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NASA NTRS1994

Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence

Ultraviolet absorption cross-section of phosgene (CCl2O), trichloroacetylchloride (CCl3-CClO) and trichloroacetaldehyde (CCl3-CHO) have been measured between 170 and 320 nm for temperature ranging from 210 to 295 K with classical double beam equipment. These data are compared with other available determinations performed at room temperature. Photodissociation coefficients are estimated and their temperature dependence is discussed. Impact of the photodissociation on the total atmospheric destruction of these compounds is illustrated.

Gillotay, D.↗
NASA NTRS1993

The (C2) 158 micrometer emission from the Horsehead nebula

The C II 158 micrometer line and the several rotational lines of CO, CO-13, and CS toward selected positions in the Horsehead extinction region in IC 434 are mapped. The observations show that the region has a gas density of about 10,000 cu cm and an external UV (Ultraviolet) flux to 20 to 100 times the average interstellar UV field. Although this is a regime where the C+ emission varies rapidly with UV intensity, fine structure line emission from gas with this range of physical conditions were not investigated previously. Comparisons of results with models of photodissociation regions show that existing plane parallel photodissociation region models are in general agreement with the observed intensity. It is not necessary to invoke a clumpy structure in the boundary layer to explain the observations, but the overall geometry of the cloud is important in determining the distribution of C+ emission.

Zhou, S.↗
NASA NTRS1994

Evolution of macromolecular dust: Far-ultraviolet spectral dust extinction and gas absorption of stellar light as measured with the Hopkins Ultraviolet Telescope

From far-ultraviolet (FUV) spectra of B stars taken with the Hopkins Ultraviolet Telescope (HUT) and Voyager space observations, we determine the far-ultraviolet extinction by Galactic dust and hydrogen absorption in the local spiral-arm clouds towards HD 25443 (B0.5 III), HD 37903 (B1.5 V), and HD 200775 (B3 Ve). We find that the (n (H)) = 1.3 cu cm and number fraction (f = 0.31) of H atoms in molecular hydrogen relative to the total hydrogen indicates a mostly diffuse medium toward HD 25443. We also determine f = 0.56 for the gas in the photodissociation region (PDR) in front of HD 37903 and f approximately equals 0.36 for the HD 200775 PDR. The inferred ratios of N(H2)/I(CO) = 2.4 to 2.8 x 10(exp 20)/K(km/s)/sq cm for cool gas in dark clouds agree with previous canonical estimates of N(H2)/I(CO) = 2 to 3 x 10(exp 20)/K(km/s)/sq cm and support the use of the ratio for determining masses of molecular clouds. We find that the shape and strength of the HD 25443 FUV extinction is the same as a diffuse-medium mean extinction (R(sub nu) = 2.95) extrapolated from mid-UV wavelengths (normal). The HD 37903 FUV extinction through a bright H2 photodissociation region is higher than a mean FUV extinction(R(sub nu) = 4.11), as is the HD 200775 extinction. Another star from the literature rho Oph, probes the dense medium and exhibits an FUV extinction of normal mean strength (R(sub nu) = 4.55) but steeper shape. The normal FUV -extinction of HD 25443 implies that the small FUV-extinction dust in the diffuse medium forms in p art from larger grains as the grains shatter under shocks. The normal strength of the rho Oph FUV-extinction indicates that the minute dust condenses onto or coagulates into larger grains in the dense medium. The high extinction deviation of the HD 37903 PDR (and HD 200775 PDR) shows that FUV radiation from hot stars with T(sub eff) approximately equals 20,000 to 23,000 K in PDRs can evaporate some of the FUV-extinction dust from grain surfaces. In contrast, previously measured extinctions in Galactic H(+) (H II) regions shows that FUV radiation at T(sub eff) greater than 25,000 K can destroy some of the dust in H(+) regions. Thus, some of the FUV-extinction dust is highly volatile. We find that the dust carrier of the variable FUV-extinction is correlated (r = 0.99) with the mid-IR (12 micrometers) radiation from hydrocarbon dust. The volatile FUV-extinction component could thus be due to minute hydrocarbon dust particles or macromolecules, probably PAHs, which are known to condense onto larger grains in the dense medium. Larger grains compsed of PAHs clustered into a solid could thus produce the steep FUV extinction of the rho Oph dense medium. After exposure to FUV photons wihtin approximately 1 pc of HD 37903, PAHs with about 30 carbon atoms would evaporate off the larger grains, increasing gaseous PAH abundance by approximately 14%. Also, after receiving shocks in the diffuse medium toward HD 25443, the larger hydrocarbon grains would shatter into PAH molecules. In summary, as the Galactic medium cycles betwee n the diffuse and dense medium, hydrocarbon dust cycles into and out of larger grains under the influence of shocks, radiation, and condensation.

