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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Selectivity in gas–liquid interactions: Molecular beam scattering of CD 4 and ND 3 from an aqueous flat liquid jet

The dynamics of polar and nonpolar molecules colliding with an aqueous surface are characterized by scattering molecular beams of deuterated methane and ammonia, CD 4 and ND 3 (E i = 28.9 and 30.3 kJ mol −1 , respectively), from a flat liquid jet of cold salty water (8 m LiBr, 230 K). Translational energy distributions of scattered species collected as a function of collision geometry probe both impulsive scattering (IS) and thermal desorption (TD) mechanisms. Here, we find that CD 4 scattering is dominated by IS and exhibits a super-specular angular distribution. The fraction of TD scattering events is notably smaller for cold salty water than for dodecane, consistent with a higher free energy of solvation for CD 4 in the water jet. In contrast, no scattering signal is seen for ND 3 from the water jet, a result attributed to the high solubility and efficient protonation of ND 3 in liquid water. The IS channel for CD 4 was analyzed using a soft-sphere model, yielding a higher internal energy (E int ) and lower effective surface mass (m eff ) than was seen for Ne/water; the higher value of E int is attributed to rotational excitation of the scattered CD 4 . These findings demonstrate that the outcomes of a gas–liquid collision—scattering trajectory, surface adherence, and energy transfer—are directed at the molecular level by both the gaseous scatterer and liquid surface.

Foreman, Madison M. [University of California, Ber↗

Dynamics of vacancy-induced modes in the non-Abelian Kitaev spin liquid

Here, we study the dynamical response of vacancy-induced quasiparticle excitations in the site-diluted Kitaev spin liquid with a magnetic field. Due to the flux-binding effect and the emergence of dangling Majorana fermions around each spin vacancy, the low-energy physics is governed by a set of vacancy-induced quasi-zero-energy modes. These localized modes result in unique characteristics of the dynamical spin correlation functions, which intriguingly mimic the single-quasiparticle density of states and further exhibit a quasi-zero-frequency peak. By recognizing the potential observability of these local correlation functions via scanning tunneling microscopy (STM), we show how the STM response is sensitive to the local flux configuration, the magnetic field strength, and the vacancy concentration. Constructing a simple model of the localized modes, we also elucidate how the local correlation functions can be interpreted in terms of the hybridization between these modes.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Two-phase flow numerical analysis of electrode geometry for alkaline water electrolyzers

Hydrogen is a promising component of a future energy-secure and efficient economy, but its competitiveness depends on reducing production costs. One strategy is to operate alkaline water electrolyzers at higher current densities to increase output. However, this intensifies performance losses due to gas bubble accumulation, which blocks transport pathways and deactivates electrochemically active surfaces. Enhancing bubble evacuation through electrode design is therefore essential. Previous studies have explored various approaches — such as modifying surface morphology, applying sonication or pressure modulation, and introducing surfactants — but these efforts have addressed a limited range of conditions due to the complexity of two-phase flow and electrode geometries. Experiments have also largely been focused on either cell level improvements, which lack the information necessary to isolate each contributing factor, or on modified geometries that are not relevant to practical cell operation. From a modeling perspective, conventional Eulerian multiphase models do not track the complex gas–liquid interfacial dynamics and often neglect surface tension and contact angle effects, reducing their predictive accuracy. To provide insights on the effects of different electrode geometries on the performance of alklaine water electrolyzers this work employs an immersed boundary volume-of-fluid method to simulate bubble behavior in 3D porous electrodes. Multiple base electrode geometries, typically used in practice, with varying porosity are evaluated under a constant surface gas generation rate. Simulation data is analyzed to quantify electrode gas coverage, bubble size dynamics and other relevant metrics. Results show that porosity strongly influences bubble accumulation on electrode surfaces, with higher porosity reducing gas coverage, and its not strictly dependent on the electrode geometry. However, the electrode’s base geometry significantly affects gas accumulation at the separator gap, independent of porosity. A foam electrode geometry resulted in the lowest gas coverage of all electrodes with a median volumetric gas coverage of 11%, but at the cost of a 70% reduction in active area compared with the largest surface area electrode, while gyroid electrodes showed the best trade-off between gas coverage, particularly at the separator surface, and electrochemically active area. In conclusion, the results highlight the need for holistic electrode design strategies.

Alkaline↗

Finite element solution of low bond number sloshing

The dynamics of liquid propellant in a low Bond number environment which are critical to the design of spacecraft systems with respect to orbital propellant transfer and attitude control system were investigated. Digital computer programs were developed for the determination of liquid free surface equilibrium shape, lateral slosh natural vibration mode shapes, and frequencies for a liquid in a container of arbitrary axisymmetric shape with surface tension forces the same order of magnitude as acceleration forces. A finite volume element representation of the liquid was used for the vibration analysis. The liquid free surface equilibrium shapes were computed for several tanks at various contact angles and ullage volumes. A configuration was selected for vibration analysis and lateral slosh mode shapes and natural frequencies were obtained. Results are documented.

Wohlen, R. L.↗

Erosional processes in channelized water flows on Mars

A hypothesis is investigated according to which the Martian outflow channels were formed by high-velocity flows of water or dynamically similar liquid. It is suggested that the outflow channels are largely the result of several interacting erosional mechanisms, including fluvial processes involving ice covers, macroturbulence, streamlining, and cavitation.

