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Cost-Effective Thermomechanical Processing of Nanostructured Ferritic Alloys: Microstructure and Mechanical Properties Investigation

Nanostructured ferritic alloys (NFAs), such as oxide-dispersion strengthened (ODS) alloys, play a vital role in advanced fission and fusion reactors, offering superior properties when incorporating nanoparticles under irradiation. Despite their importance, the high cost of mass-producing NFAs through mechanical milling presents a challenge. This study delves into the microstructure-mechanical property correlations of three NFAs produced using a novel, cost-effective approach combining severe plastic deformation (SPD) with the continuous thermomechanical processing (CTMP) method. Analysis using scanning electron microscopy (SEM)-electron backscatter diffraction (EBSD) revealed nano-grain structures and phases, while scanning transmission electron microscopy (STEM)-energy dispersive X-ray spectroscopy (EDS) quantified the size and density of Ti-N, Y-O, and Cr-O fine particles. Atom probe tomography (APT) further confirmed the absence of finer Y-O particles and characterized the chemical composition of the particles, suggesting possible nitride dispersion strengthening. Correlation of microstructure and mechanical testing results revealed that CTMP alloys, despite having lower nanoparticle densities, exhibit strength and ductility comparable to mechanically milled ODS alloys, likely due to their fine grain structure. However, higher nanoparticle densities may be necessary to prevent cavity swelling under high-temperature irradiation and helium gas production. Further enhancements in uniform nanoparticle distribution and increased sink strength are recommended to mitigate cavity swelling, advancing their suitability for nuclear applications.

36 MATERIALS SCIENCE↗

Diagnostics: Chapter 8 of the special issue: on the path to tokamak burning plasma operation

