Search NASA⌕ Search

SEARCH · Search NASA

Results for “MIXED STATES”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

JSC-Rocknest: A Large-Scale Mojave Mars Simulant (MMS) Based Soil Simulant for In-Situ Resource Utilization Water-Extraction Studies

The Johnson Space Center-Rocknest (JSC-RN) simulant was developed in response to a need by NASA's Advanced Exploration Systems (AES) In-Situ Resource Utilization (ISRU) project for a simulant to be used in component and system testing for water extraction from Mars regolith. JSC-RN was designed to be chemically and mineralogically similar to material from the aeolian sand shadow named Rocknest in Gale Crater, particularly the 1-3 wt.% low temperature (<450 ºC) water release as measured by the Sample Analysis at Mars (SAM) instrument on the Curiosity rover. Sodium perchlorate, goethite, pyrite, ferric sulfate, regular and high capacity granular ferric oxide, and forsterite were added to a Mojave Mars Simulant (MMS) base in order to match the mineralogy, evolved gases, and elemental chemistry of Rocknest. Mineral and rock components were sent to the United States Geological Survey (USGS) in Denver for mixing. Approximately 800 kg of JSC-RN was sent back to NASA in 5 gallon buckets, which were subsampled and characterized. All samples of the USGS-produced simulants had similar evolved gas profiles as a small prototype batch of JSC-RN made in JSC laboratories, with the exception of HCl, and were similar in terms of mineralogy and total chemistry. Also, all JSC-RN subsamples were homogenous and had similar mineralogy, total chemistry, and low-temperature evolved gas profiles as the Rocknest aeolian sand shadow examined with Curiosity’s instrument suite on Mars. In particular, the low temperature water releases were similar and the amount of water evolved from JSC-RN at <450 ºC was similar to the water content of Rocknest based on SAM water peak integrations. Overall, JSC-RN is ideally suited for ISRU studies of water extraction of global martian soil due to its excellent agreement with measured properties of martian soils and its proven feasibility for large-scale production.

Simulant↗

Frequency-Weighting Filter Selection, for H2 Control of Microgravity Isolation Systems: A Consideration of the "Implicit Frequency Weighting" Problem

Many space-science experiments need an active isolation system to provide them with the requisite microgravity environment. The isolation systems planned for use with the International Space Station (ISS) have been appropriately modeled using relative position, relative velocity, and acceleration states. In theory, frequency-weighting design filters can be applied to these state-space models, in order to develop optimal H2 or mixed-norm controllers with desired stability and performance characteristics. In practice, however, since there is a kinematic relationship among the various states, any frequency weighting applied to one state will implicitly weight other states. These implicit frequency-weighting effects must be considered, for intelligent frequency-weighting filter assignment. This paper suggests a rational approach to the assignment of frequency-weighting design filters, in the presence of the kinematic coupling among states that exists in the microgravity vibration isolation problem.

Hampton, Roy David↗

Frequency-Weighting Filter Selection for H2 Control of Microgravity Isolation Systems: A Consideration of the "Implicit Frequency Weighting" Problem

Many space-science experiments need an active isolation system to provide them with the requisite microgravity environment. The isolation system planned for use with the International Space Station (ISS) have been appropriately modeled using relative position, relative velocity, and acceleration states. In theory, frequency-weighting design filters can be applied to them state-space models, In order to develop optimal H2 or mixed-norm controllers with desired stability and performance characteristics. In practice. however, since there Is a kinematic relationship among the various states. any frequency weighting applied to one state will implicitly weight other states. These implicit frequency-weighting effects must be considered, for intelligent frequency-weighting filter assignment. This paper suggests a rational approach to the assignment of frequency-weighting design filters, in the presence of the kinematic coupling among states that exists in the microgravity vibration isolation problem.

