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Components Refurbishment and Chemical Analysis Facility, Hot Spot 1 SWMU #041 Year 3 Annual Performance Monitoring Report Kennedy Space Center, Florida

This Year 3 Annual Performance Monitoring Report (PMR) presents the operations, maintenance, and monitoring activities for the Hydraulic Containment System (HCS) Interim Measure (IM) at the Components Refurbishment and Chemical Analysis (CRCA) facility located at John F. Kennedy Space Center (KSC), Florida. The primary objective of the HCS is to attain hydraulic control of the dissolved-phase chlorinated volatile organic compound (CVOC) plume, with the secondary objective to reduce concentrations of CVOCs in the high-concentration plume to support transition to monitored natural attenuation (MNA). CRCA has been designated Solid Waste Management Unit 041 under the KSC Resource Conservation and Recovery Act Corrective Action Program. The timeframe for activities documented in this Year 3 PMR extends from September 2021 through October 2022. Baseline sampling activities were completed in June 2019, and full-scale startup of the HCS IM was completed in July-August 2019. The operational runtime of the HCS for the Year 3 reporting period was approximately 91%, with the majority of downtime attributed to system maintenance and repair. This is generally consistent with Year 1 and Year 2 runtimes of 85% and 92%, respectively. To help reduce downtime, an anti-scaling amendment, Redux 390, has been used to reduce scaling and help maintain system design parameters. Over nine million gallons of groundwater were treated during Year 3 of HCS operations, and concentrations of the site’s contaminants of concern (trans-1,2-dichloroethene and vinyl chloride) have been reduced by over 97%. This PMR describes the activities that were performed during Year 3 to operate and monitor the HCS IM, which includes three extraction wells, seven injection wells, and conveyance piping to a modular structure containing the control panel and an air stripper. Influent and effluent sampling results from the air stripper show that the system is operating as designed and is reducing concentrations of contaminants of concern to below detection limits. In addition to HCS operation, this PMR also discusses performance monitoring that has been implemented to assess progress of the HCS IM and overall plume conditions through scheduled groundwater (quarterly and semi-annual) and sub-slab soil gas (quarterly) sampling and analysis. Two ambient air samples were also collected on a quarterly basis in the vicinity of the modular structure and the paved driveway east of the Solvent Reclamation Area during routine operation and maintenance (O&M) activities to ensure safe breathing zone air quality for on-site personnel. All sub-slab soil gas and ambient air sampling conducted during the Year 3 operational period showed results below applicable regulatory air screening limits. Predictions made during the Year 2 groundwater model updates were in close correlation to post Year 3 plume conditions. Therefore, it can be assumed that the projected path remains valid for transition to MNA in one to two years of continuous HCS operation. The contents of this Year 3 PMR were presented during the February 2023 KSC Remediation Team meeting, where Team consensus was reached on several items including continued O&M of the HCS, and continued monitoring of groundwater, ambient air, and sub-slab soil gas. Replacement of MW0019 and VMP04 was also recommended, as well as additional direct-push technology sampling to further delineate the downgradient plume and confirm overall site-wide low-concentration plume boundaries. Sampling for per- and polyfluoroalkyl substances at CRCA is ongoing and will be submitted under separate cover.

K. Alex Murphy↗

Launch Complex 39B, SWMU 009 Air Sparging System Expansion Implementation Work Plan Kennedy Space Center, Florida

