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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

An X-Ray Study of Grain Evolution behind Non-Radiative Shock

We model the dynamics, the destruction by sputtering, and the infrared (IR) emission from collisionally heated dust grains in fast (>/= 400 km s(exp -1)) astrophysical shocks in order to develop IR diagnostics for the destruction of grains in these environments. The calculations take into account the feedback from sputtering and IR emission on the gas-phase abundances, the cooling, and the ionization and thermal structure of the shock. Sputtering changes the initial grain size distribution, creating a deficiency of small (radius <50 A) grains compared to their preshock abundances. The altered grain size distribution depends on shock velocity and the density of the interstellar medium. Dust particles with sizes below approximately equal 300 A are stochastically heated, undergo temperature fluctuations, and radiate an excess of near-infrared emission (i </= 40 (micron)meter) over that expected for grains in thermal equilibrium. This near-infrared excess is a measure of the abundance of small grains and therefore a powerful diagnostic for the amount of destruction the grains were subjected to in the shock. We present here IR spectra from collisionally heated dust for a variety of shocks, and depict the changes in the spectra as a function of postshock column density. Our studies compliment those of Vancura et at. that examined the effects of the release of the sputtered refractory elements on the ultraviolet and X-ray emission. Multiwavelength observations at X-ray, Ultraviolet (UV), and IR wavelengths are therefore essential in piecing together a comprehensive picture of the physics of grain destruction in fast astrophysical shocks.

Vancura, Olaf↗
NASA NTRS2016

Tholins as Coloring Agents on Pluto and Other Icy Solar System Bodies

Tholins are refractory organic solids of complex structure and high molecular weight, with a wide range of color ranging from yellow and orange to dark red, and through tan to black. They are made in the laboratory by energy deposition (photons or charged particles) in gases and ices containing the simple molecules (e.g., N2, CH4, CO) found in planetary atmospheres or condensed on planetary surfaces. They are widely implicated in providing the colors and albedos, particularly in the region 0.3-1.0 microns, of several outer Solar System bodies, including Pluto, as well as aerosols in planetary atmospheres such as Titan. Recent color images of Pluto with the New Horizons spacecraft show concentrations of coloring agent(s) in some regions of the surface, and apparent near-absence in other regions. Tholins that may to some degree represent surface chemistry on Pluto have been synthesized in the laboratory by energetic processing of mixtures of the ices (N2, CH4, CO) known on Pluto's surface, or the same molecules in the gas phase. Details of the composition and yield vary with experimental conditions. Chemical analysis of Pluto ice tholins shows evidence of amides, carboxylic acids, urea, carbodiimides, and nitriles. Aromatic/olefinic, amide, and other functional groups are identified in XANES analysis. The ice tholins produced by e- irradiation have a higher concentration of N than UV ice tholins, with N/C approx. 0.9 (versus approx. 0.5 for UV tholins) and O/C approx.0.2. Raman spectra of the electron tholin show a high degree of structural disorder, while strong UV fluorescence indicates a large aromatic content. EUV photolysis of a Pluto gaseous atmosphere analog yields pale yellow solids relatively transparent in the visual, and with aliphatic CH bonds prominent in IR spectra. This or similar material may be responsible for Pluto's hazes.

Tholins↗
NASA NTRS1994

SN 1994I in M51 and the nature of type Ibc supernovae

Early spectra of SN 1994I in M51 (NGC 5194) are presented along with arguments that is a member of the class of helium-poor Type Ic supernovae. The issue of H and He in the spectra of Type Ib and Ic events is reexamined with the conclusion that Type Ib eject substantially less H than even transition events like SN 1993J and that Type Ic eject substantially less He than Type Ib and their optical spectra are consistent with no H or He. Type Ic show and absorption of the Si II lambda 6355 blend that characterizes Type Ia. This feature requires only a solar abundance of Si. Some Type Ic show an absorption that is probably C II lambda 6580. IR spectra are presented of SN 1990W which show the line of He I lambda 10830. The strength of this feature and the rather slow decay of the late time light curve suggest that this event could be better classified as a Type Ib. Even if trace abundances of H are present in Type Ib and of He in Type Ic the spectral differences still imply a distinctly different evolution for the progenitors of Type Ib from Type Ic and events like SN 1993J.