This chapter presents the activity conducted by the ITPA topical group (TG) on Diagnostics over about the last 15 years. Following a general introduction of the ITER Diagnostics led by their measurement roles, the document is organized in several subchapters detailing the design support, research and development activity conducted by each of the specialist working groups (WGs) of the TG. Please note that the magnetic diagnostics were supported at the TG without a specific WG. Their status is included in the general introduction. In the following some highlights of the subchapter’s contents are provided. Recent advances in ITER first wall (FW) diagnostics for the measurements of plasma-metallic wall interaction in support of the ITER research plan are reported. An InfraRed imaging Video Bolometer for ITER has been developed and tested on several tokamaks to measure the radiated power loss. A laser-induced breakdown spectroscopy (LIBS) technique which utilizes a pulsed laser beam to ablate locally by forming a crater, will measure local tritium inventory in the FW material. Real-time Residual Gas Analyzers will measure the neutral gas composition in a divertor port and an equatorial port during plasma operation. Due to the full metallic FW environment, the plasma-wall interaction in ITER will face several challenges such as the compromised radiated power and divertor heat flux measurements by reflection. Ray tracing and analysis codes have been developed to eliminate and correct the effects of reflection in the measurements. The characteristics of the reflecting surfaces depending on the roughness and angle of the incidence have been measured by dedicated experiments, and the results were applied to the reflection elimination. For the measurement of the metallic impurity radiation induced by eroded metallic atoms, a vacuum ultraviolet spectrometer has been developed and tested. An extensive thermonuclear diagnostic suite will be required to support the operation of ITER and the planned experimental program for future burning plasma experiments. Due to the harsh environmental conditions, the implementation of diagnostic systems in ITER is a major challenge. These conditions include high levels of neutron and gamma fluxes, neutron heating, particle bombardment. Therefore, the selection and design of diagnostic systems must take into account a number of phenomena previously unseen in diagnostic design. For this reason, the measurement of neutrons and confined or lost fast ions, with particular emphasis on alpha particles, is critical to ITER. The diagnostics associated with these measurements will be important for future plasma-burning experiments at ITER. The high neutron emission and very large plasma size in ITER make neutron diagnostics the main diagnostic method used to measure plasma parameters such as fusion power, fusion power density, ion temperature, energy of fast ions and their spatial distributions in the plasma core. Active spectroscopy techniques are methods where a neutral particle beam is injected into the plasma and information on plasma parameters is extracted from the measurement of line emission resulting from the beam-plasma interaction, either by plasma ions or by beam atoms. Spatial localization is achieved by crossing the beamline and multiple observation lines. The ITER plasma will be a high temperature, moderately dense, fully ionized collisional plasma. The plasma facing surfaces are principally metallic being fashioned from beryllium or tungsten but many other elements, arising from either structural or from operational needs, may enter this plasma. The energy range of the emitted photons range from meV (infra-red) to multi keV (x-rays) and originate from all areas of the plasma volume. The primary role of passive emission diagnostics is to identify what is in the plasma from spectral signatures. Extracting quantitative information from these measurements such as impurity content, ion temperature, rotation, degree of detachment and radiated power depends on calibrated instruments, a physics model of the atomic and molecular processes and plasma transport and an analysis workflow that takes into account environmental effects such as reflections. The particular needs for ITER have prompted a multi-machine, many-year effort to address all these aspects and this chapter reviews the work on diagnostic design, experiments and new analysis techniques. An overview of the laser diagnostics to be implemented on ITER is also provided in this paper. This includes descriptions of the Thomson scattering in the core, edge and divertor regions, polarimetry and interferometry diagnostics used for measuring plasma density and also measurements of helium density in the divertor using Laser Induced Flourescence. Techniques which can allow improvements on current measurements are also addressed in particular expanding poloidal polarimetry measurements to measure field fluctuations and proposed use of dispersion interferometery which has a number of advantages over existing methods. This paper identifies particular areas where further research and testing on existing tokamaks is useful even at this advanced stage to inform the design of diagnostics for ITER. Outstanding areas of concern for the implementation of laser diagnostics, in particular with a view to reliable operation are identified. An overview of the latest developments of microwave diagnostic systems and techniques is given. The primary focus is the contributions for ITER—the next step burning plasma experiment—which is supplemented by describing recent progress of techniques applicable for fusion experiments beyond ITER. The contributions are intentionally kept concise, and are being supplemented by a rich list of references for further studies. Radiation induced effects are receiving continuous and well-deserved attention of the ITER diagnostic community and they are in many cases one of the primary design drivers of the ITER diagnostic systems. The paper summarizes recent progress in this area focusing primarily on the ITER diagnostics but in some cases provides also outlook for the possible solutions for even more demanding radiation environment of fusion reactors beyond ITER. Despite advancements in the area of modeling and simulation of various radiation induced effects, experimental testing in a nuclear environment as close as possible to the target one is still seen as unavoidable for proper qualification of particular diagnostic functional elements. Recent advancement within three diagnostic areas: optical diagnostics, magnetics and bolometers is covered. Encouraging results on qualification of silica glass vacuum window assemblies are presented. In the area of magnetic sensors, progress of irradiation tests performed on ITER in-vessel LTCC inductive sensors is presented with outlook for novel technological approaches to inductive sensors utilizing thick printing and photolithography technologies being highlighted. Summary of advancements in the area of steady state magnetic field sensors based on Hall effect is given. New results of neutron irradiation test of the ITER borosilicate glass inserts for vacuum electrical feedthroughs are summarized finding negligible swelling at target level of neutron fluence. Off-line irradiation tests of fiber optic current sensors for plasma current measurement demonstrated that both for gamma doses up to 5 MGy and a total neutron fluence up to 10 15 cm −2 , radiation induced changes are still compatible with required measurement accuracy on ITER. The ITER bolometers are given as an example how considering radiation effects may influence the diagnostic design. Finally, outlook for future main R&D directions is outlined. All optical and laser-based diagnostics in ITER will be using mirrors to guide plasma radiation toward detectors, cameras and sensors. In the hostile plasma, radiation and particle environment the optical characteristics of diagnostic mirrors will degrade directly affecting the entire performance of involved diagnostic systems. An assessment of factors affecting mirror performance is provided. Among the prime adverse factors are deposition of plasma impurities, sputtering of mirror surface and steam ingress in the vicinity of mirrors. Within the International Tokamak Physics Activity with active support by ITER central team and domestic agencies, the structured research and development (R&D) program on mitigation of risks for diagnostic mirrors is underway. Within this program the mirror material development, the passive mitigation of mirror degradation by using diagnostic ducts and shutters along with an active mirror recovery program comprising the in-situ mirror cleaning and calibration is underway. Recent developments in diagnostic mirror R&D are described in this Chapter along with an example of their implementation of R&D solutions in ITER Infrared Thermography diagnostic. An assessment of still open engineering and physics questions, considerations on mirror risks during an early phase of ITER operation are given along with an overview of diagnostic mirror evolution in the late ITER operation stage toward the demonstration fusion power plant. Several crucial areas of diagnostic R&D outlined in ITER Research Plan are addressed. The basic control groups in a fusion reactor can be broken-down in five categories: (1) plasma position, magnetic configuration, and plasma current control, (2) profile control and confinement optimization, (3) MHD control and suppression, (4) edge dissipation control, radiation and plasma exhaust control and (5) break-down optimization. These categories are coupled via the physics (a control action in one domain will affect the other domains) and via shared actuators (e.g. ECRH for impurity accumulation avoidance, current density distribution control and MHD suppression). Consequently, a supervisory control system should determine the priority of the various control tasks, their couplings, and the interfaces with the safety and interlock system. For the systematic development of the various controllers taking the complexity of the plasma and the control system into account, a model-based approach is required. A short historical overview is given of the developments in systems and control theory and control engineering with special emphasis on those developments that are most relevant for Nuclear Fusion research and operation. An overview is given of the state of the field of fusion plasma control for the control categories. It will be shown how synthetic diagnostics are being developed in ITER and how they are used in diagnostic design and design validation and how they can be in model-based controller synthesis using relatively simple models. In modern control methods, multiple diagnostics are used to constrain relatively simple models. The constrained models provide an estimate for the state. This opens the route to state controllers, such as model predictive control. A major challenge in nuclear fusion research is the coherent combination of data from heterogeneous diagnostics and modeling codes for machine control and safety as well as physics studies. Measured data from different diagnostics often provide information about the same subset of physical parameters. Additionally, information provided by some diagnostics might be needed for the analysis of other diagnostics. A joint analysis of complementary and redundant data allows, e.g. to improve the reliability of parameter estimation, to increase the spatial and temporal resolution of profiles, to obtain synergistic effects, to consider diagnostics interdependencies and to find and resolve data inconsistencies. Physics-based modeling and parameter relationships provide additional information improving the treatment of ill-posed inversion problems. A coherent combination of all kind of available information within a probabilistic framework allows for improved data analysis results. The concept of integrated data analysis (IDA) in the framework of Bayesian probability theory is outlined and contrasted with conventional data analysis. Components of the probabilistic approach are summarized and specific ingredients beneficial for data analysis at fusion devices are discussed.

