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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Spacecraft contamination: Sources and prevention; Thermophysics Conference, 18th, Montreal, Canada, June 1-3, 1983, Selected Papers

Results of current research in the field of spacecraft contamination are presented. An overview of the various sources of contamination is given, showing the many and diverse mechanisms associated with the degradation of thermal and optical performance of spacecraft surfaces and optics. Some of the causes of contamination are discussed, including spallation of foam insulation on cryogenic fuel tanks, dispersion of particle contamination about a spacecraft, particle contamination of optical sensors, and the influence of the location of venting systems. Contamination prevention is addressed. Infrared transmittance and infrared optical properties of contaminants are considered along with the effects and properties of mixtures of exhaust species, of plume boundary layer flow, and of the contamination associated with bipropellant attitude control thrusters proposed for the Galileo spacecraft. Also discussed are: degradation of 'clean' thermal control surfaces over four years in orbit, in-orbit measurement of solar absorptance, and contamination from postfire efflux of a solid-propellant rocket motor.

Roux, J. A.↗
NASA NTRS1982

Improved multilayer insulation applications

Multilayer insulation blankets used for the attenuation of radiant heat transfer in spacecraft are addressed. Typically, blanket effectiveness is degraded by heat leaks in the joints between adjacent blankets and by heat leaks caused by the blanket fastener system. An approach to blanket design based upon modular sub-blankets with distributed seams and upon an associated fastener system that practically eliminates the through-the-blanket conductive path is described. Test results are discussed providing confirmation of the approach. The specific case of the thermal control system for the optical assembly of the Space Telescope is examined.

Mikk, G.↗
NASA NTRSDate not supplied

Low Energy Ionizing Radiation and Plasma Contributions to Radiation Dose in Materials at Sun-Earth Lagrange Points

- High energy radiation environments responsible for radiation damage to thick materials are well characterized and modeled: - Galactic cosmic rays — Badhwar-O’Neil 2020, CREME96, Nymmik - Solar particle events — Emission of Solar Protons, SAPPHIRE, JPL, King 1972 - Trapped radiation belts — AE8/AP8, AE9/AP9/IRENE - Low energy radiation environments responsible for radiation damage to thin materials relevant to Lagrange points and interplanetary missions have not been treated as comprehensively to date: - Solar wind - Magnetosheath - Magnetotail - Concern to spacecraft design and operations is radiation damage to surfaces and thin materials with mission critical applications on exterior of spacecraft - Applications: thermal control coatings, sunshields, multilayer insulation, optical thin film coatings, solar sails, thermo-optical properties of space exposed materials - Damage processes: radiation degradation (total dose), light ion sputtering, proton blistering of soft metals, modification of optical properties (α/ε), modification of charging properties (SEY, surface conductivity)

Joseph I. Minow↗
NASA NTRS2006

Terahertz NDE for Metallic Surface Roughness Evaluation

Metallic surface roughness in a nominally smooth surface is a potential indication of material degradation or damage. When the surface is coated or covered with an opaque dielectric material, such as paint or insulation, then inspecting for surface changes becomes almost impossible. Terahertz NDE is a method capable of penetrating the coating and inspecting the metallic surface. The terahertz frequency regime is between 100 GHz and 10 THz and has a free space wavelength of 300 micrometers at 1 THz. Pulsed terahertz radiation, can be generated and detected using optical excitation of biased semiconductors with femtosecond laser pulses. The resulting time domain signal is 320 picoseconds in duration. In this application, samples are inspected with a commercial terahertz NDE system that scans the sample and generates a set of time-domain signals that are a function of the backscatter from the metallic surface. Post processing is then performed in the time and frequency domains to generate C-scan type images that show scattering effects due to surface non-uniformity.

