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At least 199 records · Page 11

Modeling Flow and Mass Transfer within Hollow Fiber Packaging for Gas Separation

Hollow fiber membrane modules are used for gas purification by their selective permeation properties. Intensification of the process to minimize the retentate loss and gas pressure involves optimization at various scales. In this work, we outline a numerical investigation of the gas separation performance at the scale of fiber bundles and its impact on module performance. Flow channeling and anisotropy govern the mass-transfer coefficient in axial and cross-flow configurations. These effects are quantified in terms of a permeability tensor or an anisotropy ratio and the effective mass-transfer coefficient or the Sherwood number. The results show a trade-off between purification and recovery. While smaller fibers offer a large specific surface area to enable high purification, it comes at a huge penalty on the separation performance due to reduced penetration within bundles. Optimum performance indicators are emphasized.

Fibers↗

Tailoring polyvinyl alcohol-sodium alginate (PVA-SA) hydrogel beads by controlling crosslinking pH and time

Abstract Hydrogel-encapsulated catalysts are an attractive tool for low-cost intensification of (bio)-processes. Polyvinyl alcohol-sodium alginate hydrogels crosslinked with boric acid and post-cured with sulfate (PVA-SA-BS) have been applied in bioproduction and water treatment processes, but the low pH required for crosslinking may negatively affect biocatalyst functionality. Here, we investigate how crosslinking pH (3, 4, and 5) and time (1, 2, and 8 h) affect the physicochemical, elastic, and process properties of PVA-SA-BS beads. Overall, bead properties were most affected by crosslinking pH. Beads produced at pH 3 and 4 were smaller and contained larger internal cavities, while optical coherence tomography suggested polymer cross-linking density was higher. Optical coherence elastography revealed PVA-SA-BS beads produced at pH 3 and 4 were stiffer than pH 5 beads. Dextran Blue release showed that pH 3-produced beads enabled higher diffusion rates and were more porous. Last, over a 28-day incubation, pH 3 and 4 beads lost more microspheres (as cell proxies) than beads produced at pH 5, while the latter released more polymer material. Overall, this study provides a path forward to tailor PVA-SA-BS hydrogel bead properties towards a broad range of applications, such as chemical, enzymatic, and microbially catalyzed (bio)-processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advancing Desalination and Treatment of Non-Traditional Source Water: The First 3.5 Years of the National Alliance for Water Innovation (NAWI)

The National Alliance for Water Innovation (NAWI) is the U.S. DOE's 5-year, $110M research Hub focused on desalination and water reuse. NAWI is organized into three Topic Areas in which projects are managed and coordinated: Materials and Manufacturing R&D (M&M), Process Innovation and Intensification R&D (PI&I), and Data, Modeling, and Analysis (DMA). In its first 3.5 years, NAWI has established the largest integrated DOE Innovation Hub (108 Research Consortium member organizations, 440 Alliance member organizations) anchored around its APRIME vision for lowering the cost and energy of desalination and water reuse. NAWI has selected 74 research projects to date, and several have reported major advances in desalination research and technology in leading scientific publications.

desalination↗

Cobalt promotion of the InO x –TiO 2 heterojunction for dual photothermal reduction of CO 2

A series of cobalt-promoted indium–titanium composite oxides was synthesized using a microemulsion method. Their functional properties were investigated for the photothermal reduction of carbon dioxide. In this series, the indium content varied between 2.5 and 20%, while the cobalt percentage was kept constant at 4% throughout the series. In all cases, carbon monoxide formation occurred selectively through the reverse water gas shift reaction. The sample with 2.5% In maximized the synergistic use of the two energy sources, while the sample with 10% In showed the highest catalytic activity under both thermal and dual photo-thermo conditions. A physicochemical characterization was performed for all samples. The use of microscopy and X-ray absorption spectroscopy demonstrated that sub-nanometric indium entities, in combination with atomically dispersed cobalt oxide entities, achieved a balance between high thermal activity and significant synergy between light and heat in a catalytic process. The system with 10% indium is thus able to improve the thermal catalytic process through the use of light, providing an intensification procedure for the classic process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Genesis of Twin Tropical Cyclones as Revealed by a Global Mesoscale Model: The Role of Mixed Rossby Gravity Waves

