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At least 199 records · Page 11

Procedures to validate/correct calibration error in solar backscattered ultraviolet instruments

The Nimbus 7 SBUV measures the same latitude ozone at widely different sun angle conditions at the ascent and descent part of the orbit during the summer solstice. This situation is used in a particular procedure (Ascent/Descent) to obtain the relative channel-to-channel calibration error for channels 273 nm to 306 nm. These estimated errors are combined with results from the Pair Justification procedure to correct the sun-view diffuser drift in calibration from November 1978 to February 1987 for the shorter wavelength channels that measure upper stratospheric ozone. Some preliminary re-calirated Nimbus 7 SBUV data in 1989 is compared with the first set of SBUV measurements flown on the Space Shuttle.

Taylor, Steven L.↗

Top-of-the-Atmosphere Shortwave Flux Estimation from Satellite Observations: An Empirical Neural Network Approach Applied with Data from the A-Train Constellation

Estimates of top-of-the-atmosphere (TOA) radiative flux are essential for the understanding of Earth's energy budget and climate system. Clouds, aerosols, water vapor, and ozone (O3) are among the most important atmospheric agents impacting the Earth's shortwave (SW) radiation budget. There are several sensors in orbit that provide independent information related to these parameters. Having coincident information from these sensors is important for understanding their potential contributions. The A-train constellation of satellites provides a unique opportunity to analyze data from several of these sensors. In this paper, retrievals of cloud/aerosol parameters and total column ozone (TCO) from the Aura Ozone Monitoring Instrument (OMI) have been collocated with the Aqua Clouds and Earth's Radiant Energy System (CERES) estimates of total reflected TOA outgoing SW flux (SWF). We use these data to develop a variety of neural networks that estimate TOA SWF globally over ocean and land using only OMI data and other ancillary information as inputs and CERES TOA SWF as the output for training purposes. OMI-estimated TOA SWF from the trained neural networks reproduces independent CERES data with high fidelity. The global mean daily TOA SWF calculated from OMI is consistently within 1% of CERES throughout the year 2007. Application of our neural network method to other sensors that provide similar retrieved parameters, both past and future, can produce similar estimates TOA SWF. For example, the well-calibrated Total Ozone Mapping Spectrometer (TOMS) series could provide estimates of TOA SWF dating back to late 1978.

CERES data with high fidelity↗

Getting Astrophysical Information from LISA Data

Gravitational wave signals from a large number of astrophysical sources will be present in the LISA data. Information about as many sources as possible must be estimated from time series of strain measurements. Several types of signals are expected to be present: simple periodic signals from relatively stable binary systems, chirped signals from coalescing binary systems, complex waveforms from highly relativistic binary systems, stochastic backgrounds from galactic and extragalactic binary systems and possibly stochastic backgrounds from the early Universe. The orbital motion of the LISA antenna will modulate the phase and amplitude of all these signals, except the isotropic backgrounds and thereby give information on the directions of sources. Here we describe a candidate process for disentangling the gravitational wave signals and estimating the relevant astrophysical parameters from one year of LISA data. Nearly all of the sources will be identified by searching with templates based on source parameters and directions.

Stebbins, R. T.↗

Populating the brown dwarf and stellar boundary: Five stars with transiting companions near the hydrogen-burning mass limit

