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At least 199 records · Page 11

SXRP - An X-ray polarimeter for the SPECTRUM-X-Gamma mission

The Stellar X-ray Polarimeter (SXRP) is a focal plane instrument which will be flown on the SPECTRUM-X-Gamma mission in 1993. The polarimeter is composed of two separate instruments: the first exploits the dependence on the polarization of the Bragg reflection from a graphite crystal, and of the Thomson scattering from a metallic lithium target. The second instrument makes use of the recently discovered polarization dependence of X-ray photoemission from CsI. The SXRP will permit sensitive measurements of several classes of galactic X-ray sources, such as X-ray pulsars, black-hole candidates and supernova remnants. Moreover, and for the first time, SXRP will be able to perform highly sensitive measurements of the brightest extragalactic sources.

Costa, E.↗

Long-wave infrared (LWIR) detectors based on III-V materials

Future NASA missions for earth observation and planetary science require large photovoltaic detector arrays with high performance in the long wavelength region to 18 microns and at operating temperatures above 65 K where single-cycle long-life cryocoolers are being developed. Since these detector array requirements exceed the state of current HgCdTe technology, alternative detector materials are being investigated as a possible option for future missions. Advanced growth techniques (e.g., MBE and MOCVD) of column III-V semiconductors have opened opportunities for engineering new detector materials and device structures. The technical approaches under investigation at JPL (with university and industry participation) include: quantum well infrared photodetectors, heterojunction internal photoemission (HIP) photodetectors, type-II strained layer superlattices, and nipi doping superlattices. Each of these options are briefly described with some of their pros and cons. A more detailed description is given for the HIP approach being pioneered at JPL.

Maserjian, Joseph↗

Advanced Si IR detectors using molecular beam epitaxy

SiGe/Si heterojunction internal photoemission (HIP) long wavelength infrared (LWIR) detectors have been fabricated by MBE. The SiGe/Si HIP detector offers a tailorable spectral response in the long wavelength infrared regime by varying the SiGe/Si heterojunction barrier. Degenerately doped p(+) SiGe layers were grown using elemental boron, as the dopant source allows a low growth temperature. Good crystalline quality was achieved for boron-doped SiGe due to the reduced growth temperature. The dark current density of the boron-doped HIP detectors was found to be thermionic emission limited. HIP detectors with a 0.066 eV were fabricated and characterized using activation energy analysis, corresponding to a 18 micron cutoff wavelength. Photoresponse of the detectors at wavelengths ranging from 2 to 12 microns has been characterized with corresponding quantum efficiencies of 5 - 0.1 percent.

Lin, T. L.↗

Visible photoluminescence of porous Si(1-x)Ge(x) obtained by stain etching

We have investigated visible photoluminescence (PL) from thin porous Si(1-x)Ge(x) alloy layers prepared by stain etching of molecular-beam-epitaxy-grown material. Seven samples with nominal Ge fraction x varying from 0.04 to 0.41 were studied at room temperature and 80 K. Samples of bulk stain etched Si and Ge were also investigated. The composition of the porous material was determined using X-ray photoemission spectroscopy and Rutherford backscattering techniques to be considerably more Ge-rich than the starting epitaxial layers. While the luminescence intensity drops significantly with the increasing Ge fraction, we observe no significant variation in the PL wavelength at room temperature. This is clearly in contradiction to the popular model based on quantum confinement in crystalline silicon which predicts that the PL energy should follow the bandgap variation of the starting material. However, our data are consistent with small active units containing only a few Si atoms that are responsible for the light emission. Such units are present in many compounds proposed in the literature as the cause of the visible PL in porous Si.