Buss, Richard H., Jr.↗
NASA NTRS1994

An extended source for CN jets in Comet P/Halley

We examined radial intensity profiles of CN jets in comparison with the diffuse, isotropic component of the CN coma of Comet P/Halley. All images were bias-subtracted, flat-fielded, and continuum-subtracted. We calculated the diffuse profiles by finding the azimuthal mean of the coma least contaminated by jets yielding profiles similar to those of vectorial and Haser models of simple photodissociation. We found the jet profiles by calculating a mean around a Gaussian-fitted center in r-theta space. There is an unmistakable difference between the profiles of the CN jets and the profiles of the diffuse CN. Spatial derivatives of these profiles, corrected for geometrical expansion, show that the diffuse component is consistent with a simple photodissociation process, but the jet component is not. The peak production of the jet profile occurs 6000 km from the nucleus at a heliocentric distance of 1.4 AU. Modeling of both components of the coma indicate results that are consistent with the diffuse CN photochemically produced, but the CN jets need an additional extended source. We found that about one-half of the CN in the coma of Comet P/Halley originated from the jets, the rest from the diffuse component. These features, along with the width of the jet being approximately constant, are consistent with a CHON grain origin for the jets.

Klavetter, James Jay↗
NASA NTRS1994

The gas distribution of comet Halley and its relation to the nucleus rotation

We used a set of spatially resolved spectra of comet Halley to explore whether the gas distribution profile could be inverted to yield information on the rotation of the comet. The data were obtained both pre- and post-perihelion. The pre-perihelion data showed reasonable symmetry and so were used to define the lifetimes against photodissociation of the various molecules. These lifetimes were then used to define the lifetimes against photodissociation of the various molecules. These lifetimes were then used along with a nonsteady-state vectorial model to fit the post-perihelion gas distribution profiles. The resulting molecular lightcurves are compared with the photometric lightcurves of Schlicher et al. (1990) to show that the rotational information is encoded in the observed gas distribution within the coma. The molecular lightcurves can differentiate between the preferred Schlicher et al. average period and the period they find for the same time interval as the spectra.

Cochran, Anita L.↗
NASA NTRS1998

The Mid-Infrared Spectrum of the Galactic Center: A Starburst Nucleus

Using the Michelson interferometer on the Midcourse Space Experiment (MSX), we have taken spectra of many positions in the central 25 min of the Galactic Center (GC) with a 6 min x 9 min FOV. The spectral coverage was 380 to 1700/ cm (6 to 26 microns) and the resolution was approx. 21/cm. The spectra exhibit strong UIR/PAH features at 6.2, 7.7, 8.6 and 11.3 microns, in addition to the ionic lines of (Ne II), at 12.8 microns, (S III) 18.7 microns, and (Ar II) 6.98 microns. There are deep silicate absorption features at 10 and 18 microns and a cold continuum increasing at the longest wavelengths. Additional weak features are present in the spectra. We discuss the variation in the extinction at 10 microns as a function of location in the GC. Compared to the MSX spectrum of the Orion nebula, smoothed to the same resolution and multiplied by the estimated GC extinction, the GC spectra have similar PAH features, but the Orion Nebula also has strong lines of (He III) 15.6 microns, (S IV) 10.5 microns, and (Ar III) 8.99 microns and its 25 microns continuum is stronger (colder). Thus, the GC exhibits the mid-IR spectrum of a low excitation H II region and a nearby molecular cloud with a surface photodissociation region (PDR). This is in excellent agreement with the canonical model of a starburst nucleus in which the hot stars and molecular clouds are randomly distributed. The outer surfaces of the clouds are photodissociated and ionized by the photons from the stars located outside the clouds. The PAH molecules are transiently heated by the stellar photons. Since the exciting stars are located well outside the clouds, the radiation field is dilute compared to a newly-formed blister H II region like Orion; this dilute radiation field causes the relatively low excitation of the ionic lines.

