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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
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NASA NTRS1983

ANS ultraviolet observations of dwarf Cepheids

Ultraviolet observations of three dwarf Cepheids (VZ Cnc, SX Phe, and AI Vel) are presented. The UV light curves are consistent with those in the visual region. When compared to standard stars, all three dwarf Cepheids exhibit flux deficiencies at the shortest observed wavelengths. The most extreme deficiencies appear for SX Phe; these may be related to the other properties previously noted for this star, including low metallicity, high space motion, and low luminosity.

Sturch, C. R.↗
NASA NTRS1988

Images in the rocket ultraviolet - UV fluxes of M31 globular clusters

Images obtained by a rocket-borne UV imaging telescope are used here to determine near-UV fluxes for 17 sources in M31 that are optical globular-cluster candidates and for the bright open cluster vdB0 in M31. Far-UV fluxes or flux limits are determined for the same clusters. The m(NUV)-V colors for M31 clusters are similar to those of Galactic clusters, except for the high-metallicity M31 cluster Bo 171. Four of the detected clusters have optical, m(NUV) - V, and m(FUV) - V colors indicating ages of about 100 million years. These four clusters are probably similar to the so-called 'blue globular' clusters of the LMC. The existence of young LMC-type blue globulars and the possible existence of middle-aged metal-rich globulars may indicate that M31 has continued to form globular clusters throughout its life.

Bohlin, Ralph C.↗
NASA NTRS1988

A new kind of primitive chondrite, Allan Hills 85085

Allan Hills (ALH) 85085, a chemically and mineralogically unique chondrite whose components have suffered little metamorphism or alteration, is discussed. It is found that ALH 85085 has 4 wt pct chondrules (mean diameter 16 microns), 36 wt pct Fe, Ni, 56 wt pct lithic and mineral silicate fragments, and 2 wt pct trolite. It is suggested that, with the exception of matrix lumps, the components of ALH 85085 formed and accreted in the solar nebula. It is shown that ALH 85085 does not belong to any of the nine chondrite groups and is very different from Kakangari. Similarities between ALH 85085 and Bencubbin and Weatherford suggest that the latter two primitive meteorites may be chondrites with high metal abundances and very large, partly fragmented chondrules.

Scott, Edward R. D.↗
NASA NTRS1991

Thermal instabilities in proto-globular clusters resulting from time-dependent potentials

In this paper a scenario is proposed to explain the lack of young globular clusters in the Galaxy. It is argued that the formation of the Galactic disk would induce tidal compressions on protoglobular clouds during passage through the Galactic disk. Such a compression would trigger the onset of thermal instability in typical protoglobular cluster clouds, leading to rapid cooling and contraction and subsequent star formation. The clouds are thus unlikely to survive several passages through the Galactic disk following its formation. Instabilities preferentially occur in clouds with relatively high metallicity and with orbits lying more nearly in the plane of the Galaxy, possibly leading to the formation of a population of clusters with small orbital inclination, similar to the population of disk clusters observed in the Galaxy.

Murray, Stephen D.↗
NASA NTRS1994

Mg II chromospheric-emission dating of HR 1614 moving-group stars

A 2800 A Mg II line index I(Mg II) that is sensitive to chromospheric activity has been measured from International Ultraviolet Explorer spectra of a sample of eight HR 1614 moving-group dwarfs. All of these dwarfs have values of I(Mg II) indicative of ages greater than or equal to 3 Gyr. The relatively old ages of these dwarfs, together with their similar and peculiar kinematics and high metal abundance, is consistent with, although not conclusive proof of, coeval formation in close physical proximity to each other. The age, chemical abundance, and kinematics of the HR 1614 moving group -- with the notable exception of height above the Galactic plane -- are similar to the properties of the old open cluster NGC 6791.

Hufnagel, Beth↗
NASA NTRS1995

Radar Observations of Asteroids 7 Iris, 9 Metis, 12 Victoria, 216 Kleopatra, and 654 Zelinda

We report 13-cm wavelength radar observations of the main-belt asteroids 7 Iris, 9 Metis, 12 Victoria, 216 Kleopatra, and 654 Zelinda obtained at Arecibo between 1980 and 1989. The echoes are highly polarized yet broadly distributed in Doppler frequency, indicating that our targets are smooth on decimeter scales but very rough on some scale(s) larger than about I m. The echo spectra are generally consistent with existing size, shape, and spin information based on radiometric, lightcurve, and occultation data. All of our targets possess distinctive radar signatures that reveal large- scale topography. Reflectivity spikes within narrow ranges of rotation phase suggest large flat regions on Iris, Metis, and Zelinda, while bimodal spectra imply nonconvex, possibly bifurcated shapes for Kleopatra and Victoria. Kleopatra has the highest radar albedo yet measured for a main-belt asteroid, indicating a high metal concentration and making Kleopatra the best main-belt candidate for a core remnant of a differentiated and subsequently disrupted parent body. Upon completion of the Arecibo telescope upgrade, there will be several opportunities per year to resolve main-belt asteroids with hundreds of delay-Doppler cells, which can be inverted to provide estimates of both three-dimensional shape and radar scattering properties.

