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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Optimizing Transmission of Acoustic Signals to Monitor Internal Conditions of Canisters for Dry Storage of Commercial Spent Nuclear Fuel

Safe storage of spent nuclear fuel (SNF) is critical to the nuclear fuel cycle and the future of nuclear energy. In the United States, SNF is stored primarily via two methods regulated by the U.S. Nuclear Regulatory Commission: wet storage in SNF pools and dry storage in dry cask storage systems (DCSSs). After about five years of cooling in spent fuel pools, the fuel assemblies are transferred into DCSSs, and the systems are filled with helium and sealed by welding. Deterioration of conditions inside of a DCSS is reflected in changes in the internal gas properties; this motivates the development of acoustic techniques to monitor internal gas properties, over extended storage periods, using sensors mounted on the exterior of the storage packages. However, a major challenge in collecting acoustic signals is the impedance mismatch between the steel canister shell and the gas. Only a small fraction of the ultrasonic signal can be transmitted through the gas medium. This paper documents experimental studies conducted on a full-scale canister mock-up to capture the gas-borne signals. Damping materials were pasted on the outside, and blocking and unblocking tests were conducted to identify the gas-borne signal. The results show that the excitation frequency plays an important role in maximizing the gas-borne signals. The gas-borne signal was successfully detected at around the theoretical time-of-flight. A high signal-to-noise ratio was achieved in the measurements. Next, the acoustic impedance matching layers were introduced, and the gas signal was drastically improved compared with that using no AIM layers.

Spent nuclear fuel (SNF), Canisters, Internal cond↗

Sensor System and Observer Algorithm Co-Design For Modern Internal Combustion Engine Air Management Based on H2 Optimization

This paper outlines a novel sensor selection and observer design algorithm for linear time-invariant systems with both process and measurement noise based on H 2 optimization to optimize the tradeoff between the observer error and the number of required sensors. The optimization problem is relaxed to a sequence of convex optimization problems that minimize the cost function consisting of the H 2 norm of the observer error and the weighted l 1 norm of the observer gain. An LMI formulation allows for efficient solution via semi-definite programing. The approach is applied here, for the first time, to a turbo-charged spark-ignited engine using exhaust gas circulation to determine the optimal sensor sets for real-time intake manifold burnt gas mass fraction estimation. Simulation with the candidate estimator embedded in a high fidelity engine GT-Power model demonstrates that the optimal sensor sets selected using this algorithm have the best H 2 estimation performance. Sensor redundancy is also analyzed based on the algorithm results. This algorithm is applicable for any type of modern internal combustion engines to reduce system design time and experimental efforts typically required for selecting optimal sensor sets.

Zhang, Xu↗

Advanced Multi-Dimensional Capacitance Sensors Based Subsea Multiphase Mass Flow Meter to Measure and Monitor Offshore Enhanced Oil

This innovation is based on advanced multi-dimensional extensions of ECVT sensors that involve ECVT, Displacement Current Phase Tomography (DCPT), Maxwell-Wagner-Sillars polarization effect (MWS), and velocimetry which exploit the variation of electric properties between the oil, water, and gas coming out of the well. Capacitance sensors are embedded on the inside of a pipe spool and placed in-line with the subsea oil line piping on the extraction end of the well. The difference in dielectric, dielectric loss, surface polarization, and velocity of each phase are used in the multi-dimensional algorithm to measure the volume fraction, distribution, velocity, mass flow rate, and flow regime of the mixture moving through the pipe.

