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NASA NTRS2013

An Updated TRMM Composite Climatology of Tropical Rainfall and Its Validation

An updated 15-yr Tropical Rainfall Measuring Mission (TRMM) composite climatology (TCC) is presented and evaluated. This climatology is based on a combination of individual rainfall estimates made with data from the primaryTRMMinstruments: theTRMM Microwave Imager (TMI) and the precipitation radar (PR). This combination climatology of passive microwave retrievals, radar-based retrievals, and an algorithm using both instruments simultaneously provides a consensus TRMM-based estimate of mean precipitation. The dispersion of the three estimates, as indicated by the standard deviation sigma among the estimates, is presented as a measure of confidence in the final estimate and as an estimate of the uncertainty thereof. The procedures utilized by the compositing technique, including adjustments and quality-control measures, are described. The results give a mean value of the TCC of 4.3mm day(exp -1) for the deep tropical ocean beltbetween 10 deg N and 10 deg S, with lower values outside that band. In general, the TCC values confirm ocean estimates from the Global Precipitation Climatology Project (GPCP) analysis, which is based on passive microwave results adjusted for sampling by infrared-based estimates. The pattern of uncertainty estimates shown by sigma is seen to be useful to indicate variations in confidence. Examples include differences between the eastern and western portions of the Pacific Ocean and high values in coastal and mountainous areas. Comparison of the TCC values (and the input products) to gauge analyses over land indicates the value of the radar-based estimates (small biases) and the limitations of the passive microwave algorithm (relatively large biases). Comparison with surface gauge information from western Pacific Ocean atolls shows a negative bias (~16%) for all the TRMM products, although the representativeness of the atoll gauges of open-ocean rainfall is still in question.

(GPCP) Global Precipitation Project analysis↗
NASA NTRS1995

Biennial oscillation associated with the East Asian summer monsoon and tropical sea surface temperatures

In this paper, the interannual variability of the East Asian summer monsoon (EASM) rainfall and the tropical sea surface temperature (SST) have been studied. It is found that the EASM rainfall prossesses a strong biennial signal, which is particularly pronounced over the southeast China. For the SST, the biennial oscillation is the second most significant quasi-periodic signal over the entire tropical Indian and Pacific Oceans. Results indicate that the biennial variations in the SST and EASM rainfall are closely linked. The SST pattern which is best correlated with EASM rainfall appears in the form of a double see-saw with quasi-stationary centers of action over the Indian Ocean, the Asian monsoon region and the eastern Pacific. The most pronounced SST signals are found in the equatorial eastern Pacific and Indian Ocean about two seasons preceding and following the EASM rainfall. Evidence is presented suggesting that the biennial variability of the EASM rainfall is phase-locked to a global scale biennial oscillation involving the interplay of the Asian monsoon, the Hadley and Walker circulations, and basin wide fluctuations in SST. In particular, the eastward propagation of zonal wind anomalies from the Indian Ocean to the western Pacific, which regulates the moisture fluxes from the western Pacific to the East Asian region, appears to be a key component of the biennial fluctuation associated with EASM rainfall. Results suggest that the relationship between the Asian monsoon and tropical SST is more robust in the biennial that the El Nino/Southern Oscillation (ENSO) time scale, hence raising the possibility that the biennial oscillation may be more fundamentally related to monsoon-ocean-atmosphere interaction than ENSO itself.