We report the discovery of five transiting companions near the hydrogen-burning mass limit in close orbits around main sequence stars originally identified by the Transiting Exoplanet Survey Satellite (TESS) as TESS objects of interest (TOIs): TOI-148, TOI-587, TOI-681, TOI-746, and TOI-1213. Using TESS and ground-based photometry as well as radial velocities from the CORALIE, CHIRON, TRES, and FEROS spectrographs, we found the companions have orbital periods between 4.8 and 27.2 days, masses between 77 and 98 MJup , and radii between 0.81 and 1.66 RJup . These targets have masses near the uncertain lower limit of hydrogen core fusion (~73-96 MJup ), which separates brown dwarfs and low-mass stars. We constrained young ages for TOI-587 (0.2 ± 0.1 Gyr) and TOI-681 (0.17 ± 0.03 Gyr) and found them to have relatively larger radii compared to other transiting companions of a similar mass. Conversely we estimated older ages for TOI-148 and TOI-746 and found them to have relatively smaller companion radii. With an effective temperature of 9800 ± 200 K, TOI-587 is the hottest known main-sequence star to host a transiting brown dwarf or very low-mass star. We found evidence of spin-orbit synchronization for TOI-148 and TOI-746 as well as tidal circularization for TOI-148. These companions add to the population of brown dwarfs and very low-mass stars with well measured parameters ideal to test formation models of these rare objects, the origin of the brown dwarf desert, and the distinction between brown dwarfs and hydrogen-burning main sequence stars.

Nolan Grieves↗

Relative Navigation for Spacecraft in Nearly Rectilinear Halo Orbits

Lunar orbit missions are of great interest to the space exploration community. This paper is focused on the research, development, and feasibility of spacecraft docking within Nearly Rectilinear Halo Orbits (NRHO). In this work, a proximity estimation algorithm is developed using the Circular Restricted Three Body Problem (CR3BP) equations of motion, which can be used to estimate the proximity between a follower spacecraft and leader spacecraft while docking in NRHOs around the Moon. Promising initial simulation results are provided and discussed. This proximity estimation algorithm is shown to to provide useful tracking estimates which can be fed to the spacecraft control system and will help ensure mission success.

Luke J. Miller↗

Flight Mechanics/Estimation Theory Symposium 1995

This conference publication includes 41 papers and abstracts presented at the Flight Mechanics/ Estimation Theory Symposium on May 16-18, 1995. Sponsored by the Flight Dynamics Division of Goddard Space Flight Center, this symposium featured technical papers on a wide range of issues related to orbit-attitude prediction, determination, and control; attitude sensor calibration; attitude determination error analysis; attitude dynamics; and orbit decay and maneuver strategy. Government, industry, and the academic community participated in the preparation and presentation of these papers.

Hartman, Kathy R.↗

Flight Mechanics/Estimation Theory Symposium 1996

This conference publication includes 34 papers and abstracts presented at the Flight Mechanics/ Estimation Theory Symposium on May 14-16, 1996. Sponsored by the Flight Dynamics Division of Goddard Space Flight Center, this symposium featured technical papers on a wide range of issues related to orbit-attitude prediction, determination, and control; attitude sensor calibration; attitude determination error analysis; attitude dynamics; and orbit decay and maneuver strategy. Government, industry, and the academic community participated in the preparation and presentation of these papers.

Greatorex, Scott↗

Bond Dissociation Energies of the Tungsten Fluorides and Their Singly-Charged Ions: A Density Functional Survey

The dissociation of WF6 and the related singly-charged cations and anions into the lower fluorides and fluorine atoms has been investigated theoretically using density functional theory (B3LYP) and relativistic effective core potentials, with estimates of spin-orbit effects included using a simple model. The inclusion of spin-orbit is essential for a correct description of the thermochemistry. The total atomization energy of the neutral and anionic WF6 is reproduced to within 25 kcal/mol, but comparison of individual bond dissociation energies with available experimental data shows discrepancies of up to 10 kcal/mol. The results are nevertheless useful to help resolve discrepancies in experimental data and provide estimates of missing data.

