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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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197 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Interplay of structural fluctuations and charge carrier dynamics is key for high performance of hybrid lead halide perovskites

The ability of methylammonium lead triiodide (MAPbI 3 ) to achieve photoelectric conversion efficiency that is on par with crystalline silicon has led to a surge of interest in perovskite photovoltaics. However, an in-depth understanding of how the ubiquitous coupling between the fast rovibrational movements of the organic cations and the phonon vibrations of the inorganic framework affects the relaxation and recombination of hot carriers remains largely elusive. Access to such knowledge is critical to guide design and increase efficiency of new classes of perovskite solar cells. In this report, we report a time-domain ab initio investigation of temperature dependent excited state dynamics in MAPbI 3 , with particular emphasis on nuclear anharmonic effects. The observed strong anharmonicity is attributed to softness of the material and unusual dynamical coupling between the organic and inorganic components. At an elevated temperature, the hydrogen bonding between MA and iodines is weakened, enhancing rotation of MA cations, which become more dynamically disordered. As a result, thermal vibrations of the inorganic Pb–I sublattice are suppressed, and the lattice anharmonicity is decreased. Thermal fluctuations of the electronic energy levels are found to follow the trend of anharmonic motions of Pb and I atoms, with holes relaxing faster to the band edges than electrons, due to higher density of the hole states. While elevated temperature accelerates intraband carrier cooling, it slows nonradiative carrier recombination. The latter result is important for performance, since solar cells and other devices heat up during operation. The reported signatures of coupled structural dynamics of the organic cations and inorganic framework unravel the interplay between anomalous structural fluctuations and charge carrier dynamics, which is of particular importance for fundamental understanding of the structure–property relationships in hybrid metal halide perovskites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

A Statistical Evaluation of the Limitations of Single-channel Intermediate-band Photoelectric Stellar Photometry

Error distribution in differential photometry for a moving solar system object is investigated. The results of differential photometry of several dozen pairs of planetary comparison stars observed since 1972 are reviewed. Each pair of stars was observed along with the corresponding planet or satellite, typically about ten times during the course of a single apparation lasting about four months. The comparison stars are chosen to bracket the opposition position of the planet, the expected opposition magnitude, and solar color. In practice, this means that the range of spectral type was mid-F to early K, the range of B-Y color was about 0.25 to 0.95 mag, the range of differential magnitude was less than 2 mag but most often less than 1.0 mag, and the difference in declination was typically less than 3 deg. The difference in air mass at meridian transit was usually less than 0.03, and rarely exceeded 0.01. Hence, differential extinction effects are negligible, except under extraordinary conditions.

Lockweed, G. W.↗
NASA NTRS1986

Photoelectric photometry of Comet P/Halley from Mauna Kea Observatory

A program of photoelectric photometry of comet Halley yielded 60 nights of usable photometry. The uncertainty in the photometry in all filters except OH is better than 2%. Throughout the apparition, the comet is brightest in the filters that isolated the neutral gas emission features of OH, CN, C2, and C3. The fluxes in the filters that isolated the ionic emission features of CO(+) and H2O(+) are comparable to the continuum when centered upon the optocenter, thereby making the ionic emission weak to undetectable above the continuum. The continuum colors do not appear to be a function of phase angle; therefore, the colors are probably indicative of dust grain composition and are not dominated by scattering geometry effects.

Piscitelli, J. R.↗
NASA NTRS1976

Five-color photoelectric photometry of asteroid 433 Eros

Five-color (UVBGR) photoelectric light curves of Eros are presented which were obtained on nine nights during the asteroid's 1974/75 close apparition. Indications that three reversals occurred in the relative depths of the two minima between late December 1974 and late January 1975 are noted along with definite evidence of phase reddening. The maximum amplitude observed was 1.44 magnitudes, and the absolute visual magnitude at primary maximum (corrected to zero phase and to 1 AU from the earth and the sun) was about 10.8 magnitudes. Since the observations indicate that Eros has no significant rotational color variations, it is suggested that the light-curve amplitudes are due primarily to the asteroid's shape and to shadowing effects. Based on its colors relative to the sun, it is concluded that Eros appears to be an S-type asteroid.

