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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Monte Carlo simulation of charged particle impact on the satellites of Jupiter and Saturn

Ensemble-averaged lifetimes of Jovian and Saturnian trapped charged particles against loss by impact on natural satellites are presented. Precise values of these loss rates can be obtained from the known geometry of the satellite orbits, magnetic fields, and particle trajectory. These loss rates are needed as an ingredient of transport theory which is usually formulated in terms of the first and second adiabatic invariants and radial distance. The effects of satellite orbital inclination and eccentricity, ion charge to mass ratio and energy, equatorial pitch, and distance from the planet on the particle lifetime are discussed utilizing a tilted, but not offset, dipolar field geometry resulting in lifetime values expressed as functions of the first two adiabatic invariants and the equatorial radial distance from the planet.

Bell, E. V., II↗
NASA NTRS1994

Regimes of high-energy shock emission from the Be star/pulsar system PSR 1259-63

PSR B1259-63 is a 47 ms radio pulsar in a wide, eccentric orbit with a Be star. We study the shock interaction between the pulsar and the companion's mass outflow and investigate the time evolution of radiative shock regimes. We find that for small values of the Be star's mass-loss rate, inverse-Compton scattering is likely to dominate the shock emission. Alternately, for a large mass-loss rate, synchrotron emission will dominate. Multifrequency X-ray and gamma-ray observations near periastron can distinguish between these cases and yield unique constraints on the pulsar and Be star winds. The PSR B1259-63 system provides a unique laboratory to study the time-dependent interaction of a pulsar wind with the circumbinary material from its companion star.

Tavani, Marco↗
NASA NTRS1981

Model for the circumstellar gas around alpha Orionis

Models are presented to explain the physical conditions in the circumstellar envelope surrounding the red supergiant Alpha Orionis. The models of the CO density and neutral atomic potassium density are calculated for the outer shell to reproduce simultaneously both the radio detection of CO and optical measurements of the amount of scattering by neutral potassium around Alpha Ori. CO and potassium loss rates of 7 x 10 to the 39th/sec and 8 x 10 to the 37th/sec are obtained, which imply a potassium to carbon ratio greater than that of the sun by about a factor of 25. The low carbon abundance may be attributed to extensive CNO processing, and, together with the potassium abundance, indicates a total mass loss rate of 0.000015 solar masses/year. The mass loss, mass and abundance properties of Alpha Ori suggest it to be the progenitor of a Type II supernova such as Cas A.

Jura, M.↗
DOE OSTI2022

Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates

Interest in Criegee intermediates (CIs), often termed carbonyl oxides, and their role in tropospheric chemistry has grown massively since the demonstration of laboratory-based routes to their formation and characterization in the gas phase. This article reviews current knowledge regarding the electronic spectroscopy of atmospherically relevant CIs like CH 2 OO, CH 3 CHOO, (CH 3 ) 2 COO and larger CIs like methyl vinyl ketone oxide and methacrolein oxide that are formed in the ozonolysis of isoprene, and of selected conjugated carbene-derived CIs of interest in the synthetic chemistry community. Of the aforementioned atmospherically relevant CIs, all except CH 2 OO and (CH 3 ) 2 COO exist in different conformers which, under tropospheric conditions, can display strikingly different thermal loss rates via unimolecular and bimolecular processes. Calculated photolysis rates based on their absorption properties suggest that solar photolysis will rarely be a significant contributor to the total loss rate for any CI under tropospheric conditions. Nonetheless, there is ever-growing interest in the absorption cross sections and primary photochemistry of CIs following excitation to the strongly absorbing 1 ππ* state, and how this varies with CI, with conformer and with excitation wavelength. Furthermore, the later part of this review surveys the photochemical data reported to date, including a range of studies that demonstrate prompt photo-induced fission of the terminal O–O bond, and speculates about possible alternate decay processes that could occur following non-adiabatic coupling to, and dissociation from, highly internally excited levels of the electronic ground state of a CI.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2014

Secular Climate Change on Mars: An Update Using One Mars Year of MSL Pressure Data

