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NASA NTRS1999

Computer Modeling of Electrostatic Aggregation of Granular Materials in Planetary and Astrophysical Settings

Electrostatic forces strongly influence the behavior of granular materials in both dispersed (cloud) systems and semi-packed systems. These forces can cause aggregation or dispersion of particles and are important in a variety of astrophysical and planetary settings. There are also many industrial and commercial settings where granular matter and electrostatics become partners for both good and bad. This partnership is important for human exploration on Mars where dust adheres to suits, machines, and habitats. Long-range Coulombic (electrostatic) forces, as opposed to contact-induced dipoles and van der Waals attractions, are generally regarded as resulting from net charge. We have proposed that in addition to net charge interactions, randomly distributed charge carriers on grains will result in a dipole moment regardless of any net charge. If grains are unconfined, or fluidized, they will rotate so that the dipole always induces attraction between grains. Aggregates are readily formed, and Coulombic polarity resulting from the dipole produces end-to-end stacking of grains to form filamentary aggregates. This has been demonstrated in USML experiments on Space Shuttle where microgravity facilitated the unmasking of static forces. It has also been demonstrated in a computer model using grains with charge carriers of both sign. Model results very closely resembled micro-g results with actual sand grains. Further computer modeling of the aggregation process has been conducted to improve our understanding of the aggregation process, and to provide a predictive tool for microgravity experiments slated for Space Station. These experiments will attempt to prove the dipole concept as outlined above. We have considerably enhanced the original computer model: refinements to the algorithm have improved the fidelity of grain behavior during grain contact, special attention has been paid to simulation time steps to enable establishment of a meaningful, quantitative time axis, and calibration of rounding accuracies have been conducted to test cumulative numerical influences in the model. The model has been run for larger grain populations, variable initial cloud densities, and we have introduced random net charging to individual grains, as well as a net charge to the cloud as a whole. The model uses 3 positive and 3 negative charges randomly distributed on each grain, with up to 160 grains contained within various size "boxes" that define the initial number densities in the clouds. Each charge represents localized charged region on a grain, but does not necessarily imply single quantized charge carriers. The Coulomb equations are then allowed to interact for each monopole: dipoles and any higher order charge coupling is a natural product of these "free" interactions over which the modeler exerts no influence. The charges are placed on surfaces of grains at random locations. A series of runs was conducted for neutral grains that had a perfect balance of negative and positive char carriers. Runs were also conducted with grains having additional fractional charges ranging between 0 and 1. By adding fractional charges of one sign, the model created grain populations in which all grains had excess charges the same sign, giving the cloud an overall net charge. This simulates clouds subjected to ionizing radiation (e. protoplanetary debris disk around a protosun), or any other process of charge biasing in a grain population (e.g., volcanic plumes). In another run series, random fractional charges of either sign were added to the grains so th some grains had a slight net positive charge while others had a slight net negative charge. This simulates triboelectrically-charged grain populations in which acquisition of an electron by one surface is at the expense creating a hole elsewhere. This dual sign charging was applied in two ways: in one case the cloud remained neutral by ensuring that all grain excess charges added to zero; in the other case, the cloud was permitted slight net char by not imposing a charge-balance condition. Additional information is contained in the original.

Marshall, J.↗
NASA NTRS2018

Is Water Necessary for Life?