Wheeler, J. C.↗
NASA NTRS2007

Infrared and X-Ray Evidence for Circumstellar Grain Destruction by the Blast Wave of Supernova 1987A

Multiwavelength observations of supernova remnant (SNR) 1987A show that its morphology and luminosity are rapidly changing at X-ray, optical, infrared, and radio wavelengths as the blast wave from the explosion expands into the circumstellar equatorial ring, produced by mass loss from the progenitor star. The observed infrared (IR) radiation arises from the interaction of dust grains that formed in mass outflow with the soft X-ray emitting plasma component of the shocked gas. Spitzer IRS spectra at 5 - 30 microns taken on day 6190 since the explosion show that the emission arises from approx. 1.1 x 10(exp -6) solar mass of silicate grains radiating at a temperature of approx. 180+/-(15-20) K. Subsequent observations on day 7137 show that the IR flux had increased by a factor of 2 while maintaining an almost identical spectral shape. The observed IR-to-X-ray flux ratio (IRX) is consistent with that of a dusty plasma with standard LMC dust abundances. This flux ratio has decreased by a factor of approx. 2 between days 6190 and 7137, providing the first direct observation of the ongoing destruction of dust in an expanding SN blast wave on dynamic time scales. Detailed models consistent with the observed dust temperature, the ionization fluence of the soft X-ray emission component, and the evolution of IRX suggest that the radiating si1icate grains are immersed in a 3.5 x 10(exp 6) K plasma with a density of (0.3 - 1) x 10(exp 4)/cu cm, and have a size distribution that is confined to a narrow range of radii between 0.02 and 0.2 microns. Smaller grains may have been evaporated by the initial UV flash from the supernova.

Dwek, Eliahu↗
DOE OSTI2023

Using synthetic infrared spectra derived from n/k optical constants for standoff detection of chemical deposits

We report results from a recent field experiment to test the validity of using physics-based synthetic infrared spectra to serve as endmembers in a spectral database targeted at chemical deposits. Specifically, the optical constants n and k, (the real and imaginary part of the refractive index) were used to first model infrared reflectance spectra for different thicknesses of chemical layers (e.g. acetaminophen, methylphosphonic acid – MPA, etc.) on various conducting and insulating substrates such as aluminum, wood, and glass. In the experimental portion of the research, thin films of the solid and liquid analytes were deposited onto such substrates to form micron-thick layers of the analytes at different thicknesses: Standoff data from an imaging instrument were then recorded and analyzed to not only identify the different analytes, but also quantify the layer/deposit thickness. To gauge success, the detection results using the synthetic data were compared to the results from hemispherical reflectance (HRF) spectra that were collected for the same sample planchets measured in the field via standoff methods. Preliminary results indicate good agreement between the synthetic reference data as compared to the lab-measured HRF data in terms of their ability to quantitatively reduce longwave infrared data. Specifically, modeled IR spectra for acetaminophen on an aluminum planchet at various thicknesses (1, 2, 5, 10, 15, and 20 µm) were synthesized and compared with standoff field reflectance data as well as HRF laboratory reflectance spectra for two samples: a 5.2 µm- and 12.8 µm-thick layer of acetaminophen on aluminum. Using a first-order approximation, analysis of the field data estimates the thicknesses of the samples to be 2 and 10 µm for the two samples, respectively, while the HRF laboratory data yields thickness estimates of between 5-10 µm and 10 µm, respectively. Both yield reasonable estimates, with the uncertainty most likely due to factors yet to be accounted for in the synthetic spectra such as light scattering.

complex index of refraction, optical constants, hy↗
DOE OSTI2022

Determining Infrared Optical Constants for Dolomite using Single Angle Reflectance and Spectroscopic Ellipsometry

The optical constants, namely the real (n) and imaginary (k) parts of the complex refractive index, are of particular interest to generate the infrared (IR) spectra of liquid and solid materials in different morphologies. To obtain n/k, however, most materials are typically not found in the monolithic forms necessary to easily measure n/k, and thus require the use of other methods such as pressing powders to form planar, specularly-reflective pellets. In this work dolomite crystals are measured using fixed-angle IR reflectance spectroscopy in both 1) a monolithic form with the crystal fixed in epoxy and polished, but data are also recorded from 2) pressed-pellet forms of powders of the same mineral using the same spectroscopic protocols. First results for the two methods are compared. It was found that the measured reflectance can vary by as much as a factor of two between the dolomite crystals and the pressed powder forms. For the two-sample preparation approaches the preliminary spectra are compared and the implications and limitations of each method for determining the optical constants of given materials are discussed. Comparison to literature data suggest that polarization effects likely account for the differing amplitude results for reflectance (and hence the k -vectors): Dolomite is known to be biaxial with significantly differing ordinary and extraordinary rays; the pressed pellet method measures an ensemble of microcrystals in randomly oriented positions, whereas the single crystal maintains just one orientation relative to the optical axis.

