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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
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NASA NTRS1996

Stratospheric Chlorine partitioning: Constraints from Shuttle-borne Measurements of [HCl], [ClNO3] and [ClO]

Measured stratospheric mixing ratios of HCl, ClNO3, and ClO from ATMOS and MAS are poorly reproduced by models using recommended kinetic parameters. This discrepancy is not resolved by new rates for the reactions Cl+CH4 and OH+HCl derived from weighted fits to laboratory measurements. A deficit in modeled [HCl] and corresponding overprediction of [ClNO3] and [ClO], which increases with altitude, suggests that production of HCl between 20 and 50 km is much faster than predicted from recommended rates.

Michelsen, H. A.↗
NASA NTRS1997

Investigation of Cloud Properties and Atmospheric Profiles with MODIS

The WINter Cloud Experiment (WINCE) was directed and supported by personnel from the University of Wisconsin in January and February. Data sets of good quality were collected by the MODIS Airborne Simulator (MAS) and other instruments on the NASA ER2; they will be used to develop and validate cloud detection and cloud property retrievals over winter scenes (especially over snow). Software development focused on utilities needed for all of the UW product executables; preparations for Version 2 software deliveries were almost completed. A significant effort was made, in cooperation with SBRS and MCST, in characterizing and understanding MODIS PFM thermal infrared performance; crosstalk in the longwave infrared channels continues to get considerable attention.

Menzel, Paul↗
NASA NTRS1996

Land Surface Temperature Measurements form EOS MODIS Data

We have developed a physics-based land-surface temperature (LST) algorithm for simultaneously retrieving surface band-averaged emissivities and temperatures from day/night pairs of MODIS (Moderate Resolution Imaging Spectroradiometer) data in seven thermal infrared bands. The set of 14 nonlinear equations in the algorithm is solved with the statistical regression method and the least-squares fit method. This new LST algorithm was tested with simulated MODIS data for 80 sets of band-averaged emissivities calculated from published spectral data of terrestrial materials in wide ranges of atmospheric and surface temperature conditions. Comprehensive sensitivity and error analysis has been made to evaluate the performance of the new LST algorithm and its dependence on variations in surface emissivity and temperature, upon atmospheric conditions, as well as the noise-equivalent temperature difference (NE(Delta)T) and calibration accuracy specifications of the MODIS instrument. In cases with a systematic calibration error of 0.5%, the standard deviations of errors in retrieved surface daytime and nighttime temperatures fall between 0.4-0.5 K over a wide range of surface temperatures for mid-latitude summer conditions. The standard deviations of errors in retrieved emissivities in bands 31 and 32 (in the 10-12.5 micrometer IR spectral window region) are 0.009, and the maximum error in retrieved LST values falls between 2-3 K. Several issues related to the day/night LST algorithm (uncertainties in the day/night registration and in surface emissivity changes caused by dew occurrence, and the cloud cover) have been investigated. The LST algorithms have been validated with MODIS Airborne Simulator (MAS) dada and ground-based measurement data in two field campaigns conducted in Railroad Valley playa, NV in 1995 and 1996. The MODIS LST version 1 software has been delivered.

Wan, Zhengming↗
NASA NTRS1998

Assessing the Geomorphic Evolution and Hydrographic Changes Induced by Winter Storms along the Louisiana Coast

The influence that cold front passages have on Louisiana coastal environments, including land loss and land building processes, has been the primary topic of this multidisciplinary research. This research has combined meteorological, remote sensing, and coastal expertise from the University of Wisconsin (UW) and Louisiana State University (LSU). Analyzed data sets include remotely sensed radiometric data (AVHRR on NOAA-12,13,14, Multispectral Atmospheric Mapping Sensor (MAMS) and MODIS Airborne Simulator (MAS) on NASA ER-2), U.S. Army Corps of Engineers (USACE) water level data, water quality data from the Coastal Studies Institute (CSI) at LSU, USACE river discharge data, National Weather Service (NWS) and CSI wind in sitzi measurements, geomorphic measurements from aerial photography (NASA ER-2 and Learjet), and CSI ground based sediment burial pipes (for monitoring topographic change along the Louisiana coast) and sediment cores. The work reported here-in is a continuation of an initial investigation into coastal Louisiana landform modification by cold front systems. That initial effort demonstrated the importance of cold front winds in the Atchafalaya Bay sediment plume distribution (Moeller et al.), documented the sediment transport and deposition process of the western Louisiana coast (Huh et al.) and developed tools (e.g. water types identification, suspended solids estimation) from multispectral radiometric data for application to the current study. This study has extended that work, developing a Geomorphic Impact Index (GI(sup 2)) for relating atmospheric forcing to coastal response and new tools to measure water motion and sediment transport.