In this study, it is proposed that twin tropical cyclones (TCs), Kesiny and 01A, in May 2002 formed in association with the scale interactions of three gyres that appeared as a convectively coupled mixed Rossby gravity (ccMRG) wave during an active phase of the Madden-Julian Oscillation (MJO). This is shown by analyzing observational data, including NCEP reanalysis data and METEOSAT 7 IR satellite imagery, and performing numerical simulations using a global mesoscale model. A 10-day control run is initialized at 0000 UTC 1 May 2002 with grid-scale condensation but no sub-grid cumulus parameterizations. The ccMRG wave was identified as encompassing two developing and one non-developing gyres, the first two of which intensified and evolved into the twin TCs. The control run is able to reproduce the evolution of the ccMRG wave and thus the formation of the twin TCs about two and five days in advance as well as their subsequent intensity evolution and movement within an 8-10 day period. Five additional 10-day sensitivity experiments with different model configurations are conducted to help understand the interaction of the three gyres, leading to the formation of the TCs. These experiments suggest the improved lead time in the control run may be attributed to the realistic simulation of the ccMRG wave with the following processes: (1) wave deepening (intensification) associated with a reduction in wavelength and/or the intensification of individual gyres, (2) poleward movement of gyres that may be associated with boundary layer processes, (3) realistic simulation of moist processes at regional scales in association with each of the gyres, and (4) the vertical phasing of low- and mid-level cyclonic circulations associated with a specific gyre.

forecast↗

A diagnosis of two cyclones in the South Pacific Convergence Zone

The evolution of three cyclones which originated in the South Pacific Convergence Zone, two of which propagated into middle latitudes, are traced. The analysis is based on IR imagery from GOES-W, island meteorological station data, and estimates of heat and moisture budget residuals. A European Center for Medium-range Weather Forecasting Level III-b analysis was used to model the cyclones. The northward-propagating storms exhibited strong vertical shear of the horizontal wind, implicating baroclinic effects in the development of the storms. The processes which enhanced storm intensification are discussed. Attention is given to the spatial and temporal behavior of dynamic atmospheric components which were significant to baroclinicity and latent heat release, which the analysis demonstrates were coupled processes.

Vincent, D. G.↗

Analysis of cross-hemispheric influences on the monsoon trough and tropical cyclone genesis during FGGE and diurnal subsidence differences

For a number of years our project has been studying the cross-equatorial (winter to summer hemisphere) processs that can lead to the day-to-day alterations in the strength of the monsoon trough. These processes are also related to the genesis and intensification of tropical storms. The cross-hemispheric processes that occurred during the FGGE year are currently being studied with the use of the ECMWF analysis. How the winter hemisphere can affect low level cold surge penetration across the equator following cold front passage, and how upper tropospheric anticyclones of the winter hemisphere can produce an intensification of a tropical cyclone of the opposite hemisphere is described. ECMWF analysis of the 00Z versus 12Z diurnal difference in the clear region (10 deg diameter) subsidence occurring in the subtropical Pacific Ocean during FGGE is presented. The general reliability of the FGGE ECMWF analysis with regard to the specification of the large scale structure of tropical cyclones is shown.

Gray, W. M.↗

On the origin of steep edges and filaments in vorticity and potential vorticity fields

High-resolution numerical calculations are shown which capture the fundamental process responsible for the intensification of vorticity gradients in an isolated vortex subject to externally imposed distrubances. Imposition of almost any weak strain or shear field in stripping away the relatively weak vorticity at the edge of the vortex and leaves it with gradients four to six orders of magnitude greater than in the initial state. Calculations displaying such enormous gradients have never been reported previously, because of the artificial eddy diffusivities that always limit such gradients in standard numerical models. The present calculations, which have no such limitations, have been made possible by the development of a novel and robust new numerical technique for vortex dynamics called contour surgery.

