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All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

An overview of the measurements of thermophysical properties and some results on molten superalloys and semiconductors

This presentation consists of two parts: comments on the results of measurements on thermophysical properties based on the paper, 'Things Mother Never Taught Me (About Thermophysical Properties of Solids)' and results of thermophysical property measurements on selected solid and molten semiconductors and a proprietary superalloy. The first part may be considered as a tutorial for those involved in using or procuring thermophysical property data. The second part is presented as illustrations of what has been accomplished on molten materials at the Thermophysical Properties Research Laboratory (TPRL). The materials include Ge, PbTe, PbSnTe, HgCdTe and a superalloy.

Taylor, R. E.↗
NASA NTRS1994

Preliminary flight results from the second U.S. Microgravity Payload (USMP-2)

The second U.S. Microgravity Payload (USMP-2) was flown on the Space Shuttle in March 1994. It carried four major microgravity experiments plus a sophisticated accelerometer system to record the microgravity environment during USMP-2 operations. The USMP program is designed to accommodate experiments requiring extensive resources short of a full Spacelab mission, and the experiments are remotely operated and monitored. Results are reviewed from the four experiments: the Advanced Automated Directional Solidification Facility (AADSF), the Isothermal Dendrite Growth Experiment (IDGE), the Materiel por Etude des Phenomenes Interessant la Soldification sur Terre et en Orbite (MEPHISTO), and the Critical Fluid Light Scattering Experiment (Zeno). AASDF grew what is expected to be the largest steady-state sample ever of HgCdTe during 240 hours of operation. IDGE provided 60 growth cycles over a wide range of supercooling conditions studying the dendritic solidification of succinonitrile. MEPHISTO achieved 55 melt-solidify cycles and grew over 1 m of Bi/Sn alloy. Zeno located the critical point temperature for liquid Xe to 0.00001 K. IDGE and Zeno also provided the most extensive demonstrations to date of telescience.

Curreri, Peter↗
NASA NTRS1995

The JPL Field Emission Spectrometer

The Jet Propulsion Laboratory (JPL) Field Emission Spectrometer (FES) was built by Designs and Prototypes based on a set of functional requirements supplied by JPL. The instrument has a spectral resolution of 6 wavenumbers (wn) and can acquire spectra from either the Mid Infrared (3-5 mu m) or the Thermal Infrared (8-12 pm) depending on whether the InSb or HgCdTe detector is installed respectively. The instrument consists of an optical head system unit and battery. The optical head which is tripod mounted includes the interferometer and detector dewar assembly. Wavelength calibration of the interferometer is achieved using a Helium-Neon laser diode. The dewar needs replenishing with liquid Nitrogen approximately every four hours. The system unit includes the controls for operation and the computer used for acquiring viewing and processing spectra. Radiometric calibration is achieved with an external temperature-controlled blackbody that mounts on the fore-optics of the instrument. The blackbody can be set at 5 C increments between 10 and 55 C. The instrument is compact and weighs about 33 kg. Both the wavelength calibration and radiometric calibration of the instrument have been evaluated. The wavelength calibration was checked by comparison of the position of water features in a spectrum of the sky with their position in the output from a high resolution atmospheric model. The results indicatethat the features in the sky spectrum are within 6-8 wn of their position ill the model spectrum. The radiometric calibration was checked by first calibrating the instrument using the external blackbody supplied with the instrument and then measuring the radiance from another external blackbody at a series of temperatures. The temperatures of these radiance spectra were then recovered by inventing Planck's law and the recovered temperatures compared lo the measured blackbody temperature. These results indicate that radiometric calibration is good to 0.5 C over the range of temperatures 10 to 55 C. The results also indicate that the instrument drifts slowly over time and should be recalibrated every 20 to 30 minutes in the field to ensure good radiometric fidelity. The instrument has now been extensively tested in the field in the United States and Australia. These in situ field measurements are being used to validate emissivity spectra recovered from the Thermal Infrared Multispectral Scanner (TIMS) and also the Australian CO2 Laser. The availability of in situ measurements is proving crucial to validation of the spectra derived from the airborne instruments since many natural surfaces cannot be easily transported back to the laboratory.

