Search NASA⌕ Search

SEARCH · Search NASA

Results for “Hydrothermal processing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Lunar material resources: An overview

The analysis of returned lunar samples and a comparison of the physical and chemical processes operating on the Moon and on the Earth provide a basis for predicting both the possible types of material resources (especially minerals and rocks) and the physical characteristics of ore deposits potentially available on the Moon. The lack of free water on the Moon eliminates the classes of ore deposits that are most exploitable on Earth; namely, (1) hydrothermal, (2) secondary mobilization and enrichment, (3) precipitation from a body of water, and (4) placer. The types of lunar materials available for exploitation are whole rocks and their contained minerals, regolith, fumarolic and vapor deposits, and nonlunar materials, including solar wind implantations. Early exploitation of lunar material resources will be primarily the use of regolith materials for bulk shielding; the extraction from regolith fines of igneous minerals such as plagioclase feldspars and ilmenite for the production of oxygen, structural metals, and water; and possibly the separation from regolith fines of solar-wind-implanted volatiles. The only element, compound, or mineral, that by itself has been identified as having the economic potential for mining, processing, and return to Earth is helium-3.

Carter, James L.↗
NASA NTRS2004

Precipitation of Secondary Phases from the Dissolution of Silicate Glasses

Basaltic and anorthositic glasses were subjected to aqueous weathering conditions in the laboratory where the variables were pH, temperature, glass composition, solution composition, and time. Leached layers formed at the surfaces of glasses followed by the precipitation of X-ray amorphous iron and titanium oxides in acidic and neutral solutions at 25 C over time. Glass under oxidative hydrothermal treatments at 150 C yielded a three-layered surface; which included an outer smectite layer, a Fe-Ti oxide layer and an innermost thin leached layer. The introduction of Mg into solutions facilitated the formation of phyllosilicates. Aqueous hydrothermal treatment of anorthositic glasses (high Ca, low Ti) at 200 C readily formed smectite, whereas, the basaltic glasses (high Ti) were more resistant to alteration and smectite was not observed. Alkaline hydrothermal treatment at 2000e produced zeolites and smectites; only smectites formed at 200 C in neutral solutions. These mineralogical changes, although observed under controlled conditions, have direct applications in interpreting planetary (e.g., meteorite parent bodies) and terrestrial aqueous alteration processes.

Ming, Douglas W.↗
NASA NTRS2012

Hydrogen Isotope Measurements of Organic Acids and Alcohols by Pyrolysis-GC-MS-TC-IRMS: Application to Analysis of Experimentally Derived Hydrothermal Mineral-Catalyzed Organic Products

We report results of experiments to measure the H isotope composition of organic acids and alcohols. These experiments make use of a pyroprobe interfaced with a GC and high temperature extraction furnace to make quantitative H isotope measurements. This work compliments our previous work that focused on the extraction and analysis of C isotopes from the same compounds [1]. Together with our carbon isotope analyses our experiments serve as a "proof of concept" for making C and H isotope measurements on more complex mixtures of organic compounds on mineral surfaces in abiotic hydrocarbon formation processes at elevated temperatures and pressures. Our motivation for undertaking this work stems from observations of methane detected within the Martian atmosphere [2-5], coupled with evidence showing extensive water-rock interaction during Mars history [6-8]. Methane production on Mars could be the result of synthesis by mineral surface-catalyzed reduction of CO2 and/or CO by Fischer-Tropsch Type (FTT) reactions during serpentization [9,10]. Others have conducted experimental studies to show that FTT reactions are plausible mechanisms for low-molecular weight hydrocarbon formation in hydrothermal systems at mid-ocean ridges [11-13]. Our H isotope measurements utilize an analytical technique combining Pyrolysis-Gas Chromatograph-Mass Spectrometry-High Temperature Conversion-Isotope Ratio Mass Spectrometry (Py-GC-MS-TC-IRMS). This technique is designed to carry a split of the pyrolyzed GC-separated product to a Thermo DSQII quadrupole mass spectrometer as a means of making qualitative and semi-quantitative compositional measurements of separated organic compounds, therefore both chemical and isotopic measurements can be carried out simultaneously on the same sample.

