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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Temperature dependence of the reaction O/3P/ + OH/2 Pi/ yields O2 + H

Measurements of the absolute rate and temperature dependence of the rate constant for the reaction of ground state atomic oxygen with hydroxyl radicals to yield molecular oxygen and hydrogen atoms over the temperature range 211-499 K are presented. The reaction was monitored in a low-pressure discharge flow resonance fluorescence apparatus under pseudo-first-order conditions in which the oxygen concentration was greater than the hydroxyl concentration. An expression for the temperature dependence of the rate constant is derived from a least-squares fit to the observed bimolecular rate constants, which were found to range from 3.21 to 2.77 x 10 to the -11th cu cm/molecule per sec for temperatures from 211 to 499 K, indicative of a slight negative temperature dependence. Results are compared with those of previous workers, and the significance of the lower value of the rate constant obtained in the present study to models of HO(x) in the upper stratosphere is indicated.

Lewis, R. S.↗

Luminescent barometry in wind tunnels

A flexible and relatively inexpensive method and apparatus are described for continuous pressure mapping of aerodynamic surfaces using photoluminescence and imaging techniques. Platinum octaethylporphyrin (PtOEP) has a phosphorescence known to be quenched by oxygen. When dissolved in a silicone matrix, PtOEP may be distributed over a surface as a thin, uniform film. When the film is irradiated with ultraviolet light, the luminescence intensity provides a readily detectable, qualitative surface flow visualization. Moreover, since the luminescence intensity is found to be inversely proportional to the partial pressure of oxygen, a quantitative measure of pressure change may be obtained using a silicon target vidicon or a charge-coupled device video sensor to measure intensity. Luminescent images are captured by a commercial frame buffer board. Images taken in wind tunnels during airflow are ratioed to images taken under ambient 'wind-off' conditions. The resulting intensity ratio information is converted to pressure using calibration curves of I0/I vs p/p0, where I0 is the intensity at ambient pressure p0 and I is the intensity at any other pressure p.

Kavandi, Janet↗

Non-Intrusive Pressure/Multipurpose Sensor and Method

Method and apparatus are provided for determining pressure using a non-intrusive sensor that is easily attachable to the plumbing of a pressurized system. A bent mode implementation and a hoop mode implementation of the invention are disclosed. Each of these implementations is able to nonintrusively measure pressure while fluid is flowing. As well, each implementation may be used to measure mass flow rate simultaneously with pressure. An ultra low noise control system is provided for making pressure measurements during gas flow. The control system includes two tunable digital bandpass filters with center frequencies that are responsive to a clock frequency. The clock frequency is divided by a factor of N to produce a driving vibrational signal for resonating a metal sensor section.

Smith, William C.↗

Method and apparatus for testing surface characteristics of a material

A method, apparatus and system for testing characteristics of a material sample is provided. The system includes an apparatus configured to house the material test sample while defining a sealed volume against a surface of the material test sample. A source of pressurized fluid is in communication with, and configured to pressurize, the sealed volume. A load applying apparatus is configured to apply a defined load to the material sample while the sealed volume is monitored for leakage of the pressurized fluid. Thus, the inducement of surface defects such as microcracking and crazing may be detected and their effects analyzed for a given material. The material test samples may include laminar structures formed of, for example, carbon cloth phenolic, glass cloth phenolic, silica cloth phenolic materials or carbon-carbon materials. In one embodiment the system may be configured to analyze the material test sample while an across-ply loading is applied thereto.

Johnson, David L.↗

Rapid gas-phase reactions - The reaction of ammonia and the methylamines with boron trifluoride. III - Pressure dependence of rate constant.

A steady-state flow apparatus, shown earlier to be suitable for the study of rapid gas reactions, has been used to determine the pressure dependence of the relative quasi-bimolecular rate constants for the reactant pairs ammonia (AM)-trimethylamine (TMA) and dimethylamine (DMA)-trimethylamine in reaction with boron trifluoride. The pressure dependence of the former was determined in the range 0.03-75 torr and that of the latter in the range 0.02-720 torr.

Glicker, S.↗

Containerless high-pressure petrology experiments in the microgravity environment of the Space Station

The genesis of igneous rocks on terrestrial planets can only be understood through experiments at pressures corresponding to those in planetary mantles (10 to 50 kbar). Such experiments typically require a piston-cylinder apparatus, and an apparatus that has the advantage of controllable pressure and temperature, adequate sample volume, rapid sample quench, and minimal danger of catastrophic failure. It is proposed to perform high-pressure and high-temperature piston-cylinder experiments aboard the Space Station. The microgravity environment in the Space Station will minimize settling due to density contrasts and may, thus, allow experiments of moderate duration to be performed without a platinoid capsule and without the sample having to touch the container walls. The ideal pressure medium would have the same temperatures. It is emphasized, however, that this proposed experimental capability requires technological advances and innovations not currently available.

Boynton, W. V.↗

Compressibility measurements of gases using externally heated pressure vessels.

Most of the data collected under conditions of high temperature and pressure have been determined using a thick-walled bomb of carefully measured and fixed volume which is externally heated by an electric furnace or a thermostatically controlled bath. There are numerous variations on the basic method depending on the pressure-temperature range of interest, and the particular gas or gas mixture being studied. The construction and calibration of the apparatus is discussed, giving attention to the pressure vessel, the volume of the bomb, the measurement of pressure, the control and measurement of temperature, and the measurement of the amount and composition of gas in the bomb.

