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Mars Solar Balloon Landed Gas Chromatograph Mass Spectrometer

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload. The GCMS would obtain samples directly from the atmosphere at the surface and also from gases evolved from solid phase material collected from well below the surface with a Sample Acquisition and Transport Mechanism (SATM). The experiment envisioned in the Mars Micromission described would obtain samples from a much greater depth of up to one meter below the surface, and would search for organic molecules trapped in ancient stratified layers well below the oxidized surface. Insitu instruments on upcoming NASA missions working in concert with remote sensing measurement techniques have the potential to provide a more detailed investigation of mineralogy and the extent of simple volatiles such as CO2 and H2O in surface and subsurface solid phase materials. Within the context of subsequent mission opportunities such as those provided by the Ariane 5 piggyback payload based Micromissions, it is essential to implement an even broader chemical analysis and to enable a significant extension of previous isotope measurements. Such a development would enhance the presently very active study of questions of atmospheric evolution and loss and past climatic conditions. The method selected to implement this program can be based on well-established mass spectrometry techniques. Sampled gas is chemically and physically processed to separate the gas mixture into components using gas chromatograph and related enrichment techniques. This allows trace species to be identified and reveals isotopic distributions in many cases with improved precision. Samples of interest, such as organic molecules, may lie deep below the highly oxidized surface layer and the suggested program includes enhanced sampling techniques to measure volatiles preserved in solid phase material deep below the surface as well as gas from the well mixed atmosphere.

Mahaffy, P.↗

The polar caps and the climatic evolution of Mars

Mars and Earth experience quasiperiodic variations in the distribution of incident solar radiation due to secular perturbations in their orbital and axial elements. On Mars, the potential climatic effects of these perturbations are large because the mass of the Martian atmosphere may be determined by the vapor pressures of semipermanent CO2 frost deposits at the poles. The Viking Orbiter observations of the Martian polar caps suggest that the sensitivity of the Martian climate system to the variations in the polar insolation may be considerably reduced by the tendency for polar frost deposits to become brighter with increasing rates of incident solar radiation. This phenomenon can be explained by the tendency for dust particles to sink into CO2 frost at rates that depend on the magnitude of the incident solar flux.

Paige, D. A.↗

Simulating Mars' Dust Cycle with a Mars General Circulation Model: Effects of Water Ice Cloud Formation on Dust Lifting Strength and Seasonality

The dust cycle is critically important for the current climate of Mars. The radiative effects of dust impact the thermal and dynamical state of the atmosphere [1,2,3]. Although dust is present in the Martian atmosphere throughout the year, the level of dustiness varies with season. The atmosphere is generally the dustiest during northern fall and winter and the least dusty during northern spring and summer [4]. Dust particles are lifted into the atmosphere by dust storms that range in size from meters to thousands of kilometers across [5]. Regional storm activity is enhanced before northern winter solstice (Ls~200 degrees - 240 degrees), and after northern solstice (Ls~305 degrees - 340 degrees ), which produces elevated atmospheric dust loadings during these periods [5,6,7]. These pre- and post- solstice increases in dust loading are thought to be associated with transient eddy activity in the northern hemisphere with cross-equatorial transport of dust leading to enhanced dust lifting in the southern hemisphere [6]. Interactive dust cycle studies with Mars General Circulation Models (MGCMs) have included the lifting, transport, and sedimentation of radiatively active dust. Although the predicted global dust loadings from these simulations capture some aspects of the observed dust cycle, there are marked differences between the simulated and observed dust cycles [8,9,10]. Most notably, the maximum dust loading is robustly predicted by models to occur near northern winter solstice and is due to dust lifting associated with down slope flows on the flanks of the Hellas basin. Thus far, models have had difficulty simulating the observed pre- and post- solstice peaks in dust loading.