Socki, Richard A.↗
NASA NTRSDate not supplied

Argon Isotopic Constraints on Planetary Degassing and the Evolution of Earth's Atmosphere: Insights from K-bearing Phases

An enduring question in planetary science is the nature of volatile degassing from rocky planets during their evolution. The reactive nature of planetary volatiles (e.g. H2O, CO2, N, H) make them difficult to directly track through time. Noble gases, like argon, can act as passive tracers of planetary processes, with isotopic ratios providing clues on planetary volatile inventories and fluxes. Previous studies [e.g. 1, 2] use Earth’s argon degassing history to constrain the growth of continental crust. However, that record is limited to the modern 40Ar/36Ar ratio of 298.56 [3] and three time slices recorded in hydrothermal quartz of the Archean Dresser formation [1]: from ~143 (3.5 Ga) to ~212 (2.7 Ga). Due to the paucity of data, partly a result of using nominally K-free minerals, the temporal evolution of atmospheric 40Ar/36Ar remains poorly constrained. K-bearing phases from igneous rocks, forming at high temperature and upper mantle or crustal conditions, are rarely considered viable for recording ancient atmospheric 40Ar/36Ar values. We show that this possible and a potential path to more precise records of ancient atmosphere by leveraging the radiogenic endmember of isotope correlation diagrams. An isochron of coeval biotite grains from the Bushveld Complex [4], with little indication of alteration or excess 40Ar, yield an initial 40Ar/36Ar value that matches the atmospheric 40Ar/36Ar value of ~228 at 2055 Ma in the model of [2]. In addition, new multi-mineral data from the Palisade Sill also match the modelled 40Ar/36Ar value of ~293 at 202 Ma, providing another tie point in the late Triassic. Combined, the Bushveld and Palisades samples provide two new constraints on the ancient atmosphere and help define the history of planetary degassing. These results demonstrate the possibility of accurately and precisely obtaining atmospheric information from igneous rocks, not exclusively K-free phases, thus providing a surplus of ways to reconstruct planetary atmospheres and processes. A robust atmospheric 40Ar/36Ar history also has practical uses and we explore the systematic offsets that arise from using a modern 40Ar/36Ar value in 40Ar/39Ar age calculations of old samples.

J. B. Setera↗
NASA NTRS2011

MEPAG Recommendations for a 2018 Mars Sample Return Caching Lander - Sample Types, Number, and Sizes

The return to Earth of geological and atmospheric samples from the surface of Mars is among the highest priority objectives of planetary science. The MEPAG Mars Sample Return (MSR) End-to-End International Science Analysis Group (MEPAG E2E-iSAG) was chartered to propose scientific objectives and priorities for returned sample science, and to map out the implications of these priorities, including for the proposed joint ESA-NASA 2018 mission that would be tasked with the crucial job of collecting and caching the samples. The E2E-iSAG identified four overarching scientific aims that relate to understanding: (A) the potential for life and its pre-biotic context, (B) the geologic processes that have affected the martian surface, (C) planetary evolution of Mars and its atmosphere, (D) potential for future human exploration. The types of samples deemed most likely to achieve the science objectives are, in priority order: (1A). Subaqueous or hydrothermal sediments (1B). Hydrothermally altered rocks or low temperature fluid-altered rocks (equal priority) (2). Unaltered igneous rocks (3). Regolith, including airfall dust (4). Present-day atmosphere and samples of sedimentary-igneous rocks containing ancient trapped atmosphere Collection of geologically well-characterized sample suites would add considerable value to interpretations of all collected rocks. To achieve this, the total number of rock samples should be about 30-40. In order to evaluate the size of individual samples required to meet the science objectives, the E2E-iSAG reviewed the analytical methods that would likely be applied to the returned samples by preliminary examination teams, for planetary protection (i.e., life detection, biohazard assessment) and, after distribution, by individual investigators. It was concluded that sample size should be sufficient to perform all high-priority analyses in triplicate. In keeping with long-established curatorial practice of extraterrestrial material, at least 40% by mass of each sample should be preserved to support future scientific investigations. Samples of 15-16 grams are considered optimal. The total mass of returned rocks, soils, blanks and standards should be approximately 500 grams. Atmospheric gas samples should be the equivalent of 50 cubic cm at 20 times Mars ambient atmospheric pressure.

