions shows that FUV radiation at T(sub eff) greater than 25,000 K can destroy some of the dust in H(+) regions. Thus, some of the FUV-extinction dust is highly volatile. We find that the dust carrier of the variable FUV-extinction is correlated (r = 0.99) with the mid-IR (12 micrometers) radiation from hydrocarbon dust. The volatile FUV-extinction component could thus be due to minute hydrocarbon dust particles or macromolecules, probably PAHs, which are known to condense onto larger grains in the dense medium. Larger grains compsed of PAHs clustered into a solid could thus produce the steep FUV extinction of the rho Oph dense medium. After exposure to FUV photons wihtin approximately 1 pc of HD 37903, PAHs with about 30 carbon atoms would evaporate off the larger grains, increasing gaseous PAH abundance by approximately 14%. Also, after receiving shocks in the diffuse medium toward HD 25443, the larger hydrocarbon grains would shatter into PAH molecules. In summary, as the Galactic medium cycles betwee n the diffuse and dense medium, hydrocarbon dust cycles into and out of larger grains under the influence of shocks, radiation, and condensation.
Gas hydrates are implicated in the geochemical evolution of both Mars and Europa [1- 3]. Most models developed for gas hydrate chemistry are based on the statistical thermodynamic model of van der Waals and Platteeuw [4] with subsequent modifications [5-8]. None of these models are, however, state-of-the-art with respect to gas hydrate/electrolyte interactions, which is particularly important for planetary applications where solution chemistry may be very different from terrestrial seawater. The objectives of this work were to add gas (carbon dioxide and methane) hydrate chemistries into an electrolyte model parameterized for low temperatures and high pressures (the FREZCHEM model) and use the model to examine controls on gas hydrate chemistries for Mars and Europa.
The dynamics of self-gravitating gaseous density perturbations in the tightly wound spiral-arm model of the forcing potential (Brown 1969) is investigated. The cloud ensemble of the cold phase of the interstellar medium is regarded as a collisional gas whose 'molecules' are the clouds themselves, and the dynamical evolution of density perturbations is calculated assuming this gas obeys a polytropic pressure-density law. It is suggested that the formation of extreme Population I objects found predominantly along the arms of Sb/Sc systems is regulated by an overall energy balance in the cloud fluid. A single parameter is found which appears to characterize the flow's gravitational response to perturbations; this spiral parameter, Q-sub-sp, differs from the Toomre Q parameter by a factor of the square root of the density enhancement at the shock. It is necessary but not sufficient that Q-sub-sp be less than unity for significant growth to occur.
In order to eliminate potential risk from the lack of scientific understanding and resolve the current inability to assess how a rapidly growing space industry will affect Earth’s atmosphere, a well-defined research effort is recommended. As demonstrated in the white paper “Impacts of Spaceflight on the Global Atmosphere: Current Understanding, Knowledge Gaps, NASA’s Role, and Roadmap", we must improve our ability to model and observe rocket engine combustion, far field rocket plume evolution, impacts on the upper atmosphere, global launch impacts, reentry gas and aerosol production, far field reentry plume evolution, and global reentry impacts. The highly successful Atmospheric Chemistry of Combustion Emissions Near the Tropopause (ACCENT) program serves as a model for the proposed effort. ACCENT was a multiagency research program that included observation and modeling of rocket plumes and played a critical role to remove the threat of regulatory action against the Space Shuttle’s solid rocket motors. A similar effort today would be a combination of remote, in situ, and laboratory measurements that feed into model development and assessment of future launch and reentry emissions.
This review describes obervations of hot coronae around early-type galaxies. The observations show that early-type galaxies have 0.5-4.5 keV luminosities up to nearly 10 to the 43rd ergs/sec dominated by thermal emission from 10 to the 10th solar masses of hot (about 10 to the 7th K) gas. Calculations which model the evolution of the coronae are presented. These models can explain the present epoch observations as well as predict the coronal properties at large redshift.
Processes taking place during the evolution of a comet nucleus are examined, taking into account the release of gas on crystallization and the gas flow through the porous nucleus. In particular, the stresses caused by the gas pressure, the contribution of gas flow to the heat transfer, and the rate of gas emission by the comet along its orbit were determined using a model of spherically symmetric comet nucleus made of porous amorphous ice, with 10 percent CO gas trapped in it. Several values of density and pore size are considered, and for each combination of parameters, the model is evolved for 20-30 revolutions in Comet P/Halley's orbit. It is shown that a model of 0.2 g/cu cm density reproduces well many of the light-curve and activity characteristics of Comet P/Halley.
