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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
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NASA NTRS1979

Satellite measurements of the isotopic composition of galactic cosmic rays

The individual isotopes of galactic cosmic ray Ne, Mg, and Si at 100 MeV/nucleon were clearly resolved with an rms mass resolution of 0.20 amu. The results suggest the cosmic ray source is enriched in Ne-22, Mg-25, and Mg-26 when compared to the solar system. The ratio of (Mg-25)+(Mg-26) to Mg-24, which is approximately 0.49 compared to the solar system value of 0.27, suggest that the cosmic ray source and solar system material were synthesized under different conditions.

Mewaldt, R. A.↗
NASA NTRS1980

Satellite measurements of the isotopic composition of galactic cosmic rays

The individual isotopes of galactic cosmic ray Ne, Mg, and Si at about 100 MeV/nucleon have been resolved with an rms mass resolution of about 0.20 amu. The results suggest that the cosmic ray source is enriched in Ne-22, Mg-25, and Mg-26 when compared to the solar system. It is suggested that the cosmic ray source and solar system material were synthesized under different conditions.

Mewaldt, R. A.↗
NASA NTRS1983

The isotopic composition of helium at high rigidities

The isotopic abundance distribution of the cosmic radiation at energies beyond 1 GeV/AMU can at the present time be determined only with the geomagnetic method. A balloon-borne instrument was flown for 12 hours near the geomagnetic equator to measure the relative abundance of the helium isotopes He-3 and He-4 around 12 GV rigidity. The sharp rigidity cut-off at equatorial latitudes permitted separation of the two isotopes using a high-resolution-gas Cerenkov counter. The experiment thus confirms the predicted sharp cut-off at those latitudes and demonstrates the potential for isotopic separation of other elements, once flights of longer duration can be made.

Jordan, S. P.↗
NASA NTRS2002

Fe Isotopic Composition of Presolar SiC Mainstream Grains

Iron isotopic distribution was measured in SiC mainstream grains from the Murchison meteorite by time-of-flight resonance ionization mass spectrometry. All grains exhibit 54Fe depletions of 50 to 200, lower than what are predicted by calculations of s-process nucleosynthesis in AGB stars. Additional information is contained in the original extended abstract.

Tripa, C. E.↗
NASA NTRS2013

Compound Specific Hydrogen Isotope Composition of Type II and III Kerogen Extracted by Pyrolysis-GC-MS-IRMS

The use of Hydrogen (H) isotopes in understanding oil and gas resource plays is in its infancy. Described here is a technique for H isotope analysis of organic compounds pyrolyzed from oil and gas shale-derived kerogen. Application of this technique will progress our understanding. This work complements that of Pernia et al. (2013, this meeting) by providing a novel method for the H isotope analysis of specific compounds in the characterization of kerogen extracted by analytically diverse techniques. Hydrogen isotope analyses were carried out entirely "on-line" utilizing a CDS 5000 Pyroprobe connected to a Thermo Trace GC Ultra interfaced with a Thermo MAT 253 IRMS. Also, a split of GC-separated products was sent to a DSQ II quadrupole MS to make semi-quantitative compositional measurements of the extracted compounds. Kerogen samples from five different basins (type II and III) were dehydrated (heated to 80 C overnight in vacuum) and analyzed for their H isotope compositions by Pyrolysis-GC-MS-TC-IRMS. This technique takes pyrolysis products separated via GC and reacts them in a high temperature conversion furnace (1450 C) which quantitatively forms H2, following a modified method of Burgoyne and Hayes, (1998, Anal. Chem., 70, 5136-5141). Samples ranging from approximately 0.5 to 1.0mg in size, were pyrolyzed at 800 C for 30s. Compounds were separated on a Poraplot Q GC column. Hydrogen isotope data from all kerogen samples typically show enrichment in D from low to high molecular weight compounds. Water (H2O) average deltaD = -215.2 (V-SMOW), ranging from -271.8 for the Marcellus Shale to -51.9 for the Polish Shale. Higher molecular weight compounds like toluene (C7H8) have an average deltaD of -89.7 0/00, ranging from -156.0 for the Barnett Shale to -50.0 for the Monterey Shale. We interpret these data as representative of potential H isotope exchange between hydrocarbons and sediment pore water during formation within each basin. Since hydrocarbon H isotopes readily exchange with water, these data may provide some useful information on gas-water or oil-water interaction in resource plays, and further as a possible indicator of paleo-environmental conditions. Alternatively, our data may be an indication of H isotope exchange with water and/or acid during the kerogen isolation process. Either of these interpretations will prove useful when deciphering H isotope data derived from kerogen analysis. More experiments are planned to discern these two or other possible scenarios.