This Implementation Work Plan (IWP) for expansion of the Air Sparging (AS) system at Launch Complex 39B (LC39B), presents the design and coordination specifics to expand the existing AS Interim Measure (IM) at LC39B located at Kennedy Space Center (KSC), Florida. The existing AS system at LC39B was installed in 2017 and included 279 AS wells. LC39B has been designated as Solid Waste Management Unit (SWMU) 009 under the KSC Resource Conservation and Recovery Act (RCRA) Corrective Action Program. Expansion of the AS IM will include installation of an additional five AS wells to depths of approximately 13 and 17 feet below land surface (bls) to remediate contaminated groundwater identified northwest of the launch pad, near the liquid oxygen (LOX) tank. The expansion will target concentrations of cis-1,2-dichloroethene (cDCE) and vinyl chloride (VC) greater than Florida Department of Environmental Protection (FDEP) Natural Attenuation Default Concentrations (NADCs) that were identified during direct push technology (DPT) sampling events between 2019-2022 in shallow intervals between 8 and 16 feet bls. The objective for this expansion is to remediate contaminated groundwater within the treatment zone to below NADCs to support transition to monitored natural attenuation (MNA) through a long-term monitoring (LTM) program. This expansion will treat approximately 0.07-acres of residual groundwater contamination. The IWP design for this expansion will utilize the existing AS system trailer that is already onsite and operating. The five new AS expansion wells will be integrated into the existing Zone Z4 distribution manifold to deliver compressed air to the new AS wells. To deliver airflow, three existing lateral lines will be split in the field at a lateral split junction point (using 2-way or 3-way splits). Each split lateral will supply air to AS wells at the same depth interval to minimize preferential pathways. The trenching layout for the new AS wells was developed to minimize ground disturbance due to the amount of utilities in the area. One new monitoring well will also be installed and added to LC39B’s performance monitoring program to evaluate the effectiveness of the AS system expansion. This well will be sampled on a semi-annual basis for volatile organic compounds, with results evaluated to determine if system adjustments may be required. The main components of this IWP were presented to the KSC Remediation Team (KSCRT) at the October 2022 Meeting (Meeting 2210-M05). DPT delineation data from the LOX area were also presented, which included some inferred boundaries due to physical restrictions of the LOX tank and associated concrete pad and infrastructure. Planned monitoring well sampling in this area will help determine if back-diffusion may be occurring from beneath the pad. Additionally, based on potential petroleum odors and staining identified at two DPT locations during the January 2022 DPT event in the 10-16 feet bls range, a KSCRT action item was assigned during the October 2022 meeting to collect soil samples for petroleum compounds if similar odors or staining are identified during IM implementation. Construction completion and performance monitoring will be incorporated into LC39B’s groundwater monitoring reports, which are currently submitted on an annual basis to FDEP to document operation and maintenance activities and results from the AS IM.

Deborah M. Wilson↗

Per- and Polyfluoroalkyl Substances Confirmatory Sampling Report, South Repeater Building (SWMU 121), Kennedy Space Center, Florida

This Per- and Polyfluoroalkyl Substances (PFAS) Confirmatory Sampling (CS) Report was prepared by AECOM Technical Services, Inc. (AECOM) for the National Aeronautics and Space Administration (NASA) under Contract 80KSC019D0010, Task Order 80KSC021F0096. The purpose of this report is to document CS activities at the South Repeater Building, Solid Waste Management Unit (SWMU) 121, formerly known as the Area 3 Repeater Building (A3RB). A Phase I SWMU Assessment and Confirmatory Sampling Report (NASA 2019) and a Phase II and III SWMU Assessment and Confirmatory Sampling Report (NASA 2022b) were previously submitted detailing Center-Wide assessment activities performed at the John F. Kennedy Space Center (KSC) in Florida that identified 33 locations of concern and 19 areas of potential concern at KSC associated with the storage, use, or release of materials containing PFAS. A review of the analytical results from investigation derived waste samples collected in 2020 from the South Repeater Building area indicated concentrations of perfluorooctanesulfonic acid (PFOS) were above Florida Department of Environmental Protection (FDEP) provisional Groundwater Cleanup Target Levels of 70 nanograms per liter (ng/L) at a concentration of 1,750 ng/L. Following this review, the KSC Fire Chief was contacted; the Chief recalled fighting a brush fire in 1998 in the area, during which an unknown volume of aqueous film-forming foam was used to extinguish the fire. The Phase II and Phase III SWMU Assessment Report recommended this area proceed to CS. Historical results in this area are provided in Appendix A . PFAS CS activities were contracted at the South Repeater Building. Initial CS activities were conducted in accordance with the PFAS Assessment and Mitigation Work Plan (AECOM 2022), which was submitted to the NASA Remediation Project Management team and accepted by the team on November 1 and 8, 2021. The objectives of the PFAS CS were to: - - Confirm and begin to assess the extent of PFAS affected media in the South Repeater Building area. - - Identify locations for groundwater, soil, surface water, and soil core sampling. - - Qualitatively characterize the migration potential of released PFAS to environmental media (soil, groundwater, and surface water). The following activities were completed to meet the PFAS CS objectives: - - Installation of monitoring wells via direct push technology (DPT) and rotosonic techniques - - Groundwater, soil, and surface water sampling - - Collection of soil cores to evaluate site lithology - - Development of initial PFAS plume characterization