Madaras, Eric I.↗
DOE OSTI2023

Evolving a New Electron Transfer Pathway for Nitrogen Fixation Uncovers an Electron Bifurcating-Like Enzyme Involved in Anaerobic Aromatic Compound Degradation

There is increasing evidence that protein electron carriers like Fd evolved to form specific partnerships with select electron donors and acceptors to keep native electron transfer pathways insulated from one another. This makes it challenging to integrate a Fd-dependent pathway such as biological nitrogen fixation into non-nitrogen-fixing organisms and provide the high-energy reducing power needed to fix nitrogen.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Effect of insulator surface conditioning on the pinch dynamics and x-ray production of a Ne-filled dense plasma focus

The dense plasma focus (DPF) can be an intense source of x rays, wherein the insulator sleeve strongly dictates the electrical breakdown, which subsequently affects the formation of a plasma sheath and a collapse phase. Experiments on a 25 kJ DPF (operated at 4.4 kJ) are carried out to demonstrate the influence of insulator surface morphology on the pinch structure, dynamics, and x-ray yield using a Ne fill. Two borosilicate insulators are directly compared, one with a smooth finish and the other machined with four circumferential grooves traversing the perimeter of the exterior insulator surface. Comparisons are made through same-shot imaging diagnostics of the evolving plasma sheath during breakdown, rundown, and at the pinch in addition to the time-resolved measurements of emitted x rays via filtered photodiodes. The presence of structures on the insulator sleeve reduces x-ray production across all fill pressures by a factor of 2.8 ± 2.4 on average and reduces the highest x ray producing shots by a factor of 5. ± 1.8. Observations of sheath asymmetry and inhomogeneity at lift-off are observed and correlated with subsequent observations of off-axis radial collapse. Taken together, this suggests that local variations in the insulator surface decrease the spatial uniformity of the sheath, leading to an azimuthally asymmetric focus, reduced electron densities, and, ultimately, degraded x-ray production.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1999

Plumbrook Hypersonic Tunnel Facility Graphite Furnace Degradation Mechanisms

A recent rebuild revealed extensive degradation to the large graphite induction furnace in the Hypersonic Tunnel Facility (HTF). This damage to the graphite blocks and insulating felt is examined and modeled with thermochemical equilibrium codes. The primary reactions appear to be with water vapor and the nitrogen purge gas. Based on these conclusions, several changes are recommended. An inert purge gas (e.g. argon or helium) and controlling and monitoring water vapor to about 10 ppm should decrease the damage substantially.

Jacobson, Nathan S.↗
NASA NTRS2001

X-38 De-Orbit Propulsion Stage MLI Performance Test

This viewgraph presentation gives an overview of the X-38 de-orbit propulsion stage MLI performance tests. The objectives of the research include the testing of the deorbit propulsion stage (DPS) multi-layer insulation (MLI) to determine if MLI performance meets or exceeds that assumed in thermal analysis and to determine the performance degradation due to seams.

Kittredge, Ken↗
NASA NTRS2013

Pre-Proposal Assessment of Reliability for Spacecraft Docking with Limited Information

This paper addresses the problem of estimating the reliability of a critical system function as well as its impact on the system reliability when limited information is available. The approach addresses the basic function reliability, and then the impact of multiple attempts to accomplish the function. The dependence of subsequent attempts on prior failure to accomplish the function is also addressed. The autonomous docking of two spacecraft was the specific example that generated the inquiry, and the resultant impact on total reliability generated substantial interest in presenting the results due to the relative insensitivity of overall performance to basic function reliability and moderate degradation given sufficient attempts to try and accomplish the required goal. The application of the methodology allows proper emphasis on the characteristics that can be estimated with some knowledge, and to insulate the integrity of the design from those characteristics that can't be properly estimated with any rational value of uncertainty. The nature of NASA's missions contains a great deal of uncertainty due to the pursuit of new science or operations. This approach can be applied to any function where multiple attempts at success, with or without degradation, are allowed.

