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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

The upgraded summing NaI(Tl) (SuN++) absorption spectrometer

Simulations of astrophysical processes require a plethora of nuclear physics input. In particular, models of neutron-capture nucleosynthesis like the s, i, and r processes require β-decay information and experimentally constrained neutron-capture reaction rates. Past experiments with the 4π Summing NaI(Tl) (SuN) total absorption spectrometer have provided these physics quantities. Here, we outline an upgrade of SuN to SuN++, where 20 new segments (12 NaI(Tl) and 8 CeBr 3 ) have been integrated into the pre-existing SuN total absorption spectrometer to provide increased energy and time resolution in β-decay experiments. The details of the newly upgraded SuN++ total absorption spectrometer are discussed with results from the commissioning experiment at the Facility for Rare Isotope Beams (FRIB) utilizing a 70 Cu beam.

CeBr3↗

The evidence of N = 16 shell closure and β -delayed neutron emission from 25 F

We measured the β -delayed neutron emission from 25 F for the first time at the Facility for Rare Isotope Beams (FRIB). Using combined neutron and γ -ray detector systems of the FRIB Decay Station Initiator (FDSi), we observed β -decay transitions populating neutron unbound states between 4.2 and 8 MeV in 25 Ne. The experimental results led to the revision of the β -decay half-life and β -delayed neutron-emission probability of 25 F. The β -decay strength distribution of 25 F extracted from the data agrees with the shell-model predictions using the USDB and SDPF-M effective interactions. This result indicates that the spherical neutron shell gap persists in 25 F and 25 Ne.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Real-Time Detection of Hydrogen and Ammonia Isotopologues for Impurity Removal and Recovery of Tritium

To accommodate gas measurements for impurity removal and recovery of tritium, a silver-coated optical or waveguide is employed for collecting Raman scattered signals to determine relative hydrogen and ammonia isotopologue populations in real time. The data and results presented here demonstrate an analytical methodology for the analysis of four ammonia and three hydrogen isotopologues in a hydrogen–deuterium exchange reaction by gas phase Raman spectroscopy. Standard chemometric modeling techniques effectively unravel the signatures of the isotopologues involved observed here; however, a sophisticated quantum chemical approach supports the spectral assignments. An interpretation of the data presented here can emphasize the practicality and reliability of the gaseous monitoring system in complex chemical environments for the hydrogen fuel economy as well as the more distant energy source from a facility that handles tritium. There are still considerable concerns about the measurement of tritium in isotope separation and radiological impurities from gas processing. A common impurity in gas processing is ammonia, which can form readily in the presence of nitrogen and tritium. Substituted ammonia (NQ 3 ), where Q = H, D, or T, is traditionally removed through getters or diffusers along with other non-hydrogen contaminants. A preferable analytical approach is noninvasive and can be deployed for real-time process evaluation in radiological environments.

Ammonia↗

Thin-Film Fracture Behavior for Diketopyrrolopyrrole Semiconducting Polymeric Films

Fracture energy, which quantifies a material’s resistance to the propagation of a pre-existing crack, is a key parameter for ensuring the mechanical reliability of stretchable organic electronic devices. However, most existing methods, such as a four-point bending fracture energy, utilized for measuring the fracture energy of semiconducting polymeric thin films are complicated by substrate effects, making it challenging to isolate the intrinsic behavior of the film from interfacial influences. In this study, we employed a pseudo free-standing pure shear method to systematically investigate the cohesive fracture energy of poly(diketopyrrolopyrrole-terthiophene) P(DPP-T)-based thin films to examine the effects of nanoconfinement, side chain length, degree of crystallinity, and strain rates. This method effectively eliminates substrate interference, enabling a direct assessment of the cohesive fracture energy of P(DPP-T) thin films. We found that thinner films and those with lower molecular weights exhibited significantly reduced fracture energies due to diminished chain entanglements. Additionally, films with shorter side chains displayed notably higher fracture energies, which were attributed to an increase in the degree of crystallinity. Finally, slower strain rates led to higher fracture energies, consistent with an enhanced stress relaxation. These insights offer practical guidelines for designing mechanically robust semiconducting polymers, contributing to the advancement of reliable, durable, flexible, and wearable electronic devices.