The universality of water as the solvent for life is usually justified by its role in supporting the rich organic chemistry. It has been pointed out, however, that even richer synthetic chemistry is possible in other organic solvents. Does it mean that water is not necessary for life? Here, other, essential criteria for solvent for life that have not been sufficiently considered are discussed. In biological systems, complex molecules are not only constantly synthesized but also degraded. Solvent-mediated degradation is essential for regulating cell content, preventing overcrowding and allowing for recycling organic material. Achieving a balance between synthetic and degradative processes is facile in water, but not in many other organic liquids. Thus, the so-called “water paradox” according to which water is both necessary to life and toxic to biopolymer synthesis might not be paradoxical at all. The machinery of life is based on non-covalent interactions that do not involve making or breaking chemical bonds. Their strength needs to be properly tuned. If they are too weak, there might be undesired response to natural fluctuations of physical or chemical parameters. If they are too strong, the kinetics and energetics of cellular processes could adversely influenced. The solvent must allow for balancing these interactions, which provides strong, universal constraints on the medium for life. Water influences non-covalent interactions mainly by two mechanisms. First, it reduces strong, electrostatic interactions between molecules, chemical groups or atoms carrying electric charge or dipole. Second, it induces the hydrophobic effect, the tendency to remove non-polar (hydrophobic) molecules and groups from direct contact with aqueous solution and, instead, interact with each other. In living systems, the hydrophobic effect is largely responsible for self-organization of molecules to more complex structures, such as aggregation of lipid molecules to form biological membranes and protein folding. Water exists as stable liquid in a large temperature range, and the hydrophobic effects are a consequence of the temperature insensitivity of essential properties of its liquid state. In summary, water accomplishes an amazing feat – it reduces strong interactions between dissolved species and simultaneously increases the strength of weak interactions, bringing all of them to the right range. Once we consider not only synthetic capabilities but also other required traits of the solvent for life, no viable alternative to water is currently known.

Life↗
NASA NTRS2001

Northern Hemisphere Winter Climate Response to Greenhouse Gas, Ozone, Solar and Volcanic Forcing

The Goddard Institute for Space Studies (GISS) climate/middle atmosphere model has been used to study the impacts of increasing greenhouse gases, polar ozone depletion, volcanic eruptions, and solar cycle variability. We focus on the projection of the induced responses onto Northern Hemisphere winter surface climate. Changes in the model's surface climate take place largely through enhancement of existing variability patterns, with greenhouse gases, polar ozone depletion and volcanic eruptions primarily affecting the Arctic Oscillation (AO) pattern. Perturbations descend from the stratosphere to the surface in the model by altering the propagation of planetary waves coming up from the surface, in accord with observational evidence. Models lacking realistic stratospheric dynamics fail to capture these wave flux changes. The results support the conclusion that the stratosphere plays a crucial role in recent AO trends. We show that in our climate model, while ozone depletion has a significant effect, greenhouse gas forcing is the only one capable of causing the large, sustained increase in the AO observed over recent decades. This suggests that the AO trend, and a concurrent strengthening of the stratospheric vortex over the Arctic, are very likely anthropogenic in origin.

Shindell, Drew T.↗
NASA NTRS1993

Three-dimensional numerical simulation of near-surface flows over the Martian north polar cap

Measurements made by Viking Lander VL-2 (48 N) have shown that the near-surface wind and temperature regime on Mars displays striking similarities to terrestrial counterparts. The diurnal radiative cycle is responsible for establishment of a well-defined thermal circulation in which downslope (Katabatic) flows prevail during the nighttime hours and weak upslope (anabatic) conditions prevail during the daytime. Previous work has indicated that the slope flows are much like those found on Earth, particularly the Katabatic winds, which show striking similarities to drainage flows observed over Antarctica. The low-level wind regime appears to be an important factor in the scouring of the martian landscape. The north polar cap shows evidence of eolian features such as dunes, frost streaks, and grooves from Viking imagery. The direction of the prevailing wind can in cases be inferred from the eolian features. We examine the thermally induced flows that result from the radiative heating and cooling of the martian north polar region using a comprehensive three-dimensional atmospheric mesoscale numerical model. The same model has been used previously for simulation of Antarctic Katabatic winds. The model equations are written in terrain-following coordinates to allow for irregular terrain; prognostic equations include the flux forms of the horizontal momentum equations, temperature, continuity. A surface energy budget equation is also incorporated in which the surface temperature is determined. Explicit parameterization of both terrestrial (longwave) and solar (shortwave) radiation is included. Turbulent transfer of heat and momentum in the martian atmosphere is assumed to follow the similarity expressions in the surface boundary layer on Earth. The terrain heights for the martian north polar region have been obtained from the U.S. Geological Survey map and digitized onto a 57x57 grid with a spacing of 75 km. The resulting terrain map is shown in Fig. 1. The vertical grid consists of 15 levels (delta equals 0.998, 0.99, 0.98, 0.97, 0.96, 0.94, 0.92, 0.90, 0.85, 0.775, 0.70, 0.60, 0.50, 0.30, 0.10). The high resolution in the lower atmosphere is necessary to capture details of the boundary layer flows. The lowest level corresponds to a height of approximately 20 m above the ground, the seconds level 100 m.