Menzel, W. Paul↗
NASA NTRS1999

Hyperspectral Remote Sensing and Ecological Modeling Research and Education at Mid America Remote Sensing Center (MARC): Field and Laboratory Enhancement

The purpose of this project was to establish a new hyperspectral remote sensing laboratory at the Mid-America Remote sensing Center (MARC), dedicated to in situ and laboratory measurements of environmental samples and to the manipulation, analysis, and storage of remotely sensed data for environmental monitoring and research in ecological modeling using hyperspectral remote sensing at MARC, one of three research facilities of the Center of Reservoir Research at Murray State University (MSU), a Kentucky Commonwealth Center of Excellence. The equipment purchased, a FieldSpec FR portable spectroradiometer and peripherals, and ENVI hyperspectral data processing software, allowed MARC to provide hands-on experience, education, and training for the students of the Department of Geosciences in quantitative remote sensing using hyperspectral data, Geographic Information System (GIS), digital image processing (DIP), computer, geological and geophysical mapping; to provide field support to the researchers and students collecting in situ and laboratory measurements of environmental data; to create a spectral library of the cover types and to establish a World Wide Web server to provide the spectral library to other academic, state and Federal institutions. Much of the research will soon be published in scientific journals. A World Wide Web page has been created at the web site of MARC. Results of this project are grouped in two categories, education and research accomplishments. The Principal Investigator (PI) modified remote sensing and DIP courses to introduce students to ii situ field spectra and laboratory remote sensing studies for environmental monitoring in the region by using the new equipment in the courses. The PI collected in situ measurements using the spectroradiometer for the ER-2 mission to Puerto Rico project for the Moderate Resolution Imaging Spectrometer (MODIS) Airborne Simulator (MAS). Currently MARC is mapping water quality in Kentucky Lake and vegetation in the Land-Between-the Lakes (LBL) using Landsat-TM data. A Landsat-TM scene of the same day was obtained to relate ground measurements to the satellite data. A spectral library has been created for overstory species in LBL. Some of the methods, such as NPDF and IDFD techniques for spectral unmixing and reduction of effects of shadows in classifications- comparison of hyperspectral classification techniques, and spectral nonlinear and linear unmixing techniques, are being tested using the laboratory.

Cetin, Haluk↗
NASA NTRS1999

On the Oxidative Degradation of Nadic End-Capped Polyimides: Synthesis and Characterization of Model Compounds for End-Cap Degradation Products - 3

The oxidative degradation of PMR (for polymerization of monomeric reactants) polyimides at elevated temperatures was followed by cross-polarized magic angle spinning (CP-MAS) NMR. Labeling of selected sites in the polymers with C-13 allowed for direct observation of the transformations arising from oxidation processes. The formation of several degradation products has been proposed to be occurring in the cross-links derived from the nadic end caps on oxidation. Model compounds have been synthesized and characterized by CPMAS NMR with both normal and delayed decoupling to distinguish between protonated and unprotonated carbons. Comparison of these spectra to predicted chemical shifts of proposed products for the aged polymer provides further insight to degradation occurring in the cross-linked moieties.

Meador, Mary Ann B.↗
NASA NTRS1997

Oxidative Degradation of Nadic-End-Capped Polyimides: Evidence for Reactions Occurring at High Temperatures - 2

The oxidative degradation of PMR (for polymerization of monomeric reactants) polyimides at elevated temperatures was followed by cross-polarized magic angle spinning (Cp-MAS) NMR. C-13 labeling of selected sites in the polymers allowed for direct observation of the transformations arising from oxidation processes. As opposed to model compound studies, the reactions were followed directly in the polymer. The labeling experiments confirm the previously reported oxidation of the methylene carbon to ketone in the methylenedianiline portion of the polymer chain. They also show the formation of two other oxidized species, acid and ester, from this same carbon. In addition, the technique provides the first evidence of the kind of degradation reactions that are occurring in the nadic end caps. Several PMR formulations containing moieties determined to be present after oxidation, as suggested by the labeling study, were synthesized. Weight loss, FTIR, and natural abundance NMR of these derivatives were followed during aging. In this way, weight loss could be related to the observed transformations.