Ksendzov, A.↗

Effects of levitated dust on astronomical observations from the lunar surface

It is believed that a substantial population of levitated dust is present in the terminator region of the moon. Stray light scattered by this dust layer may contaminate astronomical observations made from the lunar surface using infrared, visible, and ultraviolet light. The evidence for dust levitation stems from: Surveyor vidicon images of horizon glow; anomalous brightness in photographs of the solar corona taken by Apollo astronauts while the spacecraft was just inside the moon's shadow; and observations by Apollo astronauts of streamers just prior to lunar orbital sunrise or just after lunar orbital sunset. It has been proposed that the differential charging of the lunar surface in the terminator region due to photoemission and the consequent strong local electric fields comprise the mechanism responsible for this levitation. Although quantitative data on the levitated lunar dust distribution are meager, it is possible to estimate column densities and sizes. In this paper we summarize the estimates of particulate sizes and number densities of previous authors, and construct a nominal terminator dust distribution, as a function of particulate radius and altitude above the lunar surface. Using the model we estimate the brightness of scattered sunshine for three wavelength bands. For the results in the visible wavelengths, we compare the estimated brightness with the known brightness of selected astronomical objects and discuss the implications for lunar-based astronomy.

Murphy, D. L.↗

Analysis of leading edge and trailing edge cover glass samples before and after treatment with advanced satellite contamination removal techniques

Two samples from Long Duration Exposure Facility (LDEF) experiment M0003-4 were analyzed for molecular and particulate contamination prior to and following treatment with advanced satellite contamination removal techniques (CO2 gas/solid jet spray and oxygen ion beam). The pre- and post-cleaning measurements and analyses are presented. The jet spray removed particulates in seconds. The low energy reactive oxygen ion beam removed 5,000 A of photo polymerized organic hydrocarbon contamination in less than 1 hour. Spectroscopic analytical techniques were applied to the analysis of cleaning efficiency including: Fourier transform infrared, Auger, x ray photoemissions, energy dispersive x ray, and ultraviolet/visible. The results of this work suggest that the contamination studied here was due to spacecraft self-contamination enhanced by atomic oxygen plasma dynamics and solar UV radiation. These results also suggest the efficacy for the jet spray and ion beam contamination control technologies for spacecraft optical surfaces.

Hotaling, S. P.↗

The faint limit of the Hubble Space Telescope faint object spectrograph and rejection of the cosmic-ray background

The faintest object which can be observed with the Hubble Space Telescope (HST) Faint Object Spectrograph (FOS) is set by the detector cosmic-ray background and not by object flux. We use data from Beaver and Lyons to show that 48% of the background counts are from cosmic rays which each generate a near instantaneous burst of two or more counts. Setting the FOS threshold parameter REJLIM = 1, which rejects all frames with more than one count increases the ratio of signal-to-dark counts (S/D) by a factor of 1.94, regardless of the frame time or the object signal, because half of the dark counts which arrive in single counts (from either cosmic-ray bursts or thermal dark current photoemission) are rejected at the same rate as the object signal. But the signal-to-noise ratio (SNR proportional to S/square root of S + D) increases by at most a factor of 1.35, and for realistic parameters and taking into account dead time, we expect a gain in SNR of only 1.18. If a diode has failed and now emits noise, no data at all will be recorded. The chance of this occurring is approximately = 10% , and for this reason we do not recommend the use of REJLIM. The two-point correlation function of dark counts per pixel has strong peaks every four pixels, caused by the action of quarter-stepping on the counts from large bursts. The counts from such bursts spread over at least 80-100 diodes, and we show that such bursts can be rejected during data reduction if the data are recorded in RAPID mode with individual exposures of about 35 seconds. The SNR of the spectrum can also be improved by weighting each exposure by its SNR (a function ofthe mean dark count rate at that time), since dark varies by a factor of 2 around an orbit. These two procedures together increase the SNR by a factor of 1.1.3 (a 28% gain in exposure time) in regions of a spectrum where the object is much fainter than the background. We find that the Ly-alpha and O I sky emission lines give at most 4 (counts/array/s/sq arcsec), and typically half this number. With a small frame time and a small entrance aperture, these counts cause REJLIM = 1 to reject only a few percent of the data. We discuss only the HST FOS blue side detector, but the same ideas apply to any photon counter which records bursts of noise, and the calculations resemble those for the loss of signal due to coincidences in photon counters. In the ideal photon counter the dark counts are readily distinguished from photons. One way to do this is to add detectors which records only dark current, so that every cosmic ray produces more than one count and the instrument can be operated in an anti-coincidence mode.