Hook, Simon J.↗
NASA NTRS1994

KSPEC-a near-infrared cross-dispersed spectrograph

KSPEC (k-band spectrograph) is an infrared spectrograph designed primarily for spectroscopy in the 2.0-2.5 micrometer region. It offers two different optical configurations. The first is a cross-dispersed echelle mode designed to cover the atmospheric windows from 1-2.5 micrometer in one spectral frame of a 256x256 format on a Near Infrared Camera and Multi-Object Spectrometer-3 (NICMOS-3) HgCdTe detector array. This configuration of the spectrograph provides medium spectral resolution (lambda/delta-lambda approximately = 500) for spectral classification work, emission-line detection, and redshift measurements. Alternatively, KSPEC can be equipped with a different spectrograph camera, giving a long-slit, single-order spectrum from 2.05-2.35 micrometer. The instrument uses a second NICMOS-3 infrared detector array for slit viewing, to facilitate the acquisition of optically invisible objects, to document the slit position, and to monitor it during long spectroscopic integrations. KSPEC does not contain any moving components, making it a very reliable, relatively low-cost instrument that is easy to use.

Hodapp, Klaus-Werner↗
NASA NTRS1994

Ampoule failure sensor development for semiconductor crystal growth experiments

Currently there are no devices to detect an ampoule failure in semiconductor crystal growth experiments. If an ampoule fails, it will go undetected until the containing cartridge is breached due to chemical degradation. The experiment will then be terminated resulting in a failed experiment and a loss of data. The objective of this research was to develop a reliable failure sensor that would detect a specific liquid or vapor material before the metallic cartridge is degraded and the processing furnace contaminated. The sensor is a chemical fuse made from a metal with which the semiconductor material reacts more rapidly than it does with the containing cartridge. Upon ampoule failure, the sensor is exposed to the vapor or liquid semiconductor and the chemical reaction causes a resistance change in the sensor material. The sensor shows a step change in resistance on the order of megohms when exposed to mercury zinc telluride (HgZnTe), mercury cadmium telluride (HgCdTe), or gallium arsenide (GaAs). This ampoule failure sensor is being tested for possible use on the second United States Microgravity Mission (USML-2) and is the subject of a NASA patent application.

CHEMICAL FUSE↗
NASA NTRS1994

Infrared Speckle Interferometry with 2-D Arrays

We describe results from a program of speckle interferometry with two-dimensional infrared array detectors. Analysis of observations of eta Carinae made with 58 x 62 InSb detector are discussed. The data have been analyzed with both the Labeyrie autocorrelation, a deconvolution of shift-and-add data, and a phase restoration process. Development of a new camera based on a much lower noise HgCdTe detector will lead to a significant improvement i limiting magnitude for IR speckle interferometry.

Harvey, P. M.↗
NASA NTRS1996

The Advanced Automated Directional Solidification Furnace

The Advanced Automated Directional Solidification Furnace (AADSF) is a five zone tubular furnace designed for Bridgman-Stockbarger, other techniques of crystal growth involving multiple temperature zones such as vapor transport experiments and other materials science experiments. The five zones are primarily designed to produce uniform hot and cold temperature regions separated by an adiabatic region constructed of a heat extraction plate and an insert to reduce radiation from the hot to the cold zone. The hot and cold zone temperatures are designed to reach 1600 C and 1100 C, respectively. AADSF operates on a Multi-Purpose Experiment Support Structure (MPESS) within the cargo bay of the Space Shuttle on the United States Microgravity Payload (USMP) missions. Two successful flights, both employing the directional solidification or Bridgman Stockbarger technique for crystal growth have been made, and crystals of HgCdTe and PbSnTe grown in microgravity have been produced on USMP-2 and USMP-3, respectively. The addition of a Sample Exchange Mechanism (SEM) will enable three different samples to be processed on future flights including the USMP-4 mission.