Parish, Thomas R.↗
NASA NTRS1974

Polarized magnetic field fluctuations at the Apollo 15 site - Possible regional influence on lunar induction

High-frequency (5 to 40 millihertz) induced lunar magnetic fields, observed at the Apollo 15 site near the southeastern boundary of Mare Imbrium and the southwestern boundary of Mare Serenitatis, show a strong tendency toward linear polarization in a direction radial to the Imbrium basin and circumferential to the Serenitatis basin, a property that could be indicative of a possible regional influence on the induction.

Schubert, G.↗
NASA NTRS1972

Polarization mismatch errors in radio phase interferometers.

An analysis is presented which deals with the effects of polarization mismatch errors on the accuracy of a phase interferometer used for position location of unknown emitters relative to known calibration emitters. Closed-form expressions for the induced phase difference between interferometer antennas are derived for several combinations of receiving and transmitting antenna polarizations. Errors contributed by mechanical misalignment between antennas, as well as effects of power loss attributable to polarization mismatch, are also considered. The analysis leads to the conclusion that circularly polarized interferometer and transmitter antennas are best suited for the position location application, if it is assumed that polarization tracking of the interferometer antennas is not available. It is shown that a reasonable amount of ellipticity can be tolerated before the phase error becomes significant.

Muehldorf, E. I.↗
NASA NTRS1993

The generation of magnetic fields by the polarization electric field in the ionosphere of Venus

Measurements by the magnetometer on the Pioneer Venus orbiter have established that during conditions of low solar wind dynamic pressure, large-scale magnetic fields are not present in the ionosphere of Venus but that during conditions of high solar wind dynamic pressure the ionosphere of Venus is magnetized. The source of the magnetic field is thought to be currents induced in the ionosphere by the solar wind. We will show that ionospheric polarization electric field can act as a source, or 'battery', producing a small magnetic field, even without any initial magnetic field. We have calculated this polarization source as a function of altitude and solar zenith angle. The magnetic field was then determined using a 2D kinematic dynamo model of the ionosphere of Venus. The magnetic field attains a maximum strength of about 5 nT at a solar zenith angle of about 120 deg. This magnetic field might act as a 'seed' field for magnetic flux ropes and terminator waves.

Shinagawa, H.↗
NASA NTRS1999

Non-Equilibrium Superconductivity and Magnetic Pair Breaking in Perovskite Half-Metallic Ferromagnet-Insulator-Superconductor (F-I-S) Heterostructures

The effect of spin-polarized quasiparticle currents on the critical current density (J-c) of cuprate superconductors is studied in perovskite F-I-S heterostructures as a function of insulator thickness and of underlying magnetic materials. A pulsed current technique is employed to minimize extraneous Joule heating on the superconductor. At temperatures near T-c, F-I-S samples with insulator thicknesses\1e2nm show precipitous decrease in J_c as current injection (I_m) is increased. In contrast, J_c in a controlled sample with a substituted non-magnetic material (N-I-S) exhibit no dependence on I_m. Similarly, a F-I-S sample with a 10 mn insulating barrier also show little J_c effect versus I_m. At low temperatures with I_m = 0, significant suppression of J-c is observed only in the thin barrier F-I-S samples, although T_c and the normal-state resistivity of all samples are comparable. These phenomena can be attributed to the Cooper pair breaking induced by externally-injected and internally-reflected spin-polarized quasiparticle currents. We estimate an order of magnitude range for the spin diffusion length of 100 nm to 100\ mum.