Dritschel, D. G.↗

Combustion and structure formation in SHS processes under microgravity conditions: SHS plans for microgravity experiments

This paper outlines ISMAN suggestions for the joint NASA-RSA project 'Combustion and Structure formation in SHS Processes under Microgravity Conditions'. The basic ideas of this work naturally follow from our almost 30-year experience in the field of SHS. As a matter of fact, we have already obtained some results in the following two directions closely related to the microgravity problem. One is the studies on SHS processes in the field of centrifugal forces. These studies aimed at the intensification of gravity-sensitive SHS processes in multicomponent highly caloric systems forming melts at high overloads (up to 2000 g). In other words, these studies had the objectives that are inverse to those in the microgravity studies. The second group of results directly relates to the microgravity problem and the project under consideration. These experiments played the important role in establishing links between SHS and microgravity.

Merzhanov, A. G.↗

Tropical Cyclones Feed More Heavy Rain in a Warmer Climate

The possible linkage of tropical cyclones (TC) to global warming is a hotly debated scientific topic, with immense societal impacts. Most of the debate has been focused on the issue of uncertainty in the use of non-research quality data for long-term trend analyses, especially with regard to TC intensity provided by TC forecasting centers. On the other hand, it is well known that TCs are associated with heavy rain during the processes of genesis and intensification, and that there are growing evidences that rainfall characteristics (not total rainfall) are most likely to be affected by global warming. Yet, satellite rainfall data have not been exploited in any recent studies of linkage between tropical cyclones (TC) and global warming. This is mostly due to the large uncertainties associated with detection of long-term trend in satellite rainfall estimates over the ocean. This problem, as we demonstrate in this paper, can be alleviated by examining rainfall distribution, rather than rainfall total. This paper is the first to use research-quality, satellite-derived rainfall from TRMM and GPCP over the tropical oceans to estimate shift in rainfall distribution during the TC season, and its relationships with TCs, and sea surface temperature (SST) in the two major ocean basins, the northern Atlantic and the northern Pacific for 1979-2005. From the rainfall distribution, we derive the TC contributions to rainfall in various extreme rainfall categories as a function to time. Our results show a definitive trend indicating that TCs are contributing increasingly to heavier rain events, i.e., intense TC's are more frequent in the last 27 years. The TC contribution to top 5% heavy rain has nearly doubled in the last two decades in the North Atlantic, and has increased by about 10% in the North Pacific. The different rate of increase in TC contribution to heavy rain may be related to the different rates of different rate of expansion of the warm pool (SST >2S0 C) area in the two oceans.

Lau, K.-M.↗

Continuous multimodal technologies in industrial microbiology: potential for achieving high process performance and agility

The field of industrial microbiology has great potential to tackle the most pressing challenges facing society, but today, this entails much more than classical fermentation technology followed by product upgrading. Methods are needed to confer unit-operation-level functionality and whole-system-level robustness, as well as flexibility. As examples of this concept, we focus here on methodologies often deployed at industrial scale as discrete processes—such as biological, chemical, and electrochemical unit operations—that are also capable of substantial complementarity when combined sequentially and operated continuously. A key and relatively new type of conversion step is made possible by catalyst immobilization methods at both the enzymatic and cellular level. Cases drawn from electro-fermentation for acetoin production and syngas-mediated microbial electrosynthesis of ethanol exemplify the synergy of combined operational approaches. Because modular processes can be treated as a series of reactor elements, considerable flexibility is possible. As discussed, however, not all processes are amenable to this intensification.

09 BIOMASS FUELS↗

Workflows Community Summit 2022: A Roadmap Revolution

Scientific workflows have become integral tools in broad scientific computing use cases. Science discovery is increasingly dependent on workflows to orchestrate large and complex scientific experiments that range from the execution of a cloud-based data preprocessing pipeline to multi-facility instrument-to-edge-to-HPC computational workflows. Given the changing landscape of scientific computing (often referred to as a computing continuum) and the evolving needs of emerging scientific applications, it is paramount that the development of novel scientific workflows and system functionalities seek to increase the efficiency, resilience, and pervasiveness of existing systems and applications. Specifically, the proliferation of machine learning/artificial intelligence (ML/AI) workflows, need for processing large-scale datasets produced by instruments at the edge, intensification of near real-time data processing, support for long-term experiment campaigns, and emergence of quantum computing as an adjunct to HPC, have significantly changed the functional and operational requirements of workflow systems. Workflow systems now need to, for example, support data streams from the edge-to-cloud-to-HPC, enable the management of many small-sized files, allow data reduction while ensuring high accuracy, orchestrate distributed services (workflows, instruments, data movement, provenance, publication, etc.) across computing and user facilities, among others. Further, to accelerate science, it is also necessary that these systems implement specifications/standards and APIs for seamless (horizontal and vertical) integration between systems and applications, as well as enable the publication of workflows and their associated products according to the FAIR principles.

