Ion-molecule reactions of hydrogen sulfide with ethylene and acetylene
Ion-molecule reactions in mixtures of hydrogen sulfide with ethylene and acetylene from deuterium labeling studies via ion cyclotron resonance spectroscopy
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Ion-molecule reactions in mixtures of hydrogen sulfide with ethylene and acetylene from deuterium labeling studies via ion cyclotron resonance spectroscopy
Latitudinal variations in H and He ion distribution in upper ionosphere observed by OGO 2 and 4 satellites during rising solar activity
The simultaneous time-dependent continuity equations for O(+), H(+) and He(+) in the low latitude F-region are solved. Account is taken of E x B drift, a meridional neutral wind, and ion-ion and ion-neutral drag. The calculated profiles of O(+) and H(+) concentrations at 1630 LT are in fair agreement with the observations of Hanson et al. The He(+) field-aligned velocity is almost matched to the O(+) field-aligned velocity and, above the chemical equilibrium region and around the He(+) peak, the He(+) concentration is determined largely by production and transport. There is disagreement between the theoretical vertical He(+) profile and the profile observed by Hanson et al. Satisfactory agreement is obtained with Taylor's satellite results at fixed height for O(+) and H(+). It is found that the He(+) concentration is greater in the winter hemisphere than in the summer hemisphere, even if the neutral helium distribution is symmetrical about the Equator. The He(+) results are consistent with Taylor's results.
Electrostatic ion cyclotron turbulence and the associated acceleration of ions on auroral field lines are investigated analytically and by plasma simulations. The auroral plasma is assumed to consist of drifting electrons and stationary hydrogen and oxygen ions. It is found that for a given critical drift, the maximum ion perpendicular heating is generally larger for oxygen ions than for hydrogen ions. Simulation results show that unless the oxygen ions are a minority species, oxygen transverse heating generally exceeds that of hydrogen ions. Theory and numerical simulations are in good agreement.
By the use of a new theory developed for collisions between atomic hydrogen and arbitrary ions or atoms, the cross section for the direct excitation process He(+)(1s) + H(1s) yields He(+)(2s) + H(Sigma) in which the H atom is left in any discrete or continuum final state is calculated. The results are compared with other theories and with recent measurements for He-3(+) energies between 22 and 346 keV. The theory predicts a maximum near 84 keV, in excellent agreement with the data. Above 200 keV all theories yield cross sections which do not decrease rapidly enough with increasing energy when compared with the data.
Direct interaction between hydrogen atom and positive ion with one electron, using Born and two and four state impact parameter treatments
Pumping speeds of diode and triode getter-ion pumps measured for hydrogen, helium, and nitrogen at low pressures
Solar wind composition is dominated by hydrogen (approx.96%) and helium (approx.3 to 4%) with a minor fraction (less than or equal to 1%) of heavy ions. Hydrogen (helium) ions impact spacecraft surfaces with energies from 0.5 to 5 keV (1.8 to 21 keV) due to variations in solar wind velocity from 300 km/s to 1000 km/sec with extremes of a few 10 s keV during periods of extremely high solar wind velocity exceeding 1000 km/sec. Mean impact energies are typically on the order of approximately 1 keV and 4 keV for hydrogen ions and helium ions, respectively. These energies are typically of the peak of the energy dependent light ion sputter yields for hydrogen and helium on many metals. In addition, light ions with kilovolt energies have been shown to produce blister (or exfoliation) damage to metal surfaces due to formation of high pressure gas bubbles within the materials when exposed to ion fluences on the order of 10(exp 16 to (10(exp 17 ions/sq cm. A number of spacecraft designs for current and future missions include gossamer polymer structures with thin metallic reflection coatings to shield instruments from the Sun or solar sail propulsion systems for use in a variety of locations in the inner solar system from 0.5 to 1 AU. In addition, there is interest in designing spacecraft for solar physics missions requiring operations as close to the Sun as 0.16 to 0.2 AU. Integrity of the metallic coatings is critical in many of these applications since degradation will result in modification of material thermal properties or exposure of polymers to solar UV photons which can compromise mission requirements. This paper will evaluate the relative contributions of sputtering and blister formation to material degradation in solar wind environments over a range of radial distances from the Sun to demonstrate where solar wind environments become important for materials selection. We will first review the physics and results from laboratory measurements of light ion sputtering, blistering, and exfoliation of metallic surfaces to establish the order of magnitude ion fluence required for significant surface damage. Solar wind ion fluence environments will then be evaluated due to variations in solar wind conditions as a function of solar cycle for varying distances from the Sun using models for radial variations in solar wind ion number density, temperature, and velocity to determine where sputtering and blistering is most likely to be an issue. Finally, ion fluence statistics for varying radial distances from the Sun will be shown to establish the mission duration and radial distances from the Sun where missions will encounter sufficient ion fluence to exhibit damage to metallic surfaces.
The ion implantation in a crystal such as silicon carbide will cause both damage in the ion track and in the substrate at the end of the ion track. We used both keV, and MeV Pd ions in fabricating electronic chemical sensors in silicon carbide, which can operate at elevated temperatures. In order to study the feasibility of fabricating an optical chemical sensor (litmus sensor), we need to understand the optical behavior of the embedded damage in the presence of hydrogen, as well as the potential chemical interaction of silicon carbide broken lattice bonds with the hydrogen dissociated from gas by palladium. Implanted samples of silicon carbide were studied using both Raman spectroscopy and FTIR (Fourier Transform-Infrared). The results of this work will be presented during the meeting.