Dyall, Kenneth G.↗

Integration Of Launch Vehicle Simulation/Analysis Tools And Lunar Cargo Lander Design

Part 2, which will be discussed in this report, will discuss the development of a Lunar Cargo Lander (unmanned launch vehicle) that will transport usable payload from Trans- Lunar Injection to the moon. The Delta IV-Heavy was originally used to transport the Lunar Cargo Lander to TLI, but other launch vehicles have been studied. In order to uncover how much payload is possible to land on the moon, research was needed in order to design the sub-systems of the spacecraft. The report will discuss and compare the use of a hypergolic and cryogenic system for its main propulsion system. The guidance, navigation, control, telecommunications, thermal, propulsion, structure, mechanisms, landing gear, command, data handling, and electrical power sub-systems were designed by scaling off other flown orbiters and moon landers. Once all data was collected, an excel spreadsheet was created to accurately calculate the usable payload that will land on the moon along with detailed mass and volume estimating relations. As designed, The Lunar Cargo Lander can plant 5,400 lbm of usable payload on the moon using a hypergolic system and 7,400 lbm of usable payload on the moon using a cryogenic system.

DeJean, George Brian↗

An Alternative Inter-Satellite Calibration of the UMD HIRS OLR Retrievals

The observational record for determining Outgoing Longwave Radiation (OLR) from satellites remains largely fragmented with gaps over the past three decades among the Earth Radiation Budget Experiment (ERBE), Earth Radiation Budget Satellite (ERBS) and Clouds and the Earth s Radiant Energy System (CERES) measurements. Multi-band OLR retrievals are thus an important supplement to the broadband measurements. The most semi-continuous set of OLR retrievals comes from the University of Maryland (UMD) algorithm that uses four HIRS (High Resolution Infrared Sounder) channels on the NOAA polar orbiting satellites to estimate OLR. but residual biases due principally to diurnal drift of the polar orbiter platforms remain an issue. Here we show how an alternative recalibration of the UMD retrievals taking advantage of the relative diurnal drift rates between "morning" and "evening" satellite platforms removes much of the remaining uncertainty due to changes in equator crossing times.

Robertson, Franklin R.↗

Hourly Carbon Fluxes Estimation Using the GOES Advanced Baseline Imager (ABI) Data Over the Conterminous USA

Tremendous efforts by Fluxnet scientists over the past few decades have made thousands of site-years of carbon flux observations available for advancing our understanding of carbon cycling in terrestrial ecosystems. One of key Fluxnet measurements is net ecosystem exchange (NEE) as it is directly related to carbon budget of terrestrial ecosystems. However, carbon flux estimation studies using satellite remote sensing have focused mainly on daily Gross Primary Production (GPP). The satellite based carbon flux estimation used the polar orbiting satellite sensors (e.g., Moderate Resolution Imaging Spectroradiometer (MODIS)), which allow us to observe target regions only once during the day. Because daily NEE is close to zero value, the carbon flux models using the polar orbiting satellite data have not been well used for NEE estimation. The new generation of geostationary satellite sensors (e.g., GOES Advanced Baesline Imager (ABI) and Himawari Advanced Himawari Imager (AHI)) provide frequent observations, often less than every 10 minutes. Here, we use GOES ABI data to estimate hourly NEE over the conterminous USA. We used the Terrestrial Observation Prediction System (TOPS) model for estimating hourly NEE. TOPS is a diagnostic ecosystem process model that simulates the fluxes of carbon and water through vegetation in response to climate variability. For the climate input, we developed hourly climate data using the same algorithm with NASA Earth Exchange Gridded Daily Meteorology (NEX-GDM) datasets based on machine learning techniques. The hourly climate data includes precipitation, maximum temperature, minimum temperature, dew point temperature, and, in particular, solar radiation that is directly derived from the Geostationary observations. The spatial patterns of ecosystem parameters used in TOPS are optimized using satellite Solar Induced Fluorescence (SIF) data. The high frequency GPP estimations from geostationary satellite sensors make it comparable to the instantaneous SIF data than daily GPP. We also used Fluxnet data for optimization of model parameters and the validation of the output. The derived data addresses the diurnal dynamics of carbon cycling at large scales and should help in reducing the uncertainties in carbon budget studies.