Miner, E.↗
NASA NTRS1979

Solar p-mode oscillations as a tracer of radial differential rotation

Photoelectric observations of solar p-modes obtained with improved wavenumber and frequency resolution are presented. The observations are compared with model calculations of the p-modes, and the degree of spatial and temporal coherence of the observed wave pattern is investigated. It is found that the p-mode oscillations pervade the visible surface of the sun with a high degree of coherence in space and time, so that the whole complex pattern of standing waves with its nodes and antinodes can be regarded as a fixed pattern corotating with the solar surface layers. The p-modes are introduced as a tracer of solar rotational flow velocities. The equatorial differential rotation is estimated as a function of effective depth on the basis of the theoretical contribution functions for the p-modes recently derived by Ulrich et al. (1978). The results strongly indicate that the angular speed of rotation is not uniform even in the relatively shallow layer extending about 20,000 km below the photosphere.

Deubner, F.-L.↗
NASA NTRS1979

Occultation of Epsilon Geminorum by Mars. III - Temperature structure of the Martian upper atmosphere

High-quality photoelectric observations of the April 8, 1976, occultation of Epsilon Gem by Mars are analyzed which were obtained at five different observatories. Temperature profiles are derived by numerical inversion of the star's light curves and found to be in mutual agreement. This is taken as evidence for the presence of strong atmospheric waves in the Martial upper atmosphere between number densities of 10 to the 13th and 10 to the 15th per cu cm. It is estimated that the vertical wavelength is about 20 km, the horizontal wavelength is greater than 600 km, and the peak-to-peak wave amplitude is approximately 40 K. The results are shown to be qualitatively consistent with Zurek's (1976) model of thermally driven tidal modes. No compelling evidence for turbulence effects is found in the occultation data.

French, R. G.↗
NASA NTRS1976

Mutual phenomena of the Galilean satellites in 1973. III - Final results from 91 light curves

This paper presents an analysis of photoelectric light curves of 91 mutual eclipses and occultations of the Galilean satellites that occurred from June to December 1973. From the deepest curves, radii and standard errors are deduced for J2, J3, and J4. It is shown that the substantial differences between the depths and midtimes observed and those predicted by Sampson's theory can be used in a clear and definite way to revise the orbital constants of that theory. The present analysis, which reduces all the data provided by these mutual events in one body, diminishes the latitude and longitude residuals of the unrevised theory by as much as a factor of about 10. The resulting overall consistency and the demonstrated inadequacy of an explanation based solely on surface-brightness variations argue that these corrections do represent the dominant effects required to account for the light curves. In order that these mutual events can be used with other astrometric data, the separations between a satellite pair at midevent are given. A small systematic (with solar phase angle) and unexplained difference in the longitude corrections is found for Io and Europa as obtained from nearly simultaneous pairs of occultations and eclipses.

Aksnes, K.↗
NASA NTRS1992

Potential of long-baseline infrared interferometry for narrow-angle astrometry

Narrow-angle astrometry has many astrophysical applications, from the measurement of parallaxes to the search for planets around nearby stars. Ground-based long-focus telescopes with photoelectric detectors have achieved accuracies of about 2-3 milliarcsec in 1 h. This accuracy is limited primarily by the atmosphere, and is consistent with models of atmospheric turbulence. However, applying these turbulence models to observations with long-baseline interferometers yields astrometric errors that are far smaller than can be achieved with long-focus telescopes. The predictions for the ultimate accuracy of ground-based narrow-angle astrometry using long-baseline IR (2.2 micron) stellar interferometers are very promising. With the excellent seeing at a high altitude site like Mauna Kea, the atmospheric limit for a 1 h astrometric measurement is expected to be of the order of 10 microarcsec for 1 h of integration. This two-order-of-magnitude improvement over conventional measurements is due to two effects. One is that a long-baseline IR interferometer can find useful reference stars very near an arbitrary target star, so that the atmospherically-induced motions of both stars are highly correlated. The second is that the baseline length can be much larger than the separation of the stellar beams in the turbulent atmosphere, resulting in a reduction in astrometric error with increasing baseline length.