Allen, Carlton C.↗
NASA NTRS2017

Formation Mechanism of Iron-Rich Olivine: Experimental Constrains into Early Fluid-Assisted Hydration and Dehydration Processes on Asteroids

Iron-rich olivine is one of the major minerals in the matrices of unequilibrated ordinary (UOCs) and carbonaceous (CV, CK, CO) chondrites whose petrologic type is >3.1. There has been an extensive discussion in the literature as to the formation mechanism of these olivines; however, their origin is poorly understood. The formation of ferroan olivine during hydrothermal alteration has been demonstrated to be thermodynamically viable. The stability of ferroan olivine is highly dependent on several variables, including temperature, water/ rock (W/R) ratio, pressure, oxygen fugacity, and bulk rock composition. So far, hydrothermal alteration experiments have not been successful at forming FeO-rich olivines with the compositions and textures observed in the matrices of chondrites. Therefore, understanding the formation conditions of FeO-rich olivines remains a key problem to explain the effects of hydrothermal alteration on chondrite matrices.

Iron-rich olivine↗
NASA NTRS2005

Modeling Chemical and Isotopic Variations in Lab Formed Hydrothermal Carbonates

Chemical and mineralogical data (e.g. [1]) from Mars suggest that the history of liquid water on the planet was more sporadic in nature than long-lived. The non-equilibrium chemical and isotopic compositions of the carbonates preserved in the martian meteorite ALH84001 are direct evidence of ancient secondary minerals that have not undergone significant diagenesis or stabilization processes typical of long-lived aqueous systems on Earth. Thus secondary minerals and sediments on Mars may primarily record the characteristics of the aqueous environment in which they formed without being significantly overprinted by subsequent diagenetic processes during burial.

Niles, P. B.↗
NASA NTRS2017

Scientific Investigations Associated with the Human Exploration of Mars in the Next 35 Years

A human mission to Mars would present an unprecedented opportunity to investigate the earliest history of the solar system. This history that has largely been overwritten on Earth by active geological processing throughout its history, but on Mars, large swaths of the ancient crust remain exposed at the surface, allowing us to investigate martian processes at the earliest time periods when life first appeared on the Earth. Mars' surface has been largely frozen in place for 4 billion years, and after losing its atmosphere and magnetic field what re-mains is an ancient landscape of former hydrothermal systems, river beds, volcanic eruptions, and impact craters. This allows us to investigate scientific questions ranging from the nature of the impact history of the solar system to the origins of life. We present here a summary of the findings of the Human Science Objectives Science Analysis Group, or HSO-SAG chartered by MEPAG in 2015 to address science objectives and landing site criteria for future human missions to Mars (Niles, Beaty et al. 2015). Currently, NASA's plan to land astronauts on Mars in the mid 2030's would allow for robust human exploration of the surface in the next 35 years. We expect that crews would be able to traverse to sites up to 100 km away from the original landing site using robust rovers. A habitat outfitted with state of the art laboratory facilities that could enable the astronauts to perform cutting edge science on the surface of Mars. Robotic/human partnership during exploration would further enhance the science return of the mission.

Niles, P. B.↗
NASA NTRS2012

Chemical and Mineralogical Characterization of Acid-Sulfate Alteration of Basaltic Material on Mauna Kea Volcano, Hawaii: Jarosite and Hydrated Halloysite