With a three-dimensional hydrodynamic computer code, the behavior of rotating, isothermal gas clouds as they collapse from Jeans unstable configurations is examined in order to determine whether they are susceptible to fragmentation during the initial dynamic collapse phase of evolution. It is found that a gas cloud will not fragment unless (1) it begins collapsing from a radius much smaller than the Jeans radius (i.e., the cloud initially encloses many Jeans masses) and (2) irregularities in the cloud's initial structure (specifically, density inhomogeneities) enclose more than one Jeans mass of material. Instead of fragmenting, most of the models collapse to a ring configuration. The rings appear to be less susceptible to fragmentation from arbitrary perturbations in their structure than has previously been indicated in other work. Because the models, which include the effects of gas pressure, do not readily fragment during a phase of dynamic collapse, it is suggested that gas clouds in the galactic disk undergo fragmentation only during quasi-equilibrium phases of their evolution.
The nonlinear evolution of unstable sound waves in a uranium plasma has been calculated using a multiple time-scale asymptotic expansion scheme. The fluid equations used include the fission power density, radiation diffusion, and the effects of the changing degree of ionization of the uranium atoms. The nonlinear growth of unstable waves is shown to be limited by mode coupling to shorter wavelength waves which are damped by radiation diffusion. This mechanism limits the wave pressure fluctuations to values of order delta P/P approximates 0.00001 in the plasma of a typical gas-core nuclear rocket engine. The instability is thus not expected to present a control problem for this engine.
X-ray observations of about 60 galaxies in the Virgo cluster and about 80 field galaxies are reviewed. M87 and its surrounding envelopes of gas and dark matter are described, and M87's dominance of the cluster in X-rays is discussed. The X-ray emission from early-type galaxies in Virgo and the field is discussed, and it is shown that these galaxies are surrounded by hot gaseous coronae which can be used to probe the masses of these galaxies. The gas masses of these coronae can be explained as the accumulated gas lost by stellar systems during their evolution. It is shown that supernovae can play an important role in heating the gas. Finally, early and late type field galaxies are compared to those in the Virgo cluster, and the possible effects of the cluster environment on their X-ray properties is discussed.
We present the results of hydrodynamical simulations of the orbital evolution of planets undergoing runaway gas accretion in radiative discs. We consider accreting disc models with constant mass flux through the disc, and where radiative cooling balances the effect of viscous heating and stellar irradiation. We assume that 20–30 M(sub ⨁) giant planet cores are formed in the region where viscous heating dominates and migrate outward under the action of a strong entropy-related corotation torque. In the case where gas accretion is neglected and for an α viscous stress parameter α = 2 × 10(exp -3), we find evidence for strong dynamical torques in accreting discs with accretion rates M ̇ ≳ 7 × 10(exsp -8)M(sub ⨀) yr(exp -1). Their main effect is to increase outward migration rates by a factor of ∼2 typically. In the presence of gas accretion, however, runaway outward migration is observed with the planet passing through the zero-torque radius and the transition between the viscous heating and stellar heating dominated regimes. The ability for an accreting planet to enter a fast migration regime is found to depend strongly on the planet growth rate but can occur for values of the mass flux through the disc of M ̇ ≳ 5 × 10(exp -8)M(sub ⨀) yr(exp -1).We find that an episode of runaway outward migration can cause an accreting planet formed in the 5–10 au region to temporarily orbit at star–planet separations as large as∼60–70 au. However, increase in the amplitude of the Lindblad torque associated with planet growth plus change in the streamline topology near the planet systematically cause the direction of migration to be reversed. Subsequent evolution corresponds to the planet migrating inward rapidly until it becomes massive enough to open a gap in the disc and migrate in the type II regime. Our results indicate that a planet can reach large orbital distances under the combined effect of dynamical torques and gas accretion, but an alternative mechanism is required to explain the presence of massive planets on wide orbits.
The quasi-static contraction of primordial stars composed of pure hydrogen and helium gas is studied by following numerically the evolution of a star of five solar masses from the end of protostellar accretion to the onset of hydrogen burning. Although the protostellar core of this mass is radiatively stable and undergoing nonhomologous contraction, its large surface area and luminosity force the star to a partially convective, homologously contracting state within only 100 yr. Deuterium later ignites at an off-center temperature maximum but fails to produce interior convection. The star follows a conventional premain sequence track in the HR diagram, reaching the ZAMS after 1.2 million yr, with a luminosity of 880 solar luminosities and a radius of 1.2 solar radii.