Shao, M.↗
DOE OSTI2021

Controlled photo-discharge of dust in a complex plasma

One of the limitations in studying dusty plasmas is that many of the important properties of the dust (like the charge) are directly coupled to the surrounding plasma conditions rather than being determined independently. The application of high-intensity ultraviolet (UV) sources to generate discharging photoelectric currents may provide an avenue for developing methods of controlling dust charge. Careful selection of the parameters of the UV source and dust material may even allow for this to be accomplished with minimal perturbation of the background plasma. The Auburn Magnetized Plasma Research Laboratory (MPRL) has developed a ‘proof-of-concept’ experiment for this controlled photo-discharging of dust; a high-intensity, near-UV source was used to produce large changes in the equilibrium positions of lanthanum hexaboride ( $\textrm {LaB}_6$ ) particles suspended in an argon DC glow discharge with negligible changes in the potential, density and temperature profiles of the background plasma. The shifts in equilibrium position of the dust are consistent with a reduction in dust charge. Video analysis is used to quantify the changes in position, velocity and acceleration of a test particle under the influence of the UV and Langmuir probes are used to measure the effects on the plasma.

Physics↗
NASA NTRS1992

The x ray reflectivity of the AXAF VETA-I optics

The x-ray reflectivity of the VETA-I optic, the outermost shell of the AXAF x-ray telescope, with a bare Zerodur surface, is measured and compared with theoretical predictions. Measurements made at energies of 0.28, 0.9, 1.5, 2.1, and 2.3 keV are compared with predictions based on ray trace calculations. The data were obtained at the x-ray calibrations facility at Marshall Space Flight Center with an electron impact x-ray source located 528 m from the grazing incidence mirror. The source used photoelectric absorption filters to eliminate bremsstrahlung continuum. The mirror has a diameter of 1.2 m and a focal length of 10 m. The incident and reflected x-ray flux are detected using two proportional counters, one located in the incident beam of x-rays at the entrance aperture of the VETA-I, and the other in the focal plane behind an aperture of variable size. Results on the variation of the reflectivity with energy as well as the absolute value of the reflectivity are presented. We also present a synchrotron reflectivity measurement with high energy resolution over the range 0.26 to 1.8 keV on a flat Zerodur sample, done at NSLS. We present evidence for contamination of the flat by a thin layer of carbon on the surface, and the possibility of alteration of the surface composition of the VETA-I mirror perhaps by the polishing technique. The overall agreement between the measured and calculated effective area of VETA-I is between 2.6 percent and 10 percent, depending on which model for the surface composition is adopted. Measurements at individual energies deviate from the best-fitting calculation to 0.3 to 0.8 percent, averaging 0.6 percent at energies below the high energy cutoff of the mirror reflectivity, and are as high as 20.7 percent at the cutoff. We also discuss the approach to the final preflight calibration of the full AXAF flight mirror.

Kellogg, Edwin M.↗
NASA NTRS2000

The Origin of the X-Ray and Ultraviolet Emission in NGC 7469

We present a spectral analysis of a approx 30 day, near-continuous observation of the Seyfert 1 galaxy NGC 7469 with RXTE. Daily integrations show strong spectral changes during the observation. Our main result is that we find the X-ray spectral index to be correlated with the UV flux. Furthermore, the broadband X-ray photon flux is also correlated with the UV continuum. These correlations point toward a model in which the X-rays originate via thermal Comptonization of UV seed photons. Furthermore, the UV is also correlated with the extrapolation of the X-ray power law into the soft X-ray/EUV region. Our data analysis therefore reopens the possibility that the UV photons and their variability arise from reprocessing, as long as the primary source of heating is photoelectric absorption in the re-processor, rather than Compton down-scattering. A coherent picture of the X-ray/UV variability can therefore be constructed whereby absorption and reprocessing of EUV/soft X-rays in a standard accretion disk produce a variable seed photon distribution, which is in turn up-scattered into the X-ray band. We also find a significant correlation between the 2-10 keV flux and the 6.4 keV iron K-alpha line, suggesting that at least some portion of the line originates within approx. 1 light day of the X-ray continuum source. Neither the power-law photon index nor the Compton reflection component are correlated with the 2-10 keV flux. The latter is not correlated with the iron K-alpha line flux either. We do find an apparent correlation between the X-ray spectral index and the strength of the Compton reflection component. In an Appendix we show, however, that this can be produced by a combination of statistical and systematic errors. We conclude that the apparent variations in the Compton reflection component may be an artifact of these effects.