ITER↗

Cosmic Background Rejection of the ICARUS experiment at Fermilab

The Short Baseline Neutrino program at Fermilab aims to explore significant regions of parameter space, applicable to sterile neutrinos at the eV mass scale, as suggested by existing experimental anomalies. To this purpose it exploits Liquid Argon Time Projection Chamber detectors located along the Booster Neutrino Beamline to measure both νe appearance and νµ disappearance: the Short Baseline Neutrino Detector and the ICARUS-T600 detector at 110 and 600 m from the neutrino source, respectively. The ICARUS T-600 Far Detector, located at shallow depth, is surrounded by a Cosmic Ray Tagger system to mitigate the cosmic ray background. On average ~ 11 muon tracks are expected to cross the detector during the ~ 1 ms drift time. The cosmic ray tagger is composed of plastic scintillator bars, ensuring near 4π coverage of the detector aiming at tagging cosmic muons and thus reject 𝛾s produced by muon interactions in the surrounding materials that can generate an electromagnetic showers mimicking a νe signal. The system allows one to disentangle cosmic rays from particles originated in a neutrino interaction inside the detector by measuring their position and crossing time. A synchronization of the cosmic ray tagger with the ICARUS photon detection system with a nanosecond accuracy allows one to reject cosmic particles recorded during the beam spill and thus select an enriched sample of neutrino triggered events ahead of the event reconstruction. An overview of the cosmic ray tagger system as well as its role in the neutrino events identification and cosmic background rejection will be presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Radiation asymmetry during shattered pellet and massive gas injection in DIII-D

