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At least 199 records · Page 11

Analysis of defect structure in silicon. Silicon sheet growth development for the large area silicon sheet task of the Low-Cost Solar array Project

One hundred ninety-three silicon sheet samples, approximately 880 square centimeters, were analyzed for twin boundary density, dislocation pit density, and grain boundary length. One hundred fifteen of these samples were manufactured by a heat exchanger method, thirty-eight by edge defined film fed growth, twenty-three by the silicon on ceramics process, and ten by the dendritic web process. Seven solar cells were also step-etched to determine the internal defect distribution on these samples. Procedures were developed or the quantitative characterization of structural defects such as dislocation pits, precipitates, twin & grain boundaries using a QTM 720 quantitative image analyzing system interfaced with a PDP 11/03 mini computer. Characterization of the grain boundary length per unit area for polycrystalline samples was done by using the intercept method on an Olympus HBM Microscope.

Natesh, R.↗

Acoustic microscopy of silicon carbide materials

It is shown that scanning laser acoustic microscopy (SLAM) is able to detect such fracture-controlling flaws in dense silicon carbide materials as surface voids, whose diameter-by-depth size is a minimum of 75 by 17 microns in reaction-bonded SiC and 68 by 25 microns in alpha-SiC. Surface conditions such as pitting, which have been found to limit the discernibility of drilled holes, become important when pit and drilled hole sizes become comparable.

Khandelwal, P. K.↗

On the cause of the flat spot phenomenon observed in silicon solar cells at low temperatures and low intensities

The results of an effort to determine the mechanisms involved in the flat spot (FS) effect are given. It is suggested that the FS effect is due to a resistive metal-semiconductor-like (MSL) interface in parallel with the cell PN junction. Regions responsible for the FS effect lie under the front surface metallization in these cells, where the PN junction has been destroyed and replaced with a metal silicide-semiconductor interface. Such structural changes, which appear to be due to the thermally activated dissolution of the silicon, have been induced in cells as a result of isochronal heat treatments at temperatures between 450 C and 560 C. It has been found that a 650 A layer of Ta2O5 evaporated over the metallization is sufficient to prevent the underlying silicon from pitting during the subsequent heat treatment, although pitting at the metal silicon ambient interface could still be observed.

Weizer, V. G.↗

Oceanic corrosion test of bare and zinc-protected aluminum alloys for seawater heat exchangers

Bare 3004 tubes, 7072 Alclad 3004 tubes, and bare and zinc diffusion treated 3003 extrusions from a brazed aluminum, plate-fin heat exchanger were exposed to 1.8 m/sec flowing seawater aboard an open ocean test facility moored 3.4 km off the southeast coast of Puerto Rico. After six months exposure, the average corrosion rates for most varieties of aluminum materials converged to a low value of 0.015 mm/yr (0.6 mils/yr). Pitting did not occur in bare 3003 and 3004 samples during the six month test. Pitting did occur to varying degrees in the Alclad and zinc diffusion treated material, but did not penetrate to the base metal. Biofouling countermeasures (intermittent chlorination and brushing) did not affect the corrosion rates to any significant extent. Intermittent chlorination at a level of 0.5 ppm for 28 minutes daily controlled microbiofouling of the samples but did not prevent the development of a macrobiofouling community in areas of the plumbing with low flow.

Sasscer, D. S.↗

Corrosion of simulated bearing components of three bearing steels in the presence of chloride-contaminated lubricant

Corrosion tests were run with AISI 52100, AISI M-50 and AMS 5794 under conditions that simulate the crevice corrosion found in aircraft ball and roller bearings rejected at overhaul for corrosion. Test specimens were fabricated that simulated the contacts of balls or rollers and the raceways. Corrosion cells were assembled in the presence of a lubricant contaminated with water and chloride ions. The cell was then thermally cycled between 339 K (150 F) and 276 K (37 F). The corrosion observed after 14 cycles was that of crevice and pitting corrosion typically found in aircraft bearings. AMS 5749 showed a very slight amount of corrosion. No appreciable differences were noted between AISI 52100 and AISI M-50, but both showed much greater corrosion than AMS 5749. The corrosion pits observed in AISI M-50 appeared to be fewer in number but generally deeper and larger than in AISI 52100.

Parker, R. J.↗

Cavitation Erosion of Copper, Brass, Aluminum and Titanium Alloys in Mineral Oil

The variations of the mean depth of penetration, the mean depth rate of penetration, MDRP, the pit diameter 2a and depth h due to cavitation attack on Al 6061-T6, Cu, brass of composition Cu-35Zn-3Pb and Ti-5A1-2.5Sn are presented. The experiments are conducted in a mineral oil of viscosity 110 CS using a magnetostrictive oscillator of 20 kHz frequency. Based on MDRP on the materials, it is found that Ti-5Al-2.5Sn exhibits cavitation erosion resistance which is two orders of magnitude higher than the other three materials. The values of h/a are the largest for copper and decreased with brass, titanium, and aluminum. Scanning electron microscope studies show that extensive slip and cross slip occurred on the surface prior to pitting and erosion. Twinning is also observed on copper and brass.