Shen, Suhung↗
NASA NTRS2024

Assessing the Impact of Climate Change on Atmospheric Rivers: A Modeling Perspective

Atmospheric rivers (ARs) play a crucial role in the poleward transport of water vapor, and the AR-associated precipitation is a critical component of global water supplies, making it critical that we understand how ARs may change in the future. To approach this issue, integrations of the NASA Goddard Institute for Space Studies global climate model ModelE version 2.1 (GISSE2.1) are employed. Multiple configurations of the model simulating different climates are analyzed: (1) the last-glacial maximum; (2) present day; (3) the end of the 21st century. The thermodynamic and dynamic components of changes to AR frequency are analyzed using a decomposition method. This method utilizes differences in distinct AR seasonal climatology frequencies derived from various vertically integrated water vapor transport (IVT) thresholds to resolve AR frequency into its components. Global mean state changes in poleward AR frequency for different climates are dominated by precipitable water vapor (PWV) changes. A set of idealized cold and warm climates in which present day sea surface temperatures are uniformly changed are considered for a targeted analysis of the south Pacific Ocean basin. For this analysis, frequency and distribution of AR events in the model runs are analyzed by comparing them to changes in the jet stream as well as the Eulerian storm tracks and low-level baroclinicity. Latitudinal shifts in the ARs in the south Pacific Ocean basin using our integrations are not as tightly coupled to these two storm-related climatological metrics in the midlatitudes but fare better on the poleward side of the storm tracks.

Atmospheric rivers↗
NASA NTRS1986

Mass, heat and freshwater fluxes in the South Indian Ocean

Six hydrographic sections were used to examine the circulation and property fluxes in the South Indian Ocean from 10 to 32 deg S. The calculations were made by applying an inverse method to the data. In the interior of the South Indian Ocean, the geostrophic flow is generally northward. At 18 deg S, the northward interior mass flux is balanced by the southward Ekman mass flux at the surface, whereas at 32 deg S the northward interior mass flux is balanced by the southward mass flux of the Agulhas Current. There is a weak, southward mass flux of 6 x 10 to the 9th kg/s in the Mozambique Channel. The rate of water exchange between the Pacific Ocean and the Indian Ocean is dependent on the choice of the initial reference level used in the inverse calculation. The choice of 1500 m, the depth of the deep oxygen minimum, has led to a flux of water from the Pacific Ocean to the Indian Ocean at a rate of 6.6 x 10 to the 9th kg/s. Heat flux calculations indicate that the Indian Ocean is exporting heat to the rest of the world's oceans at a rate of -0.69 x 10 to the 15th W at 18 deg S and -0.25 x 10 to the 15th W at 32 deg S (negative values being southward).

Fu, Lee-Lueng↗
NASA NTRS1989

Measurements of aerosol properties needed to infer backscatter characteristics in support of the NASA Doppler Lidar program

During the first year two areas of work were emphasized, analysis of aerosol data to provide improved estimates of backscatter over the Pacific ocean and development of a global model for backscatter at different wavelengths and preparation and planning for the aircraft flights of the GLOVE program. Significant progress was made in each of these areas. The analytical work is a continuation of the GAMETAG analysis, and was directed toward the development of a backscatter model for the Pacific Oceanic free troposphere. This has included a further evaluation of relationships between the optical effects at different wavelengths, a comparison of modeled optical effects at differing temporal resolutions, and an investigation of the effects of sampling on the modeled results. An initial investigation of the predictability of 9 to 10 micrometers Beta values from other data sets as well as some preliminary comparisons of the modeling results with experimental data. The comparison of the optical effects was extended to make the comparisons for different sets of time bases between 1 and 20 minutes.

Patterson, E. M.↗
NASA NTRS2017

The 2015-2016 El Nino and the Response of the Carbon Cycle: Findings from NASA's OCO-2 Mission