The coherent three-wave decay of a linearly unstable electrostatic hydrogen cyclotron (EHC) wave into stable EHC and ion acoustic modes is considered. The general problem of the three weakly interacting electrostatic normal modes in a Maxwellian plasma is discussed. EHC is examined in a fluid description, and the results are used to guide a similar study in a Vlasov plasma system intended to model the aurora acceleration region parameters. The time dependence of the decay in a simple three-wave interaction is presented in order to show how wave saturation can arise.
The stability of HOC(+) ions under conditions in interstellar molecular clouds is considered. In particular, the possibility that collisions with helium or hydrogen will induce isomerization to the stable HCO(+) form is examined theoretically. Portions of the electronic potential energy surfaces for interaction with He and H atoms are obtained from standard quantum mechanical calculations. Collisions with He atoms are found to be totally ineffective for inducing isomerization. Collisions with H atoms are found to be ineffective at low interstellar temperatures owing to a small (about 500 K) barrier in the entrance channel; at higher temperatures where this barrier can be overcome, however, collisions with hydrogen atoms do result in conversion to the stable HCO(+) form. Although detailed calculations are not presented, it is argued that low-energy collisions with H2 molecules are also ineffective in destroying the metastable ion.
A compilation is made of those interactions between hydrogen and helium atoms and ions whose potential curves are well established by virtue of being based on experimental data or on essentially exact quantum-mechanical calculations. These potential curves have been fitted with well-known empirical forms which should be useful in calculations of transport properties involving these interactions.
Rayleigh-Schroedinger perturbation calculations for ground state of one-electron helium-hydrogen molecular ion
The thermal energy, bimolecular ion-molecule reactions occurring in gaseous water, hydrogen sulfide, ammonia, and methane have been identified and their rate constants determined using ion cyclotron resonance methods. Absolute rate constants were determined for the disappearance of the primary ions by using the trapped ion method, and product distributions were determined for these reactions by using the cyclotron ejection method. Previous measurements are reviewed and compared with the results using the present methods. The relative rate constants for hydrogen-atom abstraction, proton transfer, and charge transfer are also determined for reactions of the parent ions.
Recent satellite observations at high altitudes (above 5000 km) in the auroral zone have shown the existence of hybrid or bimodal ion beam distributions that are evidence of both parallel and perpendicular ion acceleration. To study the nonlinear effects of the ion-ion instability in terms of plasma heating, a numerical simulation parametric study has been performed. It was found that the parallel acceleration that forms the ion beams occurs on a time scale faster than ion-ion wave growth at low drifts; thus ion-ion wave growth is expected to occur primarily for higher drift speeds, which results in strong oblique heating of the ions (both hydrogen and oxygen) forming elevated ion conics.
Recent satellite observations at high altitudes (greater than 5000 km) in the auroral zone have shown the existence of hybrid or bimodal ion beam distributions that are evidence of both parallel and perpendicular ion acceleration. Acceleration parallel to the magnetic field is most likely due to quasi-static electric fields (double layers) which can create outflowing ion beams; since ions of different mass will have different drift speeds due to this acceleration, a plasma configuration unstable to the ion-ion two-stream acoustic mode develops. When the net drift velocity (U) between the two ion species is greater than the sound speed (C(sub 0)), the ion-ion instability has maximum growth at oblique wave propagation. To study the nonlinear effects of the ion-ion instability in terms of plasma heating, a numerical simulation parametric study has been performed. It was found that the parallel acceleration that forms the ion beams occurs on a time scale faster than ion- ion wave growth at low drifts; thus ion-ion wave growth is expected to occur primarily for higher drift speeds (U greater than C(sub 0)) which results in strong oblique heating of the ions (both hydrogen and oxygen) forming elevated ion conics (sometimes called 'bowl' distributions). Also, strong parallel electron heating in the direction of the ion beams can occur, and electrons near the top of the acceleration region may attain a net upward drift along with the elevated ion conics. Variation of the oxygen density greatly affects the ion heating due to the ion-ion instability; as the oxygen density decreases, oxygen heating increases, in agreement with observations (Collin et al., 1987). Ion-ion electrostatic wave properties and the plasma heating that results over a wide range of auroral zone parameters are included.
Observations in recent years indicate the presence of energetic ions of ionospheric origin in various parts of the magnetosphere. These energetic ions have been found at all latitudes. Observations from the S3-3 satellite have made a great contribution toward an understanding of the energization of ionospheric ions. One of the most interesting observations is related to the finding that ion beams and electrostatic hydrogen cyclotron (EHC) waves are highly correlated and that they show an abrupt increase in their occurrence rate at an altitude of about 5000 km. A statistical survey of upward flowing ion (UFI) events occurring between 6000 and 8000 km has shown that the average energy of O(+) has a strong correlation with that of the H(+) ions. The present investigation has the objective to examine critically the energetics of UFI events in view of the theory of the interaction of a single coherent EHC wave with O(+), He(+), and H(+) ions. It is found that preferential acceleration of heavy ions occurs when such ions interact with an EHC wave.
R.f. power transfer to a hydrogen plasma at frequencies near the ion cyclotron frequency