Rao, B. C. S.↗

Craters and basins on Ganymede and Callisto - Morphological indicators of crustal evolution

The morphologic characteristics of craters and palimpsests on Ganymede and Callisto are surveyed, and the crustal properties of these satellites and the evolution of the properties are studied. The morphology of bowl-shaped craters, smooth-floored craters, craters without central peaks, craters with central pits, chain craters on Callisto, the Gilgamesh and Western Equatorial Basins on Ganymede, crater palimpsests and penepalimpsests, multiring structures on Callisto, and the Galileo Regio rimmed furrow system on Ganymede are described individually. The crustal evolution is addressed by examining the development of the Galileo Regio system, the distribution of crater retention ages, the record of ray clusters, the thermal history of the lithosphere of Ganymede, and the origin of the central pits. It is suggested that as the lithosphere of each satellite cooled and thickened, crater retentivity spread as a wave from the polar regions and the antapex toward the apex; at any given location, progressively larger craters were retained with the passage of time.

Passey, Q. R.↗

Stress-corrosion behavior of aluminum-lithium alloys in aqueous environments

The stress corrosion susceptibility of two powder metallurgy (P/M) alloys, Al-Li-Cu and Al-Li-Cu-Mg two mechanically attrited (M/A) alloys, Al-Li-Cu and Al-Li-Mg; and two wrought, ingot alloys, X-2020 and AA7475, are compared. Time-dependent fracture in an aqueous sodium chloride environment under alternate immersion condition was found to vary significantly between alloys. The stress corrosion behavior of the two powder metallurgy processed alloys was studied in detail under conditions of crack initiation, static crack growth, and fatigue crack growth. A variety of stress corrosion tests were performed including smooth surface, time-to-failure tests; potentiostatic tests on smooth surfaces exposed to constant applied strain rates; and fracture mechanics-type tests under static and cyclic loads. Both alloys show surface pitting and subsequent intergranular corrosion. Pitting is more severe in the magnesium-bearing alloy and is associated with stringer particles strung along the extrusion direction as a result of P/M processing.

Pizzo, P. P.↗

Relationships and tectonics of the Jg-7 quadrangle of Ganymede

Craters within the Ganymede Jg-7 quadrangle were divided into seven mappable units. The units represent: (1) irregular or elongate craters, (2) craters with dark ejecta, (3) palimpsests, (4) secondary craters, (5) and craters of young, mature, and old age. Symbols used for crater floors include: (1) flat floors, (2) floors with pits, (3) floora with a central dome or peak, (4) and floors with a central dome and pit. Grooved terrains were divided into five mappable units. Three units of light grooved material represent small, medium, and large grooves, which are arbitrarily divided. The other two units of grooved terrain represent dark grooved materials, and reticulate grooves. Two units of ungrooved dark terrain and two units of ungrooved light terrain were defined. In Galileo Regio, two units were defined repesenting large furrowed grooves, and smaller grooves which are orthogonal to the furrowed grooves.

Glotfelty, M. F.↗

Planetary Analogs in Antarctica: Mars

A study of chemical and physical weathering rates in Antarctic ice-free areas, sponsored by the National Science Foundation's Antarctic Research Program, permitted observations to be made that also have application other planetary surfaces. Four observations relevent to Mars are addressed: the effects of freezing on sand dune morphology (Mars polar dune field), chemical/physical weathering to create pits (Mars pitted rocks, Viking Lander 1 and 2 sites), armored surfaces (Mars lander sites), and mass movements (movement of Martian debris).

Malin, M. C.↗

Mechanism of strength degradation for hot corrosion of alpha-SiC

Sintered alpha SiC was corroded by thin films of Na2SO4 and Na2CO3 molten salts at 1000%. This hot corrosion attack reduced room temperature strengths by as much as 50%. Strength degradation was porportional to the degree and uniformity of corrosion pitting attack as controlled by the chemistry of the molten salt. Extensive fractography identified corrosion pits as the most prevalent source of failure. A fracture mechanics treatment of the strength/pit depth relationship produced an average K sub IC equal to 2.6 MPa sub m 1/2, which is consistent with published values.

Smialek, J. L.↗

Global map of eolian features on Mars

A variety of common eolian features on Mars have been identified from a survey of Mariner 9 and Viking orbiter images, and their regional and global distributions and orientations are discussed. Ten features have been mapped including: light and dark streaks, splotches, barchan and transverse dunes, crescentric and anomalous dunes, yardangs, wind grooves, and deflation pits. The north polar region shows a complex wind regime. Dunes and other ephemeral features reveal winds from the northwest and northeast. In the middle and low northern latitudes, northeasterly winds are the most effective winds. Southeast winds are the effective winds in most southern latitudes. Erosional features in bedrock indicate long-term and perhaps ancient wind trends, whereas depositional features may record relatively more recent winds. Deflation pits in the mantled terrain may contain the best record of both ancient and present-day winds.