The South Polar Residual Cap (SPRC) on Mars is an icy reservoir of CO2. If all the CO2 trapped in the SPRC were released to the atmosphere the mean annual global surface pressure would rise by approximately 20 Pa. Repeated MOC and HiRISE imaging of scarp retreat within the SPRC led to suggestions that the SPRC is losing mass. Estimates for the loss rate vary between 0. 5 Pa per Mars Decade to 13 Pa per Mars Decade. Assuming 80% of this loss goes directly into the atmosphere, an estimate based on some modeling (Haberle and Kahre, 2010), and that the loss is monotonic, the global annual mean surface pressure should have increased between approximately 1-20 Pa since the Viking mission (approximately 20 Mars years ago). Surface pressure measurements by the Phoenix Lander only 2.5 Mars years ago were found to be consistent with these loss rates. Last year at this meeting we compared surface pressure data from the MSL mission through sol 360 with that from Viking Lander 2 (VL-2) for the same period to determine if the trend continues. The results were ambiguous. This year we have a full Mars year of MSL data to work with. Using the Ames GCM to compensate for dynamics and environmental differences, our analysis suggests that the mean annual pressure has decreased by approximately 8 Pa since Viking. This result implies that the SPRC has gained (not lost) mass since Viking. However, the estimated uncertainties in our analysis are easily at the 10 Pa level and possibly higher. Chief among these are the hydrostatic adjustment of surface pressure from grid point elevations to actual elevations and the simulated regional environmental conditions at the lander sites. For these reasons, the most reasonable conclusion is that there is no significant difference in the size of the atmosphere between now and Viking. This implies, but does not demand, that the mass of the SPRC has not changed since Viking. Of course, year-to-year variations are possible as implied by the Phoenix data. Given that there has been no unusual behavior in the climate system as observed by a variety of spacecraft at Mars since Phoenix, its seems more likely that the Phoenix data simply did not have a long enough record to accurately determine annual mean pressure changes as Haberle and Kahre (2010) cautioned. In the absence of a strong signal in the MSL data, we conclude that if the SPRC is loosing mass it is not going into the atmosphere reservoir.

Phoenix data↗
NASA NTRS1989

Radio-continuum emission from the ionized stellar winds of warm supergiants

The Very Large Array has been used at an observing wavelength of 6 cm to survey 25 supergiants of spectral types between B2 and F8. Only one of these stars (Beta Ori, or Rigel) has been detected as a radio-continuum source, with an inferred 6 cm luminosity L6 of 7 x 10 to the 16th ergs/sec per Hz. Rigel may also be an X-ray source (and, if it were, would be the only X-ray detected star out of the 12 stars in this sample that were observed by Einstein. An extended source of more than 10 mJy flux density with the same angular dimensions and location as He 1-5, the planetary nebula surrounding the peculiar supergiant FG Sge, and a weak localized source of roughly 0.1-0.2 mJy somewhat offset from the center of the extended radio emission have also been detected. The upper limits to L6 for the F Ib stars are as much as an order of magnitude below the level at which Rigel was detected. If the radio emission from Rigel is interpreted as free-free radiation from its stellar wind, the inferred ionized mass-loss rate is 2.5 x 10 th the 7th solar mass/yr. The most stringent upper limits to the ionized mass-loss rates obtained for the F and A supergiants are not greater than 10 to the -8th solar mass/yr and less than or equal to 10 to the -7th solar mass/yr, respectively.

Drake, S. A.↗
NASA NTRS1990

Loss of ozone in the Arctic vortex for the winter of 1989

Measurements of ClO (Brune et al., 1990) acquired during the Airborne Arctic Stratospheric Expedition are used to infer concentrations of reactive chlorine (ClO + 2 x Cl2O2). Observed fields of potential temperature and potential vorticity are used to extrapolate in situ data to larger regions of the vortex. Calculated values of the loss rate of O3, based on estimates of reactive chlorine and measurements of BrO (Toohey et al., 1990), suggest that the loss of O3 was abut 12 pct for levels of the atmosphere with potential temperatures between 440 and 470 K over the 39 day duration of the ER-2 flights into the polar vortex. Calculated loss rates agree with observed rates of removal of O3, although significant uncertainties exist for each.

Salawitch, Ross J.↗
NASA NTRS1971

Mach 1 oxidation of thoriated nickel chromium at 1204 C (2200 F)

TD NiCr was exposed to a Mach 1, 1-atmosphere gas stream at 1204 C for times up to 50 hours. Weight change, metal thickness loss, X-ray diffraction, metallographic, and electron microprobe analyses were made. Neither surface preparation nor thermal cycling had an appreciable effect on the results. Initially, Cr2O3 formed and volatilized, allowing a rapid metal loss rate of 40 microns per hour. After about 1 hour the Cr2O3 broke down, resulting in an NiO overgrowth. The metal loss rate then slowed to 2.5 microns per hour and remained constant to 50 hours.

Lowell, C. E.↗
NASA NTRS1983

A second-order effect of stratospheric vertical motions

A byproduct of stratospheric motion distinct from the normal downgradient transport represented by vertical eddy diffusion is studied. It is suggested that an air parcel executes a random walk over a range that could be several kilometers, and similar amplitudes could be present in wavelike oscillations. The photochemical loss rate should therefore be averaged over this range, which give an effect that is proportional to the curvature of the profile of loss rate, and is particularly large for fluorocarbon-11, CFCl3. Test computations are presented which indicate that the known discrepancy between observations and predictions for this compound can be at least partly reconciled for plausible values of the amplitude.