Meador, Mary Ann B.↗
NASA NTRS1999

EOS Terra Validation Program

The EOS Terra mission will be launched in July 1999. This mission has great relevance to the atmospheric radiation community and global change issues. Terra instruments include ASTER, CERES, MISR, MODIS and MOPITT. In addition to the fundamental radiance data sets, numerous global science data products will be generated, including various Earth radiation budget, cloud and aerosol parameters, as well as land surface, terrestrial ecology, ocean color, and atmospheric chemistry parameters. Significant investments have been made in on-board calibration to ensure the quality of the radiance observations. A key component of the Terra mission is the validation of the science data products. This is essential for a mission focused on global change issues and the underlying processes. The Terra algorithms have been subject to extensive pre-launch testing with field data whenever possible. Intensive efforts will be made to validate the Terra data products after launch. These include validation of instrument calibration (vicarious calibration) experiments, instrument and cross-platform comparisons, routine collection of high quality correlative data from ground-based networks, such as AERONET, and intensive sites, such as the SGP ARM site, as well as a variety field experiments, cruises, etc. Airborne simulator instruments have been developed for the field experiment and underflight activities including the MODIS Airborne Simulator (MAS), AirMISR, MASTER (MODIS-ASTER), and MOPITT-A. All are integrated on the NASA ER-2, though low altitude platforms are more typically used for MASTER. MATR is an additional sensor used for MOPITT algorithm development and validation. The intensive validation activities planned for the first year of the Terra mission will be described with emphasis on derived geophysical parameters of most relevance to the atmospheric radiation community. Detailed information about the EOS Terra validation Program can be found on the EOS Validation program homepage i/e.: http://ospso.gsfc.nasa.gov/validation/valpage.html).

Starr, David↗
NASA NTRS1999

NASA's Earth Observations Program: Past, Present and Future

A presentation will be given at the Annual National Awards and President's Invited Lecture. The event is sponsored by the Associated Scientific and Technical Societies, an organization which serves the interests of 40,000 scientists and engineers all over South Africa. A general presentation will be given on the topic of NASA's Earth Observation Program and will be supplemented with visualizations using the NASA/NOAA Earth Science Electronic theater. Included will be space observations with an eye on southern Africa, including Etosha National Park, Namibia, Okavanga Delta, Botswana, Victoria Falls, Zimbabwe, and Cape Town, the Highveld around Johannesburg, Blyde River Canyon, and the Lowveld of Kruger National Park in South Africa; also included will be some AVHRR imagery of fire occurrence during the dry season, mostly the Miombo woodland of Zambia, Angola, Malawi, and northern Mozambique, supplemented with SeaWiFS imagery for VI, aerosols, clouds, AVHRR fire time series, Landsat TM (and possibly ETM+, if available), and other global data sets. Would also like to include some Terra animations from SVS, including perhaps the launch sequence. The presentation would conclude with some of the ER-2 MAS imagery from Brazil that highlights the capability that we plan to bring to Africa in August 2000.

King, Michael D.↗
NASA NTRS1999

Multi-Spectral Cloud Property Retrieval

Despite numerous studies to retrieve cloud properties using infrared measurements the information content of the data has not yet been fully exploited. In an effort to more fully utilize the information content of infrared measurements, we have developed a multi-spectral technique for retrieving effective cloud particle size, optical depth and effective cloud temperature. While applicable to all cloud types, we begin by validating our retrieval technique through analysis of MS spectral radiances obtained during the SUCCESS field campaign over the ARM SGP CART facility, and compare our retrieval product with lidar and MODIS Airborne Simulator (MAS) measurement results. The technique is then applied to the Nimbus-4 MS infrared spectral measurements to obtain global cloud information.

Carlson, Barbara E.↗
NASA NTRS1997

Improving the MODIS Global Snow-Mapping Algorithm

An algorithm (Snowmap) is under development to produce global snow maps at 500 meter resolution on a daily basis using data from the NASA MODIS instrument. MODIS, the Moderate Resolution Imaging Spectroradiometer, will be launched as part of the first Earth Observing System (EOS) platform in 1998. Snowmap is a fully automated, computationally frugal algorithm that will be ready to implement at launch. Forests represent a major limitation to the global mapping of snow cover as a forest canopy both obscures and shadows the snow underneath. Landsat Thematic Mapper (TM) and MODIS Airborne Simulator (MAS) data are used to investigate the changes in reflectance that occur as a forest stand becomes snow covered and to propose changes to the Snowmap algorithm that will improve snow classification accuracy forested areas.