Kahre, Melinda A.↗

Coupling the Mars Dust and Water Cycles: Investigating the Role of Clouds in Controlling the Vertical Distribution of Dust During N. H. Summer

The dust cycle is critically important for the current climate of Mars. The radiative effects of dust impact the thermal and dynamical state of the atmosphere (Gierasch and Goody, 1968; Haberle et al., 1982; Zurek et al., 1992). Although dust is present in the Martian atmosphere throughout the year, the level of dustiness varies with season. The atmosphere is generally the dustiest during northern fall and winter and the least dusty during northern spring and summer (Smith, 2004). Dust particles are lifted into the atmosphere by dust storms that range in size from meters to thousands of kilometers across (Cantor et al., 2001). During some years, regional storms combine to produce hemispheric or planet encircling dust clouds that obscure the surface and raise atmospheric temperatures by as much as 40 K (Smith et al., 2002). Key recent observations of the vertical distribution of dust indicate that elevated layers of dust exist in the tropics and sub-tropics throughout much of the year (Heavens et al., 2011). These observations have brought particular focus on the processes that control the vertical distribution of dust in the Martian atmosphere. The goal of this work is to further our understanding of how clouds in particular control the vertical distribution of dust, particularly during N. H. spring and summer

Mars dust↗

The Mars Reconnaissance Orbiter Mission: Continuing a Record of Exploration from Mars Orbit

The Mars Reconnaissance Orbiter (MRO) has been on station in its low altitude, sun-synchronous, primary science orbit since September 2006 performing both scientific and Mars programmatic support functions. The spacecraft is a very capable remote sensing science platform carrying six science payloads supporting seven investigations and a UHF telecommunications radio (Electra) for surface relay. Developed to support a mix of nadir mapping and targeted, highresolution surface observations, the spacecraft’s powerful telecommunications and command & data handling (C&DH) subsystems communicate an average of 16 hours a day with the Deep Space Network (DSN). To date, more than 300 TB of scientific data has been returned to Earth. All of the original science payloads are active with standard and new observing modes contributing to the advancement of Mars science through peer-reviewed paper publications and the timely dissemination of their data to the science community as a whole. Results from the science teams have revealed an amazing diversity of ancient aqueous environments and ongoing surface change is evident through gully formation, avalanches, and cratering. Extending the MRO-MGS climate record to a decade of Mars years is contributing to a better understanding of current atmospheric and polar processes. In addition to its fundamental scientific objectives, MRO is a critical element of NASA’s Mars Exploration Program (MEP) providing needed infrastructure support for landed and future missions. Using its Electra telecommunications payload, MRO provides landers and rovers critical event coverage during their entry, descent, and landing (EDL) phases and UHF relay support once they are on the Martian surface. MRO’s high-resolution imagers are used to scout potential landing sites and certify safe zones for landing. As MRO begins its Fourth Extended Mission, the spacecraft remains fully capable of carrying out an ambitious science observing plan and the programmatic tasks assigned to it. In addition to highlighting recent discoveries of the mission, this paper describes recent challenges the spacecraft engineers have faced in flight and the plans for extending spacecraft life well into the 2020’s.

Tamppari, Leslie K.↗

Mars surface gas chromatograph mass spectrometer

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload.