Nandra, K.↗
NASA NTRS1998

Standard Giant Branches in the Washington Photometric System

We have obtained CCD photometry in the Washington system C, T(sub 1) filters for some 850,000 objects associated with 10 Galactic globular clusters and 2 old open clusters. These clusters have well-known metal abundances, spanning a metallicity range of 2.5 dex from [Fe/H] approx -2.25 to +0.25 at a spacing of approx. 0.2 dex. Two independent observations were obtained for each cluster and internal checks, as well as external comparisons with existing photoelectric photometry, indicate that the final colors and magnitudes have overall uncertainties of 0.03 mag. Analogous to the method employed by Da Costa and Armandroff for V, I photometry , we then proceed to construct standard ((M(sub T),(C - T(sub 1))(sub 0)) giant branches for these clusters adopting the Lee et distance scale, using some 350 stars per globular cluster to define the giant branch. We then determine the metallicity sensitivity of the ((C - T(sub 1))(sub 0) color at a given M((sub T)(sub 1)) value. The Washington system technique is found to have three times the metallicity sensitivity of the V, I technique. At M((sub T)(sub 1)) = -2 (about a magnitude below the tip of the giant branch, roughly equivalent to M(sub I) = -3), the giant branches of 47 Tuc and M15 are separated by 1.16 magnitudes in (V - l)(sub 0) and only 0.38 magnitudes in (V - I)(sub 0). Thus, for a given photometric accuracy, metallicities can be determined three times more precisely with the Washington technique. We find a linear relationship between (C - T(sub l)(sub 0) (at M(sub T)(sub 1) = -2) and metallicity exists over the full metallicity range, with an rms of only 0.04 dex. We also derive metallicity calibrations for M(sub T)(sub 1) = -2.5 and -1.5, as well as for two other metallicity scales. The Washington technique retains almost the same metallicity sensitivity at faint magnitudes , and indeed the standard giant branches are still well separated even below the horizontal branch. The photometry is used to set upper limits in the range 0.03 - 0.09 dex for any intrinsic metallicity dispersion in the calibrating clusters. The calibrations are applicable to objects with ages approx. greater than 5 Gyr - any age effects are small or negligible for such objects. This new technique is found to have many advantages over the old two-color diagram technique for deriving metallicities from Washington photometry. In addition to only requiring 2 filters instead of 3 or 4, the new technique is generally much less sensitive to reddening and photometric errors, and the metallicity sensitivity is many times higher. The new technique is especially advantageous for metal-poor objects. The five metal-poor clusters determined by Geisler et al., using the old technique, to be much more metal-poor than previous indications, yield metallicities using the new technique which are in excellent agreement with the Zinn scale.

Geisler, Doug↗
DOE OSTI2021

AlGaN/GaN metal–insulator–semiconductor high electron mobility transistors (MISHEMTs) using plasma deposited BN as gate dielectric

AlGaN/GaN metal–insulator–semiconductor high electron mobility transistors (MISHEMTs) were fabricated on Si substrates with a 10 nm boron nitride (BN) layer as a gate dielectric deposited by electron cyclotron resonance microwave plasma chemical vapor deposition. The material characterization of the BN/GaN interface was investigated by X-ray photoelectric spectroscopy (XPS) and UV photoelectron spectroscopy. The BN bandgap from the B1s XPS energy loss is ~5 eV consistent with sp2 bonding. The MISHEMTs exhibit a low off-state current of 1 × 10 –8 mA/mm, a high on/off current ratio of 10 9 , a threshold voltage of –2.76 V, a maximum transconductance of 32 mS/mm at a gate voltage of –2.1 V and a drain voltage of 1 V, a subthreshold swing of 69.1 mV/dec, and an on-resistance of 12.75 Ω·mm. The interface state density (D it ) is estimated to be less than 8.49 × 10 11 cm –2 eV –1 . Gate leakage current mechanisms were investigated by temperature-dependent current–voltage measurements from 300 K to 500 K. The maximum breakdown electric field is no less than 8.4 MV/cm. Poole–Frenkel emission and Fowler–Nordheim tunneling are indicated as the dominant mechanisms of the gate leakage through the BN gate dielectric at low and high electric fields, respectively.