Klein, Andrew G.↗
NASA NTRS1999

Refinement of Models for VLBI Analysis

Continual refinement of models and estimation methods is an integral part of improving VLBI measurements of Earth orientation and position along with advances in instrumentation and observing strategy. The modeling of the troposphere continues to be challenging with recent improvements in treating the mean gradient and gradient variations affecting the terrestrial reference frame scale and celestial declinations near the current limits of accuracy. Revised models of nutation and solid Earth tides are implemented in CALC 9.0 to conform to the latest IERS Conventions along with other changes to facilitate use by VLBI correlators. Using data since 1995 the celestial reference frame has been extended and improved consistent with the definition and 0.25 mas accuracy limit of the ICRF. The current definition of the VLBI terrestrial reference frame places a floor on the accuracy of station velocities at the 0.4 mm/yr level. The establishment of the IVS (International VLBI Service for Geodesy and Astrometry) in the past year will provide a forum for further improvements of VLBI data analysis.

Ma, C.↗
NASA NTRS1993

Atlas 2 Animation

The Atmospheric Laboratory for Applications and Science-2 (ATLAS-2), was designed to collect data on the relationship between the sun's energy output and Earth's middle atmosphere and how these factors affect the ozone layer. The ATLAS-2 flew on the Space Shuttle Discovery's mission SST-56, launched on April 8, 1993. The videotape consists of an animated tour of the instruments that were included as part of the mission. The first half of the tape shows the various instruments, pointing to each in turn and identifying each by the associated initialisms. The instruments identified were: the Atmospheric Trace Molecule Spectroscopy (ATMOS), Millimeter Wave Atmospheric Sounder (MAS), Shuttle Solar Backscatter Ultraviolet/A (SSBUV/A) spectrometer, Solar Spectrum Measurement (SOLSPEC) instrument, Solar Ultraviolet Irradiance Monitor (SUSIM), Active Cavity Radiometer (ACR) and Solar Constant (SOLCON).) The second half of the animation shows the same tour without the pointing or the identification of the instruments.

Source record↗
NASA NTRS2000

Profiling of Atmospheric Water Vapor from the SSM/T-2 Radiometric Measurements

An advantage of using the millimeter-wave measurements for water vapor profiling is the ability to probe beyond a moderate cloud cover. Such a capability has been demonstrated from an airborne MIR (Millimeter-wave Imaging Radiometer) flight over the Pacific Ocean during an intense observation period of TOGA/COARE (Tropical Ocean Global Atmosphere/ Couple Ocean Atmospheric Response Experiment) in early 1993. A Cloud Lidar System (CLS) and MODIS Airborne Simulator (MAS) were on board the same aircraft to identify the presence of clouds and cloud type. The retrieval algorithm not only provides output of a water vapor profile, but also the cloud liquid water and approximate cloud altitude required to satisfy convergence of the retrieval. The validity of these cloud parameters has not been verified previously. In this document, these cloud parameters are compared with those derived from concurrent measurements from the CLS and AMPR (Advanced Microwave Precipitation Radiometer).

Wang, J. R.↗
NASA NTRS1999

VSOP Monitoring of the Quasar 1928+738

One limitation of the VSOP (VLBI Space Observatory Program) mission is that several famous superluminal sources such as 3C273 cannot be monitored with good uv-coverage throughout the lifetime of the VSOP Mission at regular intervals that are spaced closely enough to follow the evolution in the fine-scale source-structure. The reason for this is that the HALCA spacecraft cannot#observe sources outside certain restricted ranges of sun angle, defined to be the time variable angle between the source and the sun. However sources that lie within 10 degrees of the ecliptic poles can be observed throughout the year and observations are not restricted to narrow temporal windows. Furthermore, the best ground-based uv-coverages are obtained for circumpolar sources and consequently these will be the sources for which the maximum amount of space VLBI data will be obtained with a given ground array. We have began a VSOP monitoring campaign at 5 GHz on the relatively low redshift (z=0.3) superluminal quasar 1928+738 which is both a circumpolar source and lies 10 degrees away from the ecliptic pole. 1928+738 is in the S5 polar cap sample and has been well studied both on the arsecond-scale and mas-scale. 22 GHz observations have shown that the motion of the VLBI components in 1928+738 is inconsistent with simple linear expansion along a fixed position angle (PA) for all components. Indeed, 1928+738 was one of the first sources for which helical jet motion was proposed and it has been further proposed that a massive binary black hole (MBBH) system is responsible for the sinusoidal jet ridge line observed at 22 GHz over a S year period. our VSOP observations are designed to check this proposal.