Hampton, R. David↗

Distribution of Halon-1211 in the Upper Troposphere and Lower Stratosphere and the 1994 Total Bromine Budget

We report here on the details of the first, in situ, real-time measurements of H-1211 (CBrClF2) and sulfur hexafluoride (SF6) mixing ratios in the stratosphere up to 20 km. Stratospheric air was analyzed for these gases and others with a new gas chromatograph, flown aboard a National Aeronautics and Space Administration ER-2 aircraft as part of the Airborne Southern Hemisphere Ozone Experiment/Measurements for Assessing the Effects of Stratospheric Aircraft mission conducted in 1994. The mixing ratio of SF6, with its nearly linear increase in the troposphere, was used to estimate the mean age of stratospheric air parcels along the ER-2 flight path. Measurements of H-1211 and mean age estimates were then combined with simultaneous measurements of CFC-11 (CCl3F), measurements of brominated compounds in stratospheric whole air samples, and records of tropospheric organic bromine mixing ratios to calculate the dry mixing ratio of total bromine in the lower stratosphere and its partitioning between organic and inorganic forms. We estimate that the organic bromine-containing species were almost completely photolyzed to inorganic species in the oldest air parcels sampled. Our results for inorganic bromine are consistent with those obtained from a photochemical, steady state model for stratospheric air parcels with CFC- I I mixing ratios greater than 150 ppt. For stratospheric air parcels with CFC-11 mixing ratios less than 50 ppt (mean age greater than or equal to 5 years) we calculate inorganic bromine mixing ratios that are approximately 20% less than the photo-chemical, steady state model. There is a 20% reduction in calculated ozone loss resulting from bromine chemistry in old air relative to some previous estimates as a result of the lower bromine levels.

Wamsley, P. R.↗

On the formation of nonlinear internal waves from the gravitational collapse of mixed regions in two and three dimensions

The paper shows how trains of nonlinear, dispersive waves can be produced by allowing a region of mixed fluid, with a potential energy greater than its surroundings, to collapse towards its equilibrium state. The number of waves and their amplitude depend on the properties of the mixed region and of the ambient stratification. Three different geometrical configurations have been chosen and while each gives qualitatively the same results the form taken by the generated waves and the final equilibrium shape of the mixed region depend critically on these geometrical factors. The internal waves produced by this mechanism are related to waves produced in natural systems and it is shown that the observations support at least one possible explanation for those found in the oceans and planetary atmospheres.

Maxworthy, T.↗

Inter-species molecular attraction effect in the development of a two-species mixing layer

Simulations of fluid mixing occurring at high-pressures mandate the use of real-fluid equations of state to capture the effect of boh intermolecular repulsive forces and attractive forces which are neglected in perfect gases. Dedicated mixing rules account for these forces by providing a generic mapping of the mixture state-space onto a pure fluid domain. However, the specific inter-species molecular forces depend on the particular characteristics of the molecular pairs under consideration, and typically require the knowledge of binary interaction coefficients k_{αβ}. The impact of k_{αβ} on a flow field is as of now unclear; further, k_{αβ} is unknown for many molecular pairs and when unknown, set to be null. This study addresses the impact of k_{αβ} on the temporal evolution of a real-fluid mixing layer and uses Direct Numerical Simulation (DNS) to explore this impact. The results show differences between augmented attraction (k_{αβ}<0) and diminished attraction (k_{αβ}>0), affecting both fluid dynamics and diffusion processes. Specifically, in a binary mixing layer, it is observed that augmented attraction leads to delayed transition and mixing layer growth, manifested in the momentum layer thickness. The fractal dimension, which is a manifestation of interface corrugation, is calculated. These results provide an hitherto undocumented mechanism affecting the development of mixing layers.

Banuti, Daniel↗

Mixing by barotropic instability in a nonlinear model

A global, nonlinear, equivalent barotropic model is used to study the isentropic mixing of passive tracers by barotropic instability. Basic states are analytical zonal-mean jets representative of the zonal-mean flow in the upper stratosphere, where the observed 4-day wave is thought to be a result of barotropic, and possibly baroclinic, instability. As is known from previous studies, the phase speed and growth rate of the unstable waves is fairly sensitive to the shape of the zonal-mean jet; and the dominant wave mode at saturation is not necessarily the fastest growing mode; but the unstable modes share many features of the observed 4-day wave. Lagrangian trajectories computed from model winds are used to characterize the mixing by the flow. For profiles with both midlatitude and polar modes, mixing is stronger in midlatitude than inside the vortex; but there is little exchange of air across the vortex boundary. There is a minimum in the Lyapunov exponents of the flow and the particle dispersion at the jet maximum. For profiles with only polar unstable modes, there is weak mixing inside the vortex, no mixing outside the vortex, and no exchange of air across the vortex boundary. These results support the theoretical arguments that, whether wave disturbances are generated by local instability or propagate from other regions, the mixing properties of the total flow are determined by the locations of the wave critical lines and that strong gradients of potential vorticity are very resistant to mixing.