Fu, C.-C.↗
NASA NTRS2000

The Interaction Between Dynamics and Chemistry of Ozone in the Set-Up Phase of the Northern Hemisphere Polar Vortex

Understanding stratospheric ozone loss to the point of accurately predicting ozone in the future requires correctly distinguishing chemical from transport-induced changes in ozone. For example, evaluating the impact of chlorine reduction in controlling stratospheric ozone loss requires estimating the amount of ozone lost in chemical reactions in the polar winter and spring. The Northern Hemisphere winter polar region is a particularly crucial and interesting area because it appears that the Northern vortex may currently be poised near the threshold of extreme ozone destruction such as that which now occurs annually in the Antarctic ozone "hole." In this presentation we explore the interaction of ozone transport and chemistry through the Northern late summer and fall seasons as the vortex circulation becomes established. This phase of the seasonal cycle determines the starting point for heterogeneous processes and chlorine-driven loss that take control in the winter vortex. Using a combination of profile data from POAM, HALOE, and in situ measurements, we show that relatively low ozone at high latitudes in the middle stratosphere is associated with vortex airmasses and that these ozone abundances evolve photochemically from characteristically higher values at the end of the summer. The zonal variance of ozone mixing ratio also increases greatly at this time consistent with increasing wave-driven transport. Comparison with a three-dimensional chemistry-transport model is used to generalize the findings from the limited set of observations and quantify the relative roles of transport and chemistry in determining the ozone mixing ratio distributions.

Kawa, S.R.↗
NASA NTRS1990

Possible effects of breaking gravity waves on the circulation of the middle atmosphere of Mars

The possible effect of breaking internal gravity waves on the circulation in the middle atmosphere of Mars was investigated using a quasi-geostrophic delta-plane dynamical model of the zonal-mean flow. The results of model simulations show that breaking gravity waves of intermediate horizontal scales (100-1000 km wavelengths) could act to 'close off' the winter westerly circumpolar jet in the 40-80 km altitude region and induce strong high-latitude warming at these levels, in accordance with recent thermal measurements indicating that Martian winter polar latitudes may be very warm in this middle atmospheric region. It was also found that, below about 40 km, wave breaking does not induce much warming, consistent with available data showing that winter high altitudes are normally very cold at lower levels.

Barnes, Jeffrey R.↗
NASA NTRS1985

Transport of ions in presence of induced electric field and electrostatic turbulence - Source of ions injected into ring current

The transport of ions from the polar ionosphere to the inner magnetosphere during stormtime conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the energization rate of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary, the ions were convected adiabatically. By using as input an O(+) flux of 2.8 x 10 to the 8th per sq cm per s (w greater than 10 eV) and an H(+) flux of 5.5 x 10 to the 8th per sq cm per s (w greater than 0.63 eV), the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4 to 8), with measurements made with the ISEE-1 satellite during a storm. This O(+) flux and a large part of the H(+) flux are consistent with the DE satellite measurements of the polar ionospheric outflow during disturbed times.

Cladis, J. B.↗
NASA NTRS1992

Shallow-trap-induced positive absorptive two-beam coupling 'gain' and light-induced transparency in nominally undoped barium titanate

The asymmetry of beam coupling with respect to the orientation of the polar axis in a nominally undoped barium titanate crystal is used to determine the electro-optic and absorptive 'gain' in the usual beam-coupling geometry. For small grating wave vectors, the electrooptic coupling vanishes but the absorptive coupling remains finite and positive. Positive absorptive coupling at small grating wave vectors is correlated with the light-induced transparency of the crystal described herein. The intensity and grating wave vector dependence of the electrooptic and absorptive coupling, and the light-induced transparency are consistent with a model incorporating deep and shallow levels.