Hunten, D. M.↗
NASA NTRS1990

Ion phase space densities in the Jovian magnetosphere

The Voyager Low Energy Charged Particle ion data from the Jovian magnetosphere were analyzed to determine the phase-space densities of particles in the region between 5 and 80 Jupiter radii. Data from the Jovian current sheet crossings for locally mirroring particles were used. These are the first calculations of phase-space densities in the nondipolar field region containing the Jovian magnetodisk current sheet. The profiles are consistent with lossy inward radial transport and a source in the outer magnetosphere. The inferred loss rate in a radial diffusion model measuring how quickly particles are scattered out of the neutral sheet exceeds the usual strong diffusion loss rate.

Paranicas, C. P.↗
NASA NTRS1992

Global Kinetic Constants for Thermal Oxidative Degradation of a Cellulosic Paper

Values of global kinetic constants for pyrolysis, thermal oxidative degradation, and char oxidation of a cellulosic paper were determined by a derivative thermal gravimetric study. The study was conducted at heating rates of 0.5, 1, 1.5, 3, and 5 C/min in ambient atmospheres of nitrogen, 0.28, 1.08, 5.2 percent oxygen concentrations, and air. Sample weight loss rate, concentrations of CO, CO2, and H2O in the degradation products, and oxygen consumption were continuously measured during the experiment. Values of activation energy, preexponential factor, orders of reaction, and yields of CO, CO2, H2O, total hydrocarbons, and char for each degradation reaction were derived from the results. Heat of reaction for each reaction was determined by differential scanning calorimetry. A comparison of the calculated CO, CO2, H2O, total hydrocarbons, sample weight loss rate, and oxygen consumption was made with the measured results using the derived kinetic constants, and the accuracy of the values of kinetic constants was discussed.

Kashiwagi, Takashi↗
NASA NTRS2022

Constraining the Physical Properties of Stellar Coronal Mass Ejections with Coronal Dimming: Application to Far-ultraviolet Data of є Eridani

Coronal mass ejections (CMEs) are a prominent contributor to solar system space weather and might have impacted the Sun's early angular momentum evolution. A signal diagnostic of CMEs on the Sun is coronal dimming: a drop in coronal emission, tied to the mass of the CME, that is the direct result of removing emitting plasma from the corona. We present the results of a coronal dimming analysis of Fe XII 1349 Å and Fe XXI 1354 Å emission from ϵ Eridani ( ϵ Eri), a young K2 dwarf, with archival far-ultraviolet observations by the Hubble Space Telescope's Cosmic Origins Spectrograph. Following a flare in 2015 February, ϵ Eri's Fe XXI emission declined by 81 ± 5%. Although enticing, a scant 3.8 minutes of preflare observations allows for the possibility that the Fe XXI decline was the decay of an earlier, unseen flare. Dimming nondetections following each of three prominent flares constrain the possible mass of ejected Fe XII-emitting (1 MK) plasma to less than a few × 10 15 g. This implies that CMEs ejecting this much or more 1 MK plasma occur less than a few times per day on ϵ Eri. On the Sun, 10 15 g CMEs occur once every few days. For Eri, the mass-loss rate due to CME-ejected 1 MK plasma could be < 0.6 Ṁ Ꙩ well below the star's estimated 30 Ṁ Ꙩ mass-loss rate (wind + CMEs). The order-of-magnitude formalism we developed for these mass estimates can be broadly applied to coronal dimming observations of any star.

Stellar coronal mass ejections↗
NASA NTRS1978

The expanding envelope of Tau Sco /B0 V/

Results are reported for an analysis of the UV spectrum of Tau Sco as observed by Copernicus. It is found that the spectrum exhibits a number of resonance lines of C III, C IV, N III, N V, O VI, Si IV, and P V, all of which have extended violet absorption wings that reach several different velocities. The UV lines of Tau Sco are compared with those of Zeta Pup, the line profiles are studied by a comparison with predicted profiles, and the optical depth of the lines is derived as a function of velocity in the envelope by means of line fitting. The velocity-height relation is examined, the mass-loss rate is derived, and the ionization equilibrium in the envelope is investigated. The data are then evaluated in light of three proposed mass-loss mechanisms. The mass-loss rate is estimated to be about 7 billionths of a solar mass per year, and the observed rapid acceleration of the stellar wind is attributed to radiation pressure in the envelope. It is shown that an imperfect-flow model for the stellar wind gives qualitative agreement with the observations.

