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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1970

Solid State Studies of the Radiation Histosy of Lunar Samples

Particle track densities up to greater than 3 x 10(exp 9) per square centimeter have been measured in different samples. Rocks 17, 47, 57, and 58 have VH (Z greater than 22) galactic cosmic ray ages of 11, 14, 28, and 13 x 10(exp 6) years, respectively. Rock 57 has a calculated erosion rate of approximately less than 10(exp -7) centimeter per year. Near-surface track versus depth data in rock 17 can be fit with solar flare particles that have a differential energy spectrum alpha E(exp -s); lunar samples can be used to study the history of solar activity. The uranium in the crystalline rocks occurs principally in small regions less than 10 to approximately equal to 100 micrometers in size. The (low) thermoluminescence of the fines increases with depth in core 10004. With one possible exception, x-ray studies have not shown pronounced radiation damage effects. The total energy release upon heating is small up to 900 C and occurs in three broad regions.

Crozaz, G.↗
NASA NTRS1986

The physical basis for spectral variations in thermal infrared emittance of silicates and application to remote sensing

The use of infrared spectroscopy for the remote characterization of planetary surfaces has received attention due to efforts in the investigation of these bodies from space. In the 8 to 14 micron region, a depression in the emittance spectra of rocks (sometimes called reststrahlen) is related to the fundamental stretching vibrations of Si-O bonds and shifts in the locations of this feature are ascribed to variations in rock composition. Thus, it should be possible to investigate, quantify, and model the relationships of reststrahlen spectral band location through silicate mineralogical composition to rock classification. This concept will be tested first through the use of laboratory-acquired data on the infrared spectra and mineralogy of selected mineral and rock samples. As a suitable classification model is developed, it will be tested through overflights of appropriate rock outcrops using the Thermal Infrared Multispectral Scanner (TIMS).

Walter, Louis S.↗
NASA NTRS2016

Microbial Habitability in Gale Crater: Sample Analysis at Mars (SAM) Instrument Detection of Microbial Essential Carbon and Nitrogen

Chemical analyses of Mars soils and sediments from previous landed missions have demonstrated that Mars surface materials possessed major (e.g., P, K, Ca, Mg, S) and minor (e.g., Fe, Mn, Zn, Ni, Cl) elements essential to support microbial life. However, the detection of microbial essential organic-carbon (C) and nitrate have been more elusive until the Mars Science Laboratory (MSL) rover mission. Nitrate and organic-C in Gale Crater, Mars have been detected by the Sample Analysis at Mars (SAM) instrument onboard the MSL Curiosity rover. Eolian fines and drilled sedimentary rock samples were heated in the SAM oven from approximately 30 to 860 degrees Centigrade where evolved gases (e.g., nitrous oxide (NO) and CO2) were released and analyzed by SAM’s quadrupole mass spectrometer (MS). The temperatures of evolved NO was assigned to nitrate while evolved CO2 was assigned to organic-C and carbonate. The CO2 releases in several samples occurred below 450 degrees Centigrade suggesting organic-C dominated in those samples. As much as 7 micromoles NO3-N per gram and 200 micromoles CO2-C per gram have been detected in the Gale Crater materials. These N and C levels coupled with assumed microbial biomass (9 x 10 (sup -7) micrograms per cell) C (0.5 micrograms C per micrograms cell) and N (0.14 micrograms N per micrograms cell) requirements, suggests that less than 1 percent and less than 10 percent of Gale Crater C and N, respectively, would be required if available, to accommodate biomass requirements of 1 by 10 (sup 5) cells per gram sediment. While nitrogen is the limiting nutrient, the potential exists that sufficient N and organic-C were present to support limited heterotrophic microbial populations that may have existed on ancient Mars.

Sutter, B.↗
NASA NTRS2023

Using the Potassium-Argon Laser Experiment (KArLE) to Date Ancient, Low-K Chondritic Meteorites

Several laboratories have been investigating the feasibility of in situ K-Ar dating for use in future landing planetary missions. One drawback of these laboratory demonstrations is the insufficient analogy of the analyzed analog samples with expected future targets. We present the results obtained using the K-Ar laser experiment (KArLE) on two old and K-poor chondritic samples, Pułtusk and Hvittis, as better lunar analogs. The KArLE instrument uses laser ablation to vaporize rock samples and quantifies K content by laser-induced breakdown spectroscopy (LIBS), Ar by quadrupole mass spectrometry (QMS), and ablated mass by laser profilometry. We performed 64 laser ablations on the chondrites to measure spots with a range of K 2 O and Ar content and used the data to construct isochrons to determine the chondrite formation age. The KArLE isochron ages on Pułtusk and Hvittis are 5059 ± 892 Ma and 4721 ± 793 Ma, respectively, which is within the uncertainty of published reference ages, and interpreted as the age of their formation. The uncertainty (2σ) on the KArLE ages obtained in this study is better than 20% (18% for Pułtusk and 17% for Hvittis). The precision, which compares our obtained ages to the reference ages, is also better than 20% (11% for Pułtusk and 4% for Hvittis). These results are encouraging for understanding the limits of this technique to measure ancient planetary samples and for guiding future improvements to the instrument.