ellipsometry, dolomite, complex refractive index, ↗
NASA NTRS2013

Infrared Spectra and Optical Constants of Astronomical Ices: I. Amorphous and Crystalline Acetylene

Here we report recent measurements on acetylene (C2H2) ices at temperatures applicable to the outer Solar System and the interstellar medium. New near- and mid-infrared data, including optical constants (n, k), absorption coefficients (alpha), and absolute band strengths (A), are presented for both amorphous and crystalline phases of C2H2 that exist below 70 K. Comparisons are made to earlier work. Electronic versions of the data are made available, as is a computer routine to use our reported n and k values to simulate the observed IR spectra. Suggestions are given for the use of the data and a comparison to a spectrum of Makemake is made.

IR spectroscopy↗
NASA NTRS2004

Dusty Disks, Diffuse Clouds, and Dim Suns: Galactic Science with the Infrared Spectrograph on the Spitzer Space Telescope

The Infrared Spectrograph (IRS) on the Spitzer Space Telescope has now been in routine science operations since Dec. 14,2003. The IRS Science Team has used a portion of their guaranteed time to pursue three major science themes in galactic astronomy: the evolution of protostellar disks and debris disks; the composition and evolution of diffuse matter and clouds in the interstellar medium; and the composition and structure of brown dwarfs and low-mass main-sequence stars. We report here on the results from the first five months of IRS observations in these programs. Full IRS Spectra have already been obtained for large samples of YSO/protoplanetary disks in the Taurus and TW Hya associations, and or debris disks around main-sequence stars, in which many aspects of the evolution of planetary systems can be addressed for the first time. As anticipated, the mid-infrared IRS observations of brown dwarfs have yielded important new information about their atmospheres, including the identification of NH3 and measurements of new methane features. This work is based on observations made with the Spitzer Space Telescope, which is operated by the Jet Propulsion Laboratory, California Institute of Technology under NASA contract 1407. Support for this work was provided by NASA's Office of Space Science.

Roellig, T. L.↗
NASA NTRS1991

Emission from dust in visual reflection nebulae at infrared and submillimeter wavelengths

Far-IR and submillimeter images of five bright visual reflection nebulae, IC 446, NGC2247, NGC 2245, NGC 7023, and CED 201 are presented and used with composite IR spectra to derive parameters such as the fraction of nebulae emission attributed to molecule-sized grains, the range of nebulae grain albedos, gas densities, and gas cloud geometries. The results show that 30-45 percent of the nebulae emission lies at wavelengths of less than 30 microns. The variation in IR luminosity may be related to variations in nebulae gas density and less than optimal gas cloud geometries rather than to anomalous grain albedos. Relative extinction efficincies of roughly 1000-5000 are inferred for stellar photospheres with effective wavelengths of roughly 0.25-0.5 micron. The resultant mass-extinction coefficient is roughly 10-50 sq cm/g.

Casey, Sean C.↗
NASA NTRS1987

Near-infrared H2 emission from Herbig-Haro objects. I - A survey of low excitation objects

A survey for H2 1-0 S(1) emission in 16 Herbig-Haro (HH) objects and three exciting stars for HH objects is reported. Eleven HH objects which show low-excitation optical spectra exhibit H2 emission. One object (HH 43) is more than twice as bright as any previously reported HH object. In addition, spectra in the range 1.6-2.55 microns are reported for HH 43 and HH 120, and a 2.0-2.55 micron spectrum is presented for HH 26. The spectra yield estimates of the H2 density and temperature ranges in these objects. The role of ultraviolet H2 emission-line fluorescence in HH 43 with respect to cascading among excited vibrational states of the ground electronic state is discussed. Models which may account for the combined ultraviolet, optical, and near-IR spectra of HHs are briefly analyzed.

Schwartz, Richard D.↗
NASA NTRS1991

Infrared reflectance spectra (2.2-15 microns) of plagioclase feldspars

Laboratory results show that (1) the Christiansen frequency (CF) feature in mid-infrared reflectance spectra of powders can be used to accurately distinguish plagioclase composition, and (2) the wavelength position of the CF is not affected by vitrification of the plagioclase. Although the CF position does not distinguish glass from crystalline forms of plagioclase, other features (combination-tone, overtone, restrahlen bands) in the mid-IR spectra of plagioclase can be used for that purpose. These results have important implications for application of thermal emission spectroscopy to mapping the surface composition of regolith-covered planetary bodies like the moon, Mars, and asteroids.