97 MATHEMATICS AND COMPUTING↗

The multiple nesting of mesoscale, submesoscale, and nonhydrostatic microscale numerical models for a case of mesocyclogenesis and severe storm development

A fundamental approach involving the integration of two different numerical models over several different spatial mesh lengths is considered. Model I is a hydrostatic, incompressible, and adiabatic primitive (Newtonian) equation set with no boundary layer forcing, i.e., surface heat or moisture flux or external frictional stresses. Typically this model is initialized from conventional radiosonde data and run for a 12-15 hour forecast period over a 40 km horizontal mesh. If phase I of the tornado developmental processes develops, the data is 'frozen' in space and time, interpolated to a 20 km mesh, and integrated for a shorter time period (3 hours) with a shorter time step. Model II is a nonhydrostatic compressible 18-level complement of model I. If model II indicates the development of the intensification of phase V dynamical processes, the data is frozen and interpolated to finer mesh lengths until the tornadic circulation system is approximated

Kaplan, M. L.↗

10 MWE CDCL Large Pilot Plant – pre-FEED Study

Coal Direct Chemical Looping (CDCL) is an advanced oxy-combustion technology that has the potential to substantially reduce the energy penalty and the cost of electricity (COE) for coal-fired power generation with CO₂ capture. The Babcock & Wilcox Company (B&W) and The Ohio State University (OSU) have been collaborating on the development of an iron oxide oxygen-carrier based chemical looping technology for clean power generation with inherent carbon capture. In this process, coal is dried and pulverized prior to being transported into a moving-bed reducer. In the reducer, coal reacts with the oxygen-carrier particles, forming combustion byproducts, predominantly CO₂ and H₂O, while reducing the iron oxide oxidation state from Fe₂O₃ to a mixture of FeO and Fe. The reduced state particles are then transported to a combustor reactor and re-oxidized with air. Following the oxidation, the oxygen-carrier particles are regenerated, and a large amount of heat is released for steam production. The produced steam is sent to a turbine for electricity generation. Meanwhile, the CO₂–rich stream leaving the reducer is cooled, cleaned, and compressed for subsequent pipeline transportation and sequestration. By combining air separation and fuel conversion into a single system, the CDCL technology enables the intensification of oxy-combustion processes by eliminating the energy and cost intensive cryogenic air separation unit and thereby results in higher overall plant efficiencies and lower COE’s. The use of a moving-bed reducer results in high conversions of volatile hydrocarbons and high CO₂ purity, which reduces the cost of downstream CO₂ purification for sequestration or utilization. The Babcock & Wilcox Company in collaboration with The Ohio State University, Johnson & Matthey, The Electric Power Research Institute, and Dover Light & Power completed a Preliminary Front-End Engineering and Design (Pre-FEED) study of a 10 MWe coal-direct chemical looping (CDCL) pilot plant. The planned system is a modular 10 MWe CDCL large pilot facility consisting in 4 modules of 2.5 MWe each, working in parallel and to be hosted within the current structure at the City of Dover’s Municipal Power Plant. The CDCL system can achieve auto-thermal operation and includes a sub-critical steam cycle for power generation. The pilot system was designed to demonstrate full commercial operation at a reduced scale. The coal distribution per plan area is a representative slice of larger commercial arrangements. The system includes a CO₂ recycle system, but it does not include a compression system. The large pilot includes all the environmental control equipment and oxygen carrier and ash handling systems. As part of the project, the Team performed laboratory testing and carried out multiple pilot test campaigns to obtain design and performance information at the 250 kWth CDCL pilot facility at the Babcock & Wilcox Company’s Research Center. The Team demonstrated sustained operations at designed coal inputs, high coal conversion, high CO₂ purity, heat generation on the combustor, low carbon carryover between reactors and low particle attrition. Emissions generated in the reducer reactor were identified as SO₂ and NO x . The commercial manufacturing cost of oxygen carrier particle was evaluated by JM. A particle manufacturing report was generated and submitted to the DOE. Based on the results from the pilot tests and the pre-FEED design efforts, a techno-economic analysis was performed. The study shows that the CDCL process is a promising carbon-friendly technology capable of producing electricity with high efficiency. The estimated COE of the supercritical CDCL plant is $83.3 / MWh, which meets DOE’s target of less than 30% increase in COE when compared to a supercritical PC plant without CO₂ capture. This is the lowest among the existing carbon capture technologies (post-combustion and oxy-combustion) for fossil fuel power plant. CDCL is evaluated to be the most promising technology for carbon capture from the economic aspect.