36 MATERIALS SCIENCE↗
NASA NTRS2007

An Automated Flying-Insect Detection System

An automated flying-insect detection system (AFIDS) was developed as a proof-of-concept instrument for real-time detection and identification of flying insects. This type of system has use in public health and homeland-security decision support, agriculture and military pest management, and/or entomological research. Insects are first lured into the AFIDS integrated sphere by insect attractants. Once inside the sphere, the insect s wing beats cause alterations in light intensity that is detected by a photoelectric sensor. Following detection, the insects are encouraged (with the use of a small fan) to move out of the sphere and into a designated insect trap where they are held for taxonomic identification or serological testing. The acquired electronic wing-beat signatures are preprocessed (Fourier transformed) in real time to display a periodic signal. These signals are sent to the end user where they are graphically. All AFIDS data are preprocessed in the field with the use of a laptop computer equipped with LabVIEW. The AFIDS software can be programmed to run continuously or at specific time intervals when insects are prevalent. A special DC-restored transimpedance amplifier reduces the contributions of low-frequency background light signals, and affords approximately two orders of magnitude greater AC gain than conventional amplifiers. This greatly increases the signal-to-noise ratio and enables the detection of small changes in light intensity. The AFIDS light source consists of high-intensity Al-GaInP light-emitting diodes (LEDs). The AFIDS circuitry minimizes brightness fluctuations in the LEDs and when integrated with an integrating sphere, creates a diffuse uniform light field. The insect wing beats isotropically scatter the diffuse light in the sphere and create wing-beat signatures that are detected by the sensor. This configuration minimizes variations in signal associated with insect flight orientation. Preliminary data indicate that AFIDS has sufficient sensitivity and frequency measuring capability to differentiate between male and female mosquitoes (Figure 1, bottom panel) and fruit flies (data not shown). Similar studies show that AFIDS can be utilized to detect discrete differences between two mosquito species, Aedes aegypti and Aedes albopictus. When fully deployable, a wireless network of AFIDS monitors could be used in combination with other remotely sensed data and visually displayed in a geographic information system (GIS) to provide real-time surveillance (see Figure 2). More accurate and sensitive insect population forecasts and effective rapid response and mitigation of insect issues would then be possible.

Vann, Timi↗
NASA NTRS2017

Active Electrostatic flight for airless bodies

The environment near the surface of asteroids, comets, and the Moon is electrically charged due to the Sun’s photoelectric bombardment and lofting dust, which follows the Sun illumination as the body spins. Charged dust is ever present, in the form of dusty plasma, even at high altitudes, following the solar illumination. If a body with high surface resistivity is exposed to the solar wind and solar radiation, sunexposed areas and shadowed areas become differentially charged. The E-Glider (Electrostatic Glider) is an enabling capability for operation at airless bodies, a solution applicable to many types of in-situ missions, which leverages the natural environment. This platform directly addresses the "All Access Mobility" Challenge, one of the NASA’s Space Technology Grand Challenges. Exploration of comets, asteroids, moons and planetary bodies is limited by mobility on those bodies. The lack of an atmosphere, the low gravity levels, and the unknown surface soil properties pose a very difficult challenge for all forms of know locomotion at airless bodies. This EGlider levitates by extending thin, charged, appendages, which are also articulated to direct the levitation force in the most convenient direction for propulsion and maneuvering. The charging is maintained through continuous charge emission. It lands, wherever it is most convenient, by retracting the appendages or by firing a cold-gas thruster, or by deploying an anchor. Preliminary calculations indicate that a 1 kg mass can be electrostatically levitated in a microgravity field with a 2 m diameter electrostatically inflated ribbon structure at 19kV, hence the need for a “balloon-like” system. The wings could be made of very thin Au-coated Mylar film, which are electrostatically inflated, and would provide the lift due to electrostatic repulsion with the naturally charged asteroid surface. Since the E-glider would follow the Sun’s illumination, the solar panels on the vehicle would constantly charge a battery. Further articulation at the root of the lateral strands or inflated membrane wings, would generate a component of lift depending on the articulation angle, hence a selective maneuvering capability which, to all effects, would lead to electrostatic (rather than aerodynamic) flight.