The El Nino Southern Oscillation (ENSO) is the most important mode of tropical climate variability on interannual to decadal time scales. Correlations between atmospheric CO2 growth rate and ENSO activity are relatively well known but the magnitude of this correlation, the contribution from tropical marine vs. terrestrial flux components, and the causal mechanisms, are poorly constrained in space and time. The launch of NASA's Orbiting Carbon Observatory-2 (OCO-2) mission in July 2014 was rather timely given the development of strong ENSO conditions over the tropical Pacific Ocean in 2015-2016. In this presentation, we will discuss how the high-density observations from OCO-2 provided us with a novel dataset to resolve the linkages between El Nino and atmospheric CO2. Along with information from in situ observations of ÎpCO2 from NOAA's Tropical Atmosphere Ocean (TAO) project and atmospheric CO2 from the Scripps CO2 Program, and other remote-sensing missions, we are able to piece together the time dependent response of atmospheric CO2 concentrations over the Tropics. Our findings confirm the hypothesis from studies following the 1997-1998 El Nino event that an early reduction in CO2 outgassing from the tropical Pacific Ocean is later reversed by enhanced net CO2 emissions from the terrestrial biosphere. This implies that a component of the interannual variability (IAV) in the growth rate of atmospheric CO2, which has typically been used to constrain the climate sensitivity of tropical land carbon fluxes, is strongly influenced and modified by ocean fluxes during the early phase of the ENSO event. Our analyses shed further light on the understanding of the marine vs. terrestrial partitioning of tropical carbon fluxes during El Nino events, their relative contributions to the global atmospheric CO2 growth rate, and provide clues about the sensitivity of the carbon cycle to climate forcing on interannual time scales.

CO2↗
NASA NTRS2018

The 2015-2016 El Nino and the Response of the Carbon Cycle: Findings from NASA's OCO-2 Mission

The El Nino Southern Oscillation (ENSO) is the most important mode of tropical climate variability on interannual to decadal time scales. Correlations between atmospheric CO2 growth rate and ENSO activity are relatively well known but the magnitude of this correlation, the contribution from tropical marine vs. terrestrial flux components, and the causal mechanisms, are poorly constrained in space and time. The launch of NASA's Orbiting Carbon Observatory-2 (OCO-2) mission in July 2014 was rather timely given the development of strong ENSO conditions over the tropical Pacific Ocean in 2015-2016. In this presentation, we will discuss how the high-density observations from OCO-2 provided us with a novel dataset to resolve the linkages between El Nino and atmospheric CO2. Along with information from in situ observations of CO2 from NOAA's Tropical Atmosphere Ocean (TAO) project and atmospheric CO2 from the Scripps CO2 Program, and other remote-sensing missions, we are able to piece together the time dependent response of atmospheric CO2 concentrations over the Tropics. Our findings confirm the hypothesis from studies following the 1997-1998 El Nino event that an early reduction in CO2 outgassing from the tropical Pacific Ocean is later reversed by enhanced net CO2 emissions from the terrestrial biosphere. This implies that a component of the interannual variability (IAV) in the growth rate of atmospheric CO2, which has typically been used to constrain the climate sensitivity of tropical land carbon fluxes, is strongly influenced and modified by ocean fluxes during the early phase of the ENSO event. Our analyses shed further light on the understanding of the marine vs. terrestrial partitioning of tropical carbon fluxes during El Nino events, their relative contributions to the global atmospheric CO2 growth rate, and provide clues about the sensitivity of the carbon cycle to climate forcing on interannual time scales.

OCO-2↗
NASA NTRS2011

A Global Climatology of Tropospheric and Stratospheric Ozone Derived from Aura OMI and MLS Measurements

A global climatology of tropospheric and stratospheric column ozone is derived by combining six years of Aura Ozone Monitoring Instrument (OMI) and Microwave Limb Sounder (MLS) ozone measurements for the period October 2004 through December 2010. The OMI/MLS tropospheric ozone climatology exhibits large temporal and spatial variability which includes ozone accumulation zones in the tropical south Atlantic year-round and in the subtropical Mediterranean! Asia region in summer months. High levels of tropospheric ozone in the northern hemisphere also persist in mid-latitudes over the eastern North American and Asian continents extending eastward over the Pacific Ocean. For stratospheric ozone climatology from MLS, largest ozone abundance lies in the northern hemisphere in the latitude range 70degN-80degN in February-April and in the southern hemisphere around 40degS-50degS during months August-October. The largest stratospheric ozone abundances in the northern hemisphere lie over North America and eastern Asia extending eastward across the Pacific Ocean and in the southern hemisphere south of Australia extending eastward across the dateline. With the advent of many newly developing 3D chemistry and transport models it is advantageous to have such a dataset for evaluating the performance of the models in relation to dynamical and photochemical processes controlling the ozone distributions in the troposphere and stratosphere.