Lamers, H. J. G. L. M.↗
NASA NTRS1992

The collapse of white dwarfs to neutron stars

The observable consequences of an accreting white dwarf collapsing directly to a neutron star are considered. The outcome depends critically upon the nature of the wind that is driven by neutrino absorption in the surface layers as the dwarf collapses. Unlike previous calculations which either ignored mass loss or employed inadequate zoning to resolve it, a characteristic mass-loss rate of about 0.005 solar mass/s and an energy input of 5 x 10 exp 50 ergs/s is found. Such a large mass-loss rate almost completely obscures any prompt electromagnetic display and certainly rules out the production by this model of gamma-ray bursts situated at cosmological distances. The occurrence of such collapses with the Milky Way Galaxy might, however, be detected and limited by their nucleosynthesis and gamma-ray line emission. To avoid the overproduction of rare neutron-rich isotopes heavier than iron, such events must be very infrequent, probably happening no more than once every thousand years.

Woosley, S. E.↗
NASA NTRS1979

Preliminary estimates of mass loss from O-type stars

P Cygni profiles of C IV resonance lines (observed for O-type stars) taken with the high resolution spectrograph on IUE are presented, and data indicate that terminal velocity is proportional to photospheric escape velocity. Parameters determining these line profiles are stellar radius, mass loss rate, the velocity law, the abundance (assumed to be solar) of the absorbing ion, and atomic parameters such as wavelength and oscillator strength, while the ionization fraction is assumed to be the same as that of Zeta Pup (Lamers and Morton, 1976). Thus an electron temperature of 200,000 K, a radiation temperature of 30,000 K and an electron density of 10 to the 10th are adopted. It is concluded that mass loss rates are considerably lower in O stars than in Of stars, but that if mass loss is really proportional to luminosity, the earliest O stars should have rates at least a factor of 10 higher than were found.

Conti, P. S.↗
NASA NTRS1987

Guided-wave approaches to spectrally selective energy absorption

Results of experiments designed to demonstrate spectrally selective absorption in dielectric waveguides on semiconductor substrates are reported. These experiments were conducted with three waveguides formed by sputtering films of PSK2 glass onto silicon-oxide layers grown on silicon substrates. The three waveguide samples were studied at 633 and 532 nm. The samples differed only in the thickness of the silicon-oxide layer, specifically 256 nm, 506 nm, and 740 nm. Agreement between theoretical predictions and measurements of propagation constants (mode angles) of the six or seven modes supported by these samples was excellent. However, the loss measurements were inconclusive because of high scattering losses in the structures fabricated (in excess of 10 dB/cm). Theoretical calculations indicated that the power distribution among all the modes supported by these structures will reach its steady state value after a propagation length of only 1 mm. Accordingly, the measured loss rates were found to be almost independent of which mode was initially excited. The excellent agreement between theory and experiment leads to the conclusion that low loss waveguides confirm the predicted loss rates.

Stegeman, G. I.↗
NASA NTRS1988

Mass loss from S stars

The mass-loss process in S stars is studied using 65 S stars from the listing of Wing and Yorka (1977). The role of pulsations in the mass-loss process is examined. It is detected that stars with larger mass-loss rates have a greater amplitude of pulsations. The dust-to-gas ratio for the S stars is estimated as 0.002 and the average mass-loss rate is about 6 x 10 to the -8th solar masses/yr. Some of the properties of the S stars, such as scale height, surface density, and lifetime, are measured. It is determined that scale height is 200 pc; the total duration of the S star phase is greater than or equal to 30,000 yr; and the stars inject 3 x 10 to the -6th solar masses/sq kpc yr into the interstellar medium.

Jura, M.↗
NASA NTRS1991

Atomic oxygen testing with thermal atom systems - A critical evaluation

The use of thermal atom (kinetic energy near 0.04 eV) test methods as a materials selection and screening technique for LEO spacecraft is critically evaluated in this paper. The physics and chemistry of the thermal atom environments are shown to produce specific mass loss rates (mg/sq cm per min) and reaction efficiencies (Re) radically different from those produced in the LEO environment. A response surface study shows that specific mass loss rates change rapidly with plasma-asher parameters and seldom agree with flight data. FEP Teflon is shown to react by a different mechanism than Kapton, polyethylene, or graphite. The Re (Re = volume of material removed/oxygen atom) of Kapton, polyethylene, Mylar, Tedlar, FEP Teflon, and graphite measured in a flowing afterglow apparatus are 0.001 to 0.0001 those measured with high-energy atoms (kinetic energy 1.5 eV or greater) in beam systems or in LEO. The effect of sample temperature and atom impact energy on Re is discussed. A simple kinetic model describing the reaction of atomic oxygen with polymer surfaces is developed. Guidelines and recommendations for thermal atom testing and interpretation of test results are presented.

Koontz, Steven L.↗