Sulfates have been identified on the martian surface during robotic surface exploration and by orbital remote sensing. Measurements at Meridiani Planum (MP) by the Alpha-Particle X-ray Spectrometer (APXS) and Mossbauer (MB) instruments on the Mars Exploration Rover Opportunity document the presence of a ubiquitous sulfate-rich outcrop (20-40% SO3) that has jarosite as an anhydrous Fe3+-sulfate [1- 3]. The presence of jarosite implies a highly acidic (pH <3) formation environment [4]. Jarosite and other sulfate minerals, including kieserite, gypsum, and alunite have also been identified in several locations in orbital remote sensing data from the MEx OMEGA and MRO CRISM instruments [e.g. 5-8]. Acid sulfate weathering of basaltic materials is an obvious pathway for formation of sulfate-bearing phases on Mars [e.g. 4, 9, 10]. In order to constrain acid-sulfate pathways on Mars, we are studying the mineralogical and chemical manifestations of acid-sulfate alteration of basaltic compositions in terrestrial environments. We have previously shown that acidsulfate alteration of tephra under hydrothermal conditions on the Puu Poliahu cone (summit region of Mauna Kea volcano, Hawaii) resulted in jarosite and alunite as sulfate-bearing alteration products [11-14]. Other, more soluble, sulfates may have formed, but were leached away by rain and melting snow. Acidsulfate processes on Puu Poliahu also formed hematite spherules similar (except in size) to the hematite spherules observed at MP as an alteration product [14]. Phyllosilicates, usually smectite }minor kaolinite are also present as alteration products [13]. We discuss here an occurrence of acid-sulfate alteration on Mauna Kea Volcano (Hawaii). We report VNIR spectra (0.35-2.5 microns ASD spectrometer), Mossbauer spectra (MER-like ESPI backscatter spectrometer), powder XRD (PANalytical), and major element chemical compositions (XRF with LOI and Fe redox) for comparison to similar data acquired or to be acquired by MRO-CRISM and MEx OMEGA, MERMB, MSL-CheMin, and MER and MSL APXS, respectively.

Graff, Trevor G.↗
NASA NTRSDate not supplied

Assessing Organic Preservation and the Implications for Potential Biosignatures in the Bastide Member of the Séítah Formation, Jezero Crater

Introduction: Olivine has the highest CO2 trapping potential of ultramafic minerals, due to its rapid rate of dissolution and high percentage of divalent cations/unpolymerized silicate tetrahedra [1]. It generates divalent carbonates from CO2 and sequesters CO2 into the mineral matrix of the target lithology. The co-occurrence of olivine and carbonate within abraded targets from the Bastide Member of the Séítah Formation (Fm) of the Jezero crater floor [2] suggests the carbonation of olivine occurred within the mineral matrix hosted in a subsurface system. Hydrothermal origins for the subsurface system are hypothesized from orbital data [3]. This is supported by the detection of hydration features within the rock as well as the carbonate features are solely detected within the abrasion patch but not the rock’s surface. Organic preservation potential of abrasion patches: We incorporated the SHERLOC/WATSON results acquired from the Dourbes, Garde, and Quartier abrasion patches in the Séítah Fm to investigate the organomineral associations, and determine the biosignature preservation potential of these rocks. Dourbes is dominated by olivine and has minor amounts of carbonate, hydrated Ca-sulfate, and amorphous or microcrystalline silicate. Fluorescence features (330-340 nm) are detected in discrete locales and could be consistent with double ring aromatic organic molecules; yet, these features do not appear to be associated with an identified mineral phase. Dark subhedral to euhedral olivine grains within the Garde abrasion patch often co-occur with carbonate-consistent spectral signatures in all analyzed scans. The availability of Fe2+ is a known influence on olivine dissolution rates [1] and SuperCam estimates of the olivine composition (Forsterite-60 average for Sols 202-234) may thereby provide a constraint on the carbonation extent. Carbonated olivine phenocrysts within the matrix may be due to aqueous alteration, as the carbonation of nodules is consistent with observations in other hydrothermal systems and within Martian meteorites (ALH84001) [4]. In comparison, the Quartier abrasion patch represents an extensively altered endmember within the Bastide Member of the Séítah Fm. It contains a fluorescence doublet at 305/325 nm that coexists with multiple species of Na-sulfate and Mg-sulfate, Mg-carbonates, olivine [5]. Aqueous alteration and implications for habitability: The identification of primary and secondary mineral phases observed in the Bastide Member suggests the release of cations from primary ultramafic minerals through aqueous alteration. Within Garde, the carbonate detected appears to be Mg-rich and likely formed from the in situ alteration of Mg-rich olivine within the region as carbonate has only been detected within the rock via in situ analysis. Carbonates derived from abiotic and biotic reactions preserve biosignatures (i.e. indices of habitability) on Earth. The detected carbonate phase found in association with fluorescent features within the rock matrix may also indicate potential organic compounds preserved in a putative hydrothermal system. Fluorescent features (~330 nm) are unique to Garde and Dourbes, though they are co-located to carbonate signatures solely within Garde, and between the light toned minerals. Identification of these fluorescent features may be consistent with 1-2 ring aromatic compounds. The limit of detection for Raman is multiple orders of magnitude greater than the limit of detection required for fluorescence [6]. Implications for provenance: Hydrothermal systems represent disequilibrium chemical conditions that are hypothesized to have supported the emergence of life and also preserve ancient carbon within precipitated carbonates [7]. Hydrothermal system associated carbonates are capable of preserving biosignatures up to an estimated ~3.77 – 4.28 Gya [8]. Thus, carbonated olivine found within the Séítah Fm may represent a high-potential biosignature preserving environment on Mars. The formation of carbonates by an aqueous alteration process, such as carbonation of olivine is also consistent with hypotheses for carbonate within the greater regional-olivine bearing unit [2,3], which contains Garde, Dourbes, and Quartier. Acknowledgments: This work was carried out at the Jet Propulsion Laboratory, The California Institute of Technology under a contract from NASA. References: [1] Wood et al., (2019) ES&T, 6, 10. [2] Stack, K. et al., (2020) Space Sci Rev, 216, 127. [3] Tarnas, J. et al., (2021) JGR: Planets, 126, 11. [4] Steele et al., (2007) Meteorit. Planet. Sci., 42, 9. [5] Murphy, A.E. et al., (2022) LPSC [6] Bhartia et al., (2021) Space Sci Rev, 217, 58. [7] Luther (2021) GRL, 48, e2021GL094869. [8] Dodd et al., (2017) Nature, 543, 60-64

