A resonance igniter for hydrogen-oxygen combustors
Resonance ignition technique for gaseous oxygen and hydrogen rocket propellants
Conrad, E. W.↗
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Low frequency acoustic studies of single- component fluids in the critical region
Single component fluid behavior in liquid-vapor critical point vicinity, using LF acoustic resonant cavity technique for isochoric measurements
Carome, E. F.↗
Rocket borne ultraviolet spectrometer measurement of OH resonance fluorescence with a diffusive transport model for mesospheric photochemistry
Resonance fluorescence techniques for determining upper atmosphere hydroxyl radical
Anderson, J. G.↗
Study of rectangular-guide-like structures for millimeter wave transmission
Effects of surface roughness on conduction losses at millimeter wavelengths determined by optical techniques and resonator quality factors
Tischer, F. J.↗
Fracture Behavior in Nylon 6 Fibers
Electron paramagnetic resonance (EPR) techniques are used to determine the number of free radicals produced during deformation leading to fracture of nylon 6 fibers. A reaction rate molecular model is proposed to explain some of the deformation and bond rupture behavior leading to fracture. High-strength polymer fibers are assumed to consist of a sandwich structure of disordered and ordered regions along the fiber axis. In the disordered or critical flaw regions, tie chains connecting the ordered or crystalline block regions are assumed to have a statistical distribution in length. These chains are, therefore, subjected to different stresses. The effective length distribution was determined by EPR. The probability of bond rupture was assumed to be controlled by reaction-rate theory with a stress-aided activation energy and behavior of various loadings determined by numerical techniques. The model is successfully correlated with experimental stress, strain, and bond rupture results for creep, constant rate loadings, cyclic stress, stress relaxation and step strain tests at room temperature.
Lloyd, B. A.↗
Comparison of laser methods for the remote detection of atmospheric pollutants.
Three methods of remote air pollution detection - Raman backscattering, resonance backscattering, and resonance absorption - are discussed and compared. Theoretical expressions are derived for the minimum detectable pollutant concentration, and in each case the depth resolution and the problems of interference, pump depletion, and background noise are discussed. A brief discussion of possible laser sources is included, numerical examples of the detectabilities based on present technology are given. The atmospheric transparency limits the useful range to a few kilometers for the Raman and resonance backscattering schemes. F or the resonance absorption technique the useful range can be as great as 50 kilometers.
Kildal, H.↗
CO2 photodissociation and vibrational excitation in the planetary atmospheres
The principal subjects of investigation were the determination of the CO2 photodissociation quantum yields at the wavelengths from 1200 A to 1500 A, and the efficiency of electronic-to-vibrational energy transfer in the systems 0(1D) + CO, N2, CO2 yields 0(3P) + CO N2, CO2 vibrational energies. Measurements on the photodissociation quantum yield of CO2 in the 1200-1500 A region show that it is wavelength dependent, and for the six atomic line sources used, the quantum yield varied from 0.2 to 0.8. The data appear to fit the interpretation of stable CO2 bound states mixed with repulsive or predissociating states, since the low quantum yields coincide with the maximum structure in the CO2 absorption spectrum. The first reliable measurements were made on the efficiency of electronic-to-vibrational energy transfer in the systems 0(1D)-CO and 0(1D)-N2, using a uv resonance fluorescence technique. The 0(1D)-CO2 interaction was investigated by infrared techniques.
Slanger, T. G.↗
Absolute rate parameters for the reaction of ground state atomic oxygen with carbonyl sulfide
The rate parameters for the reaction of O(3P) with carbonyl sulfide, O(3P) + OCS yields CO + SO have been determined directly by monitoring O(3P) using the flash photolysis-resonance fluorescence technique. The value for k sub 1 was measured over a temperature range of 263 - 502 K and the data were fitted to an Arrhenuis expression with good linearity.
Klemm, R. B.↗
Absolute rate parameters for the reaction of ground state atomic oxygen with carbonyl sulfide
The rate parameters for the reaction of O(3P) with carbonyl sulfide, O(3P) + OCS yields CO + SO, have been determined directly by monitoring O(3P) using the flash photolysis-resonance fluorescence technique. The value for reaction rate was measured over a temperature range of 263-502 K and the data were fitted to an Arrhenius expression with good linearity. A comparison of the present results with those from previous studies of this reaction is also presented.
Klemm, R. B.↗
ENDOR and ESR studies of a stable radical in irradiated cytidine
A model is proposed for a stable radical species formed by X-irradiation in a single crystal of cytidine and studied by electron nuclear double resonance (ENDOR) and electron spin resonance (ESR) techniques at room temperature. ENDOR and ESR spectra are analyzed to obtain the principal values of the spectroscopic splitting factor and the spectroscopic and hyperfine splitting tensors. The results show hyperfine coupling of an unpaired electron to one hydrogen nucleus and two slightly different geometric forms of the radical with small differences in hyperfine couplings. It is proposed that this radical is formed in the ribose sugar group with a hydrogen atom in a beta position coupling with respect to a carbon-centered unpaired electron and a spin density of approximately 0.2 on a carbon atom.