Tytler, David↗

Stochastic charging of dust grains in planetary rings: Diffusion rates and their effects on Lorentz resonances

Dust grains in planetary rings acquire stochastically fluctuating electric charges as they orbit through any corotating magnetospheric plasma. Here we investigate the nature of this stochastic charging and calculate its effect on the Lorentz resonance (LR). First we model grain charging as a Markov process, where the transition probabilities are identified as the ensemble-averaged charging fluxes due to plasma pickup and photoemission. We determine the distribution function P(t;N), giving the probability that a grain has N excess charges at time t. The autocorrelation function tau(sub q) for the strochastic charge process can be approximated by a Fokker-Planck treatment of the evolution equations for P(t; N). We calculate the mean square response to the stochastic fluctuations in the Lorentz force. We find that transport in phase space is very small compared to the resonant increase in amplitudes due to the mean charge, over the timescale that the oscillator is resonantly pumped up. Therefore the stochastic charge variations cannot break the resonant interaction; locally, the Lorentz resonance is a robust mechanism for the shaping of etheral dust ring systems. Slightly stronger bounds on plasma parameters are required when we consider the longer transit times between Lorentz resonances.

Schaffer, L.↗

Polyimides That Contain Cyclobutene-3,4-Dione Moieties

Linear aromatic polyimides containing cyclobutene-3,4,-dione moieties synthesized in experiments. Polymers exhibit high thermal and thermo-oxidative stabilities, making them useful in structural components exposed to hot and/or oxidative environments, as in jet engines and on outer surfaces of supersonic aircraft. Electrons in cyclobutene-3,4-dione moieties readily excited to states of higher energy upon exposure to ultraviolet light, giving rise to electronic properties with potential utility in photovoltaic, photoconductive, and/or photoemissive devices.

St. Clair, Terry L.↗

Theoretical study of cathode surfaces and high-temperature superconductors

Calculations are presented for the work functions of BaO on W, Os, Pt, and alloys of Re-W, Os-W, and Ir-W that are in excellent agreement with experiment. The observed emission enhancement for alloy relative to tungsten dispenser cathodes is attributed to properties of the substrate crystal structure and explained by the smaller depolarization of the surface dipole on hexagonal as compared to cubic substrates. For Ba and BaO on W(100), the geometry of the adsorbates has been determined by a comparison of inverse photoemission spectra with calculated densities of unoccupied states based on the fully relativistic embedded cluster approach. Results are also discussed for models of scandate cathodes and the electronic structure of oxygen on W(100) at room and elevated temperatures. A detailed comparison is made for the surface electronic structure of the high-temperature superconductor YBa2Cu3O7 as obtained with non-, quasi-, and fully relativistic cluster calculations.

Mueller, Wolfgang↗

Infrared Detectors Containing Stacked Si(1-x)Ge(x)/Si Layers

Long-wavelength-infrared detectors containing multiple layers of high-quality crystalline p(+) Si(1-x)Ge(x) alternating with layers of Si undergoing development. Each detector comprises stack of Si(1-x)Ge(x)/Si heterojunction internal photoemission (HIP) photodetectors. In comparison with older HIP detectors containing single Si(1-x)Ge(x)/Si heterojunctions, developmental detectors feature greater quantum efficiencies and stronger photoresponses.

