Effect of acetylsalicylic acid and ascorbic acid on oxygen toxicity
Acetylsalicylic and ascorbic acids effects on mice susceptibility to oxygen toxicity, discussing in vitro sensitivity of red cells to hydrogen peroxide
Jefferson, D.↗
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Research on rechargeable oxygen electrodes
Studies were carried out on a number of factors which may influence the behavior of the platinum electrocatalyst of oxygen electrodes for use in rechargeable metal-oxygen batteries or hydrogen-oxygen fuel cells. The effects of pretreatments for various potentials and added ionic species, which could be present in such systems, were studied with reguard to: (1) the state of surface oxidation, (2) platinum dissolution, (3) the kinetics of oxygen evolution and reduction (including the role of hydrogen peroxide), and (4) changes in porous electrode structure. These studies were carried out on smooth platinum, platinized platinum, and Teflon-bonded platinum black electrodes in carefully purified electrolyte solutions. The main factors which appear to affect rechargeable oxygen electrode performance and life are: (1) the buildup of a refractory anodic layer on extended cycling, and (2) the dissolution of platinum.
Giner, J.↗
Development of a tape transport bacterial detection system
The feasibility of a tape transport chemiluminescence system for bacterial monitoring of regenerated water was demonstrated using a manually operated laboratory breadboard. The principle of detection is based on measuring the increase in chemiluminescence produced by the catalytic action of bacterial porphyrins on a luminol-hydrogen peroxide mixture. Viable organisms are distinguished from nonviable by comparing the signals of incubated and unincubated water samples. Using optimized protocols, sensitivities were obtained with 400 ml suspensions of E. coli and Cl. sporogenes. The sensitivity of the unincubated cycle E. coli (aerobe) was found to be 30 to 35 cells/m1, and that of the Cl. sporogenes (anaerobe) was 1000 to 10,000 cells/m1. The lower sensitivity toward Cl. sporogenes is attributed to several factors, namely the lower cytochrome content, the tendency to sporulate, long lag periods and the lower growth rate of Clostridia in general. The operational procedures used for processing the incubated and unincubated samples involved the following sequence: (1) concentrating the sample by filtration through a membrane filter, (2) washing with Dextrose-Thioglycollate Broth (3) incubating (0 to 4 hrs as required), (4) washing with 4M Urea, and (5) reacting with reagent in front of a photomultiplier tube. The signal output was recorded on a strip chart recorder.
Witz, S.↗
Research on rechargeable oxygen electrodes.
A research program is described which consisted of studying the effects of electrode cycling in very pure KOH solutions, with and without controlled additions of impurities, on oxide formation, oxygen evolution kinetics, oxygen reduction kinetics (including hydrogen peroxide formation), and changes in electrode structure. Bright platinum, platinized platinum, and Teflon-bonded platinum black electrodes were studied. Three main problem areas are identified: the buildup of a refractory anodic layer on prolonged cycling, which leads to a degradation of performance; the dissolution and subsequent deposition of dendritic platinum in the separator, leading to short-circuit ing and loss of electrocatalyst; and the disruptive effect of bubbling during gas evolution on charge. Each of these problem areas is analyzed, and remedial solutions are proposed.
Giner, J.↗
Design criteria monograph for liquid propellant gas generators
Monograph reviews and assesses current design practices, and from them establishes firm guidance for achieving greater consistency in design, increased reliability in end product, and greater efficiency in design effort. Main emphasis of monograph is on bipropellant gas generators using hydrogen peroxide and hydrazine monopropellants.
Source record↗
Two phase detonation studies
An experimental study of the passage of a shock wave over a burning fuel drop is described. This includes high speed framing photographs of the interaction taken at 500,000 frames per second. A theoretical prediction of the ignition of a fuel drop by a shock wave is presented and the results compared with earlier experimental work. Experimental attempts to generate a detonation in a liquid fuel drop (kerosene)-liquid oxidizer drop (hydrogen peroxide)-inert gas-environment are described. An appendix is included which gives the analytical prediction of power requirements for the drop generator to produce certain size drops at a certain mass rate. A bibliography is also included which lists all of the publications resulting from this research grant.