Ward, A. W.↗

Stress-corrosion behavior of aluminum-lithium alloys in aqueous salt environments

The stress corrosion susceptibility of two powder metallurgy (P/M) alloys, Al-Li-Cu and Al-Li-Cu-Mg; two mechanically attrited (M/A) alloys, Al-Li-Cu and Al-Li-Mg; and two wrought, ingot alloys, X-2020 and AA7475, are compared. Time-dependent fracture in an aqueous sodium chloride environment under alternate immersion condition was found to vary significantly between alloys. The stress corrosion behavior of the two powder metallurgy processed alloys was studied in detail under conditions of crack initiation, static crack growth, and fatigue crack growth. A variety of stress corrosion tests were performed including smooth surface, time-to-failure tests; potentiostatic tests on smooth surfaces exposed to constant applied strain rates; and fracture mechanics-type tests under static and cyclic loads. Both alloys show surface pitting and subsequent intergranular corrosion. Pitting is more severe in the magnesium-bearing alloy and is associated with stringer particles strung along the extrusion direction as a result of P/M processing.

Pizzo, P. P.↗

A potentiodynamic study of aluminum-lithium alloys in an aqueous sodium chloride environment

The characteristics of the potentiodynamic curves for Al-Li alloys in 3.5 percent NaCl aqueous solution are explained and the electrochemical parameters of the potentiodynamic technique are correlated to observed pitting and intergranular cracking behavior. It is shown that the oxygen content of the sodium chloride electrolyte plays an important role in the electrochemical behavior of Al-Li alloys. The potentiodynamic behavior of the alloys is found to be insensitive to variation in compositional content and heat treatment, both of which affect the stress-corrosion behavior. Stringer oxide particle attack and random pitting are observed. It is shown that alternate-immersion exposure prior to potentiodynamic polarization may offer a means of assessing susceptibility to stress-corrosion cracking.

Tsao, C.-H. T.↗

Hot corrosion of sintered alpha-SiC at 1000 C

The hot corrosion of sintered alpha-SiC by thin films of Na2SO4 and Na2CO3 was studied at 1000 C in controlled gas atmospheres. Under all conditions, corrosion led to 10 to 20 times the amount of SiO2 formed in pure oxidation after a 48-h exposure. In addition, small amounts of sodium silicate formed. Melts of Na2SO4/SO3 caused uniform pitting of the SiC substrate; Na2CO3/CO2 melts caused localized pitting and grain-boundary attack. In all cases, the protective SiO2 layer dissolved to form silicate, leading to corrosion. In the sulfate case, free carbon in the SiC promotes this process. In all cases the presence of liquid films is responsible for rapid transport rates and the subsequent rapid reaction.

Jacobson, N. S.↗

Automated scanning of plastic nuclear track detectors using the Minnesota star scanner

The problems found in an attempt to adapt an automated scanner of astronomical plates, the Minnesota Automated Dual Plate Scanner (APS), to locating and measuring the etch pits produced by ionizing particles in plastic nuclear track detectors (CR-39) are described. A visual study of these pits was made to determine the errors introduced in determining positions and shapes. Measurements made under a low power microscope were compared with those from the APS.

Fink, P. J.↗

The interplanetary micrometeoroid flux and lunar primary and secondary microcraters

It is proposed that considerable care is required to properly interpret either spacecraft in situ data or lunar crater data as well as near-earth data; in the case of the former, complications may arise which may be attributed to secondary lunar ejecta impacts, in the latter, they may result from impacting earth-orbiting debris. Experimental evidence suggests that most impact pits on lunar rocks with pit diameters smaller than 7 micrometers have been generated by lunar secondary ejecta impacts and not by primary meteoroid impacts. It is also found that lunar crater production rates are more accurate when deduced from meteoroid space experiments and not from solar flare track ages. It is concluded that in so far as all of the above qualifications are taken into account, a self-consistent meteoroid flux versus mass distribution is obtained.

Zook, H. A.↗

Locating subsurface gravel with thermal imagery

A method was discussed for using 6 band thermal imagery to locate subsurface gravel deposits in vegetated areas. Geologic history is reviewed to select potential areas of study. An overflight was made using a thermal scanner. The data were processed with a computerized system to delineate areas showing a quartz signature radiated by a gravel deposit. The method was developed during a search for gravel on National Forest land in Louisiana. Processed data from thermal imagery was compared with known gravel deposits and exploratory drill hole logs. A high correlation was noted for a wide range of deposits, from commercial pits to trace deposits only a foot thick. Overburden at these sites varied from zero to sixty feet, near the maximum annual penetration by the thermal wave. It was concluded that the method can be used to locate buried gravel deposits and that more time and effort are needed to verify the usefulness for developing gravel pits adjacent to proposed construction sites.

Scholen, Douglas E.↗