Park, Jin S.↗

The Use of Langmuir Probes in Non-Maxwellian Space Plasmas

Disturbance of the Maxwellian plasma may occur in the vicinity of a spacecraft due to photoemission, interactions between the spacecraft and thermospheric gases, or electron emissions from other devices on the spacecraft. Significant non-maxwellian plasma distributions may also occur in nature as a mixture of ionospheric and magnetospheric plasmas or secondaries produced by photoionization in the thermosphere or auroral precipitation. The general formulas for current collection (volt-ampere curves) by planar, cylindrical, and spherical Langmuir probes in isotropic and anisotropic non-maxwellian plasmas are examined. Examples are given of how one may identify and remove the non-maxwellian components in the Langmuir probe current to permit the ionospheric parameters to be determined. Theoretical volt-ampere curves presented for typical examples of non-maxwellian distributions include: two-temperature plasmas and a thermal plasma with an energetic electron beam. If the non-ionospheric electrons are Maxwellian at a temperature distinct from that of the ionosphere electrons, the volt-ampere curves can be fitted directly to obtain the temperatures and densities of both electron components without resorting to differenting the current. For an arbitrary isotropic distribution, the current for retarded particles is shown to be identical for the three geometries. For anisotropic distributions, the three probe geometries are not equally suited for measuring the ionospheric electron temperature and density or for determining the distribution function in the presence of non-maxwellian back-round electrons.

Hoegy, Walter R.↗

A New Method for Reduction of Photomultiplier Signal-Induced Noise

For lidar measurements of ozone, photomultiplier tube (PMT) detector signal-induced noise represents a fundamental problem that complicates the extraction of information from lidar data. A new method is developed to significantly reduce signal-induced noise in lidar receiver PMT detectors. The electron optics of the lidar photomultiplier detector is modified to filter the source of signal-induced noise. A mesh electrode external to the PMT is utilized to control photoemission and disorient electron trajectories from the photocathode to the first dynode. Experiments were taken both with simulated and actual lidar return signals at Langley Research Center. Results show at least 40 percent more accurate ozone number density values with a mesh voltage of 60 V applied than with no voltage applied.

Koble, Andrea↗

Low Temperature Ohmic Contact Formation of Ni2Si on N-type 4H-SiC and 6H-SiC

Nickel Silicide (Ni2Si) is investigated as possible ohmic contact to heavily nitrogen-doped N-type 4H-SiC and 6H-SiC. Nickel Silicide was deposited via electron gun with various thicknesses on both Si and C faces of the SiC substrates. The Ni2Si contacts were formed at room temperature as well as at elevated temperatures (400 to 1000 K). Contact resistivities and I-V characteristics were measured at temperatures between 100 and 700 C. To investigate the electric properties, I-V characteristics were studied and the Transmission Line Method (TLM) was used to determine the specific contact resistance for the samples at each annealing temperature. Both Rutherford Backscattering Spectroscopy (RBS) and Auger Electron Spectroscopy (AES) were used for depth profiling of the Ni2Si, Si, and C. X-ray Photoemission Spectroscopy (XPS) was used to study the chemical structure of the Ni2Si/SiC interface.

Elsamadicy, A. M.↗

Glennan Microsystems Initiative

During the 2001-2002 award period, we performed research on Pt/Ti/bare 6H-SiC and bare 4H-SiC interfaces in order to identify their electronic properties as a function of surface preparation. The overall aim of this work is to optimize the electronic properties of metal contacts to SiC as well as the active SiC material itself as a function of surface preparation and subsequent processing. Initially, this work has involved identifying bare surface, subsurface, and metal induced gap states at the metal-SiC contact and correlating energies and densities of deep levels with Schottky barrier heights. We used low energy electron-excited nanoluminescence (LEEN) spectroscopy, X-ray photoemission spectroscopy (XPS), and Secondary Ion Mass Spectrometry (SIMS) in order to correlate electronic states and energy bands with chemical composition, bonding, and crystal structure. A major development has been the discovery of polytype transformations that occur in 4H-SiC under standard microelectronic process conditions used to fabricate SiC devices. Our results are consistent with the stacking fault generation, defect formation, and consequent degradation of SiC recently reported for state-of-the-art ABB commercial diodes under localized electrical stress. Our results highlight the importance of -optimizing process conditions and material properties - anneal times, temperatures and doping to control such structural changes within epitaxial SiC layers. Thus far, we have established threshold times and temperatures beyond which 4H-SiC exhibits 3C-SiC transformation bands for a subset of dopant concentrations and process conditions. On the basis of this temperature time behavior, we have been able to establish an activation energy of approximately 2.5 eV for polytype transformation and dislocation motion. Work continues to establish the fundamental mechanisms underlying the polytype changes and its dependence on material parameters.