Nash, Douglas B.↗
NASA NTRS1999

The Beta Pictoris Phenomenon in Young Stars With Accreting Gas

Program Hae2BPIC resulted in usable ISO spectra of three young, Herbig Ae stars: HR 5999 (A7e, t=0.6 Myr), SV Cep (al-2e, t=1-3 Myr), and MW Vul (Al-2e, t=1-3 Myr). While too small a sample to pursue our original goal of surveying the silicate emission in these young, protoplanetary disk systems, comparison of these data with ground-based IR spectra, and published ISO observations of other HAe stars (especially the posters at PPIV) reveals the following: The known binary stars in the sample show signatures of partially crystal line silicate features by t=0.6 Myr, at an epoch when ostensibly single Herbig Ae stars have substantially stronger silicate emission dominated by amorphous grains. The known binary stars also show deficits in the optically thick continuum flux relative to coeval single stars. Comparison of ISO spectra indicates that the flux deficit seen in WD 163296 over 10-100 microns relative to AB Aur reflects a real deficit of material interior to 300.

Grady, Carol A.↗
NASA NTRS1997

New Dust Features Observed with ISO

This paper will review our current knowledge of circumstellar and interstellar dust with the emphasis on infrared spectroscopy with ISO. Objects embedded in or located behind molecular clouds show a wealth of absorption features due to simple molecules in an icy mantle. The SWS on ISO has provided us, for the first time, with complete 3-45 um spectra which allow an inventory of interstellar ice. Among the species identified are H2O, CH3OH, CH4, CO2, CO, and OCS. These species are formed through simple reactions among gas phase species accreted on grain surfaces, possibly modified by FUV photolysis and warm-up (ie., outgassing). The implications of the observations for our understanding of these processes will be reviewed. The IR spectra of many UV bright objects are dominated by strong emission features at 3.3, 6.2, 7.7, and 11.3 micrometers. These are generally attributed to Polycyclic Aromatic Hydrocarbons (PAHs) molecules. The observational evidence will be reviewed. The emphasis will be on recent data which show widespread spectral variations, particularly among protoplanetary and planetary nebulae, and their implications. One of the most exciting, recent discoveries on interstellar and circumstellar dust has been the detection of spectral structure due to crystalline olivine and enstatite in a variety of objects surrounded by circumstellar silicates. These spectra will be reviewed and circumstellar silicate mineralogy will be discussed.

Tielens, Alexander G. G. M.↗
NASA NTRS1987

Narrow-line Seyfert galaxies with permitted Fe II emission Markarian 507, 5C 3.100, and I Zw 1

Optical, X-ray and and/or IR spectra of Mrk 507, 5C 3.100 and I Zw 1 are compared in a discussion of the bases for classifications of Seyfert 1 and 2 galaxies. Einstein Observatory X ray data indicate that the Seyfert designation requires a continuum extending to X-rays in order to account for permitted Fe II lines observed in Seyfert galaxies. It is suggested that the IR luminosity of I Zw 1, which exceeds the X-ray luminosity by two orders of magnitude, may be accounted for by interaction between companion galaxies. The presence or absence of dense clouds such as those in I Zw 1 is identified as the factor which separates Seyfert galaxies into two mutually exclusive ranges in X-ray luminosity.

Halpern, J. P.↗
DOE OSTI2020

Unraveling the individual influences of supports and ionic liquid coatings on the catalytic properties of supported iridium complexes and iridium clusters

In this work, supported iridium complexes were synthesized by the reaction of Ir(CO) 2 (acac) (acac = acetylacetonato) with SiO 2 , γ-Al 2 O 3 , and MgO. Extended X-ray absorption fine structure (EXAFS) and infrared (IR) spectra demonstrate that the iridium was present as atomically dispersed species anchored to each support. The samples were treated in flowing H 2 at 673 K to form supported iridium clusters. EXAFS spectra and high-angle annular dark-field scanning transmission electron microscopy images demonstrate that the average diameter of the iridium clusters on each support was approximately 1.2 nm. Furthermore, the catalysts before and after cluster formation were coated with each of a family of 1,3-dialkylimidazolium ionic liquids (ILs) having varying electron-donor tendencies probed by their υ(C2H) frequencies determined by IR spectroscopy. The coated and uncoated samples were tested as catalysts for partial hydrogenation of 1,3-butadiene in a flow reactor at 333 K, with turnover frequencies determined from differential conversions. The individual influences of the IL coatings and supports on the catalyst performance were found to depend strongly on whether the iridium was site-isolated complexes or present in clusters. The IL coatings as ligands exerted dominant effects on the clusters as catalysts, whereas the supports exerted dominant effects on the isolated iridium atoms. The results indicate how to tune the effects of metal nuclearity, IL coatings, and supports on the electronic environments and catalytic properties of the metals.