01 COAL, LIGNITE, AND PEAT↗

Electrically-Active Convection and Tropical Cyclogenesis in the Atlantic and East Pacific

It has been hypothesized that deep, intense convective-scale "hot" towers may aid the process of tropical cyclogenesis and intensification through dynamic and thermodynamic feedbacks on the larger meso-to-synoptic scale circulation. In this study, we make use of NCEP Reanalysis data and Tropical Rainfall Measurement Mission (TRMM) lightning imaging sensor (LIS), precipitation radar (PR), and microwave imager (TMI) data to investigate the role that widespread and/or intense lightning-producing convection (i.e., "electrically-hot towers") present in African easterly waves (AEWs) may play in tropical cyclogenesis over the Atlantic, Caribbean, and East Pacific regions. NCEP Reanalysis 700 hPa meridional winds for the months of June to November for the years 2001-2009 were analyzed for the domain of 5degN-20degN and 130degW-20degE in order to partition individual AEWs into northerly, southerly, trough, and ridge phases. Subsequently, information from National Hurricane Center (NHC) storm reports was used to divide the waves into developing and non-developing waves and to further divide the developing waves into those waves that spawned storms that only developed to tropical storm strength and those that spawned storms that reached hurricane strength. The developing waves were also divided by the region in which they developed. To help determine the gross nature of the smaller convective scale, composites were created of all developing and non-developing waves as a function of AEW wave phase over the full analysis domain and over various smaller longitude bands by compositing TRMM PR, TMI, LIS, and IR brightness temperature data extracted from the NASA global-merged IR brightness temperature dataset. Finally, similar composites were created using various NCEP variables to assess the nature of the larger scale environment and circulation. Results suggest a clear distinction between developing and non-developing waves as developing waves near their region of development in terms of the intensity of convection (indicated by lightning flash rate), coverage of cold cloudiness (indicated by the percentage of a 2.5deg by 2.5deg box covered by IR brightness temperatures less than 210 K), and large-scale variables, such as midlevel moisture and upper-level upward motion. For example, waves that developed in the East Pacific longitude band (i.e., 130degW-95degW) were observed in that band to have a flash rate of 56.4 flashes/day, a coverage by brightness temperatures less than 210 K equal to 2.2%, a 700-hPa specific humidity anomaly of 0.4 g/kg, and a 300-hPa omega value of -0.04 Pascals/s in the trough phase compared to the non-developing wave trough values of 22.1 flashes/day, a coverage by brightness temperatures less than 210 K equal to 0.9%, a 700-hPa specific humidity anomaly of -0.3 g/kg, and a 300-hPa omega value of -0.01 Pascals/s.

Leppert, Kenneth D., II↗

Lightning Observations and Tropical Cyclogenesis in the Atlantic and East Pacific