Schaub, Hanspeter↗
NASA NTRS2018

E-Glider: Active Electrostatic Flight for Airless Body Exploration

The environment near the surface of asteroids, comets, and the Moon is electrically charged due to the Sun's photoelectric bombardment and lofting dust, which follows the Sun illumination as the body spins. Chargeddust is ever present, in the form of dusty plasma, even at high altitudes, following the solar illumination. If abody with high surface resistivity is exposed to the solar wind and solar radiation, sun-exposed areas andshadowed areas become differentially charged. The E-Glider (Electrostatic Glider) is an enabling capability foroperation at airless bodies, a solution applicable to many types of in-situ mission concepts, which leverages thenatural environment. With the E-Glider, we transform a problem (spacecraft charging) into an enablingtechnology, i.e. a new form of mobility in microgravity environments using new mechanisms and maneuveringbased on the interaction of the vehicle with the environment. Consequently, the vision of the E-Glider is toenable global scale airless body exploration with a vehicle that uses, instead of avoids, the local electricallycharged environment. This platform directly addresses the "All Access Mobility" Challenge, one of the NASA'sSpace Technology Grand Challenges. Exploration of comets, asteroids, moons and planetary bodies is limitedby mobility on those bodies. The lack of an atmosphere, the low gravity levels, and the unknown surface soilproperties pose a very difficult challenge for all forms of know locomotion at airless bodies. This E-Gliderlevitates by extending thin, charged, appendages, which are also articulated to direct the levitation force in themost convenient direction for propulsion and maneuvering. The charging is maintained through continuouscharge emission. It lands, wherever it is most convenient, by retracting the appendages or by firing a cold-gasthruster, or by deploying an anchor. The wings could be made of very thin Au-coated Mylar film, which areelectrostatically inflated, and would provide the lift due to electrostatic repulsion with the naturally chargedasteroid surface. Since the E-glider would follow the Sun's illumination, the solar panels on the vehicle wouldconstantly charge a battery. Further articulation at the root of the lateral strands or inflated membrane wings,would generate a component of lift depending on the articulation angle, hence a selective maneuveringcapability which, to all effects, would lead to electrostatic (rather than aerodynamic) flight. Preliminarycalculations indicate that a 1 kg mass can be electrostatically levitated in a microgravity field with a 2 mdiameter electrostatically inflated ribbon structure at 19kV, hence the need for a "balloon-like" system. Due tothe high density and the photo-electron sheath and associate small Debye length, significant power is requiredto levitate even a few kilograms. The power required is in the kilo-Watt range to maintain a constant chargelevel.

Electrostatic Flight↗
NASA NTRS1994

Catalogue of UBVRI photometry of T Tauri stars and analysis of the causes of their variability

A computer-based catalogue of UBVRI photoelectric photometry of T Tauri stars and their earlier type analogs has been compiled. It presently includes over 10 000 entries on 80 stars and will be updated on a regular basis; it is available on Internet. The catalogue is used to analyze the sometimes bizarre light variations of pre-main-sequence stars on time scales of days to months in an attempt to illuminate the nature and causes of the phenomenon. It is useful in discussing their light variations to divide the stars into three groups according to their spectra. These are: weak T Tauri stars (WTTS; spectral class later than K0 and W(sub H-alpha less than 10 A), classical T Tauri stars (CTTS; spectral class later than K0 and W(sub H-alpha) greater than 10 A), and early type T Tauri stars (ETTS; spectral class of K0 or earlier). Three distinct types of variability are displayed by stars in the catalogue. Type I variations are periodic in VRI and undoubtedly caused by rotational modulation of a star with an asymmetric distribution of cool spots on its surface. Irregular flare activity is sometimes seen on such stars in U and B. Type I variations are easiest to see on WTTS but are clearly present on CTTS and ETTS as well. Type II variations are caused by hot 'spots' or zones and, it is argued, result from changes in the excess or 'veiling' continuum commonly attributed to an accretion boundary layer or impact zone of a magnetically channeled accretion flow. This type of variation is seen predominantly or solely in CTTS. A subcategory, designated Type IIp, consists of stars which display periodic variations caused by hot spots. Whereas cool spots may last for hundreds or thousands of rotations, hot spots appear to come and go on a much shorter time scale. This suggests that both unsteady accretion and rotation of the star contribute to Type II variations. It is shown that a third type of variation exists among ETTS, including stars as early as A type. UX Ori is a typical example and we call these Type III variables or UXors. Their distinguishing characteristic is that they can display very large amplitudes (exceeding 2.8 mag in V) while showing little or no evidence for a veiling continuum or any substantial change in their photospheric spectra. If Type III variations are caused by changes in accretion luminosity, then boundary layers or impact zones in ETTS must be much different from CTTS which, of course, is possible since mass accretion rates are probably much higher. However, the leading hypothesis for explaining Type III variations is variable obscuration by circumstellar dust. It is argued that the putative dust clumps causing such variations cannot be confined to a disk; otherwise UXors would be rare. Perhaps magnetic effects are involved in levitating accreting dust out of the plane, as has been suggested for CTTS, or perhaps we are witnessing continuing infall of clumps from placental clouds. A third possibility is that dust may be condensing in an outflow.

Herbst, William↗