Mahaffy, P.↗

Trace Gas Measurements on Mars and Earth Using Optical Parametric Generation

Trace gases and their isotopic ratios in planetary atmospheres offer important but subtle clues as to the origins of a planet's atmosphere, hydrology, geology, and potential for biology. An orbiting laser remote sensing instrument is capable of measuring trace gases on a global scale with unprecedented accuracy, and higher spatial resolution that can be obtained by passive instruments. We have developed an active sensing instrument for the remote measurement of trace gases in planetary atmospheres (including Earth). The technique uses widely tunable, seeded optical parametric generation (OPG) to measure methane, CO2, water vapor, and other trace gases in the near and mid-infrared spectral regions. Methane is a strong greenhouse gas on Earth and it is also a potential biogenic marker on Mars and other planets. Methane in the Earth's atmosphere survives for a shorter time than CO2 but its impact on climate change can be larger than CO2. Methane levels have remained relatively constant over the last decade around 1.78 parts per million (ppm) but recent observations indicate that methane levels may be on the rise. Increasing methane concentrations may trigger a positive feedback loop and a subsequent runaway greenhouse effect, where increasing temperatures result in increasing methane levels. The NRC Decadal Survey recognized the importance of global observations of greenhouse gases and called for simultaneous CH4, CO, and CO2 measurements but also underlined the technological limitations for these observations. For Mars, methane measurements are of great interest because of its potential as a strong biogenic marker. A remote sensing instrument that can measure day and night over all seasons and latitudes can identify and localize sources of biogenic gas plumes produced by subsurface chemistry or biology, and aid in the search for extra-terrestrial life. It can identify the dynamics of methane generation over time and latitude and identify future lander mission sites for more detailed in-situ analysis. In this paper we report on remote sensing measurements of methane using a high peak power, widely tunable optical parametric generator (OPG) operating at 3.3 micron and 1.65 micron. The OPG is pumped by a passively q-switched single frequency laser (3ns, 5KHz, 50uJ) and seeded by a diode laser. The spectral width of both signal and idler of seeded OPG is nearly Fourier transform limited. The output of seeded OPG is single frequency with high spectral purity and is widely tunable. Both 1650 nm and 3300 nm can be generated with a conversion efficiency of more than 30%. We have demonstrated detection of methane at 3274 nm and 1650 nm in a cell and also performed open path atmospheric measurements of methane at the same wavelengths. Finally, we were able to demonstrate simultaneous detection of methane at 3270.4 nm and CO2 at 1578.2 nm. In this paper we will discuss the OPG performance and atmospheric open path measurement results.

Numata, Kenji↗

Investigating Mars South Residual CO2 Cap with a Global Climate Model

The CO2 cycle is one of the three controlling climate cycles on Mars. One aspect of the CO2 cycle that is not yet fully understood is the existence of a residual CO2 ice cap that is offset from the south pole. Previous investigations suggest that the atmosphere may control the placement of the south residual cap (e.g., Colaprete et al., 2005). These investigations show that topographically forced stationary eddies in the south during southern hemisphere winter produce colder atmospheric temperatures and increased CO2 snowfall over the hemisphere where the residual cap resides. Since precipitated CO2 ice produces higher surface albedos than directly deposited CO2 ice, it is plausible that CO2 snowfall resulting from the zonally asymmetric atmospheric circulation produces surface ice albedos high enough to maintain a residual cap only in one hemisphere. The goal of the current work is to further evaluate Colaprete et al.'s hypothesis by investigating model-predicted seasonally varying snowfall patterns in the southern polar region and the atmospheric circulation components that control them.

CO2 cycle↗

Stability of streams and lakes on Mars

The freezing of small Martian streams is modelled for a variety of climatic conditions, on the supposition that the Martian atmosphere may have been considerably thicker in the past, at the time of the formation of the valley networks. This model examines the energy balance at the upper and lower surfaces of ice on streams, in order to determine the rate at which ice thickens with time. Results indicate that freezing rates are not strongly dependent on atmospheric pressure, and, under windy conditions, dependence on atmospheric pressure is even weaker. It is noted that the main problem in valley formation is in initiating the flow. Groundwater seepage alone is inadequate, due to the difficulty of groundwater system replenishment.