Infrared thermography of the first wall in DIII-D is used to show the toroidal peaking of plasma radiation during mitigated disruptions with shattered pellet injection (SPI) and with massive gas injection (MGI). During MGI, the radiation peak location is shown to be due to the n = 1 magnetohydrodynamic (MHD) activity and continuously variable in toroidal phase based on externally applied error fields, consistent with previous experimental results. Furthermore, the measured toroidal peaking factor (TPF) is in agreement with the previous estimates based on radiometry, with a total TPF of 1.07 ± 0.05 when integrated over the entire duration of the disruption, and a value of 1.3 ± 0.1 during the thermal quench (TQ). For SPI, the location of the radiation peak is found to be determined predominantly by the particle source location, and thus can be varied on DIII-D by injecting from either of two toroidally separated injectors. 3D non-linear MHD simulations with the NIMROD code support this picture. The localized SPI particle source leads to higher peaking than for MGI, with a total TPF of 1.3 ± 0.1 over the full disruption and a TQ TPF of 1.9 +0.5/−0.3, a value also consistent with the NIMROD simulations. This TQ value is close to or potentially exceeding the allowable limit for the previously planned Be first wall in ITER, pointing to the importance of radiation asymmetries depending on the choice of first wall material.

Physics - Plasma physics↗

Exploring the Nature of Neutrinos with the Deep Underground Neutrino Experiment (DUNE)

The Deep Underground Neutrino Experiment (DUNE) is a next-generation experimental program designed to study the behaviour of neutrino oscillation. DUNE will utilize a neutrino beam originating at Fermilab, near Chicago, and will leverage a detector at Fermilab (Near Detector) and a detector 1300 km away in South Dakota (Far Detector), south of Saskatchewan. In the first phase of DUNE, its Far Detector will comprise of two 10,000 ton (fiducial) liquid argon (LAr) time-projection chamber (TPC) modules – powerful tracking calorimeter detectors – placed nearly a mile underground. With this large, sensitive, underground detector, DUNE aims to collect a high statistics and pure sample of neutrinos at the Far Detector. This setup also offers the potential to study non-beam physical processes via e.g. neutrinos produced in the atmosphere, supernova neutrino bursts, and/or solar neutrinos, etc. A second phase will aim to add more detector mass and expand the program. The Near Detector will consist of a LAr TPC module as well: critical to constraining systematic uncertainties in the oscillation analysis. However, this LAr TPC will have a novel design using a pixel-based readout instead of the traditional wire-based readout. This and the segmentation of the LAr TPC into multiple units are crucial in mitigating the high multiplicity of neutrino interactions expected in any readout window given its proximity to the beam. The Near Detector will feature additional components and capability beyond the LAr TPC, allowing one to deeply characterize the neutrino flux. Due to the complexity of this experimental program, several smaller-scale prototype detectors have been operating to test, validate, and improve both the technical designs and software for processing and analyzing events. By operating in charged particle test beams or neutrino beams, several of the prototypes are also capable of producing valuable results. Canadian institutions are involved in the realization of the DUNE through efforts with both the Near and Far Detectors and prototypes. DUNE is anticipated to begin operating near the end of this decade/the beginning of the next. This talk will focus on the overall DUNE program, for example its ultimate plans, status, and the efforts with prototypes.

Howard, Bruce [York U., Canada; Fermilab]↗

Moving lens effect: Simulations, forecasts, and foreground mitigation

The peculiar motion of massive objects across the line of sight imprints a dipolar temperature anisotropy pattern on the cosmic microwave background known as the moving lens effect. This effect provides a unique probe of the transverse components of the peculiar velocity field, but has not yet been detected due to its small size. We implement and validate a stacking estimator for the moving lens signal using a galaxy catalog as a tracer of massive haloes combined with reconstructed velocities from the galaxy number density field. Using simulations, we forecast detection prospects for the moving lens signal from current and upcoming microwave background and galaxy surveys. Here, we demonstrate a new foreground mitigation strategy likely sufficient for current datasets, and discuss various sources of systematic error and noise. Upcoming galaxy surveys will provide high-significance statistical detections of the moving lens effect.