Mitchell, David L.↗
NASA NTRS2002

Study of Extra-Solar Planets with the Advanced Fiber Optic Echelle

This is the final report of NASA Grant NAG5-7505, for 'Study of Extra-solar Planets with the Advanced Fiber Optic Echelle'. This program was funded in response to our proposal submitted under NASA NRA 97-OSS-06, with a total period of performance from June 1, 1998 through Feb 28 2002. Principal Investigator is Robert W. Noyes; co-Investigators are Sylvain G. Korzennik (SAO), Peter Niserison (SAO), and Timothy M. Brown (High Altitude Observatory). Since the start of this program we have carried out more than 30 observing runs, typically of 5 to 7 days duration. We obtained a total of around 2000 usable observations of about 150 stars, where a typical observation consists of 3 exposures of 10 minutes each. Using this data base we detected thc two additional planetary companions to the star Upsilon Andromedae. This detection was made independently of, and essentially simultaneously with, a similar detection by the Berkeley group (Marcy et al): the fact that two data sets were completely independent and gave essentially the same orbital parameters for this three-planet system gave a strong confirmation of this important result. We also extended our previous detection of the planet orbiting Rho Coronae Borealis to get a better determination of its orbital eccentricity: e=0.13 +/- 0.05. We detected a new planet in orbit around the star HD 89744, with orbital period 256 days, semi-major axis 0.88 AU, eccentricity 0.70, and minimum mass m sini = 7.2 m(sub Jup). This discovery is significant because of the very high orbital eccentricity, arid also because HD 89744 has both high metallicity [Fe/H] and at the same time a low [C/Fe] abundance ratio.

Noyes, Robert W.↗
NASA NTRS2004

The Fountain Hills Meteorite: A New CB(a) Chondrite from Arizona

The CR clan of meteorites has been established and a detailed review of these meteorites is presented. There are several kinds of carbonaceous chondrites included in this clan: Carbonaceous Renazzo-like (CR), Carbonaceous with High metal (CH), Carbonaceous Bencubbin-like (CB), and LEW 85332, a unique-metal rich meteorite. The CB chondrites are further divided into two subgroups: CB(sub a) and CB(sub b). Here we describe a new member of the CR chondrite clan, Fountain Hills, a recent find with a total mass of approximately 60 g.

Lauretta, D. S.↗
NASA NTRS2012

Carnegie Hubble Program: A Mid-Infrared Calibration of the Hubble Constant

Using a mid-infrared calibration of the Cepheid distance scale based on recent observations at 3.6 micrometers with the Spitzer Space Telescope, we have obtained a new, high-accuracy calibration of the Hubble constant. We have established the mid-IR zero point of the Leavitt law (the Cepheid period-luminosity relation) using time-averaged 3.6 micrometers data for 10 high-metallicity, MilkyWay Cepheids having independently measured trigonometric parallaxes. We have adopted the slope of the PL relation using time-averaged 3.6micrometers data for 80 long-period Large Magellanic Cloud (LMC) Cepheids falling in the period range 0.8 < log(P) < 1.8.We find a new reddening-corrected distance to the LMC of 18.477 +/- 0.033 (systematic) mag. We re-examine the systematic uncertainties in H(sub 0), also taking into account new data over the past decade. In combination with the new Spitzer calibration, the systematic uncertainty in H(sub 0) over that obtained by the Hubble Space Telescope Key Project has decreased by over a factor of three. Applying the Spitzer calibration to the Key Project sample, we find a value of H(sub 0) = 74.3 with a systematic uncertainty of +/-2.1 (systematic) kilometers per second Mpc(sup −1), corresponding to a 2.8% systematic uncertainty in the Hubble constant. This result, in combination with WMAP7measurements of the cosmic microwave background anisotropies and assuming a flat universe, yields a value of the equation of state for dark energy, w(sub 0) = −1.09 +/- 0.10. Alternatively, relaxing the constraints on flatness and the numbers of relativistic species, and combining our results with those of WMAP7, Type Ia supernovae and baryon acoustic oscillations yield w(sub 0) = −1.08 +/- 0.10 and a value of N(sub eff) = 4.13 +/- 0.67, mildly consistent with the existence of a fourth neutrino species.