02 PETROLEUM↗

Integrating Metal-Hydride and Gas-Detector for Tritium Gas Detection

Detection of trace amounts of environmental tritium is a challenging problem, driving the need for field-deployable systems that offer high sensitivity, selectivity, and minimal false positives. We present a technique for high-sensitivity, high-selectivity tritium measurement, which integrates metal-hydride and gas-detector concepts into a compact field-deployable tritium sensor. A hydrogen-storage metal embedded in a gas proportional counter selectively absorbs protium (1H)/tritium (3H), which are subsequently released into the counter volume with a reduced radiation background. Ionizations induced by 3H beta particles are then measured in proportional counting mode, achieving high detection efficiency. Preliminary studies conducted with palladium (Pd) thin films coated on stainless-steel substrates demonstrated 3H absorption and metal-tritide formation, followed by 3H desorption upon heating the metal-tritide. These processes were confirmed using activity concentrations measured by a commercial tritium monitor and pulse height spectra acquired from a custom-built detector.

Gas-proportional counter↗

Electronic Trap-State Modulation in Sm-Doped SnO 2 Nanofibers Enables Ultrasensitive Hydrogen Sensing

The demand for sub-ppm hydrogen (H 2 ) sensing is growing across emerging applications such as environmental monitoring, breath-based disease diagnostics, and early-stage battery failure detection. However, achieving reliable ppb-level detection with chemiresistive metal oxide sensors remains challenging. At trace gas concentrations, resistance modulation is often insufficient, particularly in the absence of noble metal catalysts. Here, we report samarium-doped tin dioxide (Sm-SnO 2 ) nanofibers in which electronic trap-state modulation is exploited to enable ultrasensitive hydrogen sensing. The 2 at% Sm-doped SnO 2 nanofibers exhibited markedly enhanced H 2 sensitivity, achieving clear detection down to 25 ppb H 2 at 200 °C, with a theoretical limit of detection of 4.5 ppb, placing this material among the most sensitive noble-metal-free SnO 2 -based H 2 sensors reported to date. Mechanistic investigations through X-ray photoelectron spectroscopy and electron energy loss spectroscopy revealed that Sm 3+ doping introduces deep trap states associated with charge-compensating defect complexes. These states reduce free carrier density, increase baseline resistance, and enable trap-assisted charge release during H 2 exposure, thereby amplifying the sensing response. Trap-state engineering via rare-earth doping, exemplified by Sm-SnO 2 , provides an effective pathway for achieving ppb-level hydrogen detection in noble-metal-free chemiresistive sensors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Acoustic diagnostic system and method for superconducting devices operating in gas or liquid

A novel system and method for detecting a quench of a superconducting conductor and detecting abnormal behavior of a superconducting conductor using acoustic sensor technology in the coolant of a superconducting cable and/or magnet is disclosed. This system and method is not only limited to use for superconductors, but also may be used for any device disposed in liquid and gas. Acoustic sensors are installed along a coolant space of a superconducting conductor and monitor coolant conditions. By monitoring acoustic changes, temperature changes or coolant flow disruption can be detected very quickly by an acoustic sensor array. By disposition of the acoustic sensor array in a coolant flow channel, the acoustic sensor system can quickly detect a local condition, such as the thermal status (temperature) of a superconducting cable and magnet with precise spatial resolution.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Adaptive sensing for a gas leak detection

A method, a system and an apparatus for adaptively sensing a gas leak. The method includes: obtaining wind data from a wind sensor, identifying at least one wireless mote in a plurality of wireless motes that is most likely to detect a gas plume from the wind data, activating the identified at least one wireless mote to trigger measuring gas concentration of the gas plume, and identifying the location of the gas leak if the gas concentration is above a predetermined threshold. Also included is a system for adaptively sensing a gas leak having a wind sensor, a plurality of wireless motes and a server in communication therewith. An apparatus for adaptively sensing a gas leak in an industrial site is also provided.