Simpson, J. P.↗
NASA NTRS1999

KWIC: A Widefield Mid-Infrared Array Camera/Spectrometer for the KAO

This grant covered a one year data analysis period for the data we obtained with the Kuiper Widefield Infrared Camera (KWIC) on the KAO during CY94 and CY95. A fairly complete list of scientific papers produced, or soon to be produced under this award is contained at the end of this report. Below we summarize some of the highlights of the work we did under this grant. KWIC Imaging of the Orion Nebula. KWIC was successfully developed under the KAO grants program (NASA grant NAG2-800). First funding arrived in November of 1992, and we flew our first two flights in February of 1994 -just 15 months later. These flights were very successful. We imaged the Orion Nebula in the 37.7 micron continuum and [SiII] 35 micron line and imaged M82 and Arp299 in the 37.7 micron continuum. Our Orion image demonstrates that the 37.7 micron continuum arises in the warm dust associated with the photodissociated surfaces (photodissociation regions, or PDRs) of molecular clouds. We use the brightness and color temperature distribution to ascertain the morphology of the Orion PDR. The [SiII] image of Orion encompassed the entire Orion A HII region and its enveloping PDR. Most of the emission in the PDR regions of the map appears to coincide very well with our 37.7 micron continuum map indicating a PDR origin for the [SiII] in agreement with theoretical predictions. The [SiII] line emission is very clumpy in the PDR directly imaging the clump spectrum indirectly ascertained by examining the distribution and flux ratios of [CII] and [0I] far-IR fine structure line, and high J CO emission. We also detected very strong [SiII] line emission from the embedded BN-KL star formation region tracing the morphology and physical conditions of the high velocity shock from these very young stars.

Stacey, Gordon J.↗
NASA NTRS2000

Photochemistry of Methane in Model Atmospheres of Jupiter and Titan

The two central findings were 1) hydrogen atoms and hydrogen molecules photodissociated from methane are relatively richer in H than in D in other words deuterium atoms have a greater probability of remaining attached to the carbon atom. Titan, a moon of Saturn has an atmosphere which is largely nitrogen but also contains about 3% methane as well as smaller amounts of C2 and C3 hydrocarbons. If all these hydrocarbons are of biological origin, the isotopic scrambling occurring in living organisms would result in equal D atom abundances. On the other hand, if the higher hydrocarbons are derived from methane by photodissociation of methane, they should be richer in D than methane. Precise values for the enrichment were derived from our photochemical data. 2) When methane is dissociated by vuv light, methylene is produced in a singlet state. This explains why the higher hydrocarbons are sparse on Jupiter but relatively rich on Titan.

Bersohn, Richard↗
NASA NTRS1997

AB Initio Study of the Structure and Spectroscopic Properties of Halogenated Thioperoxy Radicals

Thioperoxy (XSO or XOS) radicals exist in a variety of chemical environments, and they have as a consequence drawn some interest. HSO, an important species in the chemistry of the troposphere, has been examined both experimentally. The halogenated (X = F, Cl or Br) peroxy species and isovalent thioperoxy species have been studied less, but they too are potentially interesting because oxidized sulfur species and halogen sources are present in the atmosphere. Learning the fate of XSO and XOS radicals is important to understanding the atmospheric oxidation chemistry of sulfur compounds. Of these, FSO and ClSO are particularly interesting because they have been directly detected spectroscopically. Recent studies in our laboratory on the photochemistry of thionyl halides (X2SO; where X = F or Cl) have suggested new ways to generate XSO species. The laser-induced photodissociation of thionyl fluoride, F2SO, at 193 nm and thionyl chloride, ClSO, at 248 nm is characterized by a radical mechanism, X2SO -> XSO + X. The structure of FSO has been characterized experimentally by Endo et cd. employing microwave spectroscopy. Using the unrestricted Hartree-Fock (UHF) self-consistent field (SCF) method, Sakai and Morokuma computed the electronic structure of the ground (sup 2)A" and the first excited (sup 2)A' states of FSO. Electron correlation was not taken into account in their study. In a laser photodissociation experiment, Huber et al. identified ClSO mass spectromctrically. ClSO has also been detected in low temperature matrices by EPR and in the gas phase by far IR laser magnetic resonance. Although the structure of FSO is known in detail, the only study, experimental or theoretical, of CISO has been an ab initio HFSCF study by Hinchliffe. Electron correlation corrections were also excluded from this study. In order to better understand the isomerization and dissociation dynamics of the radical species, we have performed ab initio correlated studies of the potential energy surfaces (PES) of ClSO and its isomer ClOS at the QCISD(T)/6-31 G* level of theory. For FSO and FOS, more extensive QCISD/6-31 1G(2df) calculations have been possible, and the results are summarized here.