The nearby dark cloud Lynds 1551 contains one of the closest examples of a well-collimated bipolar molecular outflow. This source has the largest angular size of any known outflow and was the first bipolar outflow to be detected. The outflow originates from a low-luminosity young stellar object, IRS-5. Optical and radio continuum observations show the presence of a highly collimated, ionized stellar wind orginating from close to IRS-5 and aligned with the molecular outflow. However, we have little information on the actual mechanism that generates the stellar wind and collimates it into opposed jets. The Very Large Array (VLA) observations indicate that the winds originate within 10(15) cm of IRS-5, unfortunately at a size scale difficult to resolve. For these reasons, observations of the structure and dynamics of the hypersonic molecular gas may provide valuable information on the origin and evolution of these outflows. In addition, the study of the impact of the outflowing gas on the surrounding molecular material is essential to understand the consequence these outflows have on the evolution and star formation history of the entire cloud. Moriarty-Schieven et al. (1986) obtained a oversampled map of the CO emission of a portion of both the blueshifted and redshifted outflows in LI551 using Five College Radio Astronomy Observatory 14 m telescope. The oversampled maps have been reconstructed to an effective angular resolution of 20 arcsec using a maximum entropy algorithm. A continuation of the study of Moriarty-Schieven et al. is presented. The entire L1551 outflow has now been mapped at 12 arcsec sampling requiring roughly 4000 spectra. This data has been constructed to 20 arcsec resolution to provide the first high resolution picture of the entire L1551 outflow. This new data has shown that the blueshifted lobe is more extended than previously thought and has expanded downstream sufficiently to break out of the dense molecular cloud, but the redshifted outflow is still confined within the molecular cloud. Details of the structure and kinematics of the high velocity gas are used to test the various models of the origin and evolution of outflows.
Numerical simulations of two-component (stars + gas) self-gravitating galactic disks show that the interstellar gas can significantly affect the dynamical evolution of the disk even if its mass fraction (relative to the total galaxy mass) is as low as several percent. Aided by efficient energy dissipation, the gas becomes gravitationally unstable on local scale and forms massive clumps. Gravitational scattering of stars by these clumps leads to suppression of bar instability usually seen in heavy stellar disks. In this case, gas inflow towards the galactic center is driven by dynamical friction which gas clumps suffer instead of bar forcing.
The emergence of fuel cell systems and hybrid fuel cell systems requires the evolution of analysis strategies for evaluating thermodynamic performance. A gas turbine thermodynamic cycle integrated with a fuel cell was computationally simulated and probabilistically evaluated in view of the several uncertainties in the thermodynamic performance parameters. Cumulative distribution functions and sensitivity factors were computed for the overall thermal efficiency and net specific power output due to the uncertainties in the thermodynamic random variables. These results can be used to quickly identify the most critical design variables in order to optimize the design and make it cost effective. The analysis leads to the selection of criteria for gas turbine performance.
Electron spin resonance (ESR) spectroscopy provided evidence for formation of hydroxyl radicals during ultraviolet photolysis (254 nm) at -170 C of H2O adsorbed on silica gel or of silica gel alone. The carboxyl radical was observed when CO or CO2 or a mixture of CO and CO2 adsorbed on silica gel at -170 C was irradiated. The ESR signals of these radicals slowly disappeared when the irradiated samples were warmed to room temperature. However, reirradiation of CO or CO2, or the mixture CO and CO2 on silica gel at room temperature then produced a new species, the carbon dioxide anion radical, which slowly decayed and was identical with that produced by direct photolysis of formic acid adsorbed on silica gel. The primary photochemical process may involve formation of hydrogen and hydroxyl radicals. Subsequent reactions of these radicals with adsorbed CO or CO2 or both yield carboxyl radicals, CO2H, the precursors of formic acid. These results confirm the formation of formic acid under simulated Martian conditions and provide a mechanistic basis for gauging the potential importance of gas-solid photochemistry for chemical evolution on other extraterrestrial bodies, on the primitive earth, and on dust grains in the interstellar medium.
Some of the most important theoretical ideas and observations for quasars and the nuclei of active galaxies are reviewed, and areas of future research are suggested. Emphasis is on the nature of the power source, the radiation processes, and the mechanism for formation and collimation of jets. Phenomena that produce X-rays are of particular concern. Particular topics discussed are the observed and expected time variabilility, the gas supply mechanisms and luminosity evolution, thermal and nonthermal radiation processes, observed and theoretical spectra, criteria for thermalization of electrons and ions, effects of electron-positron pairs on relativistic plasmas, hydrodynamic, electrodynamic and inertial methods for producing and confining jets. The paper concludes with a list of needed observations.