03 NATURAL GAS↗

Feasibility of fusion plasma burn control via real-time, sub-divertor neutral gas isotopic and compositional analysis

The ability to provide fusion burn control without requiring physical access through the first wall and fuel breeding blankets, would be vital for any future, magnetically confined fusion power reactor. A multi-sensor, fusion fuel cycle exhaust, neutral gas analysis system on JET, capable of delivering real time data, and accessing only the sub-divertor region, provides an excellent example of such capability. Optimized for and operated during the deuterium–tritium experimental campaigns 2 and 3 (DTE2, DTE3), it is proving valuable for planning to explore fusion reactor burn control in ITER with a comparable diagnostic system called the Diagnostic Residual Gas Analyzer (DRGA). This paper aims to show feasibility of developing model-based controllers for ITER and next generation, reactor-relevant devices, by building both on the empirical experience in JET-DTE2, and on the already emerging experience on developing such models specifically for ITER. The paper begins with a specific use-case from JET-DTE2, pertaining to the observed sensitivity of the fusion neutron yield on the concentration of isotopic helium-3 ( 3 He), with data from one of the high-performance DT shots exhibited with emphasis on the 3 He measurement via the sub-divertor. Then, a first model is developed and then explored with simulations that aim to discover how well the controllers in the model react to either insufficient levels of 3 He or excessive levels of 3 He. The simulations then explore potential impact from a delay in the measurement (or the response) that would be comparable to the ∼1 s, conductance limited response for the ITER DRGA system, currently in its final design. The simulations show that control is feasible, and that its effectiveness is not significantly impacted by such delay.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Raw soil carbon dioxide, moisture, temperature and micrometeorological data in the East River Watershed, Colorado June 2021-June 2024. (DE-SC0021139)

This dataset contains raw data from four tripod stations along an elevation gradient on Snodgrass Mountain in the East River Watershed, CO, USA. Each station contains a datalogger connected to 3 soil Carbon Dioxide CO2 gas probes, 3 soil temperature/moisture sensors and a micrometeorological station. Sensors are scanned every minute, and the 30 minute average is reported. The file snodgrass_soil_ESS.csv contains raw data, a row of column descriptors, and units of measurements. some data processing and QA/QC was done to filter out data from sensors that went bad and extreme outliers. CO2 sensors that went bad were replaced with new sensors as soon as possible. This research was performed to investigate the ecohydrological linkages of belowground carbon processes in the East River watershed forested communities to better understand how these ecosystems will respond to a changing cold-season moisture input. This is the second version of this data set and was modified on 10/01/2024. The primary change in the data was the addition of data from the fall of 2022 to June of 2024. In addition, minor QA/QC was done to filter out data from sensors that went bad and extreme outliers. THe filtered data are now NA's in this data frame and primarily the CO2 sensors. Limited to no QA/QC has been done on the other environmental data. This is now the third version of the data set, and was modified 03/25/2026. The primary change in the data was the addition of data from the June of 2024 to December 2025. Further r QA/QC was done with the new data to filter out bad data from faulty sensors and extreme outliers. The filtered data are now NA's in this data frame and primarily the CO2 sensors. Limited to no QA/QC has been done on the other environmental data. ##This additional data was funded under DE-SC0024218( Responses of Plant and Microbial Respiration Sources to Changing Cold Season Climate Drivers in the East River Watershed)

54 ENVIRONMENTAL SCIENCES↗

Real-Time Tracking of Carbon Dioxide Concentration Using an Optical Microsphere Resonator Sensor

Whispering gallery mode resonator sensors are nondisruptive optical sensors that can detect and monitor perturbations in a gaseous environment. Through its resonant properties of peak wavelength, amplitude, and quality factor (Q factor), changes in concentration can be quantified within seconds and monitored over days with great stability. In addition, the small footprint, low cost, and high sensitivity are ideal properties for a disposable sensor that can be utilized in extreme environments. Further, the large Q factor of the resonant cavity enables long interaction lengths and amplifies the effect of small changes in the background refractive index, which is detectable in picometer shifts of the resonance wavelength. However, this measurement is susceptible to changes in other environmental factors such as temperature, pressure, and humidity, which manifest on the picometer wavelength scale, reinforcing the need to decouple the variables. In this work, we compare the spectral response of different diameter resonators to carbon dioxide, nitrogen, and its mixtures, observing the spectral shifting and broadening of the cavity resonance near 1550 nm. In addition, the effect of environmental temperature on spectral shifting due to the thermo-optic effect is characterized and quantified. Lastly, the gas concentrations are changed in real time to showcase the tracking and recovery capabilities of the resonator sensor.