It has been hypothesized that deep, intense convective-scale "hot" towers may aid the process of tropical cyclogenesis and intensification through dynamic and thermodynamic feedbacks on the larger meso-to-synoptic scale circulation. In this study, we make use of NCEP Reanalysis data and Tropical Rainfall Measurement Mission (TRMM) lightning imaging sensor (LIS), precipitation radar (PR), and microwave imager (TMI) data to investigate the role that widespread and/or intense lightning-producing convection (i.e., "electrically-hot towers") present in African easterly waves (AEWs) may play in tropical cyclogenesis over the Atlantic, Caribbean, and East Pacific regions. NCEP Reanalysis 700 hPa meridional winds for the months of June to November for the years 2001-2009 were analyzed for the domain of 5degN-20degN and 130degW-20degE in order to partition individual AEWs into northerly, southerly, trough, and ridge phases. Subsequently, information from National Hurricane Center (NHC) storm reports was used to divide the waves into developing and non-developing waves. In addition, information from the NHC reports was used to further divide the developing waves into those waves that spawned storms that only developed to tropical storm strength and those that spawned storms that reached hurricane strength. The developing waves were also divided by the region in which they developed. To assess the evolution of convection associated with the AEWs as they propagated across our analysis domain, the full 130degW-20degE domain was divided into five longitude bands, and waves were analyzed for each band. To help determine the gross nature of the smaller convective scale, composites were created of all developing and non-developing waves as a function of AEW wave phase over the full analysis domain and each longitude band by compositing TRMM PR, TMI, LIS, and IR brightness temperature data extracted from the NASA global-merged infrared brightness temperature dataset. Finally, similar composites were created using various NCEP variables to assess the nature of the larger scale environment and circulation.

Leppert, Kenneth D., II↗

Electrically-Active Convection and Tropical Cyclogenesis in the Atlantic and East Pacific

It has been hypothesized that deep, intense convective-scale hot towers may aid the process of tropical cyclogenesis and intensification through dynamic and thermodynamic feedbacks on the larger meso-to-synoptic scale circulation. In this study, we make use of NCEP Reanalysis data and Tropical Rainfall Measurement Mission (TRMM) lightning imaging sensor (LIS), precipitation radar (PR), and microwave imager (TMI) data to investigate the role that widespread and/or intense lightning-producing convection (i.e., electrically-hot towers) present in African easterly waves (AEWs) may play in tropical cyclogenesis over the Atlantic, Caribbean, and East Pacific regions. NCEP Reanalysis 700 hPa meridional winds for the months of June to November for the years 2001-2009 were analyzed for the domain of 5 deg. N-20 deg. N and 130 deg. W-20 deg. E in order to partition individual AEWs into northerly, southerly, trough, and ridge phases. Subsequently, information from National Hurricane Center (NHC) storm reports was used to divide the waves into developing and non-developing waves. In addition, information from the NHC reports was used to further divide the developing waves into those waves that spawned storms that only developed to tropical storm strength and those that spawned storms that reached hurricane strength. The developing waves were also divided by the region in which they developed. To assess the evolution of convection associated with the AEWs as they propagated across our analysis domain, the full 130 deg. W-20 deg. E domain was divided into five longitude bands, and waves were analyzed for each band. To help determine the gross nature of the smaller convective scale, composites were created of all developing and non-developing waves as a function of AEW wave phase over the full analysis domain and each longitude band by compositing TRMM PR, TMI, LIS, and IR brightness temperature data extracted from the NASA global-merged infrared brightness temperature dataset. Finally, similar composites were created using various NCEP variables to assess the nature of the larger scale environment and circulation. Results suggest a clear distinction between developing and non-developing waves as developing waves near their region of development in terms of the intensity of convection (indicated by lightning flash rate), coverage of cold cloudiness (indicated by the percentage of a 2.5 deg. by 2.5 deg. box covered by IR brightness temperatures less than 240 deg. K and 210 deg. K), and large-scale variables, such as midlevel moisture and upper-level upward motion. For example, waves that developed in the East Pacific longitude band (i.e., 130 deg. W 95 deg. W) were observed in that band to have a flash rate of 56.4 flashes per day, a coverage by brightness temperatures less than 240 deg. K equal to 15.9%, a coverage by brightness temperatures less than 210 deg. K equal to 2.2%, a 700-hPa specific humidity anomaly of 0.4 g per kilogram, and a 300-hPa omega value of -0.04 Pascals per second in the trough phase compared to the non-developing wave trough values of 22.1 flashes per day, a coverage by brightness temperatures less than 240 deg. K equal to 8.1%, a coverage by brightness temperatures less than 210 deg. K equal to 0.9%, a 700-hPa specific humidity anomaly of -0.3 g per kilogram, and a 300-hPa omega value of -0.01 Pascals per second. Further analysis is being conducted to determine if the aforementioned behavior is observed for developing waves farther from their region of development and to determine any significant differences between waves that spawned storms that reached tropical storm strength and those that spawned storms that reached hurricane strength.

Leppert, Kenneth D., II↗