Gillies, D. C.↗
NASA NTRS1998

Low Temperature Photoluminescence Characterization of Orbitally Grown CdZnTe

The II-VI ternary alloy CdZnTe is a technologically important material because of its use as a lattice matched substrate for HgCdTe based devices. The increasingly stringent requirements on performance that must be met by such large area infrared detectors also necessitates a higher quality substrate. Such substrate material is typically grown using the Bridgman technique. Due to the nature of bulk semiconductor growth, gravitationally dependent phenomena can adversely affect crystalline quality. The most direct way to alleviate this problem is by crystal growth in a reduced gravity environment. Since it requires hours, even days, to grow a high quality crystal, an orbiting space shuttle or space station provides a superb platform on which to conduct such research. For well over ten years NASA has been studying the effects of microgravity semiconductor crystal growth. This paper reports the results of photoluminescence characterization performed on an arbitrary grown CdZnTe bulk crystal.

Ritter, Timothy M.↗
NASA NTRS1999

Solidification of II-VI Compounds in a Rotating Magnetic Field

This project is aimed at using a rotating magnetic field (RMF) to control fluid flow and transport during directional solidification of elemental and compound melts. Microgravity experiments have demonstrated that small amounts of residual acceleration of less than a micro-g can initiate and prolong fluid flow, particularly when there is a static component of the field perpendicular to the liquid solid interface. Thus a true diffusion boundary layer is not formed, and it becomes difficult to verify theories of solidification or to achieve diffusion controlled solidification. The RMF superimposes a stirring effect on an electrically conducting liquid, and with appropriate field strengths and frequencies, controlled transport of material through a liquid column can be obtained. As diffusion conditions are precluded and complete mixing conditions prevail, the technique is appropriate for traveling solvent zone or float zone growth methods in which the overall composition of the liquid can be maintained throughout the growth experiment. Crystals grown by RMF techniques in microgravity in previous, unrelated missions have shown exceptional properties. The objective of the project is two-fold, namely (1) using numerical modeling to simulate the behavior of a solvent zone with applied thermal boundary conditions and demonstrate the effects of decreasing gravity levels, or an increasing applied RMF, or both, and (2) to grow elements and II-VI compounds from traveling solvent zones both with and without applied RMFs, and to determine objectively how well the modeling predicts solidification parameters. Numerical modeling has demonstrated that, in the growth of CdTe from a tellurium solution, a rotating magnetic field can advantageously modify the shape of the liquid solid interface such that the interface is convex as seen from the liquid. Under such circumstances, the defect structure is reduced as any defects which are formed tend to grow out and not propagate. The flow of liquid, however, is complex due to the competing flow induced by the rotating magnetic field and the buoyancy driven convection. When the acceleration forces are reduced to one thousandth of gravity, the flow pattern is much simplified and well controlled material transport through the solvent zone can be readily achieved. Triple axis diffractometry and x-ray synchrotron topography have demonstrated that there is no significant improvement in crystal quality for HgCdTe grown on earth from a tellurium solution when a rotating magnetic field is applied. However, modeling shows that the flow in microgravity with a rotating magnetic field would produce a superior product.

Gillies, D. C.↗
NASA NTRS1999

Effects of an Applied Magnetic Field on the Directional Solidification of Hg(1-x)Zn(x)Se Alloys

Directionally solidified Hg(0.9)Zn(0.1)Se alloys were studied as an alternative to HgCdTe for the detection of electromagnetic radiation because of predicted improvements in lattice stability. Several boules were grown using a modified Bridgman-Stockbarger method and in an applied magnetic field. Axial compositional profiles showed mass transfer was primarily diffusion controlled. Radial compositional variations were greatly reduced when solidification occurred in an applied magnetic field. Microstructural characteristics and dislocation etch pit densities were greatly improved over HgTe based alloys. The extreme importance of processing conditions on defect generation was illustrated by comparing ampoule configurations and thermal profiles.