Allison, D. L.↗
Relative quantum yield for the production of O-atom and S-atom from the photodissociation of OCS in the vacuum UV
The relative efficiencies for two dissociative channels in the vacuum UV photolysis of carbonyl sulphide have been determined using the flash photolysis-resonance fluorescence technique to measure initial yields of atomic oxygen and atomic sulphur. At wavelengths above 105 nm, the dissociation of OCS to form atomic sulphur exceeded that for the formation of atomic oxygen to such an extent that only an upper limit could be placed on the minor process. In addition, the flash photo-excitation of carbonyl sulphide produced a long-lived spontaneous emission in the UV and vacuum UV that might be due to molecular fluorescence from OCS.
Klemm, R. B.↗
Flight Flutter Testing of the P6M
On the P6M the shake behavior, i.e., the response to random excitation at subcritical speeds of lowly damped airplane modes, is as important as the actual flutter speed. The approach is to first study the problem by means of analyses and wind-tunnel tests. These predictions are compared with flight test data obtained by spectral analysis of tape recordings of the airplane vibration responses to random aerodynamic turbulence. A similar spectrum analysis approach was used in high speed wind-tunnel tests. A resonance excitation technique was developed for low speed wind-tunnel testing, and well defined V-g curves were obtained. The effect of various parameters on both shake and flutter of T-tails with and without dihedral were studied. Preliminary flight tests yielded good correlation; they also yielded interesting information concerning a low frequency transonic snaking mode, and excitation by shed vortices.
Kachadourian, G.↗
The absolute concentration of OH/X 2 Pi/ in the earth's stratosphere
The letter reports two recent in-situ measurements of OH in the stratosphere between altitudes of 29 and 43 km using a resonance fluorescence technique that was previously employed for the measurement of ground-state atomic oxygen. The experimental technique is described in detail along with the photon detector and the absolute-calibration procedure. The results are found to indicate OH concentrations that approach the maximum predicted by current stratospheric photochemical theory.
Anderson, J. G.↗
Absolute rate of the reaction of C l(2P) with methane from 200-500 K
Rate constants for the reaction of atomic chlorine with methane have been measured from 200-500K using the flash photolysis-resonance fluorescence technique. When the results from fourteen equally spaced experimental determinations are plotted in Arrhenius form a definite curvature is noted. The results are compared to previous work and are theoretically discussed.
Whytock, D. A.↗
Absolute rate of the reaction of Cl(p-2) with molecular hydrogen from 200 - 500 K
Rate constants for the reaction of atomic chlorine with hydrogen are measured from 200 - 500 K using the flash photolysis-resonance fluorescence technique. The results are compared with previous work and are discussed with particular reference to the equilibrium constant for the reaction and to relative rate data for chlorine atom reactions. Theoretical calculations, using the BEBO method with tunneling, give excellent agreement with experiment.
Whytock, D. A.↗
The O(3P) and N(4S) density measurement at 225 km by ultraviolet absorption and fluorescence in the Apollo-Soyuz test project
The densities of O(3P) and N(4S) at 225 km were determined during the Apollo Soyuz Test Project by a resonance absorption/fluorescence technique in which OI and NI line radiation produced and collimated on board the Apollo was reflected from the Soyuz back to the Apollo for spectral analysis. The two spacecraft maneuvered so that a range of observation angles of plus or minus 15 deg with respect to the normal to the orbital velocity vector was scanned. The measurements were made at night on two consecutive orbits at spacecraft separations of 150 and 500 m. The resulting relative counting rates as function of observation angle were compared to calculated values to determine the oxygen value. This value agrees with mass spectrometric measurements made under similar conditions. The nitrogen value is in good agreement with other measurements and suggests a smaller diurnal variation than is predicted by present models.
Kaufman, F.↗
Absolute rate constant for the reaction of atomic chlorine with hydrogen peroxide vapor over the temperature range 265-400 K
Rate constants for the reaction of atomic chlorine with hydrogen peroxide were measured from 265-400 K using the flash photolysis-resonance fluorescence technique. Analytical techniques were developed to measure H2O2 under reaction conditions. Due to ambiguity in the interpretation of the analytical results, the data combine to give two equally acceptable representations of the temperature dependence. The results are compared to previous work at 298 K and are theoretically discussed in terms of the mechanism of the reaction. Additional experiments on the H + H2O2 reaction at 298 and 359 K are compared with earlier results from this laboratory and give a slightly revised bimolecular rate constant.
Michael, J. V.↗
Atom-radical reaction systems
A laminar flow through resonance fluorescence technique, which permits the direct measurement of absolute density for most atomic and diatomic constituents in the stratosphere was developed. This system is shown schematically and its use in determining O(3p) and OH densities is described.
Anderson, J. G.↗