Geostationary satellite↗

Guidance, Navigation, and Control for Laser-Based Non-Cooperative Target Detumbling

Orbital debris is a well known and growing problem presenting risks to the future of spaceflight. Many pieces of debris are defunct satellites or rocket upper stages. These large objects could generate an exponentially growing cloud of debris should they be involved in a collision, i.e., Kessler Syndrome. Future orbital debris remediation efforts often propose perturbing the orbit of these large targets to mitigate risk. These plans often involve non-cooperative rendezvous. In the absence of active control, the targets are expected to be tumbling which makes rendezvous a dangerous prospect. In this work we describe a guidance, navigation, and control system for a contactless non-cooperative target detumbling methodology which will significantly increase the safety of non-cooperative rendezvous. An onboard laser generates thrust on the target by ablating its surface material. This thrust is used to control target attitude. Our guidance, navigation, and control system is able to estimate relative pose, target the laser, and maintain formation flight during the detumbling process. The system is validated with Monte Carlo simulation in a variety of scenarios.

Guidance↗

Estimating Electron Temperature and Density Using Van Allen Probe Data: Typical Behavior of Energetic Electrons in the Inner Magnetosphere

Abstract The Earth's inner magnetosphere contains multiple electron populations influenced by different factors. The cold electrons of the plasmasphere, warm plasma that contributes to the ring current, and the relativistic plasma of the radiation belts often seem to behave independently. Using omni‐directional flux and energy measurements from the HOPE and Magnetic Electron Ion Spectrometer instruments aboard the Van Allen Probes, we provide a detailed density and temperature description of the inner magnetosphere, offering a comprehensive statistical analysis of the entire Van Allen Probe era. While number density and temperature data at geosynchronous orbit are available, this study focuses on the warm plasma in the inner magnetosphere . Values of density and temperature are extracted by fitting energy and phase space density to obtain the distribution function. The fitted distributions are related to the zeroth and second moments to estimate the number density and temperature. Analysis has indicated that a two Maxwellian fit is sufficient over a wide range of and that there are two independent plasma populations. The more energetic population has a median number density of approximately and a temperature of around 130 keV, with a temperature peak observed between L * = 4 and L * = 4.5. This population is relatively uniform in magnetic local time (MLT). In contrast, the less energetic warm electron population has a median number density of about and a temperature of 7.4 keV. Strong statistical trends in density and temperature across both L * and MLT are presented, along with potential sources driving these variations.

58 GEOSCIENCES↗

Top-of-the-Atmosphere Shortwave Flux Estimation from UV Observations: An Empirical Approach

Measurements of top of the atmosphere (TOA) radiation are essential to the understanding of Earth's climate. Clouds, aerosols, and ozone (0,) are among the most important agents impacting the Earth's short-wave (SW) radiation budget. There are several sensors in orbit that provide independent information related to the Earth's SW radiation budget. Having coincident information from these sensors is important for understanding their potential contributions. The A-train constellation of satellites provides a unique opportunity to analyze near-simultaneous data from several of these sensors. They include the Ozone Monitoring Instrument (OMI), on the NASA Aura satellite, that makes TOA hyper-spectral measurements from ultraviolet (UV) to visible wavelengths, and Clouds and the Earth's Radiant Energy System (CERES) instrument, on the NASA Aqua satellite, that makes broadband measurements in both the long- and short-wave. OMI measurements have been successfully utilized to derive the information on trace gases (e.g., 0 1, NO" and SO,), clouds, and absorbing aerosols. TOA SW fluxes are estimated using a combination of data from CERES and the Aqua MODerate-resolution Imaging Spectroradiometer (MODIS). In this paper, OMI retrievals of cloud/aerosol parameters and 0 1 have been collocated with CERES TOA SW flux retrievals. We use this collocated data to develop a neural network that estimates TOA shortwave flux globally over ocean using data from OMI and meteorological analyses. This input data include the effective cloud fraction, cloud optical centroid pressure (OCP), total-column 0" and sun-satellite viewing geometry from OMI as well as wind speed and water vapor from the Goddard Earth Observing System 5 Modern Era Retrospective-analysis for Research and Applications (GEOS-5 MERRA) along with a climatology of chlorophyll content. We train the neural network using a subset of CERES retrievals of TOA SW flux as the target output (truth) and withhold a different subset of the CERES data to be used for validation.