Nicholls, J. A.↗
Cassette bacteria detection system
The design, fabrication, and testing of an automatic bacteria detection system, with a zero-g capability, based on the filter-capable approach, and intended for monitoring the sterility of regenerated water in spacecraft is discussed. The principle of detection is based on measuring the increase in chemiluminescence produced by the action of bacterial porphyrins on a luminol-hydrogen peroxide mixture. Viable organisms are detected by comparing the signal of an incubated water sample with an unincubated control. High signals for the incubated water sample indicate the presence of viable organisms.
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Absorption cross sections of stratospheric molecules
Two classes of molecular species must be considered in a calculation of photochemical rates in the stratosphere. The first class consists of molecular oxygen and ozone, while the second class contains the remainder of the minor constituents. If accurate values of the transmitted fluxes are required at large optical depths, the cross sections for molecular oxygen and ozone must be known to within a few per cent at least. On the other hand, the photochemical rates for the minor species are given simply by the relevant cross sections. A review of published cross sections is presented, giving attention to molecular oxygen, ozone, nitric oxide, nitrogen dioxide, nitrous oxide, nitric acid, ammonia, water vapor, hydrogen peroxide, carbon monoxide, carbon dioxide, and sulfur dioxide.
Hudson, R. D.↗
Results of TC-1 boost pump icing tests in the space power facility
A series of tests were conducted in the space power facility to investigate the failure of the Centaur oxidizer boost pump during the Titan/Centaur proof flight February 11, 1974. The three basic objectives of the tests were: (1) demonstrate if an evaporative freezing type failure mechanism could have prevented the pump from operating, (2) determine if steam from the exhaust of one of the attitude control engine could have entered a pump seal cavity and caused the failure, and (3) obtain data on the heating effects of the exhaust plume from a hydrogen peroxide attitude control engine.
Gentile, L. C.↗
Environmental crack-growth behavior of high strength pressure vessel alloys
Results of sustained-load environmental crack growth threshold tests performed on six spacecraft pressure vessel alloys are presented. The alloys were Inconel 718, 6Al-4V titanium, A-286 steel, AM-350 stainless steel, cryoformed AISI 301 stainless steel; and cryoformed AISI 304L steel. The test environments for the program were air, pressurized gases of hydrogen, oxygen, nitrogen, and carbon dioxide, and liquid environments of distilled water, sea water, nitrogen tetroxide, hydrazine, aerozine 50, monomethyl hydrazine, and hydrogen peroxide. Surface flaw type specimens were used with flaws located in both base metal and weld metal.
Forman, R. G.↗
Centaur propellant acquisition system study
A study was performed to determine the desirability of replacing the hydrogen peroxide settling system on the Centaur D-1S with a capillary acquisition system. A comprehensive screening was performed to select the most promising capillary device fluid acquisition, thermal conditioning, and fabrication techniques. Refillable start baskets and bypass feed start tanks were selected for detailed design. Critical analysis areas were settling and refilling, start sequence development with an initially dry boost pump, and cooling the fluid delivered to the boost pump in order to provide necessary net position suction head (NPSH). Design drawings were prepared for the start basket and start tank concepts for both LO2 and LH2 tanks. System comparisons indicated that the start baskets using wicking for thermal conditioning, and thermal subcooling for boost pump NPSH, are the most desirable systems for future development.
Blatt, M. H.↗
Investigation of the Centaur boost pump overspeed condition at main engine shutdown on the Titan Centaur TC-2 flight
An investigation was conducted to evaluate a potential boost pump overspeed condition which could exist on the Titan/Centaur launch vehicle after main engine shut-off. Preliminary analyses indicated that the acceleration imparted to the unloaded boost pump-turbine assembly, caused by purging residual hydrogen peroxide from the turbine supply lines, could result in a pump-turbine overspeed. Previous test experience indicated that turbine damage occurs at speeds in excess of 75,000 rpm. Detailed theoretical analyses, in conjunction with pump tests, were conducted to establish the maximum pump-turbine speed at main engine shut-off. The analyses predicted a maximum speed of 68,000 rpm. Testing showed the pump-turbine speed to be 66,700 rpm in the overspeed condition. Inasmuch as both the analysis and tests showed the overspeed to be sufficiently less than the speed at which damage could occur, it was concluded that no corrective action would be required for the launch vehicle.