PFAS↗

Former Central Heat Plant SWMU 045 Year 2 Air Sparge System Performance Monitoring Report

This Air Sparge (AS) Performance Monitoring (PM) Report (PMR) presents Year 2 operation, maintenance, and monitoring (OM&M) activities, PM results, and monitoring well installations supporting the AS Interim Measure (IM) at the Former Central Heat Plant (CHP) at Kennedy Space Center (KSC), Florida. CHP has been designated Solid Waste Management Unit 045 under the KSC Resource Conservation and Recovery Act Corrective Action Program. An AS IM was installed at CHP between 2019 and 2021, which included the installation of an AS system to treat a chlorinated solvent groundwater plume. Contaminants of concern (COCs) identified at CHP for the AS IM include tetrachloroethene (PCE), trichloroethene (TCE), cis-1,2-dichloroethene (cDCE), and vinyl chloride (VC). The completed AS system includes a network of 267 AS wells, which treat approximately 1.3 acres of contaminated groundwater. “Hot” compressor technology is used to treat the source zone, while a “cold” compressor is used to treat two hot spot (HS) areas (HS1 and HS2) and the high concentration plume (HCP). The AS system began operation in June-July 2021 and this document includes Year 2 of operation. The overall runtimes for the AS system for the Year 2 reporting period (October 2022 to September 2023) were approximately 69 percent for the cold trailer and 71 percent for the hot trailer. Air samples and vapor screening results collected during the reporting period showed concentrations less than applicable human health and air emissions permit criteria. Groundwater performance monitoring results show that AS treatment continues to be effective in reducing COC concentrations at CHP. At the shallow interval, COC concentrations were all non-detect, less than, or met their respective State of Florida Groundwater Cleanup Target Levels (GCTLs) at the end of Year 2 in September 2023. In the deep interval, 10 of the 15 PM wells detected COCs greater than their respective GCTLs, with two of these wells also exceeding the Natural Attenuation Default Concentration for VC. Based on Year 2 OM&M and PM results, continued operation of the AS system is required to meet the IM objective. It is therefore recommended to continue with AS IM operations at CHP with the following plan for Year 3.

Kevin Alex Murphy↗

Ground Water and Climate Change

As the world's largest distributed store of fresh water, ground water plays a central part in sustaining ecosystems and enabling human adaptation to climate variability and change. The strategic importance of ground water for global water and food security will probably intensify under climate change as more frequent and intense climate extremes (droughts and floods) increase variability in precipitation, soil moisture and surface water. Here we critically review recent research assessing the impacts of climate on ground water through natural and human-induced processes as well as through groundwater-driven feedbacks on the climate system. Furthermore, we examine the possible opportunities and challenges of using and sustaining groundwater resources in climate adaptation strategies, and highlight the lack of groundwater observations, which, at present, limits our understanding of the dynamic relationship between ground water and climate.

climate change↗

Spatial variation of primordial 3-He in crustal fluids along the East-African Rift system (the Ethiopian and the Kenya Rift section)