Gupta, P.↗

X-Ray Detection and Processing Models for Spacecraft Navigation and Timing

The current primary method of deepspace navigation is the NASA Deep Space Network (DSN). High-performance navigation is achieved using Delta Differential One-Way Range techniques that utilize simultaneous observations from multiple DSN sites, and incorporate observations of quasars near the line-of-sight to a spacecraft in order to improve the range and angle measurement accuracies. Over the past four decades, x-ray astronomers have identified a number of xray pulsars with pulsed emissions having stabilities comparable to atomic clocks. The x-ray pulsar-based navigation and time determination (XNAV) system uses phase measurements from these sources to establish autonomously the position of the detector, and thus the spacecraft, relative to a known reference frame, much as the Global Positioning System (GPS) uses phase measurements from radio signals from several satellites to establish the position of the user relative to an Earth-centered fixed frame of reference. While a GPS receiver uses an antenna to detect the radio signals, XNAV uses a detector array to capture the individual xray photons from the x-ray pulsars. The navigation solution relies on detailed xray source models, signal processing, navigation and timing algorithms, and analytical tools that form the basis of an autonomous XNAV system. Through previous XNAV development efforts, some techniques have been established to utilize a pulsar pulse time-of-arrival (TOA) measurement to correct a position estimate. One well-studied approach, based upon Kalman filter methods, optimally adjusts a dynamic orbit propagation solution based upon the offset in measured and predicted pulse TOA. In this delta position estimator scheme, previously estimated values of spacecraft position and velocity are utilized from an onboard orbit propagator. Using these estimated values, the detected arrival times at the spacecraft of pulses from a pulsar are compared to the predicted arrival times defined by the pulsar s pulse timing model. A discrepancy provides an estimate of the spacecraft position offset, since an error in position will relate to the measured time offset of a pulse along the line of sight to the pulsar. XNAV researchers have been developing additional enhanced approaches to process the photon TOAs to arrive at an estimate of spacecraft position, including those using maximum-likelihood estimation, digital phase locked loops, and "single photon processing" schemes that utilize all available time data associated with each photon. Using pulsars from separate, non-coplanar locations provides range and range-rate measurements in each pulsar s direction. Combining these different pulsar measurements solves for offsets in position and velocity in three dimensions, and provides accurate overall navigation for deep space vehicles.

Sheikh, Suneel↗

Localization of Ad-Hoc Lunar Constellations in Communication Failure Modes for Distributed Spacecraft Autonomy