1,3-Butadiene hydrogenation↗
NASA NTRS2020

A Modified Algorithm and Open-Source Computational Package for the Determination of Infrared Optical Constants Relevant to Astrophysics

Infrared (IR) telescopes, such as Spitzer and SOFIA, have revealed a rich variety of chemical species trapped in interstellar ices. The most fundamental parameters to be derived from observed IR spectra are the identity and abundance of each component. Several compounds have been conclusively or tentatively identified, but the band strengths and optical constants needed to derive accurate abundances for many of these are poorly constrained. We have developed a modified approach to the extraction of the real and imaginary parts of the refractive index (optical constants) of a thin film from a single transmission spectrum measured in the IR spectral range. Our algorithm is similar to those implemented by previous authors, with some major changes that yield results for strong absorptions where previous approaches fail: (1) an adaptive k-correction step size, (2) the use of a root-finding algorithm to obtain a more accurate k-correction at each iteration, and (3) a k-correction step that prevents non-physical results such as negative n-values that prevent convergence in the calculation algorithm. The algorithm is presented and described, with examples to show agreement with some existing results and improvements upon others. New optical-constants calculations for CH3OH, CO2, N2O, and CH4 are presented, and potential implications for the modeling of interstellar and planetary ice data from space telescopes are discussed. With the objective of being open-source and transparent, the full source code in the free Python programming language is made available along with the compiled version and the laboratory data used to produce the results shown.

Perry A. Gerakines↗
NASA NTRS2013

Insights into Collisional between Small Bodies: Comparison of Impacted Magnesium-rich Minerals

Impacts are sustained by comets and asteroids throughout their lives, especially early in the Solar system's history, as described by the Nice model. Identifying observable properties that may be altered due to impacts can lead to a better understanding their collisional histories. Here, we investigate spectral effects and physical shock features observed in infrared spectra and Transmission Electron Microscope (TEM) images, respectively, of magnesium-rich minerals subjected to shock through impact experiments. Samples of magnesium-rich forsterite (Mg2SiO4, olivine), orthoenstatite (Mg2SiO3, pyroxene), diopside (MgCaSi2O6, monoclinic pyroxene), and magnesite (MgCO3, carbonate) were impacted at speeds of 2.4 km/s, 2.6 km/s and 2.8 km/s. Impact experiments were conducted in the Johnson Space Center Experimental Impact Laboratory using the vertical gun. Clear signatures are observed in both the mid-IR spectra (shift in wavelengths of the spectral peaks and relative amplitude changes) of all minerals except magnesite, and in TEM images (planar dislocations) of both the forsterite and orthoenstatite samples. Further discussion on forsterite and enstatite analyses can be found in Jensen et al., this meeting.

Lederer, Susan M.↗
NASA NTRS2017

Testing the Universality of the Stellar IMF with Chandra and HST

The stellar initial mass function (IMF), which is often assumed to be universal across unresolved stellar populations, has recently been suggested to be bottom-heavy for massive ellipticals. In these galaxies, the prevalence of gravity-sensitive absorption lines (e.g., Na I and Ca II) in their near-IR spectra implies an excess of low-mass (m < or approx. = 0.5 Stellar Mass) stars over that expected from a canonical IMF observed in low-mass ellipticals. A direct extrapolation of such a bottom-heavy IMF to high stellar masses (m > or approx. = 8 Stellar Mass) would lead to a corresponding deficit of neutron stars and black holes, and therefore of low-mass X-ray binaries (LMXBs), per unit near-IR luminosity in these galaxies. Peacock et al. searched for evidence of this trend and found that the observed number of LMXBs per unit K-band luminosity (N/LK) was nearly constant. We extend this work using new and archival Chandra X-ray Observatory and Hubble Space Telescope observations of seven low-mass ellipticals where N/LK is expected to be the largest and compare these data with a variety of IMF models to test which are consistent with the observed N/LK. We reproduce the result of Peacock et al., strengthening the constraint that the slope of the IMF at m > or approx. = 8 Stellar Mass must be consistent with a Kroupa-like IMF. We construct an IMF model that is a linear combination of a Milky Way-like IMF and a broken power-law IMF, with a steep slope (alpha1 = 3.84) for stars < 0.5 Stellar Mass (as suggested by near-IR indices), and that flattens out (alpha2 = 2.14) for stars > 0.5 Stellar Mass, and discuss its wider ramifications and limitations.

galaxies: elliptical and lenticular↗