Fanny Cattani↗
NASA NTRS1975

Nuclear chemistry of returned lunar samples: Nuclide analysis by gamma-ray spectrometry

Primordial and cosmogenic radionuclide concentrations are determined nondestructively by gamma-ray spectrometry in soil and rock samples from the returned Apollo 17 sample collection from Taurus-Littrow and Descartes. Geochemical evidence in support of field geology speculation concerning layering of the subfloor basalt flows is demonstrated along with a possible correlation of magmatic fractionation of K/U as a function of depth. The pattern of radionuclide concentrations observed in these samples is distinct due to proton bombardment by the intense solar flares of August 4-9, 1972. Such radionuclide determinations are used in determining lunar sample orientation and characterizing solar flare activity.

Okelley, G. D.↗
DOE OSTI2026

Regularization via f -Divergence: An Application to Multi-Oxide Spectroscopic Analysis

In this paper, we explore the application of convolutional neural networks (CNNs) for predicting the chemical composition of complex geologic samples in a simulated Martian atmospheric environment. Specifically, we aim to characterize oxide weight percentages (wt.%) of rock samples analyzed by remote Laser-Induced Breakdown Spectroscopy (LIBS), framing the problem as a multi-target regression task . Neural networks trained on LIBS spectra are prone to overfitting due to high spectral complexity, limited labeled data, and measurement noise. While regularization is critical for improving generalization, common methods (e.g., ℓ 2 regularization) impose constraints not directly tied to data distribution properties. We propose a novel regularization method based on a specific ƒ-divergence induced by a graph-based estimator, designed to constrain the distributional discrepancy between predictions and targets. This regularizer serves a dual purpose: (a) mitigating overfitting by enforcing a constraint on the distributional difference between predictions and noisy targets, and (b) acting as an auxiliary loss that penalizes large divergences. To enable backpropagation, we develop a differentiable approximation of this particular ƒ-divergence, making the method feasible for neural networks. Experiments on ChemCam and SuperCam LIBS calibration spectra show that mathematical equation-divergence regularization outperforms or matches standard regularization methods (ℓ 1 , ℓ 2 , dropout) and the classical baseline, partial least squares (PLS). Combining ƒ-divergence regularization with standard regularization yields further performance gains, indicating that distributional regularization is useful in this context giving a promising direction for robust model training in planetary science applications. Source code is publicly available at Klein and Li (2025), https://doi.org/10.11578/dc.20250530.7.

58 GEOSCIENCES↗
NASA NTRS1972

Documentation of Apollo 15 samples

A catalog is presented of the documentation of Apollo 15 samples using photographs and verbal descriptions returned from the lunar surface. Almost all of the Apollo 15 samples were correlated with lunar surface photographs, descriptions, and traverse locations. Where possible, the lunar orientations of rock samples were reconstructed in the lunar receiving laboratory, using a collimated light source to reproduce illumination and shadow characteristics of the same samples shown in lunar photographs. In several cases, samples were not recognized in lunar surface photographs, and their approximate locations are known only by association with numbered sample bags used during their collection. Tables, photographs, and maps included in this report are designed to aid in the understanding of the lunar setting of the Apollo 15 samples.

Sutton, R. L.↗
NASA NTRS1988

Valles Marineris, Mars: An optimum science-sample site

The Valles Marineris troughs offer an opportunity to sample rocks that reflect various ages and compositions, giving insight into important processes on Mars. Most of the samples would be located within reasonable proximity and could be easily reached by rovers or balloons. Although landing a spacecraft on the floor of the Valles Marineris may be too dangerous for the first sample-return mission to Mars, the scientific rewards would be so great that such a landing should be considered for later flights.