As lunar missions increase in complexity inspired by NASA’s Artemis Program, they will require reliable and sufficient capability of the Position, Navigation, and Timing (PNT) system to support their scientific objectives. In addition, NASA's Commercial Lunar Payload Services (CLPS) program initiates the proliferation of public and private exploration partnerships using small satellites from commercial and private organizations, expanding traditionally confined low Earth orbit to be used for missions beyond geosynchronous orbit (Zucherman et al., 2022). Therefore, the Lunar PNT system is also required to provide navigation services compatible with the smaller platforms being sent by the public and private sectors, like CubeSats. However, traditional approaches to deep space missions’ navigation based on ground radio facilities have difficulties in providing sufficient support for the increasing number of users and communication at a distance from the Earth (Kaplev et al., 2022). In particular, the existing Lunar navigation technologies such as weak signal global positioning system (GPS) and deep space network (DSN) are not able to ensure operations of the upcoming small-scale Lunar missions due to their limitations in localization performance as well as capacity aspects. Another way to provide Lunar PNT service is to create a dedicated Lunar global navigation satellite system (GNSS) constellation, like GNSS systems on Earth. Space agencies like NASA, ESA, and JAXA are now developing the lunar communications relay and navigation systems (LCRNS) and Lunar navigation satellite systems (LNSS). In their systems, satellites will be deployed in moon orbits to provide the communication, positioning, navigation, and timing (CPNT) service at the lunar south pole region where the Artemis base camp will be expected (Murata et al., 2022). Meanwhile, common challenges considered in lunar PNT research arise from poor geometry of the terrestrial GNSS satellites when seen from the lunar user, highly perturbed lunar orbits, and limitations in power, size, and cost of the equipment on lunar satellites (Iiyama et al., 2023). It is also not clear if there will be enough Lunar users to support the cost and resources this would require as the Low-cost surface missions may not be able to support the large power, mass, and weight requirements that these navigation solutions entail (Niemoeller et al., 2022). As an alternative, existing Lunar science and exploration assets could be used to create a low-cost, autonomous, ad-hoc, and on-demand mission-centric Lunar PNT swarm capable of providing PNT services to these low-cost lunar missions (Hagenau et al., 2021). Introducing the non-dedicated and ad-hoc Lunar navigation constellation gives a way to provide PNT services on-demand. The non-dedicated swarm assets of Lunar constellations are designed to localize themselves with minimal interaction with Earth by adding cooperative autonomous localization to lunar missions, freeing up valuable bandwidth and ground segment resources. An autonomous localization of Lunar constellations is based on the concept of the decentralized PNT system with a distributed extended Kalman filter (DEKF) approach to state estimation for minimal onboard operating costs. In the distributed data processing algorithm, computation is broken down and assigned to each satellite, resulting in a considerably decreased computational amount while maintaining the accuracy of the orbit ephemeris and clock offsets as the result of centralized data processing (Wen et al., 2019). The DEKF requires spacecraft to perform two-way ranging operations with each other to communicate simultaneously, leveraging neighbor two-way intersatellite link (ISL) measurements such as pseudoranges to, and relative velocities between, visible satellites as sensor values (Frank et al., 2021). The Lunar autonomous PNT simulation (LAPS) demonstrated the feasibility of orbital asset localization among ad-hoc Lunar small-sat constellations based on the DEKF in Hagenau et al. (2021) and evaluated the matching algorithm proposed by Frank et al. (2021) in scheduling position estimation updates. In previous papers, all assets and measurements are assumed to be always available without consideration of the impact of intermittent and permanent communication failure. This study presents localization performance with increasing levels of network degradation for swarm assets and users to demonstrate the robustness of the decentralized Lunar PNT service in more realistic scenarios. Main issues arising from communication failure include spacecraft permanent or transient loss, antenna failures, message delays, etc. We tested four possible reasons for network degradation for 7 days in 21 satellites frozen with an altitude of 5500 km, evenly spaced around 3 circular, 40 inclination orbital planes where each spacecraft has two directional antennas. As anchor nodes with an independent estimate of their position are required in the DEKF approach, two ground nodes in each pole and one node in the gateway were implemented in the simulation. First, the most probable failure scenario involves the loss of a single spacecraft due to solar interference and technical malfunctions of the assets. Losing the availability of a single spacecraft means losing the two-way ISL measurement of the asset in the DEKF update. In order to provide the best possible quality of PNT service with limited time and resources, the distributed Lunar constellations must schedule the communication activities. The scheduler leverages mixed-integer linear programming (MILP) for the coordination and scheduling of the desired “as-needed” localization service (Niemoeller et al., 2022). We assume the scheduler has completely excluded the spacecraft information before the DEKF update in the failure scenario. When a random spacecraft has been turned off at a specific time, the robustness of the autonomous Lunar PNT system is evaluated. The simulation results give an 11.5% degradation in median position accuracy compared to the idealized performance excluding the asset loss. Second, a large number of assets may vanish due to major hardware problems or meteor strikes around the moon. A multiple spacecraft loss can degrade the localization performance very fast by losing the communication ability to do cross-plane measurements and in-plane measurements in a 3-plane constellation. When the matching-based scheduler is aware of ISL availability, we investigate a large number of in-plane and cross-plane asset vanishments both in close proximity and equally spaced throughout the orbital plane. According to the simulations, the loss of in-plane measurements gives 40.2% degradation while cross-plane measurements degrade 50.5% of asset localization performance among available assets. Therefore, it is concluded that cross-plane measurements are more important in improving the position estimation accuracy. Third, spacecraft failure information can be lost due to the internal message delay, resulting in the DEKF update scheduler to solve the matching problem with unavailable assets. The DEKF update cycle is comprised of network setup, communication, and computations where a global broadcast network and a 2-way ISL network setup take 6 minutes in total (Frank et al., 2021). Once the broadcast network successfully transmits and receives information, a random spacecraft may lose its availability right before solving the matching problem. This means the matching solution is no longer optimal, resulting in degradation in the localization performance. A numerical assessment shows the matching-based scheduler with knowing failure holds 11.5% of position accuracy degradation, whereas the scheduler without knowing failure gives 34% degraded localization performance without asset loss. Fourth, a transient loss of a single or multiple spacecraft may occur due to their antenna outages. After losing the two-way ISL availability for a few DEKF update cycles, the availability of spacecraft can easily be recovered as their states have been independently updated using measurements from anchor nodes. It is likely that the longer failure will result in worse localization performance. We have tested the transient failure of a random single asset for 30 min in the simulation, which is losing 3 update cycles in the DEKF system. From the simulation results, the position accuracy has been degraded to 4.84% which is better than the degraded localization performance of 11.5% from the permanent loss scenario among available assets. In conclusion, the autonomous Lunar PNT system based on the DEKF approach shows the ability to maintain resilience and robustness in the possible communication failure scenarios, ensuring that localization accuracy is preserved across various network degradation and outages. Future studies on investigating user localization performance near the South Pole and the broadcast network system will be continued in the following months.