Program↗
DOE OSTI2023

Chemodynamical Analysis of Metal-rich High-eccentricity Stars in the Milky Way's Disk

We present a chemodynamical analysis of 11,562 metal-rich, high-eccentricity halo-like main-sequence stars, which have been referred to as the Splash or Splashed Disk, selected from the Sloan Digital Sky Survey and Large Sky Area Multi-Object Fiber Spectroscopic Telescope. When divided into two groups, a low-[α/Fe] population (LAP) and a high-[α/Fe] population (HAP), based on kinematics and chemistry, we find that they exhibit very distinct properties, indicative of different origins. From a detailed analysis of their orbital inclinations, we suggest that the HAP arises from a large fraction (~90%) of heated disk stars and a small fraction (~10%) of in situ stars from a starburst population, likely induced by interaction of the Milky Way with the Gaia-Sausage/Enceladus (GSE) or another early merger. The LAP comprises about half accreted stars from the GSE and half formed by the GSE-induced starburst. Our findings further imply that the Splash stars in our sample originated from at least three different mechanisms: accretion, disk heating, and a merger-induced starburst.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Unraveling kinking: A plasticity enhancing failure mode in high strength nano metallic laminates

Kinking is an important and plasticity-enhancing deformation/failure mode in numerous mechanically anisotropic materials including high-strength nano metallic laminates (NMLs). However, our current limited understanding of the mechanics of kinking and its dependence on microstructural attributes is insufficient for thoroughly comprehending and eventually being able to control failure behaviors of materials. In this study, we investigate kinking dependencies on microstructural attributes in NMLs via in situ micropillar compression, multiscale microstructure characterization, dislocation dynamic simulations, and crystal plasticity modeling. Additionally, by examining several NML systems (Cu/Fe, Ag/Fe, Al-4Mg/Fe), we demonstrate that the development of internal stresses during loading activates local layer-parallel glide triggering kinking in NMLs. Furthermore, this work reveals the effect of key microstructural features including layer thickness, layer waviness, interface barrier strength, and work hardening capacity on kink band formation in NMLs. More broadly, our efforts represent a generically applicable approach for probing large-strain deformation behavior of complex materials via synergetic modeling and experimental efforts.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Dual-Solvent Li-Ion Solvation Enables High-Performance Li-Metal Batteries

Novel electrolyte designs to further enhance the lithium (Li) metal battery cyclability are highly desirable. Here, fluorinated 1,6-dimethoxyhexane (FDMH) is designed and synthesized as the solvent molecule to promote electrolyte stability with its prolonged –CF 2 – backbone. Meanwhile, 1,2-dimethoxyethane is used as a co-solvent to enable higher ionic conductivity and much reduced interfacial resistance. Combining the dual-solvent system with 1 m lithium bis(fluorosulfonyl)imide (LiFSI), high Li-metal Coulombic efficiency (99.5%) and oxidative stability (6 V) are achieved. Using this electrolyte, 20 µm Li||NMC batteries are able to retain ≈80% capacity after 250 cycles and Cu||NMC anode-free pouch cells last 120 cycles with 75% capacity retention under ≈2.1 µL mAh -1 lean electrolyte conditions. Such high performances are attributed to the anion-derived solid-electrolyte interphase, originating from the coordination of Li-ions to the highly stable FDMH and multiple anions in their solvation environments. This work demonstrates a new electrolyte design strategy that enables high-performance Li-metal batteries with multisolvent Li-ion solvation with rationally optimized molecular structure and ratio.

25 ENERGY STORAGE↗
NASA NTRS1988

Friction-induced ignition of metals in high-pressure oxygen

Data are presented on friction-induced metal ignition (such as occurring as a result of the possible rubbing of oxygen-pressurized hydrostatic bearings and turbine blade tips) in a high-presure oxygen environment. Friction heating tests were carried out at oxygen pressures from 1 to 300 atm and surface speeds from 10 to 33 m/sec, using the NASA/White Sands Test Facility. Test results are presented on the rubbing of like material pairs spanning a wide range of burn factors and on that of dissimilar metal pairs having significantly different burn factors, indicating that the burn factor is a suitable index for rank ordering in ignition resistance for the most, but not all, materials.