Lucchitta, B. K.↗
NASA NTRS2024

The Chemistry and Mineralogy (CheMin) X-Ray Diffractometer on the MSL Curiosity Rover: A Decade of Mineralogy From Gale Crater, Mars

For more than a decade, the CheMin X-ray diffraction instrument on the Mars Science Laboratory rover Curiosity has been returning definitive and quantitative mineralogical and mineral-chemistry data from ~3.5-billion-year-old (Ga) sediments in Gale crater, Mars. To date, 40 drilled rock samples and 3 scooped soil samples have been analyzed during the rover’s 30+ km transit. These samples document the mineralogy of over 800 meters of flat-lying fluvial, lacustrine and aeolian sedimentary rocks that comprise the lower strata of the central mound of Gale crater (Aeolis Mons; informally known as Mt. Sharp) and the surrounding plains (Aeolis Palus, informally known as the Bradbury Rise). The principal mineralogy of the sedimentary rocks is basaltic, with evidence of early and late-stage diagenetic overprinting. The rocks in many cases preserve much of their primary mineralogy and sedimentary features, suggesting that they were never strongly heated or deformed. Using aeolian soil composition as a proxy for the composition of the deposited and lithified sediment, it appears that in many cases diagenetic changes observed are principally isochemical. Exceptions to this trend include secondary nodules, calcium sulfate veining, and rare Si-rich alteration halos. A surprising and yet poorly understood observation is that nearly all the ~3.5 Ga sedimentary rocks analyzed to date contain 15-70 wt.% of X-ray amorphous material. Over-all, this >800-meter section of sedimentary rock explored in lower Mt. Sharp documents a perennial shallow lake environment grading upward into alternating lacustrine/fluvial and aeolian environments, many of which would have been habitable to microbial life.

Mars↗
NASA NTRS1975

Magnetochemistry of the Apollo landing sites

A coherent magnetochemical picture of lunar samples is presented which was determined from a synthesis of available magnetic-property data and corresponding chemical and petrographic data for soils and rock samples collected at the Apollo landing sites. The magnetic properties of the samples are correlated with Al/Si ratio as well as with telescope spectral reflectivity curves, and magnetochemical diagrams based on composition-sensitive magnetic parameters describing the Fe metal and Fe(2+) contents are used to classify the samples. It is shown that the relative metal-fraction size distribution and magnetic stability for different rock types and soils of varying Al/Si values are reflected in a plot of the ratio of saturation isothermal remanence to saturation magnetization vs the ratio of remanent coercive force to coercive force. It is concluded that all the Apollo landing sites have distinct telescope curves correlated with petrology, chemistry, Al/Si values, and magnetic properties. The established correlations suggest the possibility of estimating the magnetic properties of the regolith from remote-sensing observations.

Wasilewski, P. J.↗
DOE OSTI2017

The clumped-isotope geochemistry of exhumed marbles from Naxos, Greece

Exhumation and accompanying retrograde metamorphism alter the compositions and textures of metamorphic rocks through deformation, mineral–mineral reactions, water–rock reactions, and diffusion-controlled intra- and inter-mineral atomic mobility. Here, we demonstrate that these processes are recorded in the clumped- and single-isotope (δ 13 C and δ 18 O) compositions of marbles, which can be used to constrain retrograde metamorphic histories. We collected 27 calcite and dolomite marbles along a transect from the rim to the center of the metamorphic core-complex of Naxos (Greece), and analyzed their carbonate single- and clumped-isotope compositions. The majority of Δ 47 values of whole-rock samples are consistent with exhumation- controlled cooling of the metamorphic complex. However, the data also reveal that water–rock interaction, deformation driven recrystallization and thermal shock associated with hydrothermal alteration may considerably impact the overall distribution of Δ 47 values. We analyzed specific carbonate fabrics influenced by deformation and fluid–rock reaction to study how these processes register in the carbonate clumped-isotope system. Δ 47 values of domains drilled from a calcite marble show a bimodal distribution. Low Δ 47 values correspond to an apparent temperature of 260 °C and are common in static fabrics; high Δ 47 values correspond to an apparent temperature of 200 °C and are common in dynamically recrystallized fabrics. We suggest that the low Δ 47 values reflect diffusion-controlled isotopic reordering during cooling, whereas high Δ 47 values reflect isotopic reordering driven by dynamic recrystallization. We further studied the mechanism by which dynamic recrystallization may alter Δ 47 values by controlled heating experiments. Results show no significant difference between laboratory reactions rates in the static and dynamic fabrics, consistent with a mineral-extrinsic mechanism, in which slip along crystal planes was associated with atomic-scale isotopic reordering in the calcite lattice. An intrinsic mechanism (enhanced isotopic reordering rate in deformed minerals) is contraindicated by these experiments. We suggest that Δ 47 values of dynamically recrystallized fabrics that form below the diffusion-controlled blocking-temperature for calcite constrain the temperature of deformation. We find that Δ 47 -based temperatures of static fabrics from Naxos marbles are ~60–80 °C higher than commonly observed in slowly cooled metamorphic rocks, and would suggest cooling rates of ~10 5 °CMyr -1 . A similar thermal history is inferred for dolomite marbles from the core vicinity, which preserve apparent temperatures up to 200 °C higher than a typical blocking temperature (~300 °C). This finding could be explained by a hydrothermal event driving a brief thermal pulse and locally resetting Δ 47 values. Rapid cooling of the core-complex region is consistent with a compilation of published cooling ages and a new apatite U–Th/He age, associating the thermal event with the emplacement of a granodiorite pluton at ~12 Ma.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2014