Baud, K. W.↗
Applications of chemiluminescence to bacterial analysis
Luminol chemiluminescence method for detecting bacteria was based on microbial activation of the oxidation of the luminol monoanion by hydrogen peroxide. Elimination of the prior lysing step, previously used in the chemiluminescence technique, was shown to improve considerably the reproducibility and accuracy of the method in addition to simplifying it. An inexpensive, portable photomultiplier detector was used to measure the maximum light intensity produced when the sample is added to the reagent. Studies of cooling tower water show that the luminol chemiluminescence technique can be used to monitor changes in viable cell population both under normal conditions and during chlorine treatment. Good correlation between chemiluminescence and plate counts was also obtained in the analysis of process water used in paper mills. This method showed good potential for monitoring the viable bacteria populations in activated sludge used in waste treatment plants to digest organic matter.
Searle, N. D.↗
Investigation of effect of propulsion system installation and operation on aerodynamics of an airbreathing hypersonic airplane at Mach 0.3 to 1.2
Results from an investigation of the effects of the operation of a combined turbojet/scramjet propulsion system on the longitudinal aerodynamic characteristics of a 1/60-scale hypersonic airbreathing launch vehicle configuration are presented. Decomposition products of hydrogen peroxide were used for simulation of the propulsion system exhaust.
Cubbage, J. M.↗
Biological water quality monitoring using chemiluminescent and bioluminescent techniques
Automated chemiluminescence and bioluminescence sensors were developed for the continuous monitoring of microbial levels in water supplies. The optimal chemical procedures were determined for the chemiluminescence system to achieve maximum sensitivity. By using hydrogen peroxide, reaction rate differentiation, ethylene diamine tetraacetic acid (EDTA), and carbon monoxide pretreatments, factors which cause interference were eliminated and specificity of the reaction for living and dead bacteria was greatly increased. By employing existing technology with some modifications, a sensitive and specific bioluminescent system was developed.
Thomas, R. R.↗
Implications of the hypohydrous history of Mars
The extent to which fluvial processes occurred in Mars is considered with reference to the oxidation of soil organics by the gamma-Fe2O3/H2O2 system. Data from the Viking biology experiments suggest that the acidity of gamma-Fe2O3 controls the ionization of hydrogen peroxide - that is, in acid conditions and in the presence of large concentrations of formate, gamma-Fe2O3 reacts efficiently with peroxide to oxidize formate to CO2 and H2O. Fe3O4, alpha-Fe2O3, and calcite are basic and block the oxidation of formate. The properties of this system are consistent with the hypothesis that Mars has been under a severe regime of dryness.
Oyama, V. I.↗
Analysis and interpretation of Viking labeled release experimental results
The Viking Labeled Release (LR) life detection experiment on the surface of Mars produced data consistent with a biological interpretation. In considering the plausibility of this interpretation, terrestrial life forms were identified which could serve as models for Martian microbial life. Prominent among these models are lichens which are known to survive for years in a state of cryptobiosis, to grow in hostile polar environments, to exist on atmospheric nitrogen as sole nitrogen source, and to survive without liquid water by absorbing water directly from the atmosphere. Another model is derived from the endolithic bacteria found in the dry Antarctic valleys; preliminary experiments conducted with samples of these bacteria indicate that they produce positive LR responses approximating the Mars results. However, because of the hositility of the Martian environment to life, and the failure to find organics on the surface of Mars, a number of nonbiological explanations were advanced to account for the Viking LR data. A reaction of the LR nutrient with putative surface hydrogen peroxide is the leading candidate. Other possibilities raised include reactions caused by or with ultraviolet irradiation, gamma-Fe2O3, metalloperoxides or superoxides.
Levin, G. V.↗
Some results from the use of a control augmentation system to study the developed spin of a light plane
A control augmentation system consisting of hydrogen peroxide rockets mounted on the wing tips of a light airplane has been developed and used to study spin recovery characteristics. Recovery from spins that were unrecoverable with aerodynamic controls was accomplished in less than one turn at maximum thrust in about three turns at minimum thrust. The rocket system at maximum thrust produced spin recovery characteristics similar to those obtained using a parachute. An advantage of using the control augmentation system on any airplane being used in a spin test program is its capability to demonstrate configuration effects on stall/spin characteristics at very high angles of attack and clearly determine the existence of all possible spin modes.
Obryan, T. C.↗