Presnall, D. C.↗

Modular Apparatus and Method for Attaching Multiple Devices

A modular apparatus for attaching sensors and electronics is disclosed. The modular apparatus includes a square recess including a plurality of cavities and a reference cavity such that a pressure sensor can be connected to the modular apparatus. The modular apparatus also includes at least one voltage input hole and at least one voltage output hole operably connected to each of the plurality of cavities such that voltage can be applied to the pressure sensor and received from the pressure sensor.

Okojie, Robert S↗

Modular Apparatus and Method for Attaching Multiple Devices

A modular apparatus for attaching sensors and electronics is disclosed. The modular apparatus includes a square recess including a plurality of cavities and a reference cavity such that a pressure sensor can be connected to the modular apparatus. The modular apparatus also includes at least one voltage input hole and at least one voltage output hole operably connected to each of the plurality of cavities such that voltage can be applied to the pressure sensor and received from the pressure sensor.

Okojie, Robert S.↗

Martian Dust Devils: Laboratory Simulations of Particle Threshold

An apparatus has been fabricated to simulate terrestrial and Martian dust devils. Comparisons of surface pressure profiles through the vortex core generated in the apparatus with both those in natural dust devils on Earth and those inferred for Mars are similar and are consistent with theoretical Rankine vortex models. Experiments to determine particle threshold under Earth ambient atmospheric pressures show that sand (particles > 60 micron in diameter) threshold is analogous to normal boundary-layer shear, in which the rotating winds of the vortex generate surface shear and hence lift. Lower-pressure experiments down to approx. 65 mbar follow this trend for sand-sized particles. However, smaller particles (i.e., dust) and all particles at very low pressures (w 10-60 mbar) appear to be subjected to an additional lift function interpreted to result from the strong decrease in atmospheric pressure centered beneath the vortex core. Initial results suggest that the wind speeds required for the entrainment of grains approx. 2 microns in diameter (i.e., Martian dust sizes) are about half those required for entrainment by boundary layer winds on both Earth and Mars.

Greeley, Ronald↗

Transient processes in the combustion of nitramine propellants

A transient combustion model of nitramine propellants is combined with an isentropic compression shock formation model to determine the role of nitramine propellant combustion in DDT, excluding effects associated with propellant structural properties or mechanical behavior. The model is derived to represent the closed pipe experiment that is widely used to characterize explosives, except that the combustible material is a monolithic charge rather than compressed powder. Computations reveal that the transient combustion process cannot by itself produce DDT by this model. Compressibility of the solid at high pressure is the key factor limiting pressure buildups created by the combustion. On the other hand, combustion mechanisms which promote pressure buildups are identified and related to propellant formulation variables. Additional combustion instability data for nitramine propellants are presented. Although measured combustion response continues to be low, more data are required to distinguish HMX and active binder component contributions. A design for a closed vessel apparatus for experimental studies of high pressure combustion is discussed.

Cohen, N. S.↗

Armalcolite stability as a function of pressure and oxygen fugacity

High-pressure experiments in a piston-cylinder apparatus with silver-palladium containers were conducted to study the stability of synthetic armalcolite, (Fe,Mg)Ti2O5, as a function of pressures up to 15 kbar at 1000, 1100, and 1200 C. Three armalcolite compositions were used, each with an initial Fe/(Fe + Mg) ratio of 0.5. Composition I contained no zirconium, whereas compositions II and III were prepared with 4% and 10% by weight ZrO2. Difference in stability due to the presence or absence of Zr in these synthetic armalcolites is discussed. 4 wt% ZrO2 appears to saturate armalcolite at 1200 C and 1 atm. Zirconium is found to reduce armalcolite stability, but this effect is not great. The stability of armalcolite as a function of oxygen fugacity is determined thermogravimetrically at 1200 C and 1 atm. Knowledge of the range of oxygen fugacity at which armalcolite is stable and of the equilibrium oxide mineral assemblages outside this range provides important information about lunar cooling histories in terms of oxygen fugacity.

Friel, J. J.↗

Experimental feasibility of investigating acoustic waves in Couette flow with entropy and pressure gradients

The feasibility is discussed for an experimental program for studying the behavior of acoustic wave propagation in the presence of strong gradients of pressure, temperature, and flow. Theory suggests that gradients effects can be experimentally observed as resonant frequency shifts and mode shape changes in a waveguide. A convenient experimental geometry for such experiments is the annular region between two co-rotating cylinders. Radial temperature gradients in a spinning annulus can be generated by differentially heating the two cylinders via electromagnetic induction. Radial pressure gradients can be controlled by varying the cylinder spin rates. Present technology appears adequate to construct an apparatus to allow independent control of temperature and pressure gradients. A complicating feature of a more advanced experiment, involving flow gradients, is the requirement for independently controlled cylinder spin rates. Also, the boundary condition at annulus terminations must be such that flow gradients are minimally disturbed. The design and construction of an advanced apparatus to include flow gradients will require additional technology development.

Parrott, Tony L.↗

Seal-rotordynamic-coefficient Test Results for a Model SSME ATD-HPFTP Turbine Interstage Seal with and Without a Swirl Brake

The predictions of Scharrer's (1988) theory for rotordynamic coefficients of labyrinth gas seals were compared with measurements for a model SSME Alternate Turbopump Development High Pressure Fuel Turbopump with and without swirl brakes. Using the test apparatus described by Childs et al., tests were conducted with supply pressures up to 18.3 bars and speeds up to 16,000 rpm. Seal back pressure was controlled to provide four pressure ratios at all supply pressures. No measurable differences in leakage was detected for the seal with and without the swirl brakes. Comparisons of the measurement results for the seal without a swirl brake with the Scharrer theory showed that the theory can be used only to provide design guidelines; systematic differences were observed between theory and experiment due to changes in running speed, supply pressure, and pressure ratio.

Childs, Dara W.↗