Carr, M. H.↗

The Coupled Roles of Dust and Clouds in the Mars Climate

During the period October 1997 to September 1999 we obtained and analyzed over 100 millimeter-wave observations of Mars atmospheric CO line absorption for atmospheric temperature profiles. These measurements extend through one full Mars year (solar longitudes L(sub S) of 190 deg in 1997 to 180 deg in 1999) and coincide with atmospheric temperature profile and dust column measurements front the Thermal Emission Spectrometer (TES) experiment on board the Mars Global Surveyor (MGS) spacecraft. A comparison of Mars atmospheric temperatures retrieved by these distinct methods provides the first opportunity to place the long-term (1982-1999) millimeter retrievals of Mars atmospheric temperatures within the context of contemporaneous, spatially mapped spacecraft, observations. Profile comparisons of 0-30 km altitude atmospheric temperatures retrieved with the two techniques agree typically to within the 5 K calibration accuracy of the millimeter observations. At the 0.5 mbar pressure level (approximately 25 km altitude) the 30N/30S average for TES infrared temperatures and the disk-averaged millimeter temperatures are also well correlated in their seasonal and dust-storm-related variations over the 1997-1999 period. This period includes the Noachis Terra regional dust storm, which led to very abrupt heating (approximately 15 K at 0.5 mbar) of the global Mars atmosphere at L(sub S)=224 deg in 1997 [Christensen et al., 1998; Conrath et al., this issue; Smith et al., this issue]. Much colder (10-20 K) global atmospheric temperatures were observed during the 1997 versus 1977 perihelion periods (L(sub S)=200 deg-330 deg), consistent with the much (2 to 8 times) lower global dust loading of the atmosphere during the 1997 perihelion dust storm season versus the Viking period of the 1977a,b storms. The 1998-1999 Mars atmosphere revealed by both the millimeter and TES observations is also 10-15 K colder than presented by the Viking climatology during the aphelion season (L(sub S)=0 deg-180 deg, northern spring/summer) of Mars. We reassess the observational basis of the Viking dusty-warm climatology for this season to conclude that the global aphelion atmosphere of Mars is colder, less dusty, and cloudier than indicated by the established Viking climatology even for the Viking period. We also conclude that Mars atmospheric temperatures exhibit their most significant interannual variations during the perihelion dust storm season (10-20 K for L(sub S)=200 deg-340 deg) and during the post-aphelion northern summer season (5-10 K for L(sub S)=100 deg-200 deg).

Clancy, R. Todd↗

Evidence from Olivine-Hosted Melt Inclusions that the Martian Mantle has a Chondritic D/H Ratio and that Some Young Basalts have Assimilated Old Crust

Magmatic degassing of volatile elements affects the climate and near-surface environment of Mars. Telescopic and meteorite studies have revealed that the Martian atmosphere and near-surface materials have D/H ratios ~5-6 times terrestrial values [e.g., 1, 2]. Such high D/H ratios are interpreted to result from the preferential loss of H relative to heavier D from the Martian atmosphere, assuming that the original Martian water inventory had a D/H ratio similar to terrestrial values and to H in primitive meteorites [e.g., 1, 3]. However, the primordial Martian D/H ratio has, until now, not been well constrained. The uncertainty over the Martian primordial D/H ratio has arisen both from the scarcity of primitive Martian meteorites and as a result of contamination by terrestrial and, perhaps, Martian surface waters that obscure the signature of the Martian mantle. This study reports a comprehensive dataset of magmatic volatiles and D/H ratios in Martian primary magmas based on low-contamination, in situ ion microprobe analyses of olivine-hosted melt inclusions from both depleted [Yamato 980459 (Y98)] and enriched [Larkman Nunatak 06319 (LAR06)] Martian basaltic meteorites. Analyses of these primitive melts provide definitive evidence that the Martian mantle has retained a primordial D/H ratio and that young Martian basalts have assimilated old Martian crust.

Usui, Tomohiro↗

The Planetary Protection Strategy of Mars Sample Return’s Earth Return Orbiter Mission

The Mars Sample Return campaign aims to use three flight missions and one ground element to safely bring rock cores, regolith and atmospheric samples from the surface of Mars to Earth to answer key questions about the geologic and climate history of Mars, including the potential for ancient life. Since its landing in Jezero Crater in 2021, the first mission, NASA’s Mars 2020, has collected a number of samples on the crater floor and on the delta using the Perseverance rover. Subsequent missions would recover the sealed sample tubes, launch them into Mars orbit, and transport them back to Earth. The ground element would be a high-containment facility that would isolate and protect the samples during initial sample characterization, which would include sample safety assessments and time-sensitive scientific investigations. These elements are currently in the planning and design stages of development, and represent an international effort of NASA, the European Space Agency (ESA), and many industry partners. The work presented here provides an overview of the planetary protection strategy of the third flight mission, the ESA-led Earth Return Orbiter (ERO), which hosts the NASA-provided Capture, Containment, and Return System (CCRS). ERO-CCRS would capture the container with up to 30 sealed tubes previously put in Martian orbit, contain them in redundant containers to ensure that no potentially hazardous Mars particles are released, and return them to Earth through an entry vehicle. Both NASA and ESA policies comply with the United Nations’ Outer Space Treaty by planning to protect Earth’s biosphere from any potential adverse effects from material returned from solar system bodies beyond the Earth-Moon system. In the conduct of Mars Sample Return, the two agencies have agreed to apply approaches consistent with their own planetary protection standards to the campaign elements each provides.