Brall, Aron↗
DOE OSTI2022

Effect of electrochemical cycling on microstructures of nanocomposite silicon electrodes using hyperpolarized 129 Xe and 7 Li NMR spectroscopy

The microstructural stability of composite electrodes during electrochemical cycling is critically important as it dictates the performance of Li-ion batteries. The issue becomes even more important for the high capacity alloying anode such as silicon that typically exhibits dramatic lithiation–delithiation-induced volume changes. The solid electrolyte interphase (SEI) layer formed on the active electrode surface has a profound effect on the overall microstructural stability of composite electrodes. An ideal SEI layer allows Li+ ions in and out of the electrode, but is an insulator to electrons, preventing the electrolyte from being further reduced. However, the SEI layers formed during initial lithiation may experience changes or degradation with subsequent cycling, adversely affecting the electrode performance. A combination of hyperpolarized 129 Xe and 7 Li nuclear magnetic resonance spectroscopies was applied to probe the microstructures of nanocomposite silicon electrodes at various stages of the lithiation–delithiation cycle. The results obtained from this study shed light on the degradation mechanism of nanocomposite Si electrodes upon electrochemical cycling and should prove useful in the effort to design more robust electrodes in the future.

36 MATERIALS SCIENCE↗
NASA NTRS1971

Development of organic non-flammable spacecraft potting, encapsulating and conformal coating compounds

The overall program objective was to develop a flexible compound which not only functioned in a manned aerospace environment as an effective electrical insulation, but whose flammability characteristics in 16.5 psia, 60% oxygen/40% nitrogen were evidenced by rapid self-extinguishment and minimal thermal (pyrolysis) degradation. The following polymeric matrices were examined in depth: fluoroelastomers, modified fluoroelastomers, silicone RTV's, and modified silicone and fluorosilicone RTV's. Almost none of these systems burned in air, but all burned in 6.2 psia oxygen. Inorganic, organic, and inorganic/organic additives were evaluated in conjunction with these polymers in order to achieve the required survival in the 16.5 psia 60/40 environment. Depending upon formulations, it was possible to achieve nonflammable products when tested in the 1/4 in. x 1/4 in. x 1 in. configuration, even up to and including 16.5 psia oxygen. However, in order to assure this level of flame resistance, it was found necessary to heavily load the matrix with the additives. This resulted in a significant reduction in mechanical properties and large increases in viscosities. Optimization of formulations to obtain a suitable balance between these properties and flammability resistance led to the final selection of Formulation 387 as the primary system.

Lieberman, S. L.↗
NASA NTRS2006

Polyimides From a-BPDA and Aromatic Diamines

Polymers having low color and a favorable combination of other properties, including high glass-transition temperature (Tg) and high mechanical properties (strength, tensile modulus, and toughness) will find use in a variety of terrestrial and space applications. Some of the space applications will be in thin films used as membranes on antennas, solar concentrators, coatings on second-surface mirrors, solar sails, sunshades, thermal and optical coatings, and multi-layer thermal insulation blankets. Depending upon the application, the film will be required to exhibit a unique combination of such properties as resistance to degradation by ultraviolet light, visible light, and electrons; low color and/or low solar absorptivity; resistance to tearing and/or wrinkling during packaging and deployment; and high mechanical properties (e.g. high strength, stiffness, and toughness).

Hergenrother, Paul M.↗
DOE OSTI2023

Particle transport-driven flow dynamics and heat transfer modulation in solar photovoltaic modules: Implications on soiling

Wind-swept debris and excessive heating reduce solar photovoltaic efficiency and accelerate panel degradation. For many solar plants in open environments, particle deposition is well-understood to exacerbate efficiency losses by blocking useable light and insulating panel surfaces. However, little is known about particle behavior in multi-panel systems, where complex wakes dominate and alter trajectories. This study examines debris-laden flow within a scaled array of two model solar panels, observing convective cooling and focusing on turbulent inter-panel flow dynamics. Convection is compared between the first and second panels (P 1 and P 2 ) and for a single inflow velocity at four particle concentrations (Φ v ), including a neutrally buoyant particle (i.e. tracer) case and three water droplet cases. Tracers and Φ v > 0 concentrations show increased convective heat transfer for P 2 compared to P 1 , while inertial particle presence and increased concentration reduces this improvement from +170% to +90%. Particle image velocimetry surrounding P 2 reveals dampened inter-panel wake features for particle-laden flow compared to the tracer case, where diminished mean flow and mean kinetic energy breakdown are observed for the particles due to their inertia. Together, the reduction in comparative convection and dampened wake effects accompanying inertial particle concentration motivates further studies on coupled array physics in debris-filled flow.