Ziemke, J.R.↗
NASA NTRS1999

A Southern California Perspective of the April, 1998 Trans-Pacific Asian Dust Event

The Jet Propulsion Laboratory (JPL) coherent CO2 backscatter lidar has been in almost continuous operation since 1984 and has now accumulated a significant time-series database tracking the long-term and seasonal variability of backscatter from the atmospheric column above the Pasadena, Calif. locale. A particularly noteworthy episode observed by the lidar in 1998 was a particularly extreme instance of incursion by Asian-sourced dust during the closing days of April. Such events are not uncommon during the northern spring, when strong cold fronts and convection over the Asian interior deserts loft crustal material into the mid-troposphere whence it can be transported across the Pacific Ocean, occasionally reaching the continental US. However, the abnormal strength of the initiating storm in this case generated an atypically dense cloud of material which resulted in dramatically reduced visibility along the length of the Western Seaboard. These dust events are now recognized as a potentially significant, non-negligible radiative forcing influence. The progress of the April 1998 dust cloud eastward across the Pacific Ocean was initially observed in satellite imagery and transmitted to the broader atmospheric research community via electronic communications. The use of Internet technology in this way was effective in facilitating a rapid response correlative measurement exercise by numerous atmospheric observation stations throughout the western US and its success has resulted in the subsequent establishment of an ad hoc communications environment, data exchange medium, and mechanism for providing early-warning alert of other significant atmospheric phenomena in the future.

Tratt, David M.↗
NASA NTRS2005

Simulation of Water Sources and Precipitation Recycling for the MacKenzie, Mississippi and Amazon River Basins

An atmospheric general circulation model simulation for 1948-1997 of the water budgets for the MacKenzie, Mississippi and Amazon River basins is presented. In addition to the water budget, we include passive tracers to identify the geographic sources of water for the basins, and the analysis focuses on the mechanisms contributing to precipitation recycling in each basin. While each basin s precipitation recycling has a strong dependency on evaporation during the mean annual cycle, the interannual variability of the recycling shows important relationships with the atmospheric circulation. The MacKenzie River basin has only a weak interannual dependency on evaporation, where the variations in zonal moisture transport from the Pacific Ocean can affect the basin water cycle. On the other hand, the Mississippi River basin has strong interannual dependencies on evaporation. While the precipitation recycling weakens with increased low level jet intensity, the evaporation variations exert stronger influence in providing water vapor for convective precipitation at the convective cloud base. High precipitation recycling is also found to be partly connected to warm SSTs in the tropical Pacific Ocean. The Amazon River basin evaporation exhibits small interannual variations, so that the interannual variations of precipitation recycling are related to atmospheric moisture transport from the tropical south Atlantic Ocean. Increasing SSTs over the 50-year period are causing increased easterly transport across the basin. As moisture transport increases, the Amazon precipitation recycling decreases (without real time varying vegetation changes). In addition, precipitation recycling from a bulk diagnostic method is compared to the passive tracer method used in the analysis. While the mean values are different, the interannual variations are comparable between each method. The methods also exhibit similar relationships to the terms of the basin scale water budgets.

Bosilovich, Michael G.↗
NASA NTRS2006

Impact of Asian Dust on Global Surface Air Quality and Radiation Budget

Dust originating from Asian deserts and desertification areas can be transported regionally and globally to affect surface air quality, visibility, and radiation budget not only at immediate downwind locations (e.g., eastern Asia) but also regions far away from the sources (e.g., North America). Deposition of Asian dust to the North Pacific Ocean basin influences the ocean productivity. In this study, we will use the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model, remote sensing data form satellite and from the ground-based network, and in-situ data from aircraft and surface observations to address the following questions: - What are the effects of Asian dust on the surface air quality and visibility over Asia and North America? - What are the seasonal and spatial variations of dust deposition to the North Pacific Ocean? How does the Asian dust affect surface radiation budget?