(3)He/(4)He compositions are presented for groundwater samples from the Ethiopian segment of the East-Afrikan Rift and from its northern extension, the adjacent Afar region (Djibuti). Helium isotope data are compared to those obtained previously from the Gregory Rift, south of Ethiopia. The distribution pattern of mantle-derived volatiles along the entire East-African-Rift (-from south Kenya to Djibuti-) is discussed and their sources are identified. Helium isotope ratios (R) for samples from the Ethiopian part of the Rift range from 6.3 to 16.0 times the atmospheric ratio (Ra=1.4 x 10(exp -6) and thus show together with a MOR component a considerable hotspot helium component. These mantle helium concentrations are comparable to those observed in groundwaters and volcanic rocks from the Afar plume region in Djibuti. Here R/Ra values range from 9 to 13 times the atmospheric composition, with mantle-derived helium concentrations being higher than at spreading ocean ridges. R/Ra values from Ethiopia and Djibuti are entirely different from those observed in groundwaters at the southerly extending Gregory Rift in Kenya, where R/Ra values scatter between 0.5 and 6. At the northernmost part of the Gregory Rift, close to Ethiopia mantle helium contents are slightly higher, with R/Ra-values varying between 6.5 and 8.0.

Griesshaber, E.↗

Evaluating GCM land surface hydrology parameterizations by computing river discharges using a runoff routing model: Application to the Mississippi basin

To relate general circulation model (GCM) hydrologic output to readily available river hydrographic data, a runoff routing scheme that routes gridded runoffs through regional- or continental-scale river drainage basins is developed. By following the basin overland flow paths, the routing model generates river discharge hydrographs that can be compared to observed river discharges, thus allowing an analysis of the GCM representation of monthly, seasonal, and annual water balances over large regions. The runoff routing model consists of two linear reservoirs, a surface reservoir and a groundwater reservoir, which store and transport water. The water transport mechanisms operating within these two reservoirs are differentiated by their time scales; the groundwater reservoir transports water much more slowly than the surface reservior. The groundwater reservior feeds the corresponding surface store, and the surface stores are connected via the river network. The routing model is implemented over the Global Energy and Water Cycle Experiment (GEWEX) Continental-Scale International Project Mississippi River basin on a rectangular grid of 2 deg X 2.5 deg. Two land surface hydrology parameterizations provide the gridded runoff data required to run the runoff routing scheme: the variable infiltration capacity model, and the soil moisture component of the simple biosphere model. These parameterizations are driven with 4 deg X 5 deg gridded climatological potential evapotranspiration and 1979 First Global Atmospheric Research Program (GARP) Global Experiment precipitation. These investigations have quantified the importance of physically realistic soil moisture holding capacities, evaporation parameters, and runoff mechanisms in land surface hydrology formulations.

Liston, G. E.↗

Cluster growth modeling of plateau erosion

The pattern of erosion of a plateau along an escarpment may be modeled usng cluster growth techniques, recently popularized in models of drainage network evolution. If erosion on the scarp takes place in discrete events at rates subject to local substrate strength, the whole range of behavior is described by a combination of three cluster growth mechanisms: invasion percolation, Eden growth and diffusion-limited aggregation (DLA). These model the relative importance of preexisting substrate strength, background weathering, and seepage weathering and erosion respectively. The rate of seepage processes is determined by the efflux of groundwater at the plateau margin, which in turn is determined by the pressure field in the plateau aquifer. If this process acted alone, it would produce erosion patterns in the form of Laplacian fractals, with groundwater recharge from a distant source, or Poissionian fractals, with groundwater recharge uniform over the plateau. DLA is used to mimic the Laplacian or Poissonian potential field and the corresponding seepage growth process. The scaling structure of clusters grown by pure DLA, invasion percolation, or Eden growth is well known; this study presents a model which combines all three growth mechanisms for the first time. Mixed growth processes create clusters with different scaling properties and morphologies over distinct length scale ranges, and this is demonstrable in natural examples of plateau erosion.