Bowman, Kenneth P.↗

Investigations of coherent structures in free turbulent shear flows

The dynamics of large-scale coherent structures in general, and studies based on flow-visualization and phase-locked hot-wire measurements of the structures in the near fields of circular jets are considered. A study involving the nature of coherent structures under conditions of stable vortex pairing induced by controlled axisymmetric acoustic excitation reveals that azimuthal coherence initially enhanced by the excitation is lost before the end of the potential core through evolution of azimuthal lobe structures and turbulent breakdown. The evolution of a spark-induced spot in an axisymmetric turbulent mixing layer is also investigated, and the coherent Reynolds stress associated with the spot is found to be much higher than the background turbulence Reynolds stress. In addition, the state of organization in a high Reynolds number unperturbed axisymmetric mixing layer is examined, and it is shown that the shear layer is infrequently organized and the motions are intensely three-dimensional, while tearing and fractional pairing occur as frequently as complete pairing.

Hussain, A. K. M. F.↗

Aspects of Supercritical Turbulence: Direct Numerical Simulation of O2/H2 and C7H16/N2 Temporal Mixing Layers

Results from Direct Numerical Simulations of temporal, supercritical mixing layers for two species systems are analyzed to elucidate species-specific turbulence aspects. The two species systems, O2/H2 and C7HG16/N2, have different thermodynamic characteristics; thus, although the simulations are performed at similar reduced pressure (ratio of the pressure to the critical pressure), the former system is dose to mixture ideality and has a relatively high solubility with respect to the latter, which exhibits strong departures from mixture ideality Due to the specified, smaller initial density stratification, the C7H16/N2 layers display higher growth and increased global molecular mixing as well as larger turbulence levels. However, smaller density gradients at the transitional state for the O2/H2 system indicate that on a local basis, the layer exhibits an enhanced mixing, this being attributed to the increased solubility and to mixture ideality. These thermodynamic features are shown to affect the irreversible entropy production (i.e. the dissipation), which is larger for the O2/H2 layer and is primarily concentrated in high density-gradient magnitude regions that are distortions of the initial density stratification boundary. In contrast, the regions of largest dissipation in the C7H16/N2 layer are located in high density-gradient magnitude regions resulting from the mixing of the two fluids.

Bellan, J.↗

Martian Atmospheric Circulation and Climate

This proposal is focused on using Mars Global Surveyor (MGS) data and numerical models to address issues of atmospheric mixing of volatiles and aerosols, on defining the mean state of the atmosphere and the degree of variability, and on the processes which exchange volatiles and aerosols between the surface and atmosphere. Specifically, five areas of research were defined: In the first, we proposed to use TES data to examine the general circulation of the atmosphere both through retrieval of the residual circulation, and by comparison of the TES data with a Mars General Circulation Model (GCM). In the second, we proposed to look at synoptic and mesoscale atmospheric mixing processes (baroclinic storms, etc.) by combining TES and MOC Wide Angle data, and by employing a Mars Mesoscale Model. In the third section, we proposed to examine the record of the Martian atmospheric state provided by MGS, Viking, and Mariner 9 - as well as published ground-based observations - in order to assess the nature of interannual variability. In the forth section, we proposed to compare numerical models of the Martian water and dust cycles with TES and MOC data, specifically looking at water ice cloud distributions, dust distribution, etc. In the fifth section, we propose to use the mesoscale model to study the Mars Pathfinder Lander data. This work has now concluded its final of three years.