Cobb, S. D.↗
NASA NTRS1998

Shear/Defocus Sensitivity of the Mid Infrared Channel (MIR) of the Composite Infrared Spectrometer (CIRS) for the Cassini Mission to Saturn

The Composite Infrared Spectrometer (CIRS) of the Cassini mission to Saturn has two interferometers covering the far infrared and mid infrared wavelength region. The mid infrared wavelength interferometer has a focal plane consisting of a germanium focus lens and HgCdTe array. System level calibration of the CIRS Flight Unit indicated a discrepancy between the expected and actual signal levels. Testing on the CIRS breadboard and Engineering Unit indicated that defocus of the germanium lens could significantly reduce the modulation efficiency of the interferometer in the presence of a moderate degree of wavefront shear. Defocus of the lens in the focal plane was of concern because of the temperature dependence of the index of refraction of germanium and our nominal operation temperature of 170 K. The shear/defocus interaction was extensively investigated and correlated to a newly developed analytical model, It was eventually determined that the CIRS instrument was in focus, had no appreciable wavefront shear and was operating near theoretical limits. The shear/defocus effect is however, of considerable interest, since it has not been described in previous literature on interferometers.

Martino, Anthony J.↗
NASA NTRS1998

Magnetic Field Effect on Convective Fluid Flow in a Vertical Bridgman System

We studied the magnetic field effects on convective fluid flow in a differentially heated HgCdTe Bridgman growth system with linearly stratified vertical HgTe concentration. We followed J. E. Hart's system set-up, boundary conditions, and formulation. We obtained analytical steady parallel flow solutions for fluid flow's velocity and solutal concentration. These solutions depend only on solutal Rayleigh number. Our analytical solutions had different expressions from that of Hart's, but had similar numerical simulation results for the mean fluid velocity and solutal concentration gradient as a function of solutal Rayleigh number. We studied the effects of a transverse magnetic field on the fluid flow of the Bridgman growth systems both on the ground and in the space. The simulation results and comparison with experimental results will be presented.

Wang, J. C.↗
NASA NTRS1998

3-D Modeling of Directional Solidification of a Non-Dilute Alloy with Temperature and Concentration Fields Coupling via Materials Properties Dependence and via Double Diffusive Convection

Numerical simulation of the HgCdTe growth by the vertical Bridgman method was performed using FIDAP finite element code. Double-diffusive melt convection is analyzed, as the primary factor at controls inhomogeneity of the solidified material. Temperature and concentration fields in the model are also coupled via material properties, such as thermal and solutal expansion coefficients with the dependence on both temperature and concentration, and melting temperature evaluation from pseudobinary CdTe-HgTe phase diagram. Experimental measurements were used to obtain temperature boundary conditions. Parametric study of the melt convection dependence on the gravity conditions was undertaken. It was found, that the maximum convection velocity in the melt can be reduced under certain conditions. Optimal conditions to obtain a near flat solidified interface are discussed. The predicted interface shape is in agreement with one obtained experimentally by quenching. The results of 3-D calculations are compared with previous 2- D findings. A video film featuring 3-D melt convection will be presented.