Garrett, M. H.↗
NASA NTRS2004

Results of CoSMIR Under-Flights of the SSMIS

The first copy of the SSMIS (Special Sensor Microwave/Imager/Sounder) was launched on board the DMSP (Defense Meteorological Satellite Project) F-16 satellite in October 2003. During March-April 2004, six 5-hour SSMIS under-flights were conducted with the CoSMIR on board the NASA ER-2 aircraft over the coastal region of California. CoSMIR has nine channels at the frequencies of 50.3, 52.8, 53.6, 91.665 (V and H polarization), 150, 183.3+/-1, 183.3+/-3, and 183.3+/-6.6 GHz. All except the two 91.665 GHz channels are horizontally polarized. The instrument was carefully calibrated with LN2 target in the laboratory before the flights. Three of the aircraft flights passed over Lakes Pyramid and Tahoe that could be used to validate the in-flight sensor calibration. Immediately after these flights, an inter-comparison of the calibrated SSMIS and CoSMIR brightness temperatures (T(sub b)) followed. The results showed that, for channels at frequencies > or equal to 91.665 GHz, the SSMIS and CoSMIR T(sub b) values tracked each other very well; for some channels there were some bias with magnitude generally less than 3-4 K (SSMIS values were higher). For the three 50-54 GHz channels, the SSMIS T(sub b) values were higher and frequency-dependent. For the least opaque channel at 50.3 GHz, the SSMIS T(sub b)'s over the ocean surface were higher than those of CoSMIR by more than 20 K under the clear-sky conditions. The most plausible explanation for this to happen is to assume that the 50-54 GHx channels of the SSMIS are vertically polarized. This assumption appears to be consistent with independent radiative transfer calculations. Attempts to estimate vertically polarized radiometric responses for 50-54 GHz channels of the SSMIS based on the CoSMIR observations are not plausible and results not reliable because of the highly variable ocean surface conditions (e.g., wind-induced emissivity changes). A conversion of the CoSMIR 50-54 GHz channels from horizontal to vertical polarization, and a subsequent repetition of the SSMIS under-flights are the right approach for the calibration/validation of the 50-54 GHz channels of the SSMIS. Details of the SSMIS-CoSMIR inter-comparison will be presented.

Wang, J. R.↗
NASA NTRS1996

Mass Wasting and Ground Collapse in Terrains of Volatile-Rich Deposits as a Solar System-Wide Geological Process: The Pre-Galileo View

The polar terrains of Mars are covered in many places with irregular pits and retreating scarps, as are some of the surfaces of the outer-planet satellites. These features are interpreted by us as diagnostic of exogenic degradation due to the loss of a volatile rock-forming matrix or cement. In this study we propose that sublimation degradation is a plausible Solar Systemwide geological process. Candidate examples have been identified on Mars, Io, and Triton, and possibly Europa and Ganymede. We envision this process as having two end-member expressions (pits and scarps), for which we hypothesize two end-member mechanisms (massive localized lenses and areally extensive basal layers). In this study we focus on the role this process may play on the surfaces of the galilean satellites. Our principle modeling results are that for these satellites, H2S, CO2, and NH3 are the only viable candidate volatiles for sublimation degradation of landforms, in light of galilean satellite cosmochemistry. For Io's polar regions only H2S, and then only from slopes that face the Sun and have thin lags, is volatile enough to cause the observed sublimation-induced erosion at those latitudes. SO2 is not a viable candidate as an agent of erosion, especially for these polar landforms. In the case of Europa, only CO2 and H2S are viable candidates (given surface age constraints). Both species could be efficient eroders in nonpolar regions. H2S could generate erosion within the polar regions if the deposition and erosion conditions were essentially identical as those we invoked for Io's polar regions. For Ganymede (and Callisto) NH3 might be an agent of erosion in equatorial terrains of great age. The sublimation of CO2 and H2S is much more robust than NH3. The much slower rate of sublimation degradation from NH3 might be detectable by Galileo and used as a compositional indicator.

Moore, Jeffrey M.↗
NASA NTRS1992

Polarization-Rotating Sensors Connected To Optical Fibers

Proposed optoelectronic sensor system includes polarization-rotating sensing elements interrogated by polarized light transmitted to and from sensing elements along optical fibers. Polarization of light altered by combinations of inherent birefringence, stress-induced birefrigence, and Faraday rotation. Advantages include: light weight, fast response, immunity to electromagnetic interference at radio and lower frequencies, and no need to supply electrical power to sensing elements.