47 OTHER INSTRUMENTATION↗

Enhanced Carbon Dioxide Uptake in Drilled Hollow Core Fibers for Raman Spectroscopy

Fiber-based Raman spectroscopy enhances the Raman signal by maximizing the overlap of the optical field and the gas species. However, filling the hollow-core fiber (HCF) with gas requires time that is dependent on the fiber core diameter, fiber length, and pressure of the gas. At ambient pressure, the fiber gas uptake is driven by diffusion into the fiber ends, severely limiting the response time of the system. By laser drilling access holes to the core along the length of the fiber, the uptake time of the gas is reduced, improving the system response time. In this work, we study the carbon dioxide (CO 2 ) sensor dynamics based on Raman signal intensity generated in HCFs. The signal intensity versus gas concentration is characterized by controlling the CO 2 concentration in the surrounding environment of the fiber. Next, we characterize the gas uptake time in HCFs as a function of fiber length. Finally, we optimize the access hole configuration along the fiber, demonstrating reduced sensor uptake time by a factor of three.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High spatial resolution temperature profile measurements of solid-oxide fuel cells

Temperature gradients resulting from local electrochemical reactions, current distribution and geometry of gas flow channels in solid oxide fuel cells (SOFCs) create thermal stresses, localized thermophysical property gradients and uneven property evolution, contributing to SOFC degradation. This paper presents a new method to perform temperature measurements (up to 800°C) at high spatial resolutions to monitor the operation of SOFCs. Using femtosecond laser irradiation, distributed fiber sensors were hardened for high temperature environment applications. Distributed fiber sensors were embedded in interconnected plates using an additive manufacturing method to perform temperature measurements with 4-mm spatial resolution during the operation of a planar fuel cell. The measurement revealed the impact of various H 2 fuel concentrations and current loads have on temperature profiles of the SOFC tested. Temperature variation on the anode side was found to be less than 5°C, and 3°C on the cathode side. The measurements were compared to results from a multiphysics fuel cell performance model simulating similar conditions. These simulations predicted similar temperature gradients, indicating the experimental data obtained is reasonable. The model also predicts that the effect of the embedded sensor has on the local temperature will be minimal and that the gradient of temperature in the gas channels will be captured despite the separation between the sensor and the gas flow. Finally, the high spatial resolution data harnessed by these distributed fiber sensors provides experimental support for model-based design and optimization to improve the operational efficiency and longevity of solid oxide fuel cells and fuel cell assemblies.

25 ENERGY STORAGE↗

Spatial mapping of dissolved methane using an in situ sensor in Puget Sound

Release of methane, as gas bubbles or in the dissolved phase, from the seafloor has been observed in coastal waters (< 200 m) and deep ocean basins (> 1000 m). Methane dissolution within the water column affects the geochemistry of the surrounding water, leading to localized oxygen loss and potential escape to the atmosphere, particularly from shallower sites. Traditional methods for detecting and quantifying dissolved methane rely on collecting discrete water samples for ship- or land-based ex situ analysis and post processing. Here, we report on the use of a reduced response time, in situ methane sensor, the Sensor for Aqueous Gases in the Environment (SAGE), for detecting and quantifying dissolved methane concentrations in a wide range of seafloor environments. During a Fall 2022 research cruise on the R/V Thomas G. Thompson in Puget Sound, SAGE was integrated onto a towed conductivity/temperature/depth rosette and deep-sea camera system with live-stream 1 Hz telemetry and used to spatially map the concentration of methane approximately 1 m above the seafloor. The site had been previously identified as an active methane plume field characterized by gas bubbles, fluid venting, and a faulted seabed. The widespread background dissolved concentration of methane measured by SAGE was 83 nM, and a range of 78–670 nM was observed throughout the survey. The results highlight the capacity of SAGE to map the spatial and temporal variability of dissolved methane concentrations in situ and to identify and localize sites of variable methane emissions from the seafloor.