Zhang, Song [Univ. of Southern Mississippi, Hattie↗

Resonant Tender X-ray Scattering for Disclosing the Backbone Conformation of Conjugated Polymers

The backbone conformation of conjugated polymers (CPs) is essential to their performance in electronic applications. Contrast-variation small-angle neutron scattering (CV-SANS) techniques were used to assess the CP’s backbone conformation, which relies on synthesis of deuterated polymers. Such a technique has been proven mature and effective. One drawback is that deuteration labeling might subtly alter polymer’s physical properties due to structural modifications. To address these challenges, we introduce a novel approach utilizing tender Xray scattering near the sulfur K-edge to distinctly evaluate the backbone versus whole chain conformation for a low-bandgap donor−acceptor CP, poly[(5,6-difluoro- 2,1,3-benzothiadiazol-4,7-diyl)-alt-(3,3‴-dialkyl-2,2′;5′,2″;5″,2‴-quaterthiophen-5,5‴- diyl)] (PffBT4T). For PffBT4T dissolved in trimethylbenzene (TMB), the sulfur K-edge is identified at approximately 2477 eV using near-edge X-ray absorption fine structure spectroscopy (NEXAFS). Tender X-ray scattering conducted at presulfur K-edge and on-sulfur K-edge at elevated temperatures facilitated the distinction between the backbone and whole chain conformations. The results demonstrate that for highly flexible polymer, the backbone’s persistence length could be lower than that of the whole chains, suggesting a more flexible backbone. This rapid, label-free method enhances our ability to characterize CP’s backbone conformation efficiently, offering significant implications for the design and optimization of CPs for advanced electronics.

36 MATERIALS SCIENCE↗

Backward-Angle Electroproduction of η′ Mesons off Protons at W = 2.13 GeV and Q 2 = 0.46 (GeV/ c ) 2

The electroproduction of $\eta ^{\prime }$ mesons from a $\mathrm{^{1}H}$ target at $W=\mathrm{2.13~GeV}$, $Q^{2} = 0.46~\left( \mathrm{GeV/}c\right)^{2}$, and $\cos \theta ^{\mathrm{CM}}_{\gamma ^{*}\eta ^{\prime }} \approx -1$ has been experimentally measured. The differential cross section of virtual photoproduction has been obtained as $4.4 \pm 0.8 ~\left( \mathrm{stat.} \right) \pm 0.4 ~\left( \mathrm{sys.} \right)~ \mathrm{nb/sr}$ in the One-Photon-Exchange Approximation. This value is one-sixth of that of real photoproduction at backward angles. A comparison with newly developed isobar model calculations not only shows the validity of the theoretical framewark employed, but also imposes new constraints on coupling strength between the $\eta ^{\prime }p$ final state and nucleon resonances.

Nuclear Physics↗

EMC Effect of Tritium and Helium-3 from the JLab MARATHON Experiment

Measurements of the EMC effect in the tritium and helium-3 mirror nuclei are reported. The data were obtained by the MARATHON Jefferson Lab experiment, which performed deep inelastic electron scattering from deuterium and the three-body nuclei, using a cryogenic gas target system and the high resolution spectrometers of the Hall A Facility of the Lab. The data cover the Bjorken 𝑥 range from 0.20 to 0.83, corresponding to a squared four-momentum transfer 𝑄 2 range from 2.7 to 11.9 (GeV/𝑐) 2 , and to an invariant mass 𝑊 of the final hadronic state greater than 1.84 GeV/𝑐 2 . The tritium EMC effect measurement is the first of its kind. The MARATHON experimental results are compared to results from previous measurements by DESY-HERMES and JLab–Hall C experiments, as well as with few-body theoretical predictions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Beta-Decay Half-Lives beyond 54 Ca: A Systematic Survey of Decay Properties Approaching the Neutron Dripline

In an experiment performed at the Facility for Rare Isotope Beams (FRIB) using the FRIB Decay Station initiator, 15 new half-lives of isotopes near 54 Ca were measured. A new method of extracting lifetimes from experimental data, taking into account the unknown 𝛽-delayed neutron emission branches of very neutron-rich nuclei, was developed to enable systematic uncertainty analysis. The experiment observed a dramatic change in the half-life systematics for the isotopes with neutron number 𝑁 = 34. Beyond 𝑁 = 34, the decline of nuclear lifetime is much slower, leading to longer than anticipated lifetimes for near-dripline nuclei. State-of-the-art shell-model calculations can explain the experimental results, revealing the imprint of shell effects and the need for modification of single-particle neutron states. In conclusion, the results from a newly developed quasiparticle random phase approximation model with potential for making global predictions were also tested against the experimental results and good agreement was found.