Chin, Mian↗
NASA NTRS1999

Response to CO2 Transient Increase in the GISS Coupled Model: Regional Coolings in a Warming Climate

The (GISS) Goddard Institute for Space Studies coupled atmosphere-ocean model is used to investigate the effect of increased atmospheric CO2 by comparing a compounded 1 percent CO2 increase experiment with a control simulation. After 70 years of integration, the global surface air temperature in the 1 percent CO2 experiment is 1.43 C warmer. In spite of this global warming, there are two distinct regions, the northern Atlantic Ocean and the southern Pacific Ocean, where the surface air temperature is up to 4 C cooler. This situation is maintained by two positive feedbacks: a local effect on convection in the South Pacific and a non-local impact on the meridional circulation in the North Atlantic. The poleward transport of latent energy and dry static energy by the atmosphere is greater in the 1 percent CO2 experiment, caused by warming and therefore increased water vapor and greater greenhouse capacity at lower latitudes. The larger atmospheric transports tend to reduce upward vertical fluxes of heat and moisture from the ocean surface at high latitudes, which has the effect of stabilizing the ocean, reducing both convection and the thermohaline circulation. With less convection, less warm water is brought up from below, and with a reduced North Atlantic thermohaline circulation (by 30 percent at time of CO2 doubling), the poleward energy transport by the oceans decreases. The colder water then leads to further reductions in evaporation, decreases of salinity at high latitudes, continued stabilization of the ocean, and maintenance of reduced convection and meridional overturning. Although sea ice decreases globally, it increases in the cooling regions which reduces the overall climate sensitivity; its effect is most pronounced in the Southern Hemisphere. Tropical warming has been observed over the past several decades; if modeling studies such as this and others which have produced similar effects are valid, these processes may already be beginning.

Russell, Gary L.↗
NASA NTRS2012

Analysis of Pulsed Lidar Measurements of Atmospheric CO2 Column Absorption During the ASCENDS 2009-2011 Airborne Campaigns

We have developed a pulsed lidar technique for measuring the tropospheric CO2 concentrations as a candidate for NASA's ASCENDS mission and have demonstrated the CO2 and O2 measurements from aircraft. Our technique uses two pulsed lasers allowing simultaneous measurement of a single CO2 absorption line near 1572 nm, O2 extinction in the Oxygen A-band, surface height and backscatter profile. The lasers are stepped in wavelength across the CO2 line and an O2 line doublet during the measurement. The column densities for the CO2 and O2 are estimated from the differential optical depths (DOD) of the scanned absorption lines via the IPDA technique. For the 2009 ASCENDS campaign we flew the CO2 lidar on a Lear-25 aircraft, and measured the absorption line shapes of the CO2 line using 20 wavelength samples per scan. Measurements were made at stepped altitudes from 3 to 12.6 km over the Lamont OK, central Illinois, North Carolina, and over the Virginia Eastern Shore. Although the received signal energies were weaker than expected for ASCENDS, clear CO2 line shapes were observed at all altitudes. Most flights had 5-6 altitude steps with 200-300 seconds of recorded measurements per step. We averaged every 10 seconds of measurements and used a cross-correlation approach to estimate the range to the scattering surface and the echo pulse energy at each wavelength. We then solved for the best-fit CO2 absorption line shape, and calculated the DOD of the fitted CO2 line, and computed its statistics at the various altitude steps. We compared them to CO2 optical depths calculated from spectroscopy based on HITRAN 2008 and the column number densities calculated from the airborne in-situ readings. The 2009 measurements have been analyzed and they were similar on all flights. The results show clear CO2 line shape and absorption signals, which follow the expected changes with aircraft altitude from 3 to 13 km. They showed the expected nearly the linear dependence of DOD vs altitude. The measurements showed ~ 1 ppm random errors for 8-10 km altitudes and ~30 sec averaging times. For the 2010 ASCENDS campaigns we flew the CO2lidar on the NASA DC-8 and added an 02lidar channel. During July 2010 we made measurements of CO2 and O2 column absorption during longer flights over Railroad Valley NV, the Pacific Ocean and over Lamont OK. CO2 measurements were made with 30 steps/scan, 300 scans/sec and improved line resolution and receiver sensitivity. Analysis of the 2010 CO2 measurements shows the expected ~linear change of DOD with altitude. For measurements at altitudes> 6 km the random errors were 0.3 ppm for 80 sec averaging times. For the summer 2011 ASCENDS campaigns we made further improvements to the lidar's CO2 line scan and receiver sensitivity. We demonstrated measurements over the California Central Valley, to stratus cloud tops over the Pacific Ocean, over mountain regions with snow, and over several areas with broken clouds. Details of the lidar measurements and their analysis will be described in the presentation.