Astrophysical & cosmological simulations↗

2x2 Demonstrator High-Coverage Light Readout System in a Novel LArTPC

DUNE is a long-baseline Liquid Argon Time Projection Chamber (LArTPC) neutrino oscillation experiment. Its near detectors, located at Fermi National Laboratory, will constrain systematic errors on far detector measurements. The 2x2 Demonstrator, a novel proof of concept prototype for the ND LArTPC, has a modular TPC design that mitigates event pileup in a high-occupancy nearline beam environment, further aided by a native 3D pixelated charge readout and a 30% coverage, low profile light readout. This will be the first large-scale LArTPC to utilize pixels in place of wire planes

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Pickup Specifications for Crab Cavity Noise Feedback Pickup

The Electron-Ion Collider will employ crab cavities to compensate for the significant 25 mrad crossing angle, leading to an order of magnitude increase in luminosity. The crab cavity Radio Frequency system will inject low levels of noise to the crabbing field, generating transverse emittance growth and potentially limiting luminosity lifetime. A novel dedicated feedback system acting through the crab cavities has been proposed to mitigate emittance growth. The perfor mance of the noise feedback will largely depend on its pickup precision. In this note we present pickup specifications to achieve the required performance.

43 PARTICLE ACCELERATORS↗

Tuning Cation (Dis)Order in Cr‐Based Li‐Excess Oxide Cathode Materials to Improve Li+ Transport Properties

Abstract Li‐excess disordered rocksalts (DRXs) hold promise as next‐generation cathodes for Li‐ion batteries due to their high capacity and energy density, along with the potential to eliminate the need for Co and Ni. However, due to their low Li + diffusivity, DRXs need to be pulverized into nanoparticles to achieve high performance. Herein, a new strategy for overcoming this limitation is demonstrated, involving the design of as‐synthesized partially disordered oxides with a structure that lies between ordered layered and fully disordered, exhibiting a varying degree of local (dis)order. This unique structure activates new Li + diffusion channels, improving percolation and transport properties. This strategy allows a large content of Li + to be accessed in material with large, micron‐sized particles through highly reversible Cr 3+/6+ and O redox, yielding a first discharge capacity of 286 mAh g −1 (881 Wh kg −1 ). The Li + percolation network is further improved by substituting Ti with a mixture of multiple metals, which appears to locally decrease the migration barrier through lattice distortion. Proper tuning of the chemical composition, especially the content of metals with empty d orbitals, is established as a crucial factor for controlling the degree of disorder and mitigating voltage fade and hysteresis growth upon cycling.

Moździerz, Maciej↗

Proton Dynamics Scenarios in the Integrable Optics Test Accelerator (IOTA) at Fermilab

The Integrable Optics Test Accelerator (IOTA) at Fermilab provides a versatile platform for studying the interplay of space-charge, impedance, and non-linear optics in high-intensity hadron beams within synchrotrons and storage rings. This report examines the parameters and dynamics of 2.5~MeV proton beam operations in two configurations of the bare IOTA lattice: one for demonstrating Non-linear Integrable Optics with the Danilov-Nagaitsev magnet, and the other for use with electron cooling. We offer order-of-magnitude estimates of the transverse emittance growth rate as a function of beam intensity, highlighting contributions from residual gas scattering, intra-beam scattering, and space-charge effects. Under nominal conditions, the beam lifetime is projected to be less than 7~minutes at low intensity with the current vacuum quality, and fewer than 100,000~turns at high intensity due to strong space-charge effects. The calculations presented here will guide strategies to mitigate emittance growth and inform future IOTA experiments.

43 PARTICLE ACCELERATORS↗

Study on Electropolishing of N-Doped Niobium Surfaces and 650 MHz Cavity for High-Gradient Performance

This presentation provides an overview of the latest studies on electropolishing (EP) of nitrogen-doped niobium surfaces and 650 MHz cavities. The first study focuses on optimizing EP parameters to achieve a pit-free surface on N-doped niobium, highlighting the effects of process conditions on surface pitting and suggesting strategies for mitigation. The second study investigates the EP of 650 MHz cavities to achieve high-gradient performance comparable to that of 1.3 GHz niobium SRF cavities. Additionally, an example of a 650 MHz single-cell cavity is presented, demonstrating its record-high gradient achieved through optimized EP conditions.

43 PARTICLE ACCELERATORS↗

Interplay between the non-resonant streaming instability and self-generated pressure anisotropies

The non-thermal particles escaping from collision-less shocks into the surrounding medium can trigger a non-resonant streaming instability that converts parts of their drift kinetic energy into large amplitude magnetic field perturbations, and promote the confinement and acceleration of high energy cosmic rays. We present simulations of the instability using an hybrid-Particle-in-Cell approach including Monte Carlo collisions, and demonstrate that the development of the non-resonant mode is associated with important ion pressure anisotropies in the background plasma. Depending on the initial conditions, the anisotropies may act on the instability by lowering its growth and trigger secondary micro-instabilities. Introducing collisions with neutrals yield a strong reduction of the magnetic field amplification as predicted by linear fluid theory. In contrast, Coulomb collisions in fully ionized plasmas are found to mitigate the self-generated pressure anisotropies and promote the growth of the magnetic field.