Munoz, Luis A.↗
NASA NTRS2003

The Chemistry and Excitation of Water in Molecular Clouds

We model the chemistry and thermal balance of opaque molecular clouds exposed to an external flux of ultraviolet photons. We include the processes of gas phase and grain surface chemical reactions; in particular we examine closely the freezing of atoms and molecules onto grain surfaces and the desorption of molecules from grain surfaces as a function of depth into a molecular cloud. We find that on the surface of a molecular cloud the gas phase water abundances are low because of photodissociation, and the grain phase water (ice) abundance is low because of photodesorption of water from the grain surfaces. Deeper into the cloud, at A(sub v) less than or approximately 2-8 depending on the strength of the external ultraviolet flux, the gas phase water abundance increases with depth as the photodissociation rates decline due to dust attenuation of the ultraviolet field. However, beyond A(sub v) less than or approximately 2-8 the gas phase water abundance declines because the water freezes as water ice on the grains, and photodesorption is no longer effective in clearing the ice. A peak water abundance of about 10(exp -6) to 10(exp -7) occurs at about A(sub v) approximately 2-8, relatively independent of the gas density and the ultraviolet field. We show that such a model matches very closely the observations of the Submillimeter Wave Astronomical Satellite (SWAS), a NASA Small Explorer Mission. The model elucidates several mechanisms that have been recently invoked to understand gas phase chemistry in clouds, including-the freeze-out of molecules onto grain surface, the desorption of these molecules from the surfaces, and the abundance gradients of molecules as functions of depth into molecular clouds.

Hollenbach, David↗
NASA NTRS2011

Fluorescence Excitation Models of Ammonia and Amidogen Radical (NH2) in Comets: Application to Comet C/2004 Q2 (Machholz)

Ammonia is a major reservoir of nitrogen atoms in cometary materials. However, detections of ammonia in comets are rare, with several achieved at radio wavelengths. A few more detections were obtained through near-infrared observations (around the 3 m wavelength region), but moderate relative velocity shifts are required to separate emission lines of cometary ammonia from telluric absorption lines in the 3 micron wavelength region. On the other hand, the amidogen radical (NH2 -- a photodissociation product of ammonia in the coma) also shows rovibrational emission lines in the 3 micron wavelength region. Thus, gas production rates for ammonia can be determined from the rovibrational emission lines of ammonia (directly) and amidogen radical (indirectly) simultaneously in the near-infrared. In this article, we present new fluorescence excitation models for cometary ammonia and amidogen radical in the near-infrared, and we apply these models to the near-infrared high-dispersion spectra of comet C/2004 Q2 (Machholz) to determine the mixing ratio of ammonia to water in the comet. Based on direct detection of NH3 lines, the mixing ratio of NH3/H2O is 0.46% +/- 0.03% in C/2004 Q2 (Machholz), in agreement with other results. The mixing ratio of ammonia determined from the NH2 observations (0.31% -- 0.79%) is consistent but has relatively larger error, owing to uncertainty in the photodissociation rates of ammonia. At the present level of accuracy, we confirm that NH3 could be the sole parent of NH2 in this comet.

Kawakita, Hideyo↗
NASA NTRS2012

Revisions to Photochemical Data for Use in Atmospheric Modeling

Solar and stellar flux incident on an atmosphere can cause molecules to dissociate into highly reactive species and allows for photochemical processes to play a fundamental role in atmospheric chemistry. While models have tried to simulate such processes, they are extremely sensitive to photoabsorption cross-sections and quantum yields: two parameters that are important in determining the photodissociation rate, and hence the lifetime, of atmospheric compounds. Obtaining high-resolution and current data for these parameters is therefore highly desirable. Due to this, database and literature searches for high-quality cross-sections and quantum yields were performed and compiled for KINETICS, a Caltech/JPL Chemical Transport Model that can be used in modeling planetary atmospheres. Furthermore, photodissociation rates determined by running a Titan 1-D model were used to verify the completeness of these latest revisions.