Abshire, J. B.↗
NASA NTRS1978

Tropospheric ozone distributions measured with an airborne laser absorption spectrometer

Measurements of tropospheric ozone have been made in the southern and middle California regions and over the Pacific Ocean during two series of flights in February and May 1977. The data were obtained by using a laser absorption spectrometer, a nadir-viewing instrument which remotely measures the ozone column abundance between ground level and aircraft altitude by interacting with ozone at specific wavelengths near 9.5 microns. The measurements indicate significantly lower ozone abundances above the Mojave Desert region as compared with farm, forest, and urban areas. The average tropospheric column density was found to be 0.0027 atm cm/km over the California region and 0.0035 atm cm/km over the Pacific Ocean region 1000-2000 km west of the coast of Mexico.

Menzies, R. T.↗
NASA NTRS2012

Pulsed Lidar Measurements of Atmospheric CO2 Column Absorption in the ASCENDS 2011 Airborne Campaign

We have previously demonstrated an efficient pulsed, wavelength-resolved IPDA lidar technique for measuring the tropospheric CO2 concentrations as a candidate for NASA's ASCENDS mission. Our team participated in the 2010 ASCENDS airborne campaigns we flew airborne version of the CO2 and O2 lidar on the NASA DC-8. The CO2 lidar measures the atmospheric backscatter profiles and shape of the 1572.33 nm absorption line using 250 mW average laser power, 30 wavelength samples per scan and 300 scans per second. Most flights had 5-6 altitude steps to greater than 12 km, and clear CO2 line shapes were observed at all altitudes. Our post-flight analysis estimated the Iidar range and pulse energies at each wavelength every second. We then solved for the best-fit CO2 absorption line shape, and calculated the Differential Optical Depth (DOD) at the line peak. We compared these to CO2 DODs calculated from spectroscopy based on HITRAN 2008 and the conditions from airborne in-situ readings. Analysis of the 2010 measurements over the Pacific Ocean and Lamont OK shows the expected -linear change of the peak DOD with altitude. For measurements at altitudes greater than 6 km the random errors were approximately 0.3 ppm for 80 sec averaging times. After the 2010 flights we improved the airborne lidar's scan uniformity, calibration and receiver sensitivity. Our team participated in the seven ASCENDS science flights during late July and August 2011. These flights were made over a wide variety of surface and cloud conditions near the US, including over the central valley of California, over several mountain ranges, over both broken and solid stratus cloud deck over the Pacific Ocean, snow patches on mountain tops, over thin and broken clouds above the US Southwest and Iowa, and over forests near the WLEF tower in Wisconsin. Analyses show the retrievals of lidar range and CO2 column absorption, as wen as estimates of CO2 mixing ratio worked well when measuring over topography with rapidly changing height and reflectivity, through thin clouds and to stratus cloud tops. For regions where the CO2 concentration was relatively constant, the measured CO2 absorption profile (averaged for 50 sec) matched the predicted profile to better than 1% RMS error for all flight altitudes. For 1 & 10 second averaging, the scatter in the retrievals was limited by signal shot noise (i.e. the sigual photon count). Analysis to date shows the decrease in CO2 due to vegetation when flying easterward over the Great Plains as well as the increase in CO2 concentration in the vicinity ofthe coal-fired power plant in New Mexico. Examples of these and other results will be presented.