Physics - Nuclear physics and radiation physics↗

Ionization-based search for magnetic monopoles using the NOvA Far Detector

We report a search for highly ionizing magnetic monopoles in the cosmic-ray flux using a 2713-day dataset collected during 2015–2025 with the NOvA Far Detector, a 14-kt segmented detector located on Earth’s surface in Minnesota, United States. The search is sensitive to monopoles across a wide range of speeds, 7 × 10 −4 < 𝛽 < 0.995, and is sensitive to masses as low as 2 × 10 5 GeV for the fastest monopoles. No signal was observed. With the detector’s large surface area and minimal overburden, we achieve the strongest flux limits reported to date in several regions of speed and mass. For heavy monopoles with masses above 10 13 GeV that are able to reach the detector from above or—crossing Earth—from below, we find a flux limit 𝜙 90% < 2 × 10 −16 cm −2 s −1 sr −1 (90% confidence level) for monopoles with 0.005 < 𝛽 < 0.8. Across the same range of speeds, we report a limit 𝜙 90% < 8 × 10 −16 cm −2 s −1 sr −1 for light monopoles with masses above 10 8 GeV that can reach the detector from above.

magnetic monopoles↗

Measurement of 𝜋 0 production in $\bar{v}_μ$ charged-current interactions in the NOvA near detector

We present a high-statistics measurement of muon antineutrino-induced charged-current neutral pion production on a hydrocarbon target using the NOvA near detector. The differential cross sections as functions of the momenta and angles of the outgoing pion and muon, the squared four-momentum transfer, and the invariant mass of the hadronic system at an average neutrino energy of 2 GeV are measured and compared with predictions from various neutrino interaction models. The results agree with the GENIE prediction but suggest that other models underestimate the cross section in the Δ⁡(1232) resonance region. These results represent the most precise measurement of antineutrino-induced neutral pion production to date.

neutrino detection↗

Further steps toward the next generation of covariant energy density functionals

The present study aims at further development of covariant energy density functionals (CEDFs) towards more accurate description of binding energies across the nuclear chart. Infinite basis corrections to binding energies in the fermionic and bosonic sectors of the covariant density functional theory are taken into account in the fitting protocol within the covariant density functional theory. In addition, total electron binding energies are used in the conversion of atomic binding energies into nuclear ones. Their dependence on neutron excess is investigated across the nuclear chart within the atomic approach. Furthermore, these factors were disregarded in the previous generation of covariant energy density functionals, but their omission leads to substantial global calculation errors for physical quantities of interest. For example, these errors for binding energies are of the order of 0.8 MeV or higher for the three major classes of covariant energy density functionals.

Binding energy & masses↗

S AP F LOWER : an automated tool for sap flow data preprocessing, gap-filling, and analysis using deep learning

Sap flow, a critical process in plant water use and ecosystem water cycles, is often measured using thermal dissipation probes (TDP) due to their ease of installation and continuous data collection. However, sap flow data frequently include noise, outliers, and gaps, creating challenges for analysis and requiring substantial manual processing. We developed S AP F LOWER , a tool that automates data preprocessing, model training, gap-filling, sapwood area scaling and modeling, and water use analysis. It integrates autocleaning, machine learning and deep learning models (e.g. random forest, Gaussian process regression, long short-term memory (LSTM), bidirectional LSTM (BiLSTM)), and efficient workflows to process sap flow data. S AP F LOWER can remove over 90% of noisy data while preserving legitimate variations and achieve high accuracy in gap-filling based on user-determined parameters. Random forest, LSTM, and BiLSTM models reduced root mean square error to 10% or less for long-term gaps. Model training and prediction can be performed efficiently within seconds. S AP F LOWER significantly enhances the efficiency and accessibility of TDP data analysis by automating complex tasks, enabling researchers without programming expertise to employ advanced techniques. Future improvements will focus on species-specific corrections for TDP and support for additional measurement methods. S AP F LOWER is openly available on GitHub (https://github.com/JiaxinWang123/SapFlower) and Zenodo (doi: 10.5281/zenodo.13665919).