79 ASTRONOMY AND ASTROPHYSICS↗

A New Phase for Space Weather

As we move into the declining phase of solar cycle 25, the sunspot number is going down but space weather impacts are not disappearing. Solar energetic particle events, large x-ray flares, and geomagnetic storms are still happening and the declining phase will bring a different balance of hazards. The need for space weather science, space weather applications, and an interface between research, application, and stakeholder communities has not passed. Observations and insights from solar cycle 25 will continue to help us prepare for solar cycle 26, so that we approach the next solar maximum with better predictions, better understanding of outcomes, and a stronger community enabling more confident mitigation and clearer outreach.

99 GENERAL AND MISCELLANEOUS↗

Nanoscopic strain evolution in single-crystal battery positive electrodes

Single-crystal Ni-rich layered oxides (SC-NMC) with a grain-boundary-free configuration have effectively addressed the long-standing cracking issue of conventional polycrystalline Ni-rich materials (PC-NMC) in lithium-ion batteries, prompting a shift in optimization strategies. However, continued reliance on anisotropic lattice volume change—a well-established failure indicator in PC-NMC—as a metric for understanding strain and guiding compositional design for SC-NMC becomes controversial. Here, in this study, by leveraging multiscale diagnostic techniques, we unravelled the distinct nanoscopic strain evolution in SC-NMC during battery operation, challenging the conventional composition-driven strategies and mechanical degradation indicators used for PC-NMC. Through particle-level chemomechanical analysis, we reveal a decoupling between mechanical stability and lattice volume change in SC-NMC, identifying that structural instability in SC materials is primarily driven by multidimensional lattice distortions induced by kinetics-driven reaction heterogeneity and progressively deactivating chemical phases. Using this mechanical failure mode, we redefine the roles of cobalt and manganese in maintaining mechanical stability. Unlike cobalt’s detrimental role in PC-NMC, we find cobalt to be critical in enhancing the longevity of SC-NMC by mitigating localized strain along the extended diffusion pathway, whereas manganese exacerbates mechanical degradation.

36 MATERIALS SCIENCE↗

Tunable structure and reinforcement of polyvinyl alcohol (PVA) hydrogels using fungal chitin particles

Polysaccharides, including chitin, are one of the most abundant biopolymers in nature and are increasingly recognized as a sustainable alternative to petroleum-derived plastics and synthetic fillers in polymer composites. Traditionally sourced from crustacean shells, chitin offers mechanical strength and biocompatibility with limitations also in processability and functionality. Fungal-derived chitin material represents a promising alternative, with advantages including scalable fermentation on low-cost substrates, absence of shellfish allergens, and tunable molecular architectures that vary by species, developmental stage, and growth environment. Here, in this study, we systematically examined chitinous materials obtained from taxonomically and functionally distinct fungi, Laccaria bicolor, Trichoderma reesei and Rhizopus oryzae, to assess their structural, chemical, and morphological properties as reinforcement agents in polymer composites. Mild alkaline pretreatment was employed to obtain mycelium chitin particles, thereby improving accessibility to chitin and co-occurring β-D-glucans while maintaining microparticle integrity. Comprehensive FTIR and solid-state NMR analyses revealed species-specific differences in chemical composition and microstructure, with R. oryzae exhibiting a unique spectral signature. These fungal-derived chitin were then incorporated into poly(vinyl alcohol) (PVA) hydrogels, where they acted as reinforcing fillers without the need for additional chemical crosslinkers. Comparative evaluation of hydrogel properties demonstrated that fungal chitin significantly enhanced mechanical performance, with all mycelium fillers mitigating the water weakening in PVA hydrogels. R. oryzae-derived composites tripled the hydrogel tensile strength while the submicron fibrous morphology in L. bicolor contributes to over 45 % tensile improvement in dry PVA composites. Our findings highlight the potential of fungal biomass as a tunable, sustainable platform for producing chitin-based reinforcing agents.