Ingersoll, Andrew P.↗

A new unsteady mixing model to predict NO(x) production during rapid mixing in a dual-stage combustor

An advanced gas turbine engine to power supersonic transport aircraft is currently under study. In addition to high combustion efficiency requirements, environmental concerns have placed stringent restrictions on the pollutant emissions from these engines. A dual-stage combustor with the potential for minimizing pollutants such as NO(x) emissions is undergoing experimental evaluation. A major technical issue in the design of this combustor is how to rapidly mix the hot, fuel-rich primary stage product with the secondary diluent air to obtain a fuel-lean mixture for combustion in the secondary stage. Numerical design studies using steady-state methods cannot account for the unsteady phenomena in the mixing region. Therefore, to evaluate the effect of unsteady mixing and combustion processes, a novel unsteady mixing model is demonstrated here. This model has been used in a stand-alone mode to study mixing and combustion in hydrogen-air nonpremixed jet flames. NO(x) production in these jet flames was also predicted. Comparison of the computed results with experimental data show good agreement thereby providing validation of the mixing model.

Menon, Suresh↗

Mixed solar wind originating from coronal regions of different temperatures

Ionization states of elements in the solar wind are often used to determine thermal gradients in the lower corona. This method is based on the assumption, that in the beginning, solar wind material has a homogeneous temperature determining the original charge state of elements. Features in M/Q-spectra which might appear if the above assumption is violated are investigated and compared with observational evidence.

Bochsler, P.↗

Estimating the Distribution of Colored Dissolved Organic Matter During the Southern Ocean Gas Exchange Experiment Using Four-Dimensional Variational Data Assimilation

We diagnosed the effect of various physical processes on the distribution of mixed-layer colored dissolved organic matter (CDOM) and a sulfur hexauoride (SF6) tracer during the Southern Ocean Gas Exchange Experiment (SO GasEx). The biochemical upper ocean state estimate uses in situ and satellite biochemical and physical data in the study region, including CDOM (absorption coefcient and spectral slope), SF6, hydrography, and sea level anomaly. Modules for photobleaching of CDOM and surface transport of SF6 were coupled with an ocean circulation model for this purpose. The observed spatial and temporal variations in CDOM were captured by the state estimate without including any new biological source term for CDOM, assuming it to be negligible over the 26 days of the state estimate. Thermocline entrainment and photobleaching acted to diminish the mixed-layer CDOM with time scales of 18 and 16 days, respectively. Lateral advection of CDOM played a dominant role and increased the mixed-layer CDOM with a time scale of 12 days, whereas lateral diffusion of CDOM was negligible. A Lagrangian view on the CDOM variability was demonstrated by using the SF6 as a weighting function to integrate the CDOM elds. This and similar data assimilation methods can be used to provide reasonable estimates of optical properties, and other physical parameters over the short-term duration of a research cruise, and help in the tracking of tracer releases in large-scale oceanographic experiments, and in oceanographic process studies.

Del Castillo, C. E.↗

An Indirect Mixed-Sensitivity Approach to Microgravity Vibration Isolation: The Exploitation of Kinematic Coupling In Frequency-Weighting Design-Filter Selections

Many space science experiments need an active isolation system to provide them with the requisite microgravity environment. The isolation systems planned for use with the International Space Station have been appropriately modeled using relative position, relative velocity, and acceleration states. In theory, frequency design filters can be applied to these state-space models, in order to develop optimal H, or mixed-norm controllers with desired stability- and performance characteristics. In practice. however, the kinematic coupling among the various states can lead, through the associated frequency-weighting-filters, to conflicting demands on the Riccati design "machinery." The results can be numerically ill-conditioned regulator and estimator Riccati equations and/or reduced intuition in the design process. In addition, kinematic coupling can result in a redundancy in the demands imposed by the frequency weights. Failure properly to account for this type of coupling can lead to an unnecessary increase in controller dimensionality and, in turn, controller complexity. This paper suggests a rational approach to the assignment of frequency weighting design filters, in the presence of the kinematic coupling among states that exists in the microgravity vibration isolation problem.