Schoenman, Len↗
DOE OSTI2023

High‐Performance Lithium Metal Batteries Enabled by a Fluorinated Cyclic Ether with a Low Reduction Potential

Abstract Electrolyte engineering is crucial for developing high‐performance lithium metal batteries (LMB). Here, we synthesized two cosolvents methyl bis(fluorosulfonyl)imide (MFSI) and 3,3,4,4‐tetrafluorotetrahydrofuran (TFF) with significantly different reduction potentials and add them into LiFSI‐DME electrolytes. The LiFSI/TFF‐DME electrolyte gave an average Li Coulombic efficiency (CE) of 99.41 % over 200 cycles, while the average Li CEs for MFSI‐based electrolyte is only 98.62 %. Additionally, the TFF‐based electrolytes exhibited a more reversible performance than the state‐of‐the‐art fluorinated 1,4‐dimethoxylbutane electrolyte in both Li||Cu half‐cell and anode‐free Cu||LiNi 0.8 Mn 0.1 Co 0.1 O 2 full cell. More importantly, the decomposition product from bis(fluorosulfonyl)imide anion could react with ether solvent, which destroyed the SEI, thus decreasing cell performance. These key discoveries provide new insights into the rational design of electrolyte solvents and cosolvents for LMB.

Wu, Min↗
DOE OSTI2023

High‐Performance Lithium Metal Batteries Enabled by a Fluorinated Cyclic Ether with a Low Reduction Potential

Abstract Electrolyte engineering is crucial for developing high‐performance lithium metal batteries (LMB). Here, we synthesized two cosolvents methyl bis(fluorosulfonyl)imide (MFSI) and 3,3,4,4‐tetrafluorotetrahydrofuran (TFF) with significantly different reduction potentials and add them into LiFSI‐DME electrolytes. The LiFSI/TFF‐DME electrolyte gave an average Li Coulombic efficiency (CE) of 99.41 % over 200 cycles, while the average Li CEs for MFSI‐based electrolyte is only 98.62 %. Additionally, the TFF‐based electrolytes exhibited a more reversible performance than the state‐of‐the‐art fluorinated 1,4‐dimethoxylbutane electrolyte in both Li||Cu half‐cell and anode‐free Cu||LiNi 0.8 Mn 0.1 Co 0.1 O 2 full cell. More importantly, the decomposition product from bis(fluorosulfonyl)imide anion could react with ether solvent, which destroyed the SEI, thus decreasing cell performance. These key discoveries provide new insights into the rational design of electrolyte solvents and cosolvents for LMB.

25 ENERGY STORAGE↗
NASA NTRS1993

Microactuator production via high aspect ratio, high edge acuity metal fabrication technology

LIGA is a procession sequence which uses x-ray lithography on photoresist layers of several hundred micrometers to produce very high edge acuity photopolymer molds. These plastic molds can be converted to metal molds via electroplating of many different metals and alloys. The end results are high edge acuity metal parts with large structural heights. The LIGA process as originally described by W. Ehrfeld can be extended by adding a surface micromachining phase to produce precision metal parts which can be assembled to form three-dimensional micromechanisms. This process, SLIGA, has been used to fabricate a dynamometer on a chip. The instrument has been fully implemented and will be applied to tribology issues, speed-torque characterization of planar magnetic micromotors and a new family of sensors.

Guckel, H.↗
DOE OSTI2022

Design of a multi-functional gel polymer electrolyte with a 3D compact stacked polymer micro-sphere matrix for high-performance lithium metal batteries

We report lithium metal batteries (LMBs) are considered as promising high energy density batteries. However, they still suffer from poor cyclability due to the instability of solid electrolyte interphases (SEIs) and Li dendrite issues. Herein, a novel 3D densely packed multifunctional crosslinked gel polymer electrolyte (PHGPE) has been synthesized by in situ copolymerization of pentaerythritol tetraacrylate and 2-hydroxyethyl acrylate in a liquid electrolyte via a thermal initiation method. Due to intermolecular hydrogen bonding in the frameworks, the PHGPE exhibits a 3D compact-stacked and crosslinked micro-sphere structure, which benefits the construction of homogeneous Li + flux, enabling uniform Li plating/stripping and formation of robust SEIs onto the lithium electrode. Benefiting from the above advantages, symmetric Li cells in the PHGPE deliver excellent cyclabilities of 6000 h at a current density of 1 mA cm -2 (1 mA h cm -2 ) and 7700 h at 0.5 mA cm -2 (2 mA h cm -2 ). Moreover, the PHGPE has such a wide electrochemical window that it is compatible with both high-voltage LiNi 0.8 Co 0.1 Mn 0.1 O 2 and sulfur cathodes to realize long cycle life. Additionally, a LiFePO 4 based pouch size LMB also presents promising performance. Therefore, this study of the PHGPE has opened a new avenue for high-performance LMBs with excellent versatility and practicality.

25 ENERGY STORAGE↗