Chemical Transport Model (CTM)↗
NASA NTRS2018

Evolution of H2O Production in Comet C/2012 S1 (ISON) as Inferred from Forbidden Oxygen and OH Emission

We present H2O production rates for comet C/2012 S1 (ISON) derived from observations of [O I] and OH emission during its inbound leg, covering a heliocentric distance range of 1.8–0.44 AU. Our production rates are in agreement with previous measurements using a variety of instruments and techniques and with data from the various observatories greatly differing in their projected fields of view. The consistent results across all data suggest the absence of an extended source of H2O production, for example sublimation of icy grains in the coma, or a source with spatial extent confined to the dimensions of the smallest projected field of view (in this case < 1000 km). We find that ISON had an active area of around 10 sq km for heliocentric distances Rh > 1.2 AU, which then decreased to about half this value from Rh = 1.2–0.9 AU. This was followed by a rapid increase in active area at about Rh = 0.6 AU, corresponding to the first of three major outbursts ISON experienced inside of 1 AU. The combination of a detected outburst in the light curve and rapid increase in active area likely indicates a major nucleus fragmentation event. The 5–10 sq km active area observed outside of Rh = 0.6 AU is consistent with a 50–100% active fraction for the nucleus, larger than typically observed for cometary nuclei. Although the absolute value of the active area is somewhat dependent on the thermal model employed, the changes in active area observed are consistent among models. The conclusion of a 50–100+% active fraction is robust for realistic thermal models of the nucleus. However the possibility of a contribution of a spatially unresolved distribution of icy grains cannot be discounted. As our [OI]-derived H2O production rates are consistent with values derived using other methods, we conclude that the contribution of O2 photodissociation to the observed [O I] emission is at most 5–10% that of the contribution of H2O for ISON. This is consistent with the expected contribution of O2 photodissociation if O2/H2O ∼ 4%, meaning [O I] emission can still be utilized as a reliable proxy for H2O production in comets as long as O2/H2O ≲ 4%, similar to the abundance measured by the ROSINA instrument on Rosetta at comet 67P/Churyumov–Gerasimenko.

Coma↗
NASA NTRS2020

Novel Nuclear Reactions Observed in Bremsstrahlung-Irradiated Deuterated Metals

d-D nuclear fusion events were observed in an electronscreened, deuterated metal lattice by reacting cold deuterons with hot deuterons (d*) produced by elastically scattered neutrons originating from bremsstrahlung photodissociation (where “d” and “D” denote 2H). Exposure of deuterated materials (ErD3 and TiD2) to photon energies in the range of 2.5 to 2.9 MeV resulted in photodissociation neutrons that were below 400 keV and also the 2.45-MeV neutrons, consistent with 2H(d, n)3He fusion. Additionally, neutron energies of approximately 4 and 5 MeV for TiD2 and ErD3 were measured, consistent with either boosted neutrons from kinetically heated deuterons or Oppenheimer-Phillips stripping reactions in the highly screened environment. Neutron spectroscopy was conducted using calibrated lead shielded liquid (EJ-309) and plastic (stilbene) scintillator detectors. The data support the theoretical analysis in a companion paper, predicting fusion reactions and subsequent reactions in the highly screened environment.

Bruce M Steinetz↗
NASA NTRS2021

A Deep Search for Five Molecules in the 49 Ceti Debris Disk

Surprisingly strong CO emission has been observed from more than a dozen debris disks around nearby main-sequence stars. The origin of this CO is unclear, in particular whether it is left over from the protoplanetary disk phase or is second-generation material released from collisions between icy bodies like debris dust. The primary unexplored avenue for distinguishing the origin of the material is understanding its molecular composition. Here we present a deep search for five molecules (CN, HCN, HCO+, SiO, and CH3OH) in the debris disk around 49 Ceti. We take advantage of the high sensitivity of the Atacama Large Millimeter/submillimeter Array at Band 7 to integrate for 3.2 hr at modest spatial (1′′) and spectral (0.8 km s−1) resolution. Our search yields stringent upper limits on the flux of all surveyed molecular lines, which imply abundances relative to CO that are orders of magnitude lower than those observed in protoplanetary disks and solar system comets, and also those predicted in outgassing models of second-generation material. However, if CI shielding is responsible for extending the lifetime of any CO produced in second-generation collisions as proposed by Kral et al., then the line ratios do not reflect true ice phase chemical abundances but rather imply that CO is shielded by its own photodissociation product, CI, and other molecules are rapidly photodissociated by the stellar and interstellar radiation field.