Abshire, James B.↗
NASA NTRS1989

Ozone precursors and ozone photochemistry over eastern North Pacific during the spring of 1984 based on the NASA GTE/CITE 1 airborne observations

Simultaneous high-resolution measurements of O3, NO, CO, dew point temperature, and UV flux obtained during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation (GTE/CITE 1) spring 1984 airborne field exercise over the eastern North Pacific Ocean are analyzed. Mid-tropospheric CO, O3, and NO mixing ratios averaged about 120 parts per billion by volume (ppbv), 50 ppbv, and 10 parts per trillion by volume (pptv), respectively. Statistical analysis of the high-resolution data indicates the existence of two ozone sources, one related to the downward transport of ozone-rich air from the upper troposphere and stratosphere, and the other to the transport of ozone-rich air from the continents. Modeling calculations based on these average levels imply that, from the surface to about 8 km, photochemical reactions probably supplied a net sink of ozone to the region overlying the eastern North Pacific Ocean during the sampling period. However, because the NO levels measured during the flights were frequently at or near the detection limit of the instruments and because the results are very sensitive to the absolute NO levels and their temporal variability, the conclusion must be considered provisional.

Chameides, W. L.↗
NASA NTRS1987

Net ozone photochemical production over the eastern and central North Pacific as inferred from GTE/CITE 1 observations during fall 1983

The role of photochemistry in the budget of tropospheric ozone is studied. Measurements of O3, NO, CO, H2O vapor, and temperature obtained during the fall of 1983 during the GTE/CITE project over the eastern and central North Pacific Ocean are analyzed. The effect of altitude on the measurements is discussed. The analysis reveals a correlation between ozone and NO levels; both increase in concentration and variability with altitude. It is observed that an additional source of secondary importance associated wih CO-rich air parcels exists. A photochemical model is utilized to calculate the net rate of ozone production by photochemical reactions. A net photochemical source of ozone in the free troposphere and a net sink in the boundary layer are detected. The relation between the ozone source in the free troposphere and NO is examined. It is estimated that photochemistry provides a net ozone source to the free troposphere overlying the eastern and central North Pacific Ocean of about 5 x 10 to the 10th molecules/sq cm sec and a net sink of ozone to the boundary layer overlying this region of about 3 x 10 to the 10th molecules/sq cm sec.

Chameides, W. L.↗
NASA NTRS1994

Loss of solar He and Ne from IDPS in subducting sediment: Diffusion and the effect of phase changes

The results of the diffusion experiment for solar He and Ne in IDP's in a magnetic separate from Pacific Ocean sediment suggest that solar He and Ne would be easily released from IDP grains and hence lost from subducting slabs at shallow depths. However, since the diffusion experiments was conducted under high vacuum, there may be a possibility that magnetite grains, which are supposedly the main constituent of the magnetic fraction, might be partly reduced to form a metal phase due to low oxygen fugacity in the experimental condition. If this is the case, such a phase change might affect the gas release and hence the results of the diffusion coefficients. In order to examine whether or not such a phase change really occurred in the condition of the diffusion experiment, I conducted a heating experiment for a magnetic separate from Pacific Ocean sediment. In the same condition as in the diffusion experiment, and the run products were examined with an x ray diffraction method. Three samples were prepared: they were wrapped with platinum foil, put in a vacuum line, and heated in a molybdenum crucible for two hours at 500 C, 800 C,and 950 C, respectively. After cooling the furnace, the samples were taken out from the crucible and analyzed with an x ray diffraction method.

Hiyagon, H.↗