Socki, Richard A.↗
NASA NTRS1985

Carbon, hydrogen and nitrogen in carbonaceous chondrites Abundances and isotopic compositions in bulk samples

Whole-rock samples of 25 carbonaceous chondrites were analyzed for contents of C, H and N and delta C-13, delta D and delta N-15. Inhomogeneous distribution of these isotopes within individual meteorites is pronounced in several cases. Few systematic intermeteorite trends were observed; N data are suggestive of isotopic inhomogeneity in the early solar system. Several chondrites revealed unusual compositions which would repay further, more detailed study. The data are also useful for classification of carbonaceous chondrites; N abundance and isotopic compositions can differentiate existing taxonomic groups with close to 100 percent reliability; Al Rais and Renazzo clearly constitute a discrete 'grouplet', and there are hints that both CI and CM groups may each be divisible into two subgroups.

Kerridge, J. F.↗
NASA NTRS1983

Isotopic composition of carbonaceous-chondrite kerogen Evidence for an interstellar origin of organic matter in meteorites

Stepwise combustion has revealed systematic patterns of isotopic heterogeneity for C, H and N in the insoluble organic fraction (m-kerogen) from the Orgueil and Murray carbonaceous chondrites. Those patterns are essentially identical for both meteorites, indicating a common source of m-kerogen. The data cannot be reconciled with a single mass-fractionation process acting upon a single precursor composition. This indicates either a multi-path history of mass-dependent processing or a significant nucleogenetic contribution, or both. If mass-fractionation were the dominant process, the magnitude of the observed isotopic variability strongly suggests that ion-molecule reactions at very low temperatures, probably in interstellar clouds, were responsible. In any case, an interstellar, rather than solar nebular, origin for at least some of the meteoritic organic matter is indicated. This has interesting implications for the origin of prebiotic molecules, temperatures in the early solar system, and the isotopic compositions of volatiles accreted by the terrestrial planets.

Kerridge, J. F.↗
NASA NTRS2014

Hydrogen (H) Isotope Composition of Type II Kerogen Extracted by Pyrolysis-GC-MS-IRMS: Terrestrial Shale Deposits as Martian Analogs

Described here is a technique for H isotope analysis of organic compounds pyrolyzed from kerogens isolated from gas‐ and liquids‐rich shales. Application of this technique will progress the understanding of the use of H isotopes not only in potential kerogen occurrences on Mars, but also in terrestrial oil and gas resource plays. H isotope extraction and analyses were carried out utilizing a CDS 5000 Pyroprobe connected to a Thermo Trace GC interfaced with a Thermo MAT 253 IRMS. Also, a split of GC‐separated products was sent to a DSQ II quadrupole MS to make qualitative and semi‐quantitative compositional measurements of these products. Kerogen samples from five different basins (type II and II‐S) were dehydrated (heated to 80 C overnight under vacuum) and analyzed for their H isotope compositions by Pyrolysis‐GC‐MS‐TC‐IRMS. This technique takes pyrolysis products separated via GC and reacts them in a high temperature conversion furnace (1450 C), which quantitatively forms H2. Samples ranging from ~0.5 to 1.0mg in size, were pyrolyzed at 800 C for 30s. and separated on a Poraplot Q GC column. H isotope data from all kerogen samples typically show enrichment in D from low to high molecular weight. H2O average delta D = ‐215.2 per mille (V‐SMOW), ranging from ‐ 271.8 per mille for the Marcellus Shale to ‐51.9 per mille for a Polish shale. Higher molecular weight compounds like toluene (C7H8) have an average delta D of ‐89.7 per mille, ranging from ‐156.0 per mille for the Barnett Shale to ‐50.0 per mille for the Monterey Shale. We interpret these data as representative of potential H isotope exchange between hydrocarbons and sediment pore water during basin formation. Since hydrocarbon H isotopes readily exchange with water, these data may provide some useful information on gas‐water or oil‐water interaction in resource plays, and further as a possible indicator of paleoenvironmental conditions. Alternatively, our data may be an indication of H isotope exchange with water and/or acid during the kerogen isolation process. Either of these interpretations will prove useful when deciphering H isotope data derived from kerogen analyses. Understanding the role that these H‐bearing compounds play in terrestrial shale paleo‐environmental reconstruction may also prove useful as analogs for understanding the interactions of water and potential kerogen/organic compounds on the planet Mars.