Stark, Colin P.↗

Magmatic Intrusions and a Hydrothermal Origin for Fluvial Valleys on Mars

Numerical models of Martian hydrothermal systems demonstrate that systems associated with magmatic intrusions greater than several hundred cubic kilometers can provide sufficient groundwater outflow to form the observed fluvial valleys, if subsurface permeability exceeds about 1.0 darcy. Groundwater outflow increases with increasing intrusion volume and subsurface permeability and is relatively insensitive to intrusion depth and subsurface porosity within the range considered here. Hydrothermally-derived fluids can melt through 1 to 2 km thick ice-rich permafrost layers in several thousand years. Hydrothermal systems thus provide a viable alternative to rainfall for providing surface water for valley formation. This mechanism can form fluvial valleys not only during the postulated early warm, wet climatic epoch, but also during more recent epochs when atmospheric conditions did not favor atmospheric cycling of water. The clustered distribution of the valley networks on a given geologic surface or terrain unit of Mars may also be more compatible with localized, hydrothermally-driven groundwater outflow than regional rainfall. Hydrothermal centers on Mars may have provided appropriate environments for the initiation of life or final oases for the long-term persistence of life.

Gulick, Virginia C↗

Thermographic Data Analyses for Karst Watersheds

Aerial thermography is an emerging technology unsurpassed for locating groundwater discharges. Thermography can be used to locate submerged discharges that are extremely difficult to find by other means. In two large projects, thermography was used to identify almost every significant spring at sites underlain by karst aquifers. This technology effectively converts Brown's Type 5 topology to types 1 or 2 (all discharges known), which has a significant impact on dye tracing. At a north Alabama site, springs located by thermography quadrupled the known groundwater discharge in and around the site. For submerged discharges, thermographic temperatures can be measured down the center of the groundwater plume that rises to the surface in the winter. Using the Cornell Mixing (CORMIX) model, flow rate for one submerged spring was estimated. Once identified, estimates of spring recharge area were desired. The size of the area of recharge was estimated by hydrograph separation of flow data from nearby, unregulated surface streams. Monthly recharge estimates were also made and used to show that in north Alabama the mean annual recharge/discharge occurs during May and December. Spring flow measurements for the same county of north Alabama were averaged to obtain mean flows. Then measurements for May only, were averaged. The two averages usually agreed to within 20 percent. This provides evidence that hydrograph separation determinations of recharge are valid.

Campbell, C. Warren↗

RFI to CMS: An Approach to Regulatory Acceptance of Site Remediation Technologies

Lockheed Martin made a smooth transition from RCRA Facility Investigation (RFI) at the National Aeronautics and Space Administrations'(NASA) Michoud Assembly Facility (MA-F) to its Corrective Measures Study (CMS) phase within the RCRA Corrective Action Process. We located trichloroethylene (TCE) contamination that resulted from the manufacture of the Apollo Program Saturn V rocket and the Space Shuttle External Tank, began the cleanup, and identified appropriate technologies for final remedies. This was accomplished by establishing a close working relationship with the state environmental regulatory agency through each step of the process, and resulted in receiving approvals for each of those steps. The agency has designated Lockheed Martin's management of the TCE-contamination at the MAF site as a model for other manufacturing sites in a similar situation. In February 1984, the Louisiana Department of Environmental Quality (LDEQ) issued a compliance order to begin the clean up of groundwater contaminated with TCE. In April 1984 Lockheed Martin began operating a groundwater recovery well to capture the TCE plume. The well not only removes contaminants, but also sustains an inward groundwater hydraulic gradient so that the potential offsite migration of the TCE plume is greatly diminished. This effort was successful, and for the agency to give orders and for a regulated industry to follow them is standard procedure, but this is a passive approach to solving environmental problems. The goal of the company thereafter was to take a leadership, proactive role and guide the MAF contamination clean up to its best conclusion at minimum time and lowest cost to NASA. To accomplish this goal, we have established a positive working relationship with LDEQ, involving them interactively in the implementation of advanced remedial activities at MAF as outlined in the following paragraphs.