E L Cardarelli↗
NASA NTRS2021

Spectrally Blue Parent Body of Asteroid (162173) Ryugu and its Hydrothermal History

Small rubble pile asteroids record the thermal evolution of their much larger parent bodies. However, recent ‘space weathering’ and/or ‘solar heating’ create ambiguities between the uppermost layer observable by remote-sensing and the pristine material from the parent body. Hayabusa2 remote-sensing observations found that on the asteroid (162173) Ryugu both north and south pole regions preserve the material least processed by space weathering: spectrally blue carbonaceous chondritic material with a 0.7-μm band absorption, indicative of Fe-bearing phyllosilicates. This discovery suggests that Ryugu’s parent body experienced intensive aqueous alteration and subsequent thermal metamorphism at 670 – 970 K. Ryugu’s parent body was heated by radioactive decay of short-lived radionuclides possibly because of its early formation 2-2.5 Ma. Ryugu’s parent body which is spectrally blue represents some of the most ancient of carbonaceous chondritic compositions from the solar system. The samples being brought to Earth by Hayabusa2 will give us our first insights into this epoch in solar system history.

Eri Tatsumi↗
NASA NTRS2003

Mound Spring Complexes in Central Australia: An Analog for Martian Groundwater Fed Outflow Channels?

The arid inland of Australia contains a diversity of landscapes and landscape processes, often of great antiquity, extending back to the Mesozoic and Paleozoic. The potential of this landscape as a source of Mars analogs has, however, been little explored. The few examples studied so far include radiation-tolerant microbes in thermal springs and hematite-silica hydrothermal alteration near Arkaroola in the Finders Ranges, and aeolian landforms at Gurra Gurra water hole the north east of Arkaroola. Further Australian Mars analog studies were provided by the studies of Bourke and Zimbelman of the paleoflood record of the Todd and Hale Rivers in central Australia. To facilitate study of such analogues, Mars Society Australia has embarked on a project to construct a Mars Analog Research Station near Arkaroola. The international scientific community will soon have the opportunity to participate in Mars analog studies in central Australia utilizing this facility. An area of considerable Mars analog potential is the mound spring complexes that occur at the margins of the Great Artesian Basin (GAB) which underlies 22% of the Australian continent and covers 1.7 million km2. The mound springs are formed when ground water flows to a topographic low, and subsurface strata dips up causing a hydrological head at the surface. Minerals precipitated at the spring discharge zone form low mesas or "mounds", the height of which are controlled by the hydrological head. This paper describes the Dalhousie Mound Spring Complex (DMC) in the northern part of South Australia (Figure 1), and its potential as a Mars analog. Hydrogeology: The DMC consists of a cluster of more than 60 active springs formed by natural discharge from the GAB). Total measured discharge from the GAB is 1.74 GL per day, estimated unfocussed natural leakage through the aquaclude is thought be approximately equal to this figure. Some 54 ML per day are currently discharged by the DMC, 3% of the measured total. The discharged artesian waters are of low to moderate salinity (700 - 9400 ppm), near neutral pH (6.8-7.3) and warm (20-46 C). The elevated temperatures are due to passage of the groundwater through deeply buried (up to 3 km) aquifers in an region of high heat flow, rather than magmatic heating. The waters also contain high levels of dissolved iron and H2S and less than 1 ppm dissolved oxygen. The water is carried in the Late Jurassic Algebuckina Sandstone beneath the aquaclude of the Bulldog Shale. It is brought near the surface by the mid-Cenozoic Dalhousie anticline and the ground water flow focused along a series of faults that breach the anticline's crest.