Frazer, Robert E.↗
NASA NTRS1992

Astronomical variation experiments with a Mars general circulation model

In time scales of a hundred thousand to a million years, the eccentricity of Mars orbit varies in a quasi-periodic manner between extremes as large as 0.14 and as small as 0 and the tilt of its axis of rotation with respect to the orbit normal also varies quasi-periodically between extremes as large as 35 deg and as small as 15 deg. In addition, the orientation of the axis precesses on comparable time scales. These astronomical variations are much more extreme than those experienced by the Earth. These variations are thought to have strongly modulated the seasonal cycles of dust, carbon dioxide, and water. One manifestation of the induced quasiperiodic climate changes may be the layered terrain of the polar regions, with individual layers perhaps recording variations in the absolute and/or relative deposition rates of dust and water in the polar regions, most likely in association with the winter time deposition of carbon dioxide ice. In an attempt to understand the manner in which atmospheric temperatures and winds respond to the astronomical forcings, we have initiated a series of numerical experiments with the NASA/Ames general circulation model of the Martian Atmosphere.

Pollack, J. B.↗
NASA NTRS2007

Improving Forecast Skill by Assimilation of Quality-controlled AIRS Temperature Retrievals under Partially Cloudy Conditions

The National Aeronautics and Space Administration (NASA) Atmospheric Infrared Sounder (AIRS) on board the Aqua satellite has been long recognized as an important contributor towards the improvement of weather forecasts. At this time only a small fraction of the total data produced by AIRS is being used by operational weather systems. In fact, in addition to effects of thinning and quality control, the only AIRS data assimilated are radiance observations of channels unaffected by clouds. Observations in mid-lower tropospheric sounding AIRS channels are assimilated primarily under completely clear-sky conditions, thus imposing a very severe limitation on the horizontal distribution of the AIRS-derived information. In this work it is shown that the ability to derive accurate temperature profiles from AIRS observations in partially cloud-contaminated areas can be utilized to further improve the impact of AIRS observations in a global model and forecasting system. The analyses produced by assimilating AIRS temperature profiles obtained under partial cloud cover result in a substantially colder representation of the northern hemisphere lower midtroposphere at higher latitudes. This temperature difference has a strong impact, through hydrostatic adjustment, in the midtropospheric geopotential heights, which causes a different representation of the polar vortex especially over northeastern Siberia and Alaska. The AIRS-induced anomaly propagates through the model's dynamics producing improved 5-day forecasts.

Reale, O.↗
NASA NTRS2009

Continuous Lidar Monitoring of Polar Stratospheric Clouds at the South Pole

Polar stratospheric clouds (PSC) play a primary role in the formation of annual ozone holes over Antarctica during the austral sunrise. Meridional temperature gradients in the lower stratosphere and upper troposphere, caused by strong radiative cooling, induce a broad dynamic vortex centered near the South Pole that decouples and insulates the winter polar airmass. PSC nucleate and grow as vortex temperatures gradually fall below equilibrium saturation and frost points for ambient sulfate, nitrate, and water vapor concentrations (generally below 197 K). Cloud surfaces promote heterogeneous reactions that convert stable chlorine and bromine-based molecules into photochemically active ones. As spring nears, and the sun reappears and rises, photolysis decomposes these partitioned compounds into individual halogen atoms that react with and catalytically destroy thousands of ozone molecules before they are stochastically neutralized. Despite a generic understanding of the ozone hole paradigm, many key components of the system, such as cloud occurrence, phase, and composition; particle growth mechanisms; and denitrification of the lower stratosphere have yet to be fully resolved. Satellite-based observations have dramatically improved the ability to detect PSC and quantify seasonal polar chemical partitioning. However, coverage directly over the Antarctic plateau is limited by polar-orbiting tracks that rarely exceed 80 degrees S. In December 1999, a NASA Micropulse Lidar Network instrument (MPLNET) was first deployed to the NOAA Earth Systems Research Laboratory (ESRL) Atmospheric Research Observatory at the Amundsen-Scott South Pole Station for continuous cloud and aerosol profiling. MPLNET instruments are eye-safe, capable of full-time autonomous operation, and suitably rugged and compact to withstand long-term remote deployment. With only brief interruptions during the winters of 2001 and 2002, a nearly continuous data archive exists to the present.

OZONE DESTRUCTION↗