Socki, Richard A.↗
NASA NTRS1990

Experiments to study cosmic ray isotopic composition up to Zr-40

An overview is presented of instruments and techniques being developed with improved mass resolution and large geometry factor for the study of isotopes. The Advanced Composition Explorer and the Large-Isotope Spectrometer for Astromag are presented as two experiment systems that can reduce statistical uncertainty for the iron isotopes to a small percentage. The instruments are capable of studying isotopes with values of Z of 30-40 by means of orbiting or lunar-based platforms when used for long-duration exposure.

Milliken, Barrett↗
NASA NTRS2001

The isotopic composition of cosmic-ray calcium

We find that the relative abundance of cosmic ray calcium isotopes in the cosmic-ray source are very similar to those found in solar-system material, in spite of the fact that different types of stars are thought to be responsible for producing these two isotopes. This observation is consistent with the view that cosmic rays are derived from a mixed sample of interstellar matter.

cosmic rays calcium isotopes advanced composition ↗
NASA NTRS2024

Bulk Oxygen Isotope Composition of Aggregate Samples From Asteroid Bennu Returned By OSIRIS-REx

On 24 September 2023, the OSIRIS-REx spacecraft delivered to Earth material collected from the surface of the B-type asteroid Bennu. During its ~2.5-year encounter with the asteroid, OSIRIS-REx made many important discoveries, including establishing its extremely primitive chemical composition, the presence of at least two lithologies, and evidence of fluid flow on its parent asteroid. One of the driving hypotheses of the Sample Analysis Plan is that Bennu’s dominant lithologies are comparable to the most aqueously altered carbonaceous chondrites. Oxygen three-isotope analysis is a powerful tool for defining the relationship between different meteorite groups and can be used to understand the nature of the returned Bennu samples. The O isotope signatures reflect the materials that parent asteroids accreted from and the geological processes that operated during asteroidal evolution. Aggregate samples of particles (typically <500 μm) likely sampled many different larger stones and boulders, and their composition may therefore represent the average composition of Bennu. Fractionation of the sample, e.g. comparison of aliquots of finer material with coarser particles within the aggregate samples, offers the opportunity to identify different isotopic reservoirs within the returned material. The average O isotope composition will also provide a baseline from which to identify and characterize any exogenous clasts present in the sample.

I. A. Franchi↗
NASA NTRS1980

Elemental composition, isotopes, electrons and positrons in cosmic rays

Experimental studies on the composition of cosmic rays are reviewed. Studies of elemental composition and time variation, Fe and near-Fe nuclei, trans-iron, high-energy spectra, antiprotons, isotopes, and electrons and positrons are discussed. Some theoretical studies of electrons are also considered.

Balasubrahmanyan, V. K.↗
NASA NTRS1983

The isotopic composition of solar flare noble gases

The relative elemental and isotopic abundances of noble gases provide insights into a number of topics related to the solar system. Neon is in many ways the most diagnostic of the noble gases. The diagnostic character is mainly related to the variation in the relative abundance of the two most abundant neon isotopes, Ne-20 and Ne-22. The available evidence suggests that trapped neon found in meteorites and in lunar samples consists of as many as five isotopically distinct components, including neon A, B, C, D, and E. Neon B has been shown to be due to solar wind neon which has been directly implanted into the material found in a meteorite. It appears that neon E is extrasolar in origin. There exist ambiguities regarding the origins of the remaining three components. The present investigation is concerned with a reexamination of the existing data in an effort to eliminate or at least clarify these ambiguities. It is found that neon C is apparently due to directly implanted, low-energy solar flare neon nuclei.

Black, D. C.↗
NASA NTRS2000

Carbon isotopic composition of individual Precambrian microfossils

Ion microprobe measurements of carbon isotope ratios were made in 30 specimens representing six fossil genera of microorganisms petrified in stromatolitic chert from the approximately 850 Ma Bitter Springs Formation, Australia, and the approximately 2100 Ma Gunflint Formation, Canada. The delta 13C(PDB) values from individual microfossils of the Bitter Springs Formation ranged from -21.3 +/- 1.7% to -31.9 +/- 1.2% and the delta 13C(PDB) values from microfossils of the Gunflint Formation ranged from -32.4 +/- 0.7% to -45.4 +/- 1.2%. With the exception of two highly 13C-depleted Gunflint microfossils, the results generally yield values consistent with carbon fixation via either the Calvin cycle or the acetyl-CoA pathway. However, the isotopic results are not consistent with the degree of fractionation expected from either the 3-hydroxypropionate cycle or the reductive tricarboxylic acid cycle, suggesting that the microfossils studied did not use either of these pathways for carbon fixation. The morphologies of the microfossils suggest an affinity to the cyanobacteria, and our carbon isotopic data are consistent with this assignment.

Non-NASA Center↗