Nanoscale Compositional Relations in Lunar Rock Patina: Deciphering Sources for Patina Components on an Apollo 17 Station 6 Boulder

Space weathering on the Moon and other airless bodies modifies the surfaces of regolith grains as well as the space-exposed surfaces of larger rocks and boulders. As space weathering witness plates, rocks and boulders are distinguished from regolith grains based on their ability to persist as physically intact substrates over longer time scales before being disaggregated by impact processes. Because lunar surfaces, including exposed rocks, quickly develop an optically thick layer of patina, it is important to understand the compositional relationship between patinas and their underlying rock substrates, particularly to support remote-sensing of rocky lunar terrains. Based on analytical TEM techniques, supported by focused ion beam (FIB) cross-sectioning, we have begun to systematize the multi-layer microstructural complexity of patinas on rock samples with a range of space exposure histories. Our on-going work has particularly focused on lunar rock 76015, both because it has a long (approx. 22 my) exposure history, and because its surface was exposed to patina development approximately 1 m off the regolith surface on a boulder in the Apollo 17 Station 6 boulder field. Potential sources for the 76015 patina therefore include impact-melted and vaporized material derived from the local rock substrate, as well as from the mix of large boulders and regolith in the Station 6 area. While similar, there are differences in the mineralogy and chemistry of the rocks and regolith at Station 6. We were interested to see if these, or other sources, could be distinguished in the average composition, as well as the compositional nanostratigraphy of the 76015 patina. To date we have acquired a total of 9 TEM FIB cross-sections from the 76015 patina, giving us reasonable confidence of being able to arrive at an integrated average for the patina major element composition based on analytical TEM methods.

Christoffersen, R.↗
NASA NTRS2018

Silica Dissolution and Precipitation in Galciated Volcanic Environments and Implications for Mars

The surface of Mars exhibits strong evidence for a widespread and long-lived cryosphere. Observations of the surface have identified phases produced by water-rock interactions, but the contribution of glaciers to the observed alteration mineralogy is unclear. To characterize the chemical alteration expected on an icy early Mars, we collected water and rock samples from terrestrial glaciated volcanics. We related geochemical measurements of meltwater to the mineralogy and chemistry of proglacial rock coatings. In these terrains, water is dominated by dissolved silica relative to other dissolved cations, particularly at mafic sites. Rock coatings associated with glacial striations on mafic boulders include a silica-rich component, indicating that silica precipitation is occurring in the subglacial environment. We propose that glacial alteration of volcanic bedrock is dominated by a combination of high rates of silica dissolution and precipitation of opaline silica. On Mars, cryosphere-driven chemical weathering could be the origin of observed silica-enriched phases.

Rutledge, A. M.↗
DOE OSTI2024

Technical note: Optimizing the in situ cosmogenic 36 Cl extraction and measurement workflow for geologic applications