Yeji Kim↗

Ab initio studies of the electronic structure of UF6, UF6/+/, and UF6/-/ using relativistic effective core potentials

The paper presents ab initio calculations performed on the electronic states of UF6, UF6(+), and UF6(-) using a relativistic effective core potential (ECP) for uranium and a nonrelativistic ECP for fluorine. In most of the calculations 56 valence electrons are treated explicitly using a contracted (3s 3p 2d 2f/2s2p) Gaussian basis. It is noted that various ECP's were explored, but all yield an overall charge density of U(+2.4)/F(-0.4)/6. In addition, the bonding in the ground state of UF6 is discussed. SCF and CI calculations on UF6(+) are compared with the experimental photoelectron spectrum and with previous scattered wave calculations. Further, the role of spin-orbit coupling in the states of UF6(+) and UF6(-) is covered. Finally, it is concluded that the calculated electron affinity of UF6 (7.1 eV) is considerably larger than in current experimental estimates, but the relative energies of the states of UF6(-) are in agreement (0.1-0.2 eV) with those of the experiment.

Hay, P. J.↗

An intercomparison of longwave measurements by ERBE radiometers on the NOAA-9 and ERBS satellites

Two instrument modules of each satellite on which the Earth Radiation Budget Experiment (ERBE) is orbiting observe components of the earth radiation budget with three different scales of earth view. An intercomparison of longwave measurements by these instruments provides relative information concerning radiometric performance at satellite altitude, techniques of estimating upwelling exitances, and an end-to-end evaluation of the data processing system. Results indicate that the ERBE radiometers are mildly sensitive to varying thermal loads from the spacecraft and/or the earth-space environment. Radiometric variations at the satellite and methods of data interpretation contribute about equally to the uncertainty of radiant exitances from the earth.

House, Frederick B.↗