Clarke, J. D. A.↗
NASA NTRS2003

Alpha-amylase from the Hyperthermophilic Archaeon Thermococcus thioreducens

Extremophiles are microorganisms that thrive in, from an anthropocentric view, extreme environments such as hot springs. The ability of survival at extreme conditions has rendered enzymes from extremophiles to be of interest in industrial applications. One approach to producing these extremozymes entails the expression of the enzyme-encoding gene in a mesophilic host such as E.coli. This method has been employed in the effort to produce an alpha-amylase from a hyperthermophile (an organism that displays optimal growth above 80 C) isolated from a hydrothermal vent at the Rainbow vent site in the Atlantic Ocean. alpha-amylases catalyze the hydrolysis of starch to produce smaller sugars and constitute a class of industrial enzymes having approximately 25% of the enzyme market. One application for thermostable alpha-amylases is the starch liquefaction process in which starch is converted into fructose and glucose syrups. The a-amylase encoding gene from the hyperthermophile Thermococcus thioreducens was cloned and sequenced, revealing high similarity with other archaeal hyperthermophilic a-amylases. The gene encoding the mature protein was expressed in E.coli. Initial characterization of this enzyme has revealed an optimal amylolytic activity between 85-90 C and around pH 5.3-6.0.

Bernhardsdotter, E. C. M. J.↗
NASA NTRS2004

Measured Fluid Flow in an Active H2O-CO2 Geothermal Well as an Analog to Fluid Flow in Fractures on Mars: Preliminary Report

Water in the Earth's crust generally contains dissolved gases such as CO2. Models for both 'Blue Mars' (H2O-driven processes) and 'White Mars' (CO2-driven processes) predict liquid H2O with dissolved CO2 at depth. The fate of dissolved CO2 as this mixture rises toward the surface has not been quantitatively explored. Our approach is a variation on NASA's 'Follow the Water' as we 'Follow the Fluid' from depth to the surface in hydrothermal areas on Earth and extrapolate our results to Mars. This is a preliminary report on a field study of fluid flow in a producing geothermal well. For proprietary reasons, the name and location of this well cannot be revealed, so we have named it 'Earth1' for this study.

Kieffer, Susan W.↗
NASA NTRS1983

Evaluation of radiometric and geometric characteristics of LANDSAT-D imaging system

With vegetation masked and noise sources eliminated or minimized, different carbonate facies could be discriminated in a south Florida scene. Laboratory spectra of grab samples indicate that a 20% change in depth of the carbonate absorption band was detected despite the effects of atmospheric absorption. Both bright and dark hydrothermally altered volcanic rocks can be discriminated from their unaltered equivalents. A previously unrecognized altered area was identified on the basis of the TM images. The ability to map desert varnish in semi-arid terrains has economic significance as it defines areas that are less susceptible desert erosional process and suitable for construction development.