ecosystem water balance↗

Search for Accelerator-Produced Sub-GeV Dark Matter with the NOvA Near Detector

The NuMI facility at Fermilab produces a high-intensity beam of muon neutrinos and antineutrinos, designed to study neutrino oscillations. This beam may also be a source of dark matter particles produced through a light mediator. We search for dark matter particles with masses between 1 and 200 MeV that interact with Standard Model particles via a vector portal, producing forward-scattered single-electron events in the NOvA near detector. We set limits on the dark-visible coupling based on an exposure of 2.55x10^21 protons of 120 GeV energy on the NuMI target. For the dark matter mass range 10-20 MeV, this analysis sets the tightest constraints on the coupling to date.

Abubakar, S. [Erciyes U.] (ORCID:0000000315112219)↗

Commodity Thermoplastic Elastomer-Enabled Templated Synthesis of Large-Pore Ordered Mesoporous Materials

Fabrication of ordered mesoporous materials (OMMs) has predominantly relied on templating-based methods. However, these methods are constrained by several limitations, especially the limited pore sizes attainable with commercially available surfactants used as structure-directing agents. To unlock the full potential of the OMMs, it is essential to develop synthetic strategies that facilitate the production of large-pore OMMs using scalable processes and cost-effective precursors. This work demonstrates the use of thermoplastic elastomer (TPE)-derived carbon replicas for synthesizing ordered mesoporous silica (OMS) and metal oxides (OMMOs) via precursor infiltration and template removal. The nanostructural evolution of the resulting inorganic materials was systematically investigated. Specifically, using tetraethyl orthosilicate (TEOS) as a silica precursor, this method can produce an OMS with relatively large pores. To establish the generalizability of this process, the fabrication approach was extended to other commercially available TPEs with varied chemical compositions and molecular weights while consistently resulting in ordered structures. Additionally, this synthetic strategy can be successfully applied to the production of OMMOs, including tin and titanium oxide matrix chemistries, yielding pore sizes of 16.0 and 19.2 nm, respectively. By developing a general method and using low-cost precursors, this work presents a scalable approach for fabricating large-pore OMMs with tunable pore textures and matrix chemistries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Who is benefiting from the dramatic decline in U.S. cancer mortality? Place-based evidence of disparities in rates of improvement

After decades of increasing cancer mortality, U.S. rates declined from 1991 to 2019, a 32% decrease. we investigated rates of cancer mortality improvement across 2954 counties and selected characteristics associated with mortality improvements. Data was 21,381,009 county-level neoplasm deaths gleaned from death certificates via CDC WONDER. Analytical techniques included GIS and Moran’s I, OLS, GWR models, and trend comparisons. Counties with the greatest improvement (reduction) in cancer mortality tended to be coastal, higher-income, metropolitan locations. OLS model (R 2 = 0.65) indicated that greatest improvements were observed in counties with higher initial mortality ($\beta =.32$) closely followed by percent urban ($\beta =.31$) and median household income ($\beta =.16$). Whereas percent Black residents ($\beta =-.06$), and percent with education beyond high school ($\beta =-.10$) was less associated on outcomes. Highest income counties were the first to experience improvement in cancer mortality, the highest rates of mortality decline, and the greatest reduction in excess deaths. Even though there was significant improvement in cancer mortality nationally, there were variations in the degree of improvement linked to county location, income, and urbanisation. These results underlie the need to expand place-based initiatives designed to advance cancer health and more equitable improvements in cancer mortality outcomes.

developing world↗

Recent progress in global optimizations of covariant energy density functionals

The recent progress on global optimizations of covariant energy den­sity functionals (CEDFs) and global calculations of binding energies within the covariant density functional theory (CDFT) has been analyzed and reviewed. Recently developed anchor-based optimization approach of Ref. [1] allows global optimizations of CEDFs at a reasonable numerical cost. Moreover, it permits such optimizations in a very large fermionic basis with a proper extrap­olation to an infinite one. This allows to accurately estimate global calculation errors due to use of truncated fermionic basis and neglect of some contributions to binding energies (such as total electron binding energy).

Afanasjev, A. V. [Mississippi State University, MS↗