Mars Sample Return↗

The Planetary Protection Strategy of Mars Sample Return Earth Return Orbiter Mission

The Mars Sample Return campaign aims to use three flight missions and one ground element to safely bring rock cores, regolith and atmospheric samples from the surface of Mars to Earth to answer key questions about the geologic and climate history of Mars, including the potential for ancient life. Since its landing in Jezero Crater in 2021, the first mission, NASA’s Mars 2020, has collected a number of samples on the crater floor and on the delta using the Perseverance rover. Subsequent missions would recover the sealed sample tubes, launch them into Mars orbit, and transport them back to Earth. The ground element would be a high-containment facility that would isolate and protect the samples during initial sample characterization, which would include sample safety assessments and time-sensitive scientific investigations. These elements are currently in the planning and design stages of development, and represent an international effort of NASA, the European Space Agency (ESA), and many industry partners. The work presented here provides an overview of the Planetary Protection strategy of the third flight mission, the ESA-led Earth Return Orbiter (ERO), which hosts the NASA-provided Capture, Containment, and Return System (CCRS). ERO-CCRS would detect and capture the container with up to 30 sealed tubes previously put in Martian orbit, contain them in redundant containers to ensure that no potentially hazardous Mars particles are released, and return them to Earth through an entry vehicle. Both NASA and ESA policies comply with the United Nations’ Outer Space Treaty by planning to protect Earth’s biosphere from any potential adverse effects from material returned from solar system bodies beyond the Earth-Moon system. In the conduct of Mars Sample Return, the two agencies have mutually agreed to apply approaches consistent with their own planetary protection standards to the campaign elements they each provides.

mars sample return↗

Lessons Learned in Designing A Proposed Ultraviolet Sterilization System for Space

This paper presents a number of lessons learned while designing a proposed sterilization system for Mars Sample Return. This sterilization system is needed to inactivate any potentially hazardous Mars material on the exterior surface of the vessel containing sealed sample tubes filled with Mars rock cores, regolith and atmosphere. These returned samples would provide information on the geologic history of Mars, the evolution of its climate and the potential for ancient life. Mars Sample Return is categorized at Planetary Protection Category V Restricted Earth Return, so it is required to protect the Earth–Moon system from the biological impact of returning samples from Mars to Earth. This article reviews lessons learned in the development of a particular engineering implementation to support the protection of the Earth–Moon biosphere: the use of in situ ultraviolet LED illumination. The details of the biological efficacy of this approach or the policy-related impacts are outside of the scope of this manuscript. The lessons learned presented here include establishing design requirements for the system, the selection of a light source, optical design options, contamination control and approaches to thermal and power management.

Planetary Protection↗

The Planetary Protection Strategy of Mars Sample Return’s Earth Return Orbiter Mission

The Mars Sample Return campaign aims to use three flight missions and one ground element to safely bring rock cores, regolith and atmospheric samples from the surface of Mars to Earth to answer key questions about the geologic and climate history of Mars, including the potential for ancient life. Since its landing in Jezero Crater in 2021, the first mission, NASA’s Mars 2020, has collected a number of samples on the crater floor and on the delta using the Perseverance rover. Subsequent missions would recover the sealed sample tubes, launch them into Mars orbit, and transport them back to Earth. The ground element would be a high-containment facility that would isolate and protect the samples during initial sample characterization, which would include sample safety assessments and time-sensitive scientific investigations. These elements are currently in the planning and design stages of development, and represent an international effort of NASA, the European Space Agency (ESA), and many industry partners. The work presented here provides an overview of the planetary protection strategy of the third flight mission, the ESA-led Earth Return Orbiter, which hosts the NASA-provided Capture, Containment, and Return System. The orbiter would detect and capture the container with up to 30 sealed tubes previously put in Martian orbit, contain them in redundant containers to ensure that no potentially hazardous Mars particles are released, and return them to Earth through an entry vehicle. Both NASA and ESA policies comply with the United Nations’ Outer Space Treaty by planning to protect Earth’s biosphere from any potential adverse effects from material returned from solar system bodies beyond the Earth-Moon system. In the conduct of Mars Sample Return, the two agencies have mutually agreed to apply approaches consistent with their own planetary protection standards to the campaign elements they each provide.