Salisbury, J. W.↗
NASA NTRS1992

Expert system-based mineral mapping using AVIRIS

Integrated analysis of imaging spectrometer data and field spectral measurements were used in conjunction with conventional geologic field mapping to characterize bedrock and surficial geology at the northern end of Death Valley, California and Nevada. A knowledge-based expert system was used to automatically produce image maps from Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data showing the principal surface mineralogy. The imaging spectrometer data show the spatial distribution of spectrally distinct minerals occurring both as primary rock-forming minerals and as alteration and weathering products. Field spectral measurements were used to verify the mineral maps and field mapping was used to extend the remote sensing results. Geographically referenced image-maps produced from these data form new base maps from which to develop improved understanding of the processes of deposition and erosion affecting the present land surface. The 'northern Grapevine Mountains' (NGM) study area was reported on in numerous papers. This area is an unnamed northwestward extension of the range. Most of the research here has concentrated on mapping of Jurassic-age plutons and associated hydrothermal alteration, however, the nature and scope of these studies is much broader, pertaining to the geologic history and development of the entire Death Valley region. AVIRIS data for the NGM site were obtained during May 1989. Additional AVIRIS data were acquired during September 1989 as part of the Geologic Remote Sensing Field Experiment (GRSFE). The area covered by these data overlaps slightly with the May 1989 data. Three and one-half AVIRIS scenes total were analyzed.

Kruse, Fred A.↗
NASA NTRS2008

Gusev Crater on Mars: Wet and Dry

The Mars Exploration Rover Spirit has traversed over 7.5 km in 1470 sols of operations at the Gusev Crater landing site. Chemical and mineralogical evidence from approximately 200 in-situ samples indicate various degrees of exposure to liquid water, from wet and saturated to dry and unaltered. (1) Six samples with concentrations of amorphous silica between 60 and 95 wt% were discovered in a small valley less than 50 meters in length. Associated enrichments in titanium oxide, relatively insoluble at low pH, suggest that these silica deposits formed as a result of acidic leaching processes. Liquid water interactions with these surface materials were necessary to remove cations solubilized in the low pH environment or to concentrate silica in solution prior to precipitation. (2) Hydrated ferric sulfates are found in subsurface deposits which have the unmistakable chemical signatures of nearby rocks. The movement of hydrothermal fluids and/or fumarolic vapors through local rocks prior to precipitation of these materials is suggested by these observations. (3) Goethite (alpha-FeOOH), a mineral phase which requires water to form, represents 20% to 35% of the iron in numerous rock samples (Clovis Class) on the West Spur of the Columbia Hills. Alteration of iron under aqueous conditions is clearly indicated by this presence of goethite. (4) Nearly isochemical signatures are found in elemental analyses of over ten distinct samples (Wishstone/Watchtower class rocks), yet the ratio of ferric iron to total iron varies from 0.4 to 0.95. Small quantities of water, insufficient to flush cations from the samples, were likely responsible for this weathering. (5) Bromine, a trace element readily mobilized by water, is found in high concentrations in certain rock interiors and is enhanced in subsurface soils, consistent with transport to localized cold traps by water thin-films. (6) Also relevant to the characterizing the role of liquid water is the discovery of an areally extensive ultramafic sequence of rocks where over 70% of the iron is in unaltered olivine and the ferric to total iron ratio is 0.1. This result indicates that certain materials at the martian surface have been protected from aqueous alteration.

Yen, Albert↗
NASA NTRS1985

Planetary ecology; Proceedings of the Sixth International Symposium on Environmental Biogeochemistry, Santa Fe, NM, October 10-14, 1983

Topics presented include biological evolution and planetary chemistry; C-1 compounds; transport, deposition, and weathering; sulfur transformations; ground water; transformation processes for nitrogen oxides; and soils. Papers are presented on immunological studies on the organic matrix of recent and fossil invertebrate shells; biogenic gases in sediments deposited since Miocene times on the Walvis Ridge, South Atlantic Ocean; aspects of the biogeochemistry of Big Soda Lake, NV; mesophilic manganese-oxidizing bacteria from hydrothermal discharge areas at 21 deg North on the East Pacific Rise; and autotrophic growth and iron oxidation and inhibition kinetics of Leptospirillum ferrooxidans. Consideration is also given to thermophilic archaebacteria occurring in submarine hydrothermal areas; fate of sulfate in a soft-water, acidic lake; geochemical conditions in the ground water environment; microbial transformations as sources and sinks for nitrogen oxides; and the biogeochemistry of soil phosphorus.

Caldwell, D. E.↗