Rowland, Martin A.↗

Representation of Stormflow and a More Responsive Water Table in a TOPMODEL-Based Hydrology Model

This study presents two new modeling strategies. First, a methodology for representing the physical process of stormflow within a TOPMODEL framework is developed. In using this approach, discharge at quickflow time scales is simulated and a fuller depiction of hydrologic activity is brought about. Discharge of water from the vadose zone is permitted in a physically realistic manner without a priori assumption of the level within the soil column at which stormflow saturation can take place. Determination of the stormflow contribution to discharge is made using the equation for groundwater flow. No new parameters are needed. Instead, regions of near saturation that develop during storm events, producing vertical recharge, are allowed to contribute to soil column discharge. These stormflow contributions to river runoff, as for groundwater flow contributions, are a function of catchment topography and local hydraulic conductivity at the depth of these regions of near saturation. The second approach improves groundwater flow response through a reduction of porosity and field capacity with depth in the soil column. Large storm events are better captured and a more dynamic water table develops with application of this modified soil column profile (MSCP). The MSCP predominantly reflects soil depth differences in upland and lowland regions of a watershed. Combined, these two approaches - stormflow and the MSCP - provide a more accurate representation of the time scales at which soil column discharge responds and a more complete depiction of hydrologic activity. Storm events large and small are better simulated, and some of the biases previously evident in TOPMODEL simulations are reduced.

Shaman, Jeffrey↗

A Preliminary Relationship Between the Depth of Martian Gullies and the Abundance of Hydrogen on Near-Surface Mars

Recent compelling evidence has been presented to suggest the presence of near-surface water or water ice on Mars. The Mars Orbiter Camera (MOC) has photographed relatively young fluvial features in the form of gullies which have been attributed to groundwater seepage. The Gamma Ray Spectrometer (GRS) from the Mars Odyssey spacecraft has detected large amounts of hydrogen in the Martian soil, inferred to come from water or water ice within the upper meter of the surface. We explore the model of groundwater seepage as the mechanism of gully formation as opposed to other mechanisms. We investigate the abundance of hydrogen to the depth at which gully-like features form. We see a positive correlation, which implies the presence of a groundwater system for Mars.

Frey, E. L.↗

Chlorine stable isotopes in sedimentary systems: does size matter?

Stable isotope abundances vary because of size differences. The chlorine stable isotope system was one of the first described theoretically, but had a slow, disappointment strewn development, relative to other elements. Method improvement gave only small, but significant, differences in compositions of geological materials. Eventually, brines and groundwater chlorides gave larger differences. Physical processes like diffusion and adsorption, probably are the main controls of groundwater compositions. Recent work on anthropogenic groundwater contaminants shows variations resulting from manufacturing processes; implying possibilities of tracing sources.

chlorine stable isotopes↗

Possible Link Between Irrigation in the U.S. High Plains and Increased Summer Streamflow in the Midwest

We have previously presented evidence that higher rates of evapotranspiration (ET) associated with irrigation in the U.S. High Plains has likely caused an increased downwind precipitation (P). July P over the Midwest increased by 20%-30% from the pre-irrigation period (1900-1950) to the post-irrigation (1950-2000) period. In this study, we test the hypothesis that the increased July P has had hydrologic consequences, possibly increasing groundwater storage and streamflow. Seasonal analyses of hydrologic variables over Illinois suggest that the water table and streamflow response lags P - ET by 1-2 months, indicating August and September as the months when the increased July P may be detected. We analyzed long-term observations of water table depth at 10 wells in Illinois and streamflow at 46 gauges in Illinois-Ohio basins. The Mann-Kendal test for trends suggests field significant increases in groundwater storage and streamflow in August-September over the period of irrigation expansion. Examination of soil moisture response to present-day above-normal July P suggests that the increased July P can reach the water table in normal to wet years. Mann-Kendall tests suggest that there has been no change in pan evaporation and atmospheric vapor pressure deficit. This implies that soil water availability is the driver of changes in ET, and the increased P may have possibly increased ET. Other studies in the literature give further evidence of increased ET due to increased P. By ruling out a reduction in ET, we suggest that the observed increase in groundwater storage and streamflow in the Midwest is linked to the increased July precipitation attributed to High Plains irrigation. We note that the increases in late summer streamflow are rather small when placed in the context of seasonal dynamics, but they are conceptually important in that they point to a different cause of change.