Brillson, Leonard J.↗

Laboratory Measurements of Optical Properties of Micron Size Individual Dust Grains

A laboratory program is being developed at NASA Marshall Space Flight Center for experimental determination of the optical and physical properties individual dust grains in simulated astrophysical environments. The experimental setup is based on an electrodynamic balance that permits levitation of single 0.1 - 10 micron radii dust grains in a cavity evacuated to pressures of approx. 10(exp -6) torr. The experimental apparatus is equipped with observational ports for measurements in the UV, visible, and infrared spectral regions. A cryogenic facility for cooling the particles to temperature of approx. 10-50K is being installed. The current and the planned measurements include: dust charging processes, photoelectric emissions and yields with UV irradiation, radiation pressure measurements, infrared absorption and scattering properties, and condensation processes, involving the analogs of cosmic dust grains. Selected results based on photoemissions, radiation pressure, and other laboratory measurements will be presented.

Abbas, M. M.↗

Aqueous nitrite ion determination by selective reduction and gas phase nitric oxide chemiluminescence

An improved method of flow injection analysis for aqueous nitrite ion exploits the sensitivity and selectivity of the nitric oxide (NO) chemilluminescence detector. Trace analysis of nitrite ion in a small sample (5-160 microL) is accomplished by conversion of nitrite ion to NO by aqueous iodide in acid. The resulting NO is transported to the gas phase through a semipermeable membrane and subsequently detected by monitoring the photoemission of the reaction between NO and ozone (O3). Chemiluminescence detection is selective for measurement of NO, and, since the detection occurs in the gas-phase, neither sample coloration nor turbidity interfere. The detection limit for a 100-microL sample is 0.04 ppb of nitrite ion. The precision at the 10 ppb level is 2% relative standard deviation, and 60-180 samples can be analyzed per hour. Samples of human saliva and food extracts were analyzed; the results from a standard colorimetric measurement are compared with those from the new chemiluminescence method in order to further validate the latter method. A high degree of selectivity is obtained due to the three discriminating steps in the process: (1) the nitrite ion to NO conversion conditions are virtually specific for nitrite ion, (2) only volatile products of the conversion will be swept to the gas phase (avoiding turbidity or color in spectrophotometric methods), and (3) the NO chemiluminescence detector selectively detects the emission from the NO + O3 reaction. The method is free of interferences, offers detection limits of low parts per billion of nitrite ion, and allows the analysis of up to 180 microL-sized samples per hour, with little sample preparation and no chromatographic separation. Much smaller samples can be analyzed by this method than in previously reported batch analysis methods, which typically require 5 mL or more of sample and often need chromatographic separations as well.

NASA Discipline Environmental Health↗

A Dynamic Fountain Model for Lunar Dust

During the Apollo era of exploration it was discovered that sunlight was scattered at the terminators giving rise to horizon glow and streamers above the lunar surface. This was observed from the dark side of the Moon during sunset and sunrise by both surface landers and astronauts in orbit. These observations were quite unexpected, as the Moon was thought to be a pristine environment with a negligible atmosphere or exosphere. Subsequent investigations have shown that the sunlight was most likely scattered by electrostatically charged dust grains originating from the surface. It has since been demonstrated that this dust population could have serious implications for astronomical observations from the lunar surface. The lunar surface is electrostatically charged by the Moon s large-scale interaction with the local plasma environment and the photoemission of electrons due to solar ultra-violet (UV) light and X-rays. The like-charged surface and dust grains then act to repel each other, such that under certain conditions the dust grains are lifted above the surface. We present a dynamic fountain model which can explain how sub-micron dust is able to reach altitudes of up to approximately 100 km above the lunar surface. Previous static dust levitation models are most applicable to the heavier micron-sized grains in close proximity proximity to the surface, but they cannot explain the presence of extremely light grains at high altitudes. If we relax the static constraint applied to previous models, and instead assume that the grains are in constant motion (under the action of dynamic forces), a new picture emerges for the behavior of sub-micron lunar dust.

Stubbs, T. J.↗