Padilla, Alexandra M. [Woods Hole Oceanographic In↗

Anomaly Detection for Online Monitoring of Thermocouple Sensors in the Advanced Test Reactor

This study explores data-driven anomaly detection methods to analyze sensor fail- ures in the Advanced Gas Reactor (AGR) nuclear fuel irradiation experiments. Specifically, we examine failures of thermocouples (TCs), which are critical for mon- itoring and controlling in-reactor temperatures during operation. Failures were pri- marily observed during abrupt power transitions and manifested as sensor drop-outs, drifts, or unexplained behavior. We applied three time-series analysis techniques— rolling mean smoothing, matrix profile, and vector auto-regression (VAR)—to de- tect anomalies in TC data prior to failure events. The rolling mean method effec- tively highlighted deviations aligned with reported failures, while the matrix profile provided partial early warning but sometimes flagged normal fluctuations during power-down periods. VAR shows potential in capturing multivariate dependencies but requires further calibration. A rare case of TC drift was also documented, which did not result in failure, underscoring the challenge of building predictive models with sparse positive examples. Our findings demonstrate that traditional statistical tools can aid anomaly detection but have limited predictive power without richer training data. We propose future directions including synthetic data generation, real- time surrogate modeling, and multi-modal feature integration. This work provides a foundation for applying robust anomaly detection frameworks to mission-critical sensor systems in experimental settings.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Safety Compliance Verification of Fuel Cell Electric Vehicle Exhaust

NREL has been developing compliance verification tools for allowable hydrogen levels prescribed by the Global Technical Regulation Number 13 (GTR-13) for hydrogen fuel cell electric vehicles (FCEVs). As per GTR-13, FCEV exhaust is to remain below 4 vol% H2 over a 3-second moving average and shall not at any time exceed 8 vol% H2 and that this requirement is to be verified with an analyzer that has a response time of less than 300 ms. To be enforceable, a means to verify regulatory requirements must exist. In response to this need, NREL developed a prototype analyzer that meets the GTR metrological requirements for FCEV exhaust analysis. The analyzer was tested on a commercial fuel cell electric vehicle (FCEV) under simulated driving conditions using a chassis dynamometer at the Emissions Research and Measurement Section of Environment and Climate Change Canada and FCEV exhaust was successfully profiled. Although the prototype FCEV Exhaust Analyzer met the metrological requirements of GTR-13, the stability of the hydrogen sensor was adversely impacted by condensed water in the sample gas. FCEV exhaust is at an elevated temperature and nearly saturated with water vapor. Furthermore, condensed water is present in the form of droplets. Condensed water in the sample gas can collect on the hydrogen sensing element, which would not only block access of hydrogen to the sensor but can also permanently damage the sensor. In the past year, the design of the gas sampling system was modified to mitigate against the transport of liquid water to the sensing element. Laboratory testing confirmed the effectiveness of the modified sampling system water removal strategy while maintaining the measurement range and response time required by GTR-13. Testing of the upgraded analyzer design on an FCEV operating on a chassis dynamometer is scheduled for the summer of 2021.

DIRECT ENERGY CONVERSION,HYDROGEN↗

A High-Temperature Multipoint Hydrogen Sensor Using an Intrinsic Fabry–Perot Interferometer in Optical Fiber

This paper presents a multiplexable fiber optic chemical sensor with the capability of monitoring hydrogen gas concentration at high temperatures up to 750 °C. The Pd-nanoparticle infused TiO 2 films coated on intrinsic Fabry–Perot interferometer (IFPI) array were used as sensory films. Strains induced upon exposure to hydrogen with varied concentrations can be monitored by IFPI sensors. The fiber sensor shows a repetitive and reversible response when exposed to a low level (1–6%) of hydrogen gas. Uniform sensory behavior across all the sensing cavities is demonstrated and reported in this paper.

47 OTHER INSTRUMENTATION↗