14 SOLAR ENERGY↗
DOE OSTI2020

Origin of Capacity Degradation of High-Voltage KVPO 4 F Cathode

Potassium vanadium fluorophosphate (KVPO 4 F) is one of the most promising cathode candidates for K-ion batteries because of its high specific capacity, voltage, and energy density. However, reducing its capacity fade remains an important challenge. This work leverages structure and electrochemical analysis to understand the capacity degradation mechanism of the KVPO 4 F cathode. Interestingly, no structural degradation of the KVPO4F cathode is detected after 200 cycles in the wide voltage window of 5.0-2.5 V (vs K/K + ). Instead, the capacity degradation is attributed to electrolyte decomposition at high voltage ( > 4.5 V vs K/K + ), which causes drying of the electrolyte and the formation of insulating layers on the cathode surface, significantly increasing the polarization. The properties of four KPF 6 - A nd carbonate-based K electrolytes are compared, and 0.7 M KPF 6 in ethylene carbonate/propylene carbonate exhibits the highest oxidation stability and results in the best cycling stability for the KVPO 4 cathode. These findings suggest that the key to improving the cycling stability of KVPO 4 F is to develop novel K electrolytes with even higher oxidation stability.

25 ENERGY STORAGE↗
NASA NTRS1972

Shuttle/Agena study. Annex C: Space shuttle candidate insulator/propellant

The problem associated with the absorption of space tug propellants by the thermal insulation of the space shuttle orbiter during an emergency propellant dump was investigated. A test program was conducted to determine the compatibility of two space shuttle candidate insulation samples with earth-storable propellants. The propellant combinations used were placed in contact with the thermal insulation for two hours. Following exposure to propellants, the insulation samples were heated to 850 F for five minutes. A thermal conductivity index was determined before and after testing to evaluate possible degradation of sample chemical conductivity.

Source record↗
DOE OSTI2022

Extension of Cable Electrical Assessment Techniques to Detect and Discriminate Radiation Aging on Cable Insulation Systems (Abstract)

The purpose of this study of the electrical responses of gamma radiation aged low voltage nuclear cables is to advance tools to determine cable condition (extent of damage) and identify degradation location along the cable length. The developed technology will provide nuclear plant operators with the options to focus cable repair, mitigation, or replacement efforts locally and avoid wholesale cable replacement.

42 ENGINEERING↗
NASA NTRS1985

Degradation of Dielectrics in Space

Effects of radiation (principally, electrons and protons) on dielectric materials summarized in report. Report based on radiation tests of optical coatings, temperature-control coatings, adhesives, radomes, thermal insulators, and light-control surfaces. Materials are primarily polymers and metal/organic coatings.

Bouquet, F. L.↗
DOE OSTI2021

Fragmentation of photovoltaic backsheets after accelerated weathering exposure

The backsheet of a photovoltaic (PV) module functions primarily to provide safe operation through electrical insulation and protect the interior from environmental exposure. For most applications, backsheets consist of opaque, but highly reflective, films that protect inner layers from degradation from ultraviolet (UV) light. Backsheets can fail if they delaminate or form cracks under strain. In a PV module, the maximum strains that can be applied are only on the order of a few percent. The greatest strains are likely to be highly localized around topographical features. Therefore, to assess the likelihood of a crack being initiated in a backsheet, we apply small amplitude strains to backsheet films under microscopic examination using a laser scanning confocal microscope. Furthermore, this allows us to monitor both the depth and density of cracks as well as the onset strain. Here we perform these measurements after exposure to UV light.

14 SOLAR ENERGY↗