Bune, Andris V.↗
NASA NTRS1999

Microstructural Development of Directionally Solidified Hg(1-x)Zn(x)Se Alloys

Hg(1-x)Zn(x)Se alloys have been studied as an alternative to Hg(1-x)Cd(x)Te for the detection of electromagnetic radiation, because the shorter ZnSe and HgSe bonds have been predicted to improve lattice stability. Several ingots with x = 0.1 were directionally solidified using a modified Bridgman-Stockbarger method; one was grown in an applied magnetic field, which greatly reduced radial compositional variations. A method was developed to reduce wetting. This, combined with the convex liquid-solid interface shape, produced boules that were single crystalline after growing about 3.5 cm. Observed surface features indicated ampoule wetting was eliminated using a graphite getter. Microstructural characteristics were greatly improved over HgCdTe alloys. In six boules, a total of only one twin was observed. A method for polishing and producing dislocation etch pits was developed for these alloys, revealing dislocation etch pit densities one to two orders of magnitude less than HgTe-based alloys. A kink in the thermal profile during processing of one boule generated more dislocations than did lattice mismatch due to compositional variations. This alloy has improved microstructural properties and resistance to dislocation formation compared with similar II-VI alloys.

Cobb, S. D.↗
NASA NTRS1999

Near-Infrared Hyperspectral Image Cubes of Mars during the 1999 Opposition

We used the Goddard Space Flight Center, Acousto-Optic Tunable Filter (AOTF) Camera to obtain near-IR spectral image sets of Mars over the 1.6-3.6 micron region during the April 1999 opposition. A complete image set consists of 280 images with a spectral full-width-half maximum of 10 wavenumbers (fixed in frequency), 90 images in H-band (1.55-1.80 micron), 115 images in K-band (1.95-2.50 micron) and 75 images in L-band (2.90-3.70 micron). The short-wavelength limit is set by transmission of AOTF cell and long-wavelength limit is imposed by sensitivity of PICNIC, 256x256, HgCdTe array detector. We will discuss the new array performance and provide preliminary interpretations of some of these results. These measurements were part of a 4-observatory coordinated effort whose overall objective was to assemble a photometrically calibrated, spectrally complete ground-based image cube over the visible and near-IR spectral region. To accomplish this, four observing teams conducted the investigations with instruments spanning 0.4 to 5.0 micron. The instruments and observing facilities were (a) AOTF camera at Apache Point Observatory, 3.5m, f/10, Nasymth focus (this abstract). Primary science targets included the 3 micron water-of hydration feature and CO2, H2O ice (polar regions and clouds); (b) Visible/NIR interference-filter (24 filters) camera at Lowell Observatory, 72" telescope. 430-1050 nm. Science targets were Fe(2+), Fe(3+) mineralogy and coarse grain hematite search; (c) NMSU Tortugas Mountain Observatory, 60 cm telescope, CCD photometry with same filter set as Lowell; (d) KPNO cryogenic grating/slit spectrometer (CRSP/SALLY) at KPNO 2.1 m, f/15 Cassegrain focus (see abstract by D. Glenar, et. al., this meeting). Selected wavelengths in 3-5 micron region (L, M band). Science targets included water-of-hydration feature (3-4 micron long wave extension) and sulfate mineralogy. Observers participating in this campaign included Dave Glenar, John Hillman, Gordon Bjoraker and Fred Espenak from GSFC, Nancy Chanover, Jim Murphy and A. S. MurTell from NMSU, Leslie Young from BU, Diana Blaney from JPL and Dick Joyce from KPNO.

Hillman, John J.↗
NASA NTRS2000

Characterization of Electronic Materials HgZnSe and HgZnTe Using Innovative and Conventional Techniques