Abstract. In situ cosmogenic 36Cl analysis by accelerator mass spectrometry (AMS) is routinely employed to date Quaternary surfaces and assess rates of landscape evolution. However, standard laboratory preparation procedures for 36Cl dating require the addition of large amounts of isotopically enriched chlorine spike solution; these solutions are expensive and increasingly difficult to acquire from commercial sources. In addition, the typical workflow for 36Cl dating involves measuring both 35Cl/37Cl and 36Cl/Cl concurrently on the high-energy (post-accelerator) end of the AMS system, but 35Cl/37Cl determinations using this technique can be complicated by isotope fractionation and system memory during measurement. The traditional workflow also does not provide 36Cl extraction laboratories with the data needed to calculate native Cl concentrations in advance of 36Cl/Cl measurements. In light of these concerns, we present an improved workflow for extracting and measuring chlorine in geologic materials. Our initial step is to characterize 35Cl/37Cl on sample aliquots of up to ∼1 g prepared in Ag(Cl, Br) matrices, which greatly reduces the amount of isotopically enriched spike solution required to measure native Cl content in each sample. To avoid potential issues with isotope fractionation through the accelerator, 35Cl/37Cl is measured on the low-energy, pre-accelerator end of the AMS line. Then, for 36Cl/Cl measurements, we extract Cl as AgCl or Ag(Cl, Br) in analytical batches with a consistent total Cl load across all samples; this step is intended to minimize source memory effects during 36Cl/Cl measurements and allows the preparation of AMS standards that are customized to match known Cl contents in the samples. To assess the efficacy of this extraction and measurement workflow, we compare chlorine isotope ratio measurements on seven geologic samples prepared using standard procedures and the updated workflow. Measurements of 35Cl/37Cl and 36Cl/Cl are consistent between the two workflows, and 35Cl/37Cl values measured using our methods have considerably higher precision than those measured following standard protocols. The chemical preparation and measurement workflow presented here (1) reduces the amount of isotopically enriched chlorine spike used per rock sample by up to 95 %; (2) identifies rocks with high native Cl concentrations, which may be lower priority for 36Cl surface exposure dating, at an early stage of analysis; and (3) allows laboratory users to maintain control over the total chlorine content within and across analytical batches. These methods can be incorporated into existing laboratory and AMS protocols for 36Cl analyses and will increase the accessibility of 36Cl dating for geologic applications.

58 GEOSCIENCES↗
NASA NTRS1974

Sulfur abundances and distributions in the valley of Taurus-Littrow

Total sulfur abundances have been determined for 36 Apollo 17 soil, breccia and crystalline rock samples. Sulfur concentrations range from 550 to 1300 micrograms S/g for soil samples, with the orange soil containing the lowest amount of sulfur. Noritic breccias contain between 720 and 950 micrograms S/g, while the anorthositic rocks have sulfur contents of 270 and 368 micrograms S/g. The dunite 72415 contained the lowest sulfur content (44 micrograms S/g) of any Apollo 17 sample studied. Apollo 17 basalts have unusually high sulfur contents (1580-2770 micrograms S/g) as compared to Apollo 12 and 15 basalts and terrestrial basalts. Sulfur abundances for the Apollo 17 basalts are almost identical to those from Apollo 11 basalts. A negative correlation between percent metallic iron and total sulfur for the Apollo 17 and 15 basalts was found and suggests that a portion of the metallic iron in lunar basalts may result from desulfuration of the melt prior to crystallization from the lunar magma.

Gibson, E. K., Jr.↗
NASA NTRS1972

Lunar 'dunite', 'pyroxenite' and 'anorthosite.'

Photomicrographic study of 200 thin sections of Apollo 14 rock samples suggests that these monomineralic aggregates are recrystallized single-mineral grains. It is contended, therefore, that the source rocks are not properly characterized by igneous rock names, being more moderately coarse-grained gabbroic rather than ultramafic rocks.

Wilshire, H. G.↗
NASA NTRS1992

Telerobotic field geologist - Preliminary results of a feasibility study

Results of three laboratory studies conducted to explore the feasibility of developing a telerobot to perform planetary field geology are presented. A total of 72 college students attempted to match each of 15 geologic rock samples viewed either directly or on a TV screen with its matched pair contained in a matrix of 24 rocks which they viewed directly. The first study showed that rocks viewed on TV could be matched at levels well above chance, but significantly less than by direct view. Performance under remote view was improved by adding color and by magnifying the TV image. The second study showed a large decrease in performance when viewing a miniature LCK monitor as compared to a 19-in. CRT monitor of higher resolution. In the third study performance using the 2.9-in. LCK monitor showed only insignificant increases when images were presented in 3D view or when the rock was moved. It is suggested that it is feasible to conduct geologic observations with telerobots, and the critical role that image quality plays in determining performance is demonstrated.

Cole, Robert E.↗
NASA NTRSDate not supplied

Astrobiological Potential of Rocks Acquired By the Perseverance Rover in Jezero Crater, Mars

The scientific community has prioritized the return of Martian rock samples with known geologic context for more than a decade (Beatty et al., 2019). Thus, the main objectives of the Perseverance rover mission on Mars include identifying past habitable environments, collecting rocks that are likely to preserve biosignaturesand using the rover’s instruments to look for potential biosignatures in these rocks (Farley et al., 2020). Here, we present an overview of the bedrock samples collected bythe Perseverance rover in Jezero crater to date and discuss the potential of the sampled materials to address astrobiological questions upon sample return to Earth.

Mars 2020↗