Debris disks↗
NASA NTRSDate not supplied

Heterogeneity of Bulk Oxygen Isotopic Compositions in Anhydrous Interplanetary Dust Particles

Introduction: Anhydrous interplanetary dust particles are one of the least altered ancient solar systemmaterials. Their bulk chemical compositions match those of CI chondrites within a factor of 2-3, except for carbonwhich is enriched in both anhydrous and hydrated IDPs by ~4x CI [1]. Hydrous IDPs often show 16O-poor isotopiccompositions, likely due to the interaction with isotopically heavy H2O [2]. Anhydrous IDPs are interpreted tooriginate from comets from the outer solar system [3]. Oxygen isotopic data for these materials is scarce, but resultspoint to a wider range of compositions [4]. This heterogeneity might be a result of mixing between a 16O-rich and a16O-poor reservoir formed via self-shielding and photodissociation of CO [5]. Here, we report bulk oxygen isotopiccompositions of three anhydrous IDPs in context of their mineralogical composition and discuss possible origins ofisotopic heterogeneity. Experimental: Bulk chemical composition and mineralogy of 70 nm thin ultramicrotomed sections of threeanhydrous IDPs (L2099A7, L2099A8, and L2071AB1) were analyzed using a Thermo Scientific Titan Themis G360-300 TEM equipped with a four-quadrant energy-dispersive X-ray detector (Super-X G2) at University ofMünster. Bulk oxygen isotopic compositions were measured using a NanoSIMS 50 at the Max-Planck-Institut fürChemie in Mainz. A focused Cs+ ion beam (~1 pA, ~100 nm) was rastered over a field of view varying from 5 x 5 to6 x 6 μm2, depending on particle size for 15 layers. Negative secondary ions of 16O, 17O, 18O, 12C14N, and 28Si werecollected on electron multipliers. The 16OH contribution to the 17O peak was 1-2 ‰. As a standard, a matrix regionof meteorite CR2 Queen Alexandra Range (QUE) 99177 was used, whose oxygen isotopic composition wasmeasured by [6]. Results and Discussion: Particles A7 and A8 are both fine-grained, consisting mostly of small, 100 nm-sizedequilibrated aggregates (EA). Both particles exhibit discontinuous magnetite rims with thicknesses up to 50 nm inA7 and 100 nm in A8 on the outsides. In Particle AB1, the upper part of the particle consists of a few EAs, while thelower part contains lots of small GEMS grains with 100-200 nm diameter clustered together. Magnetite rims arenearly absent, the rare rims reaching maximum 20 nm thickness, indicating that AB1 is of more primitive naturethan the other two IDPs [1]. Furthermore, it contains several diffuse GEMS-like areas, identified by an amorphoussilicate groundmass with small nano-inclusions of Fe,Ni-metal and Fe-sulfides. All three particles are subsolar forall major element/Si ratios. Mean S/Si of particles A7 and A8 is 0.046 and 0.048, respectively, while it is an order ofmagnitude higher in AB1 (0.184). This reflects the higher degree of thermal alteration in A7 and A8, resulting in theloss of volatile S and oxidation of Fe-sulfides and FeNi-metal to magnetite as present in particle rims. A8 is rather16O-poor with δ17OSMOW = 7.8 ± 3.4 ‰ and δ18OSMOW = 9.5 ± 3.1 ‰ (1σ), followed by A7 with δ17OSMOW = − 0.8 ±4.6 ‰ and δ18OSMOW = −2.2 ± 3.4 ‰. In contrast to that, AB1 has the most 16O-rich bulk composition with δ17OSMOW= −24.2 ± 5.4 ‰ and δ18OSMOW = −25.3 ± 3.6 ‰. All investigated IDPs plot slightly above the CCAM line aspreviously reported for other anhydrous IDPs [4], maybe due to a contribution from circumstellar dust from AGBstars enriched in 17O [7]. The 16O-rich composition of AB1 is similar to the most 16O-rich anhydrous IDP U2015D21measured by [8] which is dominated by GEMS [9] and the GEMS-rich IDP GM4-2 reported by [10]. Nevertheless,it is unlikely that GEMS are the carrier for the 16O-rich composition of AB1 because most GEMS have O isotopiccompositions indistinguishable from terrestrial values, although errors on these analyses are large [11]. The isotopicheterogeneity is best explained by contribution of grains from different regions in the protoplanetary disk, samplingdifferent O isotope reservoirs, created by self-shielding and photodissociation of CO. This process resulted in 16O-rich CO gas and 16O-poor H2O that froze as ice-mantles onto dust grains [12]. Alternatively, the higher degree ofheating in A7 and A8 could have influenced isotopic fractionation, because higher δ17,18O values are reported fromthe regions of the atmosphere where small particles are heated and oxidized, as observed for the thermal alteration ofcosmic spherules [13]. Acknowledgements: We would like to thank NASA Astromaterials Acquisition & Curation Office for providing IDPsamples and DFG for funding this project (VO1816/5-1)

B Schulz↗