HgZnSe and HgZnTe are electronic materials of interest for potential IR detector and focal plane array applications due to their improved strength and compositional stability over HgCdTe, but they are difficult to grow on Earth and to fully characterize. Conventional contact methods of characterization, such as Hall and van der Paw, although adequate for many situations are typically labor intensive and not entirely suitable where only very small samples are available. To adequately characterize and compare properties of electronic materials grown in low earth orbit with those grown on Earth, innovative techniques are needed that complement existing methods. This paper describes the implementation and test results of a unique non-contact method of characterizing uniformity, mobility, and carrier concentration together with results from conventional methods applied to HgZnSe and HgZnTe. The innovative method has advantages over conventional contact methods since it circumvents problems of possible contamination from alloying electrical contacts to a sample and also has the capability to map a sample. Non- destructive mapping, the determination of the carrier concentration and mobility at each place on a sample, provides a means to quantitatively compare, at high spatial resolution, effects of microgravity on electronic properties and uniformity of electronic materials grown in low-Earth orbit with Earth grown materials. The mapping technique described here uses a 1mm diameter polarized beam of radiation to probe the sample. Activation of a magnetic field, in which the sample is placed, causes the plane of polarization of the probe beam to rotate. This Faraday rotation is a function of the free carrier concentration and the band parameters of the material. Maps of carrier concentration, mobility, and transmission generated from measurements of the Faraday rotation angles over the temperature range from 300K to 77K will be presented. New information on band parameters, obtained by combining results from conventional Hall measurements of the free carrier concentration with Faraday rotation measurements, will also be presented. One example of how this type of information was derived is illustrated in the following figure which shows Faraday rotation vs wavelength modeled for Hg(l-x)ZnxSe at a temperature of 300K and x=0.07. The plasma contribution, total Faraday rotation, and interband contribution to the Faraday rotation, are designated in the Figure as del(p), FR tot, and del(i) respectively. Experimentally measured values of FR tot, each indicated by + , agree acceptably well with the model at the probe wavelength of 10.6 microns. The model shows that at the probe wavelength, practically all the rotation is due to the plasma component, which can be expressed as delta(sub p)= 2pi(e(sup 3))NBL/c(sup 2)nm*(sup 2) omega(sup 2). In this equation, delta(sub p) is the rotation angle due to the free carrier plasma, N is the free carrier concentration, B the magnetic field strength, L the thickness of the sample, n the index of refraction, omega the probe radiation frequency, c the speed of light, e the electron charge, and m* the effective mass. A measurement of N by conventional techniques, combined with a measurement of the Faraday rotation angle allows m* to be accurately determined since it is an inverse square function.

Tanton, George↗
NASA NTRS2000

Ground-Based Measurements of Stratospheric Composition from Mt. Barcroft, California

The MkIV is an FTIR spectrometer designed and built at JPL in the 1980's for remote sensing the composition of the Earth's atmosphere by solar absorption spectrometry. Optically, MkIV is very similar to the JPL ATMOS instrument, which flew three times on the Space Shuttle. Both use double-passed configurations with a KBr beamsplitter and compensator, in order to cover the mid-infrared. The main advantage of the MkIV is that it uses two detectors in parallel, a HgCdTe photoconductor for the long wavelengths and an InSb photodiode for the short wavelengths, allowing the entire 650 to 5650/cm region to be measured simultaneously. At a 10 kHz sampling rate, each 130 cm OPD interferogram takes 3 minutes to acquire. This paper describes how the MkIV instrument was adapted for remote operation from the Barcroft site, where the harsh winter conditions make access difficult. Some of the main technical challenges will be discussed including, (i) operation from solar panels and batteries, (ii) cooling the detectors with LN2, (iii) instrument control and monitoring over a cellular phone, and (iv) data storage, processing and analysis. Finally, MkIV spectra measured from Barcroft are compared with those measured from JPL to highlight the advantages of the higher altitude site.

Toon, G. C.↗
NASA NTRS2000

Earth Observing-1 Advanced Land Imager: Radiometric Response Calibration

The Advanced Land Imager (ALI) is one of three instruments to be flown on the first Earth Observing mission (EO-1) under NASA's New Millennium Program (NMP). ALI contains a number of innovative features, including a wide field of view optical design, compact multispectral focal plane arrays, non-cryogenic HgCdTe detectors for the short wave infrared bands, and silicon carbide optics. This document outlines the techniques adopted during ground calibration of the radiometric response of the Advanced Land Imager. Results from system level measurements of the instrument response, signal-to-noise ratio, saturation radiance, and dynamic range for all detectors of every spectral band are also presented.

Mendenhall, J. A.↗