Chitin↗

Insights into Preceramic Polymer-Based Additive Manufacturing Inks via Rheological and Scattering Studies of Preceramic Polymer-Grafted Nanoparticles Suspended in Polycarbosilane

Preceramic polymers (PCPs) offer advantages in producing ceramics due to their processability and ability to tailor the final chemistry of the produced material. However, challenges such as volumetric shrinkage and mass loss during pyrolysis often result in polymer-derived ceramics containing pores and cracks. PCP-grafted ceramic nanoparticles (PCPGNPs) have been proposed and studied as a route to mitigate the shrinkage issues associated with neat PCPs. Prior studies on PCPGNPs have principally focused on the synthesis and characterization of neat materials. Dispersing PCPGNPs in commercial preceramic polymer is another attractive, but underexplored, route to control the rheological and char yield properties of PCP systems. In this work, a systematic rheological study of commercial PCP (SMP-877) and PCPGNP (silica with poly(1,1-dimethylpropylsilane) corona) mixtures was executed to develop design rules for the processing of such systems. A rheological study demonstrated the effect of increasing particle concentration on network formation with percolation occurring between 50 and 60 wt %. Samples above the percolation threshold exhibited higher viscosities and rapid shear thinning thus demonstrating their direct-write printability. X-ray photon correlation spectroscopy (XPCS) corroborated the rheology and showed two diffusive modes when the material was above percolation. Mixtures of PCPGNPs and SMP-877 had synergistically higher char yields upon thermal treatment and pyrolysis. XPCS and rheological measurements during thermal treatment identified thermal jamming of the polymer grafts as a key factor in improving the char yield. In conclusion, with the insights gained here, we expect these mixed systems to provide attractive feedstocks for polymer-derived ceramics, with proof-of-principal application as feedstocks for direct ink write (DIW) additive manufacturing.

36 MATERIALS SCIENCE↗

Broadening of the Divertor Heat Flux Profile in High Confinement Tokamak Fusion Plasmas with Edge Pedestals Limited by Turbulence in DIII-D

Multimachine empirical scaling predicts an extremely narrow heat exhaust layer in future high magnetic field tokamaks, producing high power densities that require mitigation. Here, in the experiments presented, the width of this exhaust layer is nearly doubled using actuators to increase turbulent transport in the plasma edge. This is achieved in low collisionality, high confinement edge pedestals with their gradients limited by turbulent transport instead of large-scale, coherent instabilities. The exhaust heat flux profile width and divertor leg diffusive spreading both double as a high frequency band of turbulent fluctuations propagating in the electron diamagnetic direction doubles in amplitude. The results are quantitatively reproduced in electromagnetic XGC particle-in-cell simulations which show the heat flux carried by electrons emerges to broaden the heat flux profile, directly supported by Langmuir probe measurements.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Joint Analysis of Small-scale Galaxy Clustering and Galaxy–Galaxy Lensing from BOSS Galaxies

We present a joint analysis of galaxy clustering and galaxy–galaxy lensing measurements from BOSS galaxies using a simulation-based emulation method combined with a halo occupation distribution model. Our emulators are constructed with the Aemulus ν simulations, a suite of wνCDM N-body simulations with massive neutrinos as independent particle species. We combine small-scale analysis of clustering from 0.1 to 60.2 h −1 Mpc and lensing from 1.7 to 60.2 h −1 Mpc to perform cosmological constraints. We split the BOSS galaxies into three redshift bins to measure their clustering and employ galaxies from Dark Energy Camera Legacy Survey and Hyper Suprime-Cam as source galaxies to measure lensing separately. We find that the addition of lensing significantly improves the constraining power on $S_8 = σ_8(Ω_m/0.3)^{0.5}$, with a weak improvement for fσ 8 . Our results of fσ 8 indicate tensions of around 1σ−4σ below the results of the cosmic microwave background observations of Planck. For S 8 , our results are also lower than Planck, and the tension can be mitigated when considering possible systematics in lensing measurement. As a by-product, our analysis prefers a nonzero neutrino mass but without strong significance, with the constraining power dominated by the clustering. Given the accuracy and precision of our model and the observational data, it is anticipated that larger and higher-quality spectroscopic data sets will improve the constraints on this fundamental property in the near future.

Gao, Wenhao [Shanghai Jiao Tong University (China)↗