Baker, V. R.↗

Space processing applications rocket project. SPAR 8

The Space Processing Applications Rocket Project (SPAR) VIII Final Report contains the engineering report prepared at the Marshall Space Flight Center (MSFC) as well as the three reports from the principal investigators. These reports also describe pertinent portions of ground-based research leading to the ultimate selection of the flight sample composition, including design, fabrication, and testing, all of which are expected to contribute immeasurably to an improved comprehension of materials processing in space. This technical memorandum is directed entirely to the payload manifest flown in the eighth of a series of SPAR flights conducted at the White Sands Missile Range (WSMR) and includes the experiments entitled Glass Formation Experiment SPAR 74-42/1R, Glass Fining Experiment in Low-Gravity SPAR 77-13/1, and Dynamics of Liquid Bubbles SPAR Experiment 77-18/2.

Chassay, R. P.↗

Fusion Target Technology

In order to produce the high quality spherical shells that are required, three parameters must be controlled accurately: the shell dimensions, shell sphericity and concentricity, and the surface topology of the shell. Attempts to conduct experiments on the dynamics of liquid bubbles (molten shells) in laboratories are limited by a strong coupling among the three parameters, time, gravity, and temperature. These limitations are circumvented and detailed study of each of the important processes is carried out through the use of low gravity environments collectively available in drop towers, in KC-135 flights, in a neutrally buoyant immiscible system, and in an acoustic levitation system.

Wang, T. G.↗

Analysis of radiative and phase-change phenomena with application to space-based thermal energy storage

The simplified geometry for the analysis is an infinite, axis symmetric annulus with a specified solar flux at the outer radius. The inner radius is either adiabatic (modeling Flight Experiment conditions), or convective (modeling Solar Dynamic conditions). Liquid LiF either contacts the outer wall (modeling ground based testing), or faces a void gap at the outer wall (modeling possible space based conditions). The analysis is presented in three parts: Part 3 considers and adiabatic inner wall and linearized radiation equations; part 2 adds effects of convection at the inner wall; and part 1 includes the effect of the void gap, as well as previous effects, and develops the radiation model further. The main results are the differences in melting behavior which can occur between ground based 1 g experiments and the microgravity flight experiments. Under 1 gravity, melted PCM will always contact the outer wall having the heat flux source, thus providing conductance from this source to the phase change front. In space based tests where a void gap may likely form during solidification, the situation is reversed; radiation is now the only mode of heat transfer and the majority of melting takes place from the inner wall.

Lund, Kurt O.↗

Tenth Workshop for Computational Fluid Dynamic Applications in Rocket Propulsion, part 1

Experimental and computational fluid dynamic activities in rocket propulsion were discussed. The workshop was an open meeting of government, industry, and academia. A broad number of topics were discussed including computational fluid dynamic methodology, liquid and solid rocket propulsion, turbomachinery, combustion, heat transfer, and grid generation.

R.W. Williams↗

Probing the microscopic corrugation of liquid surfaces with gas-liquid collisions

We have measured the directions and velocities of Ne, Ar, and Xe atoms scattering from perfluorinated ether and hydrocarbon liquids to probe the relationship between the microscopic roughness of liquid surfaces and gas-liquid collision dynamics. Impulsive energy transfer is governed by the angle of deflection: head-on encounters deposit more energy than grazing collisions. Many atoms scatter in the forward direction, particularly at glancing incidence. These results imply that the incoming atoms recoil locally from protruding C-H and C-F groups in hard spherelike collisions.

King, Mackenzie E.↗

Eleventh Workshop for Computational Fluid Dynamic Applications in Rocket Propulsion

Conference publication includes 79 abstracts and presentations and 3 invited presentations given at the Eleventh Workshop for Computational Fluid Dynamic Applications in Rocket Propulsion held at George C. Marshall Space Flight Center, April 20-22, 1993. The purpose of the workshop is to discuss experimental and computational fluid dynamic activities in rocket propulsion. The workshop is an open meeting for government, industry, and academia. A broad number of topics are discussed including computational fluid dynamic methodology, liquid and solid rocket propulsion, turbomachinery, combustion, heat transfer, and grid generation.

Williams, R. W.↗

Eleventh Workshop for Computational Fluid Dynamic Applications in Rocket Propulsion, Part 1

Conference publication includes 79 abstracts and presentations given at the Eleventh Workshop for Computational Fluid Dynamic Applications in Rocket Propulsion held at the George C. Marshall Space Flight Center, April 20-22, 1993. The purpose of this workshop is to discuss experimental and computational fluid dynamic activities in rocket propulsion. The workshop is an open meeting for government, industry, and academia. A broad number of topics are discussed including computational fluid dynamic methodology, liquid and solid rocket propulsion, turbomachinery, combustion, heat transfer, and grid generation.

Williams, Robert W.↗

Short-duration low-gravity experiments - Time scales, challenges and results

Short-duration low-gravity experiments can be conducted either in drop tubes and drop towers, or on sounding rockets and aircraft on ballistic trajectories. While these facilities offer more frequent flight opportunities and higher cost effectiveness than orbiting spacecraft, their relatively short low-gravity times are often perceived as limiting their utility to only a narrow range of applications and research areas. In this review it is shown, based on scaling laws for diffusive transport of momentum, species and heat, radiative heat transfer and capillarity-driven motion, that with proper consideration of the characteristic length scales, a host of phenomena can be meaningfully investigated during a few seconds. This usefulness of short-duration low-gravity facilities is illustrated with numerous results of recent studies of solidification, combustion, transport in multiphase systems, statics and dynamics of liquid surfaces, magnetic Benard convection, fluid management, transport properties and the graviperception in cells.

Rosenberger, F.↗