Mars Sample Return↗

Atmosphere Assessment for MARS Science Laboratory Entry, Descent and Landing Operations

On August 6, 2012, the Mars Science Laboratory rover, Curiosity, successfully landed on the surface of Mars. The Entry, Descent and Landing (EDL) sequence was designed using atmospheric conditions estimated from mesoscale numerical models. The models, developed by two independent organizations (Oregon State University and the Southwest Research Institute), were validated against observations at Mars from three prior years. In the weeks and days before entry, the MSL "Council of Atmospheres" (CoA), a group of atmospheric scientists and modelers, instrument experts and EDL simulation engineers, evaluated the latest Mars data from orbiting assets including the Mars Reconnaissance Orbiter's Mars Color Imager (MARCI) and Mars Climate Sounder (MCS), as well as Mars Odyssey's Thermal Emission Imaging System (THEMIS). The observations were compared to the mesoscale models developed for EDL performance simulation to determine if a spacecraft parameter update was necessary prior to entry. This paper summarizes the daily atmosphere observations and comparison to the performance simulation atmosphere models. Options to modify the atmosphere model in the simulation to compensate for atmosphere effects are also presented. Finally, a summary of the CoA decisions and recommendations to the MSL project in the days leading up to EDL is provided.

Cianciolo, Alicia D.↗

Diurnal Waves Forced By Horizontal Convergence of Near-Surface Winds on Mars

Boundary-layer winds near steeply sloped topography excite a distinct type of atmospheric wave. Basic properties of the waves were determined through analysis of 7 Mars years of temperature profiles from the Mars Climate Sounder on Mars Reconnaissance Orbiter. A more complete understanding of the waves was derived from a simulation with the NASA Ames Mars General Circulation Model. This type of wave appears in the tropics in the vicinity of conspicuous surface features, such as large volcanoes and the rim of Isidis Planitia. The amplitude is typically 5–10 K, the vertical wavelength is about 40 km, the zonal wavelength is about 1400 km, and the zonal phase speed relative to the surface is about 25 m s−1. The wave forcing comes from horizontal convergence of the near-surface winds, which generates a daily surge in the vertical winds. These convergence zones were not previously recognized as an important source of atmospheric waves on Mars. Strong forcing occurs only within a limited range of local time, producing wave packets (diurnal pulses) rather than steady oscillations. Waves are present throughout the year and their properties vary with season. Near the solstices, the wave amplitude is largest in the tropics of the summer hemisphere, where the convergence zones are stronger than in the winter hemisphere. The diurnal-mean zonal winds, which vary with latitude and season, control the direction of propagation of the predominant waves through filtering by critical levels.

Mars↗

Chaotic obliquity and the nature of the Martian climate

Recent calculations of the Martian obliquity suggests that it varies chaotically on timescales longer than about 10(exp 7) years and varies between about 0 and 60 deg. We examine the seasonal water behavior at obliquities between 40 and 60 deg. Up to several tens of centimeters of water may sublime from the polar caps each year, and possibly move to the equator, where it is more stable. The CO2 frost and CO2-H2O clathrate hydrate are stable in thepolar deposits below a few tens of meters depth, so that the polar cap could contain a significant CO2 reservoir. If CO2 is present, it could be left over from the early history of Mars; also, it could be released into the atmosphere during periods of high obliquity, causing occasional periods of more-clement climate.

Jakosky, Bruce M.↗