Kustu, M. Deniz↗

Using Enhanced Grace Water Storage Data to Improve Drought Detection by the U.S. and North American Drought Monitors

NASA's Gravity Recovery and Climate Experiment (GRACE) satellites measure time variations of the Earth's gravity field enabling reliable detection of spatio-temporal variations in total terrestrial water storage (TWS), including groundwater. The U.S. and North American Drought Monitors rely heavily on precipitation indices and do not currently incorporate systematic observations of deep soil moisture and groundwater storage conditions. Thus GRACE has great potential to improve the Drought Monitors by filling this observational gap. GRACE TWS data were assimilating into the Catchment Land Surface Model using an ensemble Kalman smoother enabling spatial and temporal downscaling and vertical decomposition into soil moisture and groundwater components. The Drought Monitors combine several short- and long-term drought indicators expressed in percentiles as a reference to their historical frequency of occurrence. To be consistent, we generated a climatology of estimated soil moisture and ground water based on a 60-year Catchment model simulation, which was used to convert seven years of GRACE assimilated fields into drought indicator percentiles. At this stage we provide a preliminary evaluation of the GRACE assimilated moisture and indicator fields.

Houborg, Rasmus↗

Fate of Water Pumped from Underground and Contributions to Sea Level Rise

The contributions from terrestrial water sources to sea-level rise, other than ice caps and glaciers, are highly uncertain and heavily debated1-5. Recent assessments indicate that groundwater depletion (GWD) may become the most important positive terrestrial contribution6-10 over the next 50 years, probably equal in magnitude to the current contributions from glaciers and ice caps6. However, the existing estimates assume that nearly 100% of groundwater extracted eventually ends up in the oceans. Owing to limited knowledge of the pathways and mechanisms governing the ultimate fate of pumped groundwater, the relative fraction of global GWD that contributes to sea-level rise remains unknown. Here, using a coupled climate-hydrological model11,12 simulation, we show that only 80% of GWDends up in the ocean. An increase in runo to the ocean accounts for roughly two-thirds, whereas the remainder results from the enhanced net flux of precipitation minus evaporation over the ocean, due to increased atmospheric vapour transport from the land to the ocean. The contribution of GWD to global sea-level rise amounted to 0.02 (+/- 0.004)mm yr(sup-1) in 1900 and increased to 0.27 (+/- 0.04)mm yr(sup-1) in 2000. This indicates that existing studies have substantially overestimated the contribution of GWD to global sea-level rise by a cumulative amount of at least 10 mm during the twentieth century and early twenty-first century. With other terrestrial water contributions included, we estimate the net terrestrial water contribution during the period 1993-2010 to be +0.12 +/-0.04)mm yr(sup-1), suggesting that the net terrestrialwater contribution reported in the IPCC Fifth Assessment Report report is probably overestimated by a factor of three.

water↗

Assimilation of GRACE Terrestrial Water Storage Observations into a Land Surface Model for the Assessment of Regional Flood Potential

We evaluate performance of the Catchment Land Surface Model (CLSM) under flood conditions after the assimilation of observations of the terrestrial water storage anomaly (TWSA) from NASA's Gravity Recovery and Climate Experiment (GRACE). Assimilation offers three key benefits for the viability of GRACE observations to operational applications: (1) near-real time analysis; (2) a downscaling of GRACE's coarse spatial resolution; and (3) state disaggregation of the vertically-integrated TWSA. We select the 2011 flood event in the Missouri river basin as a case study, and find that assimilation generally made the model wetter in the months preceding flood. We compare model outputs with observations from 14 USGS groundwater wells to assess improvements after assimilation. Finally, we examine disaggregated water storage information to improve the mechanistic understanding of event generation. Validation establishes that assimilation improved the model skill substantially, increasing regional groundwater anomaly correlation from 0.58 to 0.86. For the 2011 flood event in the Missouri river basin, results show that groundwater and snow water equivalent were contributors to pre-event flood potential, providing spatially-distributed early warning information.

flood↗