Hampton, R. David↗

The Surface Compositions of Pluto and Charon

The surface of Pluto as it is understood on the eve of the encounter of the New Horizons spacecraft (mid-2015) consists of a spatially heterogeneous mix of solid N2, CH4, CO, C2H6, and an additional component that imparts color, and may not be an ice. The known molecular ices are detected by near-infrared spectroscopy. The N2 ice occurs in the hexagonal crystalline b-phase, stable at T greater than 35.6 K. Spectroscopic evidence for wavelength shifts in the CH4 bands attests to the complex mixing of CH4 and N2 in the solid state, in accordance with the phase diagram for N2 + CH4. Spectra obtained at several aspects of Plutos surface as the planet rotates over its 6.4-day period show variability in the distribution of CH4 and N2 ices, with stronger CH4 absorption bands associated with regions of higher albedo, in correlation with the visible rotational light curve. CO and N2 ice absorptions are also strongly modulated by the rotation period; the bands are strongest on the anti-Charon hemisphere of Pluto. Longer term changes in the strengths of Plutos absorption bands occur as the viewing geometry changes on seasonal time-scales, although a complete cycle has not been observed. The non-ice component of Plutos surface may be a relatively refractory material produced by the UV and cosmic-ray irradiation of the surface ices and gases in the atmosphere, although UV does not generally penetrate the atmospheric CH4 to interact with the surface. Laboratory simulations indicate that a rich chemistry ensues by the irradiation of mixtures of the ices known to occur on Pluto, but specific compounds have not yet been identified in spectra of the planet. Charons surface is characterized by spectral bands of crystalline H2O ice, and a band attributed to one or more hydrates of NH3. Amorphous H2O ice may also be present; the balance between the amorphization and crystallization processes on Charon remains to be clarified. The albedo of Charon and its generally spatially uniform neutral color indicate that a component, not yet identified, is mixed in some way with the H2O and NH3nH2O ices. Among the many known small bodies in the transneptunian region, several share characteristics with Pluto and Charon, including the presence of CH4, N2, C2H6, H2O ices, as well as components that yield a wide variety of surface albedo and color. The New Horizons investigation of the Pluto-Charon system will generate new insight into the physical properties of the broader transneptunian population, and eventually to the corresponding bodies expected in the numerous planetary systems currently being discovered elsewhere in the Galaxy.

surface composition↗

An Indirect Mixed-Sensitivity Approach to Microgravity Vibration Isolation: The Exploitation of Kinematic Coupling In Frequency-weighting Design-Filter Selections

Many space-science experiments need an active isolation system to provide them with the requisite microgravity environment. The isolation systems planned for use with the International Space Station have been appropriately modeled using relative position relative velocity, and acceleration states. In theory, frequency-weighting design filters can be applied to these state-space models, in order to develop optimal H2 or mixed-norm controllers with desired stability and performance characteristics. In practice, however, the kinematic coupling among the various states can lead, through the associated frequency-weighting-filters, to conflicting demands on the Riccati design "machinery." The results can be numerically ill-conditioned regulator and estimator Riccati equations and/or reduced intuition in the design process. In addition, kinematic coupling can result in a redundancy in the demands imposed by the frequency weights. Failure properly to account for this type of coupling can lead to an unnecessary increase in controller dimensionality and, in turn, controller complexity. This paper suggests a rational approach to the assignment of frequency-weighting design filters, in the presence of the kinematic coupling among states that exists in the microgravity vibration isolation problem.

Hampton, R. David↗

Collisional broadening, line shifting, and line mixing in the stimulated Raman 2nu2 Q branch of CH4

Self-, argon-, and helium-broadening coefficients have been measured for 13 lines in the 2nu2 Raman Q branch of CH4 using stimulated inverse Raman spectroscopy. The linewidths clearly show the symmetry-state dependence characteristic of pressure broadening, and inelastic processes in general, involving spherical-top molecules. Pressure-induced line shifts have also been measured for these features in pure methane. The pressure-shift coefficients do not display the symmetry-state dependence found for the linewidths. By applying the Rosenkranz perturbation treatment to a pair of collisionally mixed lines, an estimate of individual state-to-state contributions to the overall linewidth has been obtained.

Millot, G.↗

Basic analysis of terminal operation benefits resulting from reduced vortex separation minima

The impact of reducing the wake vortex minimum separation required behind heavy jets on terminal area operation rate was analyzed. The effect on arrival saturation and steady state average delay was determined for various percentages mix of heavy and large jet traffic samples operating under various precision of interarrival spacing. Benefits increase with percentage of heavy aircraft and with precision of control. These results demonstrate the payoff possible from research to reduce the severity of the trailing vortex by aerodynamic means.

Credeur, L.↗