Murphy, D. W.↗
NASA NTRS2000

Monitoring of Earth Rotation by VLBI

Monitoring Earth rotation with Very Long Baseline Interferometry (VLBI) has unique potential because of direct access to the Celestial Reference System (CRF and Terrestrial Reference System (TRF) and the feasibility of re-analyzing the entire data set. While formal precision of better than 0.045 mas for pole and 0.002 ms for UT 1 has been seen in the best 24-hr data, the accuracy of the Earth Orientation Parameter (EOP) time series as a whole is subject to logistical, operational, analytical and conceptual constraints. The current issues related to the VLBI data set and the CORE program for greater time resolution such as analysis consistency, network jitter and reference frame stability will be discussed.

Ma., Chopo↗
NASA NTRS2000

EOS Terra Validation Program

The EOS Terra mission will be launched in July 1999. This mission has great relevance to the atmospheric radiation community and global change issues. Terra instruments include Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), Clouds and Earth's Radiant Energy System (CERES), Multi-Angle Imaging Spectroradiometer (MISR), Moderate Resolution Imaging Spectroradiometer (MODIS) and Measurements of Pollution in the Troposphere (MOPITT). In addition to the fundamental radiance data sets, numerous global science data products will be generated, including various Earth radiation budget, cloud and aerosol parameters, as well as land surface, terrestrial ecology, ocean color, and atmospheric chemistry parameters. Significant investments have been made in on-board calibration to ensure the quality of the radiance observations. A key component of the Terra mission is the validation of the science data products. This is essential for a mission focused on global change issues and the underlying processes. The Terra algorithms have been subject to extensive pre-launch testing with field data whenever possible. Intensive efforts will be made to validate the Terra data products after launch. These include validation of instrument calibration (vicarious calibration) experiments, instrument and cross-platform comparisons, routine collection of high quality correlative data from ground-based networks, such as AERONET, and intensive sites, such as the SGP ARM site, as well as a variety field experiments, cruises, etc. Airborne simulator instruments have been developed for the field experiment and underflight activities including the MODIS Airborne Simulator (MAS) AirMISR, MASTER (MODIS-ASTER), and MOPITT-A. All are integrated on the NASA ER-2 though low altitude platforms are more typically used for MASTER. MATR is an additional sensor used for MOPITT algorithm development and validation. The intensive validation activities planned for the first year of the Terra mission will be described with emphasis on derived geophysical parameters of most relevance to the atmospheric radiation community.

Starr, David↗
NASA NTRS2000

Near-Infrared Interferometric Images of the Solar System Sized Disk Surrounding the Herbig Ae/Be Star MWC 349A

We present images of the Herbig Ae/Be star MWC 349A at 1.65 and 2.27, and 3.08 micrometers, reconstructed from complex visibility data obtained with an aperture masking interferometric technique on the Keck I telescope. These images have an approximately elliptical shape, and are consistent with the expected shape of a nearly edge-on Keplerian disk. Visibility data were fitted with uniform ellipses with major axes 36 +/- 2, 47 +/- 2, and 62 +/- 1 mas, respectively. The axial ratio of the ellipses is approximately 0.5 +/- 0.1, and the major axis is at a position angle of 100 +/- 3 degrees, consistent with the position angle of the dark lane observed previously in the Very Large Array (VLA) radio continuum maps at 8 and 22 GHz, perpendicular to the symmetry axis of the bipolar lobes of H66(alpha) recombination line emission, and consistent with positions of the recombination line maser spots at 1.3 mm. At an assumed distance of 1.2 kpc, the linear sizes of the disk are 44 and 57 AU at 1.65 and 2.2 micrometers, respectively. The disk is the presumed source of ionized material in the bipolar